Silver is an elegant white precious metal, but it is easily oxidized by O3, SO2, and H2S in the air, turning yellow or dark, which affects its decorative effect. The existing silver coating, primarily prepared through the electroplating process, poses serious environmental pollution problems. It is necessary to seek new, green, and environmentally friendly coating processes while also enhancing the color palette of silver jewelry coatings. Titanium film layers were deposited on Ag925 and Ag999 surfaces using magnetron sputtering coating technology. The effects of sputtering time, substrate surface state, reaction gas type and time, and film thickness on the color of the film layers were studied, and the anti discoloration performance of the obtained film layers under the optimal process was tested. The experimental results show that when the sputtering time varies from 5 to 10 minutes, injecting argon, oxygen, and nitrogen into the coating chamber yields rich colors such as purple with a red tint, blue, yellow green, yellowish purple, and blue purple. The precise control of gas injection time has a significant impact on the color of the film layer. In terms of anti tarnish performance, the film showed good stability in the artificial sweat immersion test. From an environmental perspective, the magnetron sputtering titanium film process has no harmful gas or liquid emissions, which aligns with the sustainable development trend of the jewelry industry and holds great promise for application. This study has improved the visual effect and practical performance of the product, providing important theoretical basis and experimental data support for the application of environmentally friendly silver surface vacuum magnetron sputtering titanium thin film coating technology.
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