Gate Electric Field Research Articles

Transition metal oxides: a new frontier in spintronics driven by novel quantum states and efficient charge-spin interconversion

Transition metal oxides (TMOs) have emerged as promising candidates for spintronic applications due to their unique electronic properties and novel quantum states. The intricate interplay between strong spin-orbit coupling and electronic correlations in TMOs gives rise to distinct spin and orbital textures, leading to enhanced spin-momentum locking and efficient charge-spin interconversion. Remarkably, recent researches have unveiled the significant and highly tunable nature of charge-spin interconversion efficiency in TMOs, which can be manipulated through strategies such as electric field gating, epitaxial strain, and heterostructure engineering. This review provides a comprehensive overview of the recent advances in understanding the electronic band structures of TMOs and their correlation with charge-spin interconversion mechanisms. We summarize the tunability of these properties through various experimental approaches and discuss the potential implications for spintronic device applications. The insights gained from this review can guide future research efforts towards the development of high-performance, energy-efficient spintronic devices based on TMOs.

(Invited) Oxide Semiconductor Gain Cell Memory

The energy and delay consumed by the off-chip memory (DRAM) and memory-to-logic chip data movement becomes the bottleneck (known as the memory wall) for the computing systems nowadays, especially for abundant-data computing and neural network accelerators. Larger on-chip memory capacity with high bandwidth can be a solution, yet it is difficult to achieve using SRAM and DRAM. Oxide semiconductor FET (OSFET)-based gain cell memory on the logic platform provides higher density than SRAM due to 3D stacking and is an attractive complement to off-chip DRAM. OSFET with extremely low leakage is used as the write transistor for long retention time, while the read transistor can either adopt OSFET for multiple-layer stacking (OS-OS gain cell) or Si FET for higher read speed (Hybrid gain cell). Designing OSFET gain cell is more than simply choosing materials/device designs that have the lowest off-state leakage current for the longest retention time. Atomic Layer Deposition (ALD) Indium Tin Oxide (ITO) FET is chosen to balance retention time with memory bandwidth. With material, process, and device co-design, the ITO films deposited by ALD with TMIn precursor, 9:1 In:Sn cycle ratio, and 2nm thickness exhibited optimized characteristics for OSFET-based gain cell. The experimentally optimized device exhibits low off-current 2×10-18 A/µm, high on-current 26.8 µA/µm, low SS 70 mV/dec, and high mobility 27 cm2/Vs. It also shows good stability with small VTH shift < 0.2 V under 125 °C, low PBS shift < 0.35 V and low NBS shift < 0.1 V under 1000s bias stress. Oxide semiconductor transistors is an accumulation mode transistor that requires a gate electric field to turn off the transistor. The transistor design calls for nanometer-thin oxide semiconductor channels. Significant device design tradeoffs exists between high on-current, low off-current, short gate length scalability, and the setting of proper threshold voltages. This talk will give an overview of the above experimental achievements today and the device design considerations for future gain cell memories.

Predictable Gate-Field Control of Spin in Altermagnets with Spin-Layer Coupling.

Spintronics, a technology harnessing electron spin for information transmission, offers a promising avenue to surpass the limitations of conventional electronic devices. While the spin directly interacts with the magnetic field, its control through the electric field is generally more practical, and has become a focal point in the field. Here, we propose a mechanism to realize static and almost uniform effective magnetic field by gate-electric field. Our method employs two-dimensional altermagnets with valley-mediated spin-layer coupling (SLC), in which electronic states display valley-contrasted spin and layer polarization. For the low-energy valley electrons, a uniform gate field is approximately identical to a uniform magnetic field, leading to predictable control of spin. Through symmetry analysis and abinitio calculations, we predict altermagnetic monolayer Ca(CoN)_{2} and its family materials as potential candidates hosting SLC. We show that an almost uniform magnetic field (B_{z}) indeed is generated by gate field (E_{z}) in Ca(CoN)_{2} with B_{z}∝E_{z} in a wide range, and B_{z} reaches as high as about 10^{3} T when E_{z}=0.2 eV/Å. Furthermore, owing to the clean band structure and SLC, one can achieve perfect and switchable spin and valley currents and significant tunneling magnetoresistance in Ca(CoN)_{2} solely using the gate field. Our work provides new opportunities to generate predictable control of spin and design spintronic devices that can be controlled by purely electric means.

