This paper reports novel features like photo-voltaic and energy storage capacity as dual performance in Zinc-Perylene Tetra-Carboxylic Di-Anhydride (Zn-PTCDA) composite have synthesized via hydrothermal method. This follows escape-by-crafty mechanism chemical reaction that produces the orthorhombic crystal structure. The Morphology transformation from stacked pyramids of PTCDA into hexagonal plates and rod structures of Zn-PTCDA. The optical study suggest that Zn-PTCDA composite provide compelling evidence for the Dye sensitized solar cell (DSSC) with Power Conversion Efficiency (PCE) is lower 0.2 % due to charge carrier recombination and promote to utilize this as transport layer of any solar cell. The electrochemical performance of pure Zn-PTCDA exhibits capacitance retention of 44.2 % while Zn-PTCDA-Graphene Oxide (Zn-PTCDA-GO) has capacitance retention 84.5 % over 5000 Galvanostatic-Charging and Discharging (GCD) cycles. The best specific capacitance 561 F/g at 2 A/g along with discharge through light emitting diode (LED) illumination for 2–3 min and also excellent energy density 31.5 Whr/kg and power density 4.5 kW/kg values. The incorporation of Zinc into PTCDA dye demonstrates Metal Organic Frameworks can provide improvements in the performances of both supercapacitors and dye-sensitized solar cells. The integration of both can instant storage of converted energy is needed solution to solve energy demand in future.