With the rapid development of sensor and communication technologies, a large amount of spatiotemporal traffic data has been accumulated, presenting the characteristics of big data. The potential information and regularity of traffic state evolution can be extracted from the huge traffic flow time series data and applied to intelligent transportation systems. This study proposes a dynamic spatiotemporal causality modeling approach to analyze traffic causal relationships for the large-scale road network. Transfer entropy algorithm is utilized to detect the spatiotemporal causality of network traffic states based on the extensive traffic time series data, which could measure the amount and direction of information transmission. A combination of Gaussian kernel density estimation and sliding window approach is proposed to calculate the transfer entropy and construct dynamic spatiotemporal causality graphs based on the causality significance test. The indexes of affected coefficient, influence coefficient, input degree, and output degree are defined to evaluate the causal interaction of traffic states among different road segments and identify the critical roads and potential bottlenecks of the existing road network. Experimental results based on real-world traffic sensor data indicate that the structures of traffic causality graphs are time-varying; the traffic cause-effect interaction among different road segments during the peak time is more significant than that during the nonpeak time; and the critical road segments can be identified, which are mainly located at the intersections of arterial roads, undertaking the convergence and dispersion of large traffic flows.