Ambipolar current suppression in drain elevated TFET using a novel extended drain structure with a moderate doping profile

In this paper, a simple and compact silicon-based Elevated and Extended Drain with Hetero-Dielectric Gate Oxide TFET (EED HDGO TFET) is proposed to suppress the ambipolar current in Elevated Drain TFET (ED TFET). The proposed device structure uses a moderately doped drain with a doping concentration of ∼1018 cm−3 and a high drain length of ∼50–100 nm. The combination of the moderate drain doping profile and the extended drain length reduced the impact of the electrostatic potential from the positive voltage of the drain electrode on the channel–drain junction. This structural technique widens the tunneling width at the channel–drain region causing the tunneling current to decrease significantly. The tunneling width is further increased by structurally isolating the channel–drain junction region from the gate electrode. Thus, distancing the channel–drain junction from both the gate electric field and the static drain potential of the drain electrode causes full suppression of the ambipolar (Iamb) current. The proposed structure yields Iamb and Ioff as low as ∼10−18 A/μm and ∼10−17 A/μm respectively, while maintaining the Ion as ∼0.3 mA. The device is optimized for low power and high-speed digital circuits through intensive parametric analysis on gate–drain Cgd and the gate–source Cgs capacitances for various device parameters.

Graphite/h-BN van der Waals heterostructure as a gate stack for HgTe quantum wells

Two-dimensional topological insulators have attracted much interest due to their potential applications in spintronics and quantum computing. To access the exotic physical phenomena, a gate electric field is required to tune the Fermi level into the bulk band gap. Hexagonal boron nitride (h-BN) is a promising alternative gate dielectric due to its unique advantages such as flat and charge-free surface. Here we present a h-BN/graphite van der Waals heterostructure as a top gate on HgTe heterostructure-based Hall bar devices. We compare our results to devices with h-BN/Ti/Au and HfO2/Ti/Au gates. Devices with a h-BN/graphite gate show no charge carrier density shift compared to as-grown structures, in contrast to a significant n-type carrier density increase for HfO2/Ti/Au. We attribute this observation mainly to the comparable work function of HgTe and graphite. In addition, devices with h-BN gate dielectric show slightly higher electron mobility compared to HfO2-based devices. Our results demonstrate the compatibility between layered materials transfer and wet-etched structures and provide a strategy to solve the issue of significant shifts of the carrier density in gated HgTe heterostructures.

Modulation of charge transfer at the pentacene/graphene quantum dot interface by localized surface plasmonic resonance

We, for the first time, quantified localized surface plasmon resonance (LSPR)-induced charge transfer, and tuned charge carrier concentration in field-effect transistors (FETs) by incorporating silver nanoparticles (Ag NPs) at the pentacene/graphene quantum dot (GQD) interface. This resulted in a significant threshold voltage shift under illumination at a resonance frequency of 450 nm, primarily due to LSPR-induced charge transfer at the Ag NP/GQD interface. Further, the formation of an Ag NP-induced interface dipole in the dark accumulated holes in the pentacene layer in the absence of the gate electric field. Our research not only contributes to a deeper understanding of the interplay between plasmonics and semiconductor physics but also paves the way for new applications in electronics and photonics.

