Geological Background Research Articles

Assessment of health risks posed by toxicological elements of the food chain in a typical high geologic background

Enrichment of toxicological elements in soils of high geologic background has a significant effect on toxicity. The aim of this study was to assess the health risks associated with the transfer of toxicological elements in the food chain in a typical high geologic background. We systematically collected data on rocks, soils and food crops belonging to a typical black rock system geological body and at the same time belonging to the main grain-producing areas in Hunan Province, and analyzed the exposure and health threat of toxicological elements Cr, Cd, Pb, Hg, As and Se in cucumber, rape, soybean, peanut and ginger. Based on the JISEVM method to establish the spatial contamination constitutive relationship between rock-soil-food, we deduced the conclusions from the bioconcentration factor (BCF), integrated crop contamination index (P) and hazard index (HI). Our results showed that Cr, Cd, Pb, Hg, and Se were exceeded in agricultural soils, with Hg and Se levels severely exceeding the standard Se was most bioconcentrated in soybean (BCF = 0.5855), followed by Cd (BCF = 0.5603) and Se (BCF = 0.3800) in peanut and Se (BCF = 0.4255) in rape, and the BCFs of all the BCF of crops were less than 1, and the enrichment of these six elements in the food chain did not reach a dangerous level; the overall spatial distribution of radioactive contamination was centered on the black rocky geologic body; and the contamination and absorption levels of foods in the study area were: leafy vegetables (oilseed rape) > legumes (soybeans and peanuts) > stem vegetables (ginger) > fruit vegetables (cucumber). The intake of Cd and Se through consumption of oilseed rape was the most important source of health risk among foods in the study area. This study, since it can fill the gap in risk assessment due to endogenous factors in a high geologic background, can also guide studies in other specialized contexts or in a multi-media background.

Organic Petrologic Characterization and Paleoenvironmental Analysis of Permian Shale in Northeast Sichuan Province, China

The Permian shale in Northeast Sichuan is an important shale oil and gas resource potential area, and the study of its organic matter characteristics and paleoenvironmental analysis is of great significance for revealing the shale oil and gas formation mechanism and resource evaluation. In this study, the organic matter of Permian shales in northeast Sichuan was carefully studied based on various analytical tools, such as petrology, laser Raman, microscopy, and principal trace elements, and the paleoenvironmental parameters of the shales were comprehensively analysed. A detailed study of the organic matter characteristics of Permian shales in northeast Sichuan reveals important features such as organic matter fractions, structural characteristics, maturity and sources. The results show that the organic matter of the shale consists mainly of solid bitumen, putrescine group, specular group and multicellular planktonic algae. Petrological observations and laser Raman analyses indicate a high maturity of the organic matter and a high content of organic carbon (TOC), showing good hydrocarbon potential. In this study, we reconstructed the palaeoenvironmental parameters and inferred the palaeoenvironmental evolution through palaeoenvironmental analyses of Permian shales in northeast Sichuan. The results of the comprehensive multi-indicator study show that the type of palaeoenvironment at the time of shale deposition was mainly an anoxic-reducing environment, and the depositional conditions were favourable to the enrichment and preservation of organic matter. In summary, the organic matter characteristics and paleoenvironmental analyses of the Permian shales in Northeast Sichuan provide important geological background information for an in-depth understanding of the formation mechanism, exploration potential and development prospect of shale hydrocarbons in this area. The results of this study can provide a scientific basis for the evaluation and development of shale oil and gas resources in this area, which is of great significance to geologists and the energy industry.

