Fusion Zone Research Articles

Effects of resistance spot welding parameters on microstructure and mechanical properties of the dissimilar welded joint of quenching and partitioning steels

Abstract In this study, the effect of welding currents and welding times on the microstructure and mechanical properties of the dissimilar welded joints of Q&P980 and Q&P1180 steel was investigated. The macrostructure and microstructure of the dissimilar welded joints were characterized and the relationship between the welding parameters and the mechanical performance was analyzed using confocal laser scanning microscope, scanning electron microscope, and mechanical properties testers. Results show that with the increasing welding current and welding time, the nugget diameter, indentation rate, and maximum shear force of the dissimilar joint increase. The absorption energy of the dissimilar joint increases when the welding current rises, while it increases first and then decreases with elevating welding time. All the hardness distributions of the dissimilar Q&P980/Q&P1180 joints exhibit the highest hardness value in the fusion zone and a gradually decreasing hardness value in the heat-affected zone. Moreover, with increasing current and time, much higher hardness occurs at the FZ/HAZ boundary. The microstructure characterization illustrates the martensite fraction in the intercritical heat-affected zone of the Q&P1180 side is higher than that of the Q&P980 side after the welding process. With the increase of welding current and time, the lath martensite in the fusion zone gradually coarsens. The coarsening martensite and the nugget diameter are responsible for the change in the shear force and energy absorption of the dissimilar Q&P980/Q&P1180 joints.

Evolution of NbC during laser welding and its impacts on the performance of molybdenum alloy joint

Influences of addition of niobium carbide (NbC) in the fusion zone (FZ) on room-temperature and high-temperature mechanical properties of laser-welded joints of molybdenum (Mo) alloys were studied. Results show that after adding NbC powder, the average Vickers microhardness in the upper part of the FZ increases from 183.0 HV to 712.3 HV; the room-temperature tensile strength grows from 33.9 MPa to 323.1 MPa, reaching 45.4 % that of base metal (BM). In addition, the fracture mode of joints turns from intergranular fractures into transgranular fracture; at 1100 °C, the high-temperature tensile strength of joints added with NbC is 141.6 MPa, which is 65.9 % that of BM. Energy dispersive spectrometer (EDS) and electron backscattered diffraction (EBSD) results show that after adding NbC powder, the average grain size in the FZ diminishes from 40.3 μm to 32.9 μm, where the number of low-angle grain boundaries (LAGBs) increases; the FZ not only contains NbC phase but also a large quantity of Nb2O5 and Mo2C phases dispersed on grain boundaries (GBs), and the number of MoO2 phase on GBs decreases apparently. Therefore, physical mechanisms underlying significant improvement of room-temperature and high-temperature tensile strengths of laser-welded joints of Mo alloys added with NbC in the FZ mainly include fine-grain strengthening, GB purification, and GB strengthening.

Induction assisted autogenous plasma arc welding of HSLA steel

In this work, a high frequency induction heating (HFIH) assisted plasma arc welding (IPAW) technique is proposed to weld 6 mm thick S690QL high strength low alloy steel plates in square butt joint configuration and without using any filler material. A 3D finite element based coupled electromagnetic-thermal analysis is carried out to ascertain the weld's thermal characteristics. Microstructure evolution and mechanical performance are investigated using scanning electron microscopy, electron back scattered diffraction, transmission electron microscopy, tensile test, Charpy impact test and micro hardness test. The results demonstrate that 15 s initial static heating using a co-directional current coil with magnetic flux concentrator predominantly improves the weld penetration by 48 % and joint efficiency reaches 90 % to the base plate strength. Microstructural study shows that the addition of HFIH promotes low angle grain boundaries (LAGB) with bainite ferrite and granular bainite micro-constituents in the fusion zone, which causes localised yielding and failure in this zone during tensile test. Further investigation reveals that the HFIH encourages the formation of BI-type bainite ferrite laths of 1.3–2.2 μm width, combined with slender martensite-austenite (M-A) island at the bainite ferrite lath boundaries. The results also reveal that the induction heating promotes the formation of M23C6 precipitates and B2 structured Cu-enrich nano precipitates in the fusion zone (FZ). The microhardness distribution indicates that the FZ and coarse grain heat affected zone are significantly reduced due to the assistance of the HFIH. The impact test result shows a lower energy absorption by the IPAW weldments due to dominance of the LAGB with unfavourable strain distribution.