Boosting Bidirectional Photoresponse with Wavelength Selectivity through Ambipolar Transport Modulation

AbstractNegative photoconductive phototransistors, referring to transistors that exhibit a decrease in photocurrent under illumination, have the potential to revolutionize optoelectronic applications involving light, such as optoelectronic logic circuits and visual neural simulation. Currently, achieving negative photoconductivity (NPC) requires complex material design or interface structure construction. However, achieving precise control over NPC behaviors poses a significant challenge. Herein, a simple yet effective strategy is demonstrated for realizing controllable NPC responses in organic phototransistors through ambipolar transport modulation. Due to the controversy between the preferred exciton dissociation/charge separation direction and the gate electric field driven charge drift direction, the main semiconductor channel (n‐ or p‐channel) exhibits NPC behavior under illumination. The validity of this mechanism has been confirmed through intensive studies by varying the component and combination of the p‐n heterostructure. Moreover, devices utilizing ambipolar transport exhibit a wavelength‐selectivity NPC response due to the absorption characteristics of the combined semiconductor materials. Most encouragingly, by incorporating both negative and positve photoconductivity along with wavelength‐selective responses, high‐contrast image sensing, information encryption and decryption, as well as optoelectronic logic circuit design is successfully achieved. This work promotes the design and development of bidirectional optoelectronic devices and offers a new route for developing attractive multifunctional optoelectronic devices.

Simulation and analysis of enhancement-mode AlGaN/GaN HEMT with P-I-N junction gate

To improve the threshold voltage and gate reliability of conventional enhancement-mode p-GaN-gated AlGaN/GaN high electron mobility transistors while maintaining a low on-resistance, an improved design solution for p-GaN HEMTs with P-I-N junction gate (PIN-HEMTs) has been proposed. Simulation results show that energy band modulation is achieved by adjusting the doping concentration and thickness of each layer of the PIN junction, and high-performance p-GaN gate HEMTs with adjustable threshold voltages ranging from 0.56 V to 4.75 V and gate breakdown voltages ranging from 19.8 V to 30.3 V would be prepared. The PIN-HEMT has a quasi-self-alignment property, which means that good gate control is independent of gate metal alignment. This not only improves the production efficiency but also solves the problems of weak gate control and electric field aggregation at the gate edge caused by the gate misalignment in conventional p-GaN gate HEMTs, thus realizing lower on-resistance and higher gate breakdown voltage, which demonstrates this proposed structure has excellent potentials for realizing effective and reliable high-power transistors.

Liquid-Film Rupture for Web-like Ag Nanowires toward High-Performance Organic Schottky Barrier Transistors.

Organic vertical transistors are promising device with benefits such as high operation speed, high saturation current density, and low-voltage operation owing to their short channel length. However, a short channel length leads to a high off-current, which is undesirable because it affects the on-off ratio and power consumption. This study presents a breakthrough in the development of high-performance organic Schottky barrier transistors (OSBTs) with a low off-current by utilizing a near-ideal source electrode with a web-like Ag nanowire (AgNW) morphology. This is achieved by employing a humidity- and surface-tension-mediated liquid-film rupture technique, which facilitates the formation of well-connected AgNW networks with large pores between them. Therefore, the gate electric field is effectively transmitted to the semiconductor layer. Also, the minimized surface area of the AgNWs causes complete suppression of the off-current and induces ideal saturation of the OSBT output characteristics. p- and n-type OSBTs exhibit off-currents in the picoampere range with on/off ratios exceeding 106 and 105, respectively. Furthermore, complementary inverters are prepared using an aryl azide cross-linker for patterning, with a gain of >16. This study represents a significant milestone in the development of high-performance organic vertical transistors and verifies their applicability in organic electronic circuitry.

High photoresponsivity MoS2 phototransistor through enhanced hole trapping HfO2 gate dielectric

Phototransistor using 2D semiconductor as the channel material has shown promising potential for high sensitivity photo detection. The high photoresponsivity is often attributed to the photogating effect, where photo excited holes are trapped at the gate dielectric interface that provides additional gate electric field to enhance channel charge carrier density. Gate dielectric material and its deposition processing conditions can have great effect on the interface states. Here, we use HfO2 gate dielectric with proper thermal annealing to demonstrate a high photoresponsivity MoS2 phototransistor. When HfO2 is annealed in H2 atmosphere, the photoresponsivity is enhanced by an order of magnitude as compared with that of a phototransistor using HfO2 without annealing or annealed in Ar atmosphere. The enhancement is attributed to the hole trapping states introduced at HfO2 interface through H2 annealing process, which greatly enhances photogating effect. The phototransistor exhibits a very large photoresponsivity of 1.1 × 107 A W−1 and photogain of 3.3 × 107 under low light illumination intensity. This study provides a processing technique to fabricate highly sensitive phototransistor for low optical power detection.