A Fully Coupled Gas–Water–Solids Mathematical Model for Vertical Well Drainage of Coalbed Methane

The coupling relationship between the deformation field, the diffusion field, and the seepage field is an important factor in fluid transport mechanisms in the long-term coalbed methane (CBM) exploitation process. A mathematical model of gas–water two-phase fluid–structure coupling in a double-porosity medium in coal reservoirs is established in this paper. Taking Hancheng Block, a typical production block in Qinshui Basin, as the geological background critical desorption pressure, reservoir permeability anisotropy is considered in the model. COMSOL Multiphysics (COMSOL_6.0) was used to create the model. The accuracy and rationality of the model were verified by comparing field production data with the results of the simulation. Using the simulation, the influence law of various reservoir geological characteristics parameters (Langmuir strain constant, ratio of critical desorption pressure to reservoir pressure of coal seam (CDPRP), elastic modulus, initial water saturation, Langmuir pressure, etc.) on CBM productivity, reservoir pressure, and permeability ratio was discussed, and a thorough analysis of the factors affecting productivity was obtained using the orthogonal test method. The findings of this study indicate that the change in permeability is the result of the superposition effect of many factors. Different stages of drainage have different primary regulating factors. Rock skeleton stress has a consequence on coal matrix permeability in the early drainage stage, and coal matrix shrinkage is primarily impacted in the later drainage stage. Besides the initial water saturation, other reservoir geological parameters (e.g., CDPRP, Langmuir volume, Langmuir strain constant, elastic modulus) have a strong relationship with productivity. When the value of coal geological parameters increases, the degree of productivity release is higher (as the initial water saturation increases, the production decreases correspondingly). Different coal and rock parameters have varying levels of impact on the drainage stage of CBM wells. The influences of the CDPRP, Langmuir volume, Langmuir strain constant, and elastic modulus on gas production are mainly concentrated in the initial and intermediate drainage stages and begin to fall off during the last drainage stage. Per the multi-factor analysis, the main coal–rock parameters affecting the productivity release are the Langmuir strain constant, followed by the CDPRP and other parameters. The analysis findings can offer theoretical guidance for CBM well selection and layer selection and enhance the block’s overall CBM development level. The improved productivity prediction model for CBM, which is based on fluid–structure coupling theory, can offer a new technical benchmark for CBM well productivity prediction.

Formation mechanisms of fluvial residues from eastern watersheds of China: Insights from corrected weathering process and sediment provenance

Investigating the weathering process and provenance of fluvial residues plays a crucial role in revealing superficial circulation on earth. Although the transfer and inheritance processes have been well elaborated for intra-watersheds, the limitations and applications of geochemical proxies need to be further explored for cross-watersheds. Geochemical analysis was performed on 541 surficial sediment samples from 12 intertidal zones in China, combined with traditional weathering indices, mass transfer coefficients, and rare earth element parameters, to gain a better understanding of their geochemical behavior. Based on the interactions of lithology, hydrodynamic sorting, and sedimentary recycling on various weathering indices, the metamorphic and succession processes of the residues were fully characterized during the source-to-sink process. The weathering index of Parker (3.9–66.2) was more susceptible to the hydrodynamic sorting effect, whereas the chemical index of alteration (45.8–83.9) was heavily influenced by the sedimentary recycling process. In comparison, the mass transfer coefficient of Na provides better performance in the early weathering stage and is optimally protected from the effects of hydrodynamic sorting and sedimentary recycling. As confirmed by the corrected mass transfer coefficients and weathering indices, regional temperature and precipitation co-dominated the weathering heterogeneity. Parameters excluding heavy rare earth elements were hardly affected by the weathering process and grain-size effect, and were the most sensitive geochemical proxies for tracing the provenance of fluvial residues. This could provide a scientific basis for cross-watershed research, source apportionment, and regional geological background.

