Hydrogen has the potential to produce energy with no emissions, and therefore offers a strategic opportunity for rapid development of renewable energy storage. However, jet flames caused by the leakage of high-pressure hydrogen may cause casualties and damage equipment, so the safety issues associated with hydrogen incidents are a key issue restricting its development. Barrier walls can be an important mitigative action to reduce the hazard of hydrogen jet flames. Previous studies have evaluated the protective effect of different vertical or inclined arrangements of a single barrier wall in the vertical direction. However, in the vertical direction, a single barrier wall is not sufficient to reduce the hazards associated with high-pressure hydrogen jet flames. In this paper, a two-dimensional CFD model of high-pressure hydrogen jet flames are established. A simplified form of the hydrogen real gas equation of state is used to describe the complex behavior of high-pressure hydrogen. This CFD study employs the standard k-ε turbulence model, the eddy dissipation concept (EDC) model, and the discrete ordinate (DO) radiation model. The results display good agreement with the experimentally obtained flame shape and thermal radiation values, which confirms the applicability of the model. Based on this model, the characteristics of high-pressure jet flames are systematically studied under different forms of barrier walls and different pressures of hydrogen storage. Compared with the vertical barrier wall, barrier walls with complex structures can block the flames in front of the wall more effectively. This is proven through a remarkable decline in the vertical flame length and a reduction in the high temperature area. Comparing the five barrier wall patterns for their combined flame shape and flame temperature, it is more preferred to choose 60° Plate. The results of this study will help to better analyze the consequences of hydrogen jet flames and provide guidance for better design of barrier walls for mitigation.