Orbital multiferroicity in pentalayer rhombohedral graphene.

Ferroic orders describe spontaneous polarization of spin, charge and lattice degrees of freedom in materials. Materials exhibiting multiple ferroic orders, known as multiferroics, have important parts in multifunctional electrical and magnetic device applications1-4. Two-dimensional materials with honeycomb lattices offer opportunities to engineer unconventional multiferroicity, in which the ferroic orders are driven purely by the orbital degrees of freedom and not by electron spin. These include ferro-valleytricity corresponding to the electron valley5 and ferro-orbital-magnetism6 supported by quantum geometric effects. These orbital multiferroics could offer strong valley-magnetic couplings and large responses to external fields-enabling device applications such as multiple-state memory elements and electric control of the valley and magnetic states. Here we report orbital multiferroicity in pentalayer rhombohedral graphene using low-temperature magneto-transport measurements. We observed anomalous Hall signals Rxy with an exceptionally large Hall angle (tanΘH > 0.6) and orbital magnetic hysteresis at hole doping. There are four such states with different valley polarizations and orbital magnetizations, forming a valley-magnetic quartet. By sweeping the gate electric field E, we observed a butterfly-shaped hysteresis of Rxy connecting the quartet. This hysteresis indicates a ferro-valleytronic order that couples to the composite fieldE·B(where Bis the magnetic field), but not to the individual fields. Tuning E would switch each ferroic order independently and achieve non-volatile switching of them together. Our observations demonstrate a previously unknown type of multiferroics and point to electrically tunable ultralow-power valleytronic and magnetic devices.

Simulation analysis of electrical characteristics of P-gate enhanced HEMT with C-doped buffer layer

The C-doped P-gate-enhanced HEMT (PEHEMT) is simulated by using the Silvaco T-CAD tool. The interaction among the C acceptor trap, electron, and hole in the buffer layer at different voltages promotes interesting electrical characteristic within the device. In off-state conditions, the peak electric field position shifts from the edge of gate to the edge of drain. During the process of peak electric field transfer, the gate electric field gradually saturates, and the increase rate of peak electric field shows a turning point at 350 V (Vd &amp;lt; 600 V). As the voltage further increases (Vd &amp;gt; 600 V), the increase rate of the drain electric field gradually slows down and tends to saturation, and the corresponding saturated gate electric field begins to increase. The uniform, quasi-linear, and step distributions of three different C acceptor in the buffer layer exhibit different degrees of current collapse under 1 ms bias stress, with values of 21.8%, 12.7%, and 12.8%, respectively. In this work, we have provided appropriate explanations for the above phenomena.

Layer-dependent exciton polarizability and the brightening of dark excitons in few-layer black phosphorus

The evolution of excitons from 2D to 3D is of great importance in photo-physics, yet the layer-dependent exciton polarizability hasn’t been investigated in 2D semiconductors. Here, we determine the exciton polarizabilities for 3- to 11-layer black phosphorus—a direct bandgap semiconductor regardless of the thickness—through frequency-resolved photocurrent measurements on dual-gate devices and unveil the carrier screening effect in relatively thicker samples. By taking advantage of the broadband photocurrent spectra, we are also able to reveal the exciton response for higher-index subbands under the gate electrical field. Surprisingly, dark excitons are brightened with intensity even stronger than the allowed transitions above certain electrical field. Our study not only sheds light on the exciton evolution with sample thickness, but also paves a way for optoelectronic applications of few-layer BP in modulators, tunable photodetectors, emitters and lasers.