Stream sediment pollution: a compositional baseline assessment

AbstractA high concentration of potentially toxic elements (PTEs) can affect ecosystem health in many ways. It is therefore essential that spatial trends in pollutants are assessed and monitored. Two questions must be addressed when quantifying pollution: how to define a non-polluted sample and how to reduce the problem’s dimensionality. A geochemical dataset is a composition of variables (chemical elements), where the components represent the relative importance of each part of the whole. Therefore, to comply with the compositional constraints, a compositional approach was used. A novel compositional pollution indicator (CPI) based on compositional data (CoDa) principles such as the properties of sparsity and simplicity was computed. A dataset of 12 chemical elements in 33 stream-sediment samples were collected from depths of 0–10 cm in a grid of 1 km × 1 km and analyzed. Maximum concentrations of 3.8% Pb, 750 µg g−1 As, and 340 µg g–1 Hg were obtained near the mine tailings. The methodological approach involved geological background selection in terms of a trimmed subsample that could be assumed to contain only non-pollutants (Al and Fe) and the selection of a list of pollutants (As, Zn, Pb, and Hg) based on expert knowledge criteria and previous studies. Finally, a stochastic sequential Gaussian simulation of the new CPI was performed. The results of the hundred simulations performed were summarized through the mean image map and maps of the probability of exceeding a given statistical threshold, allowing the characterization of the spatial distribution and the associated variability of the CPI. A high risk of contamination along the Grândola River was observed. As the main economic activities in this area are agricultural and involve animal stocks, it is crucial to establish two lines of intervention: the installation of a surveillance network for continuous control in all areas and the definition of mitigation actions for the northern area with high levels of contamination. Graphical Abstract

Detection of long-term slope displacement using time-series DInSAR and geological factor analysis for susceptibility assessment of landslides in northwestern Kyushu Island

Ongoing climate change has increased the impact of landslides and related slope disasters on infrastructure and human lives. Microwave satellite remote sensing, particularly interferometric analysis of synthetic aperture radar (InSAR) data, is a powerful tool for routine monitoring of the displacement of slopes on small wavelength scales, independently from solar illumination and cloud coverage. Although various sophisticated techniques for time-series InSAR have been developed, practical application in conjunction with geological analysis to reveal intrinsic and triggering factors of slope displacement is still limited. In this paper, we describe a practical case of time-series InSAR analysis with a special focus on its geological implications in northwestern Kyushu, a high-risk area for slope-related disasters in Japan. The extracted susceptible polygons from the InSAR results show accuracy comparable with that of other recent research on landslide mapping. Intrinsic factor analysis based on a geographic information system reveals that the displacement occurs on relatively gentle slopes instead of steep areas, corresponding to the transient zone of Paleogene-Neogene sedimentary rocks and basalt. Triggering factor analysis based on correlation coefficients reveals a significant link between some displacement areas with mean and/or maximum precipitation for each observation duration. Those findings confirm the importance of carefully accounting for the geological background for landslide susceptibility assessment and policy making, apart from topographic and meteorological conditions.

Cretaceous fossil birds from China

Abstract The explosive radiation of early birds has been well documented by the extraordinary discoveries of the Early Cretaceous fossil birds in China in the past three decades. They have greatly expanded the diversity, disparity and temporal distribution of Mesozoic birds, refining our knowledge of the evolutionary path leading to the characteristic avian body plan, including feathers and powered flight, locomotion and habitat differentiation, diet and digestion, reproduction and development, feather colours and display. In addition, studies on the geological background of the Jehol Biota that produced the majority of the Chinese Cretaceous birds have provided important clues to our understanding of the taphonomy as well as the interaction between deep geological process and biological evolution in northeastern China and East Asia during the Early Cretaceous. Future multidisciplinary studies are expected to advance our knowledge of the palaeogeography of Early Cretaceous birds, what impacted the changes in the diversity of early birds in China, and the roles that early birds played in the Early Cretaceous terrestrial ecosystem.

Characteristics of Cd Fluxe in Topsoil Around Typical Mining Area in Hezhou, Guangxi