Investigating an abnormal hump phenomenon in top gate a-InGaZnO thin-film transistors due to mobile sodium diffusion

Top gate a-InGaZnO (IGZO) thin-film transistors (TFTs) annealed at high temperature show excellent initial current–voltage (I–V) characteristics. However, when they are exposed to positive gate bias for a long time, hump can occur in the subthreshold region. This abnormal hump is accelerated at a higher positive gate voltage and mitigate by a negative gate voltage. While the strength of the hump is irrelevant to a change in channel width, it relies significantly on channel length. This phenomenon might be due to mobile Na ions diffused from a glass substrate migrating toward the back and edge side of the IGZO semiconductor by a vertical gate electric field. When a layer of Al2O3 is formed between the IGZO semiconductor and the glass substrate, the hump phenomenon could be successfully solved by serving as a barrier for Na ions moving into the IGZO.

Phase Transition Field Effect Transistor Observed in an α-(BEDT-TTF)2I3 Single Crystal

The metal–insulator transition induced by the gate electric field in the charge order phase of the α-(BEDT-TTF)2I3 single-crystal field-effect transistor (FET) structure was clearly observed near the phase transition temperature. An abrupt increase in the electrical conductance induced by the applied gate electric field was evident, which corresponds to the partial dissolution of the charge order phase triggered by the gate electric field. The estimated nominal dissolved charge order region (i.e., the gate-induced metallic region) was overestimated in 130–150 K, suggesting additional effects such as Joule heating. On the other hand, in the lower temperature region below 120 K, the corresponding dissolved charge order was several monolayers of BEDT-TTF, suggesting that it is possible to dissolve the charge order phase within the bistable temperature region.

Ultrafast Subpicosecond Magnetization of a 2D Ferromagnet.

Strong spin-charge interactions in several ferromagnets are expected to lead to subpicosecond (sub-ps) magnetization of the magnetic materials through control of the carrier characteristics via electrical means, which is essential for ultrafast spin-based electronic devices. Thus far, ultrafast control of magnetization has been realized by optically pumping a large number of carriers into the d or f orbitals of a ferromagnet; however, it is extremely challenging to implement by electrical gating. This work demonstrates a new method for sub-ps magnetization manipulation called wavefunction engineering, in which only the spatial distribution (wavefunction) of s (or p) electrons is controlled and no change is required in the total carrier density. Usinga ferromagnetic semiconductor (FMS) (In,Fe)As quantum well (QW), instant enhancement, as fast as 600fs, of the magnetization is observed upon irradiating a femtosecond (fs) laser pulse. Theoreticalanalysis shows that the instant enhancement of the magnetization is induced when the 2D electron wavefunctions (WFs) in the FMS QW are rapidly moved by a photo-Dember electric field formed by an asymmetric distribution of the photocarriers. Because this WF engineering method can be equivalently implemented by applying a gate electric field, these results open a new way to realize ultrafast magnetic storage and spin-based information processing in present electronic systems.

Magnetic ε-Phosphorene for Sensing Greenhouse Gas Molecules.

It is critical for gas sensors that sense greenhouse gas molecules to have both good sensitivity and selectivity for water molecules in the ambient environment. Here, we study the charge transfer, IV curves, and electric field tuning of vanadium-doped monolayer ϵ-phosphorene as a sensor for NO, NO2, and H2O gas molecules via first-principle and transport calculations. We find that the paramagnetic toxic molecules of NO and NO2 have a high adsorption energy on V-ϵ-phosphorene, which originates from a large amount of charge transfer driven by the hybridisation of the localised spin states of the host with the molecular frontier orbital. Using the non-equilibrium Green's function, we investigate the IV responses with respect to the adsorption of different molecules to study the performance of gas molecule sensors. Our IV curves show a larger amount of changes in resistance of the paramagnetic NO and NO2 than nonmagnetic H2O gas molecules, suggesting both sensitivity and selectivity. Moreover, our calculations show that an applied external electric field (gate voltage) can effectively tune the amount of charge transfer. More charge transfer makes the sensor more sensitive to the molecule, while less charge transfer can reduce the adsorption energy and remove the adsorbed molecules, allowing for the repeated use of the sensor.