Guangxi is a typical geological high background area in southwest China, where carbonates, black rock series, basic-ultrabasic rock mass, and metal deposits (mineralized bodies) exhibit strong weathering into loam, resulting in higher cadmium (Cd) content in the soil than that in other areas of China. In order to investigate the degree of influence of mining activities on topsoil environmental quality in the area with high geological background, we chose a mining area and control area in Hezhou for this research and systematically carried out a comparative study on Cd transport routes and transport flux density in topsoil. The results showed that the average atmospheric dry and wet deposition flux densities of Cd in the soil of the mining area and control area were 1.87 g·(hm2·a)-1 and 1.52 g·(hm2·a)-1, accounting for 61.5% and 60.3% of the total input flux density, respectively. The flux density of Cd in the soil by fertilization and irrigation was lower. Surface water infiltration was the main avenue of soil Cd output in both the mining area and control area, accounting for 75.4% and 86.6% of the total output flux density, respectively. The harvest output flux density in the mining area was higher than that in the control area, and the Cd content of rice planted in the mining area was higher than the standard, whereas that of maize was safe. On the whole, the net transport flux densities of soil Cd in the mining area and control area were -3.05 g·(hm2·a)-1 and -4.05 g·(hm2·a)-1, both of which showed Cd leaching in the soil. However, the points of high atmospheric deposition flux density and exceeding Cd content in rice were mainly distributed around the mining area, which may have posed a potential threat to the health of local residents. Therefore, it is suggested to control the soil Cd pollution through monitoring and planting structure adjustment.

Excavation response and reinforcement practice of large underground caverns within high-stress hard rock masses: The case of Shuangjiangkou hydropower Station, China

The construction of large-scale underground caverns poses numerous challenges due to their massive scale and high complexity. Among them, stability has always been a major concern during the construction process of large underground caverns within high-stress hard rock masses. It is not only influenced by the geological background of the project but also by the engineering activities during construction. This study takes the construction of the Shuangjiangkou (SJK) hydropower station as a case study and combines field investigations to summarize engineering issues and solutions under high geostress in three aspects. Firstly, it focuses on estimating and modifying the in-situ stress field of the underground caverns in the deep-cut valley area using limited geostress testing data and the observed failure phenomena in the pilot tunnel. Secondly, it discusses the typical failure phenomena of caverns under high geostress, including global stress-induced failures and local vein-controlled failures, as well as the corresponding failure mechanisms and treatment measures. Finally, it addresses the special failure phenomena occurring in the protective layer of the rock-anchored beam and optimizes the excavation scheme based on the observed failure patterns. The research results and solutions provided in this study, based on the case of the SJK hydropower station, are expected to serve as a reference for subsequent construction of large underground caverns within high-stress hard rock masses.

Geochemistry of high temperature initial geothermal fluids in the Dabie orogenic belt

Analyzing the genesis and resource potential of orogenic geothermal systems poses significant challenges due to their complex geological backgrounds and evolutionary histories. This paper presents a novel synthesis of hydrogeochemical and isotope geochemical data, coupled with geological and geophysical results, to comprehensively understand the origins of deep, high-temperature orogenic geothermal systems. This understanding is achieved through the utilization of advanced geochemical modeling techniques to analyze the geochemical attributes of initial geothermal fluids. The hydrochemical and H/O/S isotopic composition of a total of 67 geothermal and non-geothermal water samples from the Dabie orogenic belt (DOB) were analyzed. Integrated multicomponent geothermometry (IMG) was employed to reconstruct the characteristics of the initial geothermal fluids, and PHREEQC inverse simulations creatively determined the most likely pathways of their genesis and evolution. The findings indicate that all geothermal waters from the three major geothermal fields of Luotian, Yingshan, and Yuexi are alkali-sulfate type waters. The initial geothermal fluids are acidic sulfate type with reservoir temperatures of 156–222 °C, 115–179 °C, and 100–189 °C, respectively. The primary processes responsible for the formation of these initial geothermal fluids are the dissolution of anhydrite from sulfide oxidation and, to a lesser extent, direct sulfide oxidation. Generally, the formation of geothermal systems in the investigated geothermal fields is associated with the extensional collapse and lithospheric thinning of the Dabie orogen since the Early Cretaceous Period. The spatial distribution of the three geothermal fields in this study corresponds to the tectonic-magmatic framework of magmatic intrusion-induced domes (Luotian and Yuexi) in the DOB. The reactivation of the Tan-Lu Fault during the Cenozoic Era suggests the presence of a deep heat source comprising magmatic and metamorphic components. This heat source, combined with the infiltration of paleo-atmospheric and modern atmospheric precipitation water along regional fault systems, results in the formation and gradual dilution of initial geothermal fluids. Neutralization occurs through interactions with calcite and fine-grained sodium aluminosilicates, ultimately leading to the formation of the collected geothermal water. The conceptual model established in this study elucidates the distinctive genesis and formation mechanism of the orogenic geothermal system exemplified by the DOB.

Organic Geochemical Evidence for the Formation of Condensate from Coaly Source Rocks in the Wumaying Buried Hill of the Huanghua Depression, Bohai Bay Basin.

Although oil and gas from coaly source rocks have been widely discovered worldwide, the role of oil generated from coal measures in marine-continental coaly deposits during the Carboniferous-Permian period in the Bohai Bay Basin has long been a subject of debate. The recent discovery of a condensate reservoir in the Wumaying buried hill within the Huanghua Depression of the Bohai Bay Basin offers new potential insights into this issue. In this study, we employed organic geochemical methods to explore the possibility of the Carboniferous-Permian coal deposit being a primary source of the condensate. The distribution of light hydrocarbons and the biomarker assemblage indicate that the condensate did not undergo significant secondary alterations such as thermal cracking, gas invasion fractionation, or biodegradation. The hydrocarbon generation potential of the Carboniferous-Permian coaly source rocks suggests that they could be an important contributor to the formation of condensate. High pristine/phytane ratios (1.0-7.5), an abundant presence of benzene series, and the dominance of C29 steranes (>50%) within the condensate could be indicative of coaly organic matter. These features are comparable to those found in coaly source rocks. Moreover, the stable carbon isotopic compositions of n-alkanes in the condensate, ranging from -26.0 to -30.0‰, correlate well with those from coaly mudstone (-25.4 to -30.0‰). This suggests that the condensate of the Wumaying buried hill may predominantly originate from the Carboniferous-Permian coaly mudstone. When integrated with the geological background, the results distinctly demonstrate that the Carboniferous-Permian coaly source rocks have significantly contributed to the formation of the condensate reservoir in the Wumaying buried hill. This provides an essential reference for future exploration of oil and gas resources derived from the carboniferous-Permian coaly source rocks in the Bohai Bay Basin.

Differences in the activities of six soil enzymes in response to cadmium contamination of paddy soils in high geological background areas

East Yunnan province in southwest China is a region with elevated natural abundance (high geological background levels) of Cd due to high metal (loid) contents in the soils. Enzyme activities are useful indicators of metal (loid) toxicity in contaminated soils and whether Cd inhibits enzyme activities in paddy soils in high geological background areas is of considerable public concern. A pot experiment combined with field investigation was conducted to assess the effects of Cd on six soil enzymes that are essential to the cycling of C, N, and P in soils. Inhibitory effects of Cd fractions on enzyme activities were assessed using ecological dose-response models. The impact of soil properties on the inhibition of sensitive soil enzymes by Cd were assessed using linear and structural equation models. Cadmium was enriched in the paddy soils with 72.2 % of soil samples from high geological background areas exceeding the Chinese threshold values (GB 15618–2018) of Cd. Enzyme responses to Cd contamination varied markedly with a negative response by catalase but a positive response by invertase. Urease, β-glucosidase, and alkaline phosphatase activities were stimulated at low Cd concentrations and inhibited at high concentrations. The average inhibition ratios of β-glucosidase, urease, and catalase in high Cd levels were 19.9, 38.9, and 51.9%, respectively. Ecological dose-response models indicate that catalase and urease were the most Cd-sensitive of the enzymes studied and were suitable indicators of soil quality in high geological background areas. Structural equation modeling (SEM) indicates that soil properties influenced sensitive enzymes through various pathways, indicating that soil properties were factors determining Cd inhibition of enzyme activities. This suggests that Cd concentrations and soil physicochemical properties under a range of environmental conditions should be considered in addressing soil Cd pollution.