Proton-Assisted Redox-Based Three-Terminal Memristor for Synaptic Device Applications

Emerging technologies, i.e., spintronics, 2D materials, and memristive devices, have been widely investigated as the building block of neuromorphic computing systems. Three-terminal memristor (3TM) is specifically designed to mitigate the challenges encountered by its two-terminal counterpart as it can concurrently execute signal transmission and memory operations. In this work, we present a complementary metal-oxide-semiconductor-compatible 3TM with highly linear weight update characteristics and a dynamic range of ∼15. The switching mechanism is governed by the migration of oxygen ions and protons in and out of the channel under an external gate electric field. The involvement of the protonic defects in the electrochemical reactions is proposed based on the bipolar pulse trains required to initiate the oxidation process and the device electrical characteristics under different humidity levels. For the synaptic operation, an excellent endurance performance with over 256k synaptic weight updates was demonstrated while maintaining a stable dynamic range. Additionally, the synaptic performance of the 3TM is simulated and implemented into a four-layer neural network (NN) model, achieving an accuracy of ∼92% in MNIST handwritten digit recognition. With such desirable conductance modulation characteristics, our proposed 3T-memristor is a promising synaptic device candidate to realize the hardware implementation of the artificial NN.

Measurement and gate-voltage dependence of channel and series resistances in lateral depletion-mode β-Ga2O3 MOSFETs

Lateral depletion-mode, beta-phase gallium oxide (β-Ga2O3) metal-oxide-semiconductor field-effect transistors (MOSFETs) with source-drain spacings of 3 µm, 8 µm, and 13 µm are studied using a modified transfer length method (TLM) to obtain sheet resistances in the gated and ungated regions as well as to observe their gate electric field dependence. The modified TLM requires the contact resistance to be independent of the gate-source voltage, or changing current density. We verify this by performing measurements on conventional TLM structures in dark and UV conditions and observe a changing current density with constant contact resistance, enabling the development of the proposed method. The conventional and modified TLM give sheet resistances of 20.0 kΩ sq−1 ± 1.0 kΩ sq−1 and 27.5 kΩ sq−1 ± 0.8 kΩ sq−1, respectively. Using a traditional method for determining the channel resistance, the modified TLM improves the convergence of the channel resistances between the three devices, showing higher accuracy than the conventional TLM structures. Gate-source voltage dependence of the sheet resistances is seen in the ungated regions, leading to non-ideal behavior which cannot be observed using the traditional method and conventional TLM structures. These results and analysis methods are important in improving MOSFET parameter extraction and understanding the gate electric field effects on the channel and series resistances in β-Ga2O3 MOSFETs.

Gate-Dependent Nonlinear Hall Effect at Room Temperature in Topological Semimetal GeTe

We experimentally investigate nonlinear Hall effect as zero-frequency and second-harmonic transverse voltage responses to ac electric current for topological semimetal GeTe. A thick single-crystal GeTe flake is placed on the Si/SiO2 substrate, where the p-doped Si layer serves as a gate electrode. We confirm that electron concentration is not gate-sensitive in thick GeTe flakes due to the gate field screening by bulk carriers. In contrast, by transverse voltage measurements, we demonstrate that the nonlinear Hall effect shows pronounced dependence on the gate electric field at room temperature. Since the nonlinear Hall effect is a direct consequence of a Berry curvature dipole in topological media, our observations indicate that Berry curvature can be controlled by the gate electric field. This experimental observation can be understood as a result of the known dependence of giant Rashba splitting on the external electric field in GeTe. For possible applications, the zero-frequency gate-controlled nonlinear Hall effect can be used for the efficient broad-band rectification.