The minerals of Jules Verne

Many rock and mineral collectors have roots in the movies and books of Jules Verne, such as Journey to the Centre of the Earth (1864). It seems only fitting that the mineral verneite was recently named after him, one of only three writers (Verne, Goethe and Theophrastus) to have a mineral named after them. Verne was an active amateur geologist, visiting sites throughout Europe. Of Verne's 80 novels, many have geological themes, subthemes or backgrounds second only to the sea. Like in his Journey to the Center of the Earth, Verne's lesser geological novels offer a remarkable literary guide to rocks, minerals and geology. Verne's geology‐based novels and writings are extensive and provide a means to re‐energize your childhood love of mineral collecting.

Comprehensive physicochemical characterization of Algerian coal powders for the engineering of advanced sustainable materials

The object of the research is the intriguing and versatile material known as coal that attracted a lot of attention lately because of its potential use in a variety of fields, including cutting-edge building materials, environmental remediation methods, and creative energy storage solutions. This study presents an extensive characterization of Algerian natural coal powders, employing a multifaceted analytical approach that includes Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and Raman Spectroscopy, to reveal their physicochemical properties including morphology, particle size distribution, crystalline structure, and functional groups. The SEM analysis unveiled a heterogeneous morphology with a broad particle size distribution, indicative of the coal's complex structure. The XRD findings, refined using Rietveld analysis, distinguish Carbon (C) and Silicon Dioxide (SiO2) as the primary phases, with crystallite sizes measuring 18.7539 nm for C and 16.6291 nm for SiO2. These phases constitute 98.8 % and 12 % of the composition, respectively, while the presence of quartz underscores the coal’s geological background and its thermal resilience. Regarding the results of the FTIR spectroscopy, absorption peaks corresponding to various functional groups are highlighted, suggesting a rich organic and inorganic composition. Raman spectroscopy corroborates the presence of disordered and graphitic carbon structures, emphasizing the coal's potential for diverse applications. These findings underline the significance of Algerian coal powders for environmental remediation, energy storage, and advanced construction materials, contributing to the advancement of sustainable energy solutions.

Research on characteristics and geological genesis of large-scale deep-seated landslide in tuff formation

In engineering practice, engineers generally treated tuff as a lumpy material with a poorly defined laminated structure and a rock group that was not susceptible to slide failure. Most studies of tuff landslides had focused on small clastic landslides in shallow strata with weathering boundaries and lithologic interfaces as slip surfaces. This paper takes a large-scale, deep-seated tuff landslide on the southeast coast of China as the research project. We used borehole TV imaging and exploration tunnels to confirm the material composition and structural characteristics of the tuff stratum and used exploration tunnels to expose the slip soil directly. Microscopic identification, mineralogical composition analysis, zircon U-Pb isotope dating, and Hf isotope analysis of slip soils collected from the exploration tunnels elucidated the geologic background and genesis of the large-scale deep-seated landslides in the tuff stratum. It was found that the formation of a tuff stratum in the landslide area was caused by multi-volcanic orogeny and multi-phase tectonics. The timing of the melting of the original magma from these volcanic events also differs. During these intervals between eruptions, deposition occurred, and this sedimentary material formed the slip soil.

Source analysis and contamination evaluation of potentially toxic elements in soil in typical high geological background areas at the county scale in northeastern Yunnan, China

The pollution risk of potentially toxic elements (PTEs) in soil is a common concern in the fields of environmental science and agriculture. The spatial distribution characteristics, pollution risk assessment and genetic sources of PTEs in soil in high geological background areas are crucial to the safe use of land. Based on the data for five PTEs in 921 surface soil samples from typical high geological background areas in SW China, we discuss their spatial distribution characteristics using geostatistics, the semivariance function and its model. We carry out pollution risk assessment using the influence index of comprehensive quality (IICQ) and analyse their genetic sources using the UNMIX receptor model. The spatial distribution of element content has a high spatial coupling with the stratigraphic spread, which is affected by external random factors, resulting in a weakened autocorrelation. The IICQ indicates that soil is dominated by mild and moderate pollution, accounting for 42.24 and 44.95%, respectively, with cadmium contributing up to 63.00% to the IICQ. Chromium and cadmium are controlled by natural sources, accounting for 83.98 and 69.39%, respectively. Arsenic and mercury have anthropogenic sources, accounting for 68.7 and 44.0%, respectively. Lead is controlled by both lead–zinc mining and geological background, accounting for 47.7 and 36.4%, respectively. The UNMIX model demonstrates that the spatial variability of PTEs is influenced by anthropogenic factors, such as coal combustion emissions, which account for 30.1% of the pollution sources. Soil parent material sources contribute 49.4%, followed by lead–zinc mining and smelting activities at 20.5%.

Numerical Evaluation of Commingled Production Potential of Marine Multilayered Gas Hydrate Reservoirs Using Fractured Horizontal Wells and Thermal Fluid Injection

Multilayered reservoirs with coexisting free gas and hydrates are primary targets for commercialization, nevertheless, the extremely low permeability greatly limits their extraction efficiency. Herein, multilayer commingled production using horizontal wells stimulated by hydraulic fracturing and thermal fluid injection was proposed to enhance productivity, and the effects of key factors on co-production performance were numerically examined, with the reservoir located in the Shenhu Area as the geological background. The results indicated that due to severe interlayer contradictions, the stimulation capabilities of using fracturing or thermal fluid injection alone were limited, in particular, the extraction of hydrates severely lagged behind. However, their combination exhibited tantalizing productivity due to strengthened inter-well interaction. Reducing the fracture spacing was more effective than increasing fracture conductivity in shortening the production cycle, and intensive fractures with adequate flow capacity were suggested for gas enhancement and water control. When the fracture spacing was reduced from 30 to 5 m and the fracture conductivity increased from 10 to 100 D·cm, the horizontal section length for commercial production (average daily gas production of 50,000 m3 and recovery ratio of 0.7) was reduced from 1758 to 146 m, which is lower than the on-site horizontal section length of 250–300 m. Therefore, the proposed development mode is promising for the commingled production of gas and hydrates.

Identification of groundwater pollution sources and health risk assessment in the Songnen Plain based on PCA-APCS-MLR and trapezoidal fuzzy number-Monte Carlo stochastic simulation model

The source of inorganic pollutants in the groundwater of the Songnen Plain are complex; therefore, it is urgent to analyze the pollution sources and their contribution rates, and to determine the effects of pollutants on human health. In this study, the solution for the insufficient extraction of characteristic information and subjective weight in principal component analysis (PCA) was found using log-centralization and the entropy weight method. Based on 896 groundwater samples, the types and distribution characteristics of pollution sources were identified, and the APCS-MLR receptor model was used to quantitatively characterize the contribution of pollution sources to water quality. Considering the uncertainty of the health risk assessment process, a trapezoidal fuzzy number-Monte Carlo stochastic simulation model (TFN-MCS) was constructed. Overcoming the inapplicability of triangular fuzzy numbers in dealing with highly discrete water quality data. The results showed that: (1) The five potential pollution sources in the Songnen Plain were salinity factor (34.086 %), agricultural pollution factor (15.854 %), geological background factor (13.11 %), industrial pollution factor (10.382 %) and organic pollution factor (7.382 %). The degree of groundwater pollution in the study area is controlled by the terrain, hydrogeological conditions, land use type, and industrial layout. (2) The APCS-MLR receptor model was suitable for the allocation of potential sources of groundwater pollution. The average contributions rate of the five common factors to groundwater pollution were 38.86, 14.12, 15.73, 14.6, and 6.77 %. Salinity factor plays a major role in groundwater quality. (3) The THI of children and adults were 2.15–15.03 and 0.86–7.261, respectively, much higher than the safety threshold of one. In general, the THI of children from ingesting contaminated groundwater is twice that to adults. NO3– and F- are the primary risk control indicators for groundwater in the study area. These results support the formulation of effective groundwater pollution control strategies.

Antagonistic Effects, Sources, and Distribution of Selenium and Toxic Metals in Fish from Selenium-Rich and High Cadmium Areas, Dashan Region, China.

The Gongxin River is one of the main rivers in the Dashan Region of Anhui Province in China, which is a Se-rich and high-Cd area, but no research has focused on the concentration, source, antagonism, and health risks of Se and TMs in fish. In this study, 120 fish samples (14 species), 24 sediment samples, and 24 water samples were collected to investigate the antagonistic effects, sources, and health risks of TMs and Se in fish from a typical selenium-rich and high cadmium region. Zn and Se in fish from the Gongxin River were higher than in the background, which might be attributed to the different feeding habits of different fish species. The apparent antagonism between Se and Cu, Pb, and Cd was explored, and the results showed that 30%, 75%, and 100% of the Se/Cu, Se/Pb, and Se/Cd ratios were greater than one, indicating that Cu, Pb, and Cd in fish might be combined with or detoxicated by Se. The source analysis of the elements showed that the geological background was the source of TMs and Se in fish samples. The amounts of Se and TMs were all within China's acceptable level guidelines, signifying no harm to citizens from eating fish.

Magmatic-hydrothermal fluid evolution of the tin-polymetallic metallogenic systems from the Weilasituo ore district, Northeast China

The large Weilasituo Sn-polymetallic deposit is a recent exploration discovery in the southern Great Xing’an Range, northeast China. The ore cluster area shows horizontal mineralization zoning, from the inner granite body outward, consisting of high-T Sn–W–Li mineralization, middle-T Cu–Zn mineralization and peripheral low-T Pb–Zn–Ag mineralization. However, the intrinsic genetic relationship between Sn-W-Li mineralization and peripheral vein-type Pb–Zn–Ag–Cu mineralization, the formation mechanism and the deep geological background are still insufficiently understood. Here, we use fluid inclusions, trace elements concentrations in quartz and sphalerite, and H–O isotope studies to determine the genetic mechanism and establish a metallogenic model. Fluid inclusion microthermometry and Laser Raman spectroscopic analysis results demonstrates that the aqueous ore-forming fluids evolved from low-medium salinity, medium–high temperature to low salinity, low-medium temperature fluids. Laser Raman spectroscopic analysis shows that CH4 is ubiquitous in fluid inclusions of all ore stages. Early ore fluids have δ18OH2O (v–SMOW) values from + 5.5 to + 6.2‰ and δD values of approximately − 67‰, concordant with a magmatic origin. However, the late ore fluids shifted toward lower δ18OH2O (v–SMOW) (as low as 0.3‰) and δD values (~ − 136‰), suggesting mixing between external fluids derived from the wall rocks and a contribution from meteoric water. Ti-in-quartz thermometry indicates a magmatic crystallization temperature of around 700 °C at a pressure of 1.5 kbar for the magmatic ore stage. Cathodoluminescence (CL) imaging and trace element analysis of quartz from a hydrothermal vug highlight at least three growth episodes that relate to different fluid pulses; each episode begins with CL-bright, Al-Li-rich quartz, and ends with CL-dark quartz with low Al and Li contents. Quartz from Episode 1 formed from early Sn-(Zn)-rich fluids which were likely derived from the quartz porphyry. Quartz from episodes 2 and 3 formed from Zn-(Sn)-Cu-rich fluid. The early magmatic fluid is characterized by low fS2. The SO2 produced by magma degassing reacted with heated water to form SO42−, causing the shift from low fS2 to high fS2. The SO42− generated was converted to S2– by mixing with CH4-rich, Fe and Zn-bearing external fluid which led to late-stage alteration and dissolution of micas in vein walls, thus promoting crystallization of pyrrhotite, Fe-rich sphalerite and chalcopyrite and inhibiting the precipitation of anhydrite. This study shows that ore formation encompassed multiple episodes involving steadily evolved fluids, and that the addition of external fluids plays an important role in the formation of the later Cu–Zn and Ag–Pb–Zn mineralization in the Weilasituo ore district.