Driving forces of solid-state Cu-to-Cu direct bonding suppressing the work-hardening loss by refill friction stir spot welding

In this study, the solid-state bonding of the Cu-to-Cu parallel connection with no fusion zone and keyhole formation was achieved using the refill friction stir spot welding (RFSSW) process. During the refilling process, significant plastic flow and thermo-compressive behavior promoted geometric and continuous dynamic recrystallization behaviors and highly oriented (111) microstructures, serving as key mechanisms to prevent work-hardening loss and reinforce the joint. Furthermore, the refinement of the grain size without work-hardening loss, increased by 50.8 % which was from 61 Hv in the base material to 92 Hv in the thermo-mechanically affected zone (TMAZ). Even, the hardness of the TMAZ/stir zone interface noticeably increased up to 138 Hv as the reduction in the stacking fault energy (SFE) due to the infiltration of Al element at the trace from the tool. The contribution of microstructural features to the mechanical property was quantitatively investigated by a modified Hall-Petch relationship in terms of the grain size, sub-grain size, and dislocation density. This study systematically investigated the driving forces for the implementation of Cu-to-Cu direct bonding, where work-hardening loss can be suppressed, through the RFSSW process from the perspective of dynamic recrystallization behavior and SFE due to partial alloying of Al elements.

Effect of Bias Arc on Microstructure and Corrosion Resistance of Q235/304 Dissimilar-Steel-Welded Joints.

To fully exploit the advantages of steel, the welding connection of dissimilar steels has been developed. In this work, the metallographic microstructures, elemental distributions, and electrochemical corrosion properties of the Q235 and 304 welds under different bias arcs were investigated. The arc bias caused the Q235-side heat-affected zone to widen, the microstructure consisted of ferrite and pearlite, and the ratio varied with decreasing distance from the fusion line. Elemental scans show that Cr and Ni concentration gradients exist near the fusion line. The 304-stainless-steel-side heat-affected zone was mainly composed of austenite grains, and the fusion zone was narrower but prone to cracking. Electrochemical tests revealed that 304 stainless steel had the best corrosion resistance, while Q235 had the worst corrosion resistance, and that the welded joints with an arc bias toward the 304 side had the best corrosion resistance. The samples' the passivation film which formed via electrochemical polarization had limited stability, but the over-passivation potential could be used as a reference for corrosion resistance. Overall, the arc bias and weld material properties significantly affected the microstructure and corrosion resistance of the joints.

Electron beam welding of the novel L12 nanoparticles-strengthened medium-entropy alloy Ni41.4Co23.3Cr23.3Al3Ti3V6: Microstructures, mechanical properties, and fracture

Although low levels of vanadium-doping can enhance the friction stress and strength of L12-nanoparticles strengthened medium-entropy alloys (MEA), how high concentrations of vanadium affect the weldability, microstructure, mechanical properties, and fracture behavior remains unknown. In this work, we designed a vanadium-doped, L12-nanoparticle-strengthened MEA Ni41.4Co23.3Cr23.3Al3Ti3V6 (at.%), which showed a high fracture toughness of 238 MPa × m1/2, a high friction stress of 410 MPa, and a Hall-Petch strengthening coefficient of 782 MPa × μm1/2. Pieces of the HEA were joined using electron-beam welding (EBW). Strong yet ductile defect-free joints were produced which had coarse columnar grains (88 μm) with a {110}<001> texture in the fusion zone, which was larger than the equiaxed grains in the heat-affected zones (14.9 μm) which had strong {110}<001> and relatively weak {110}<112> texture. In contrast, the base materials had fine grains (2.2 μm) with a strong {110}<111> and a relatively weak {110}<112> texture. The EBWed MEA showed a high yield strength of 599 MPa, a high ultimate tensile strength of 939 MPa, a good fracture strain of 20 %, and a fracture toughness of 198 MPa × m1/2, which were 75 %, 83 %, 58 %, and 83 %, respectively, of the values of for the thermo-mechanically treated counterpart. The reduced strength arose from the coarse columnar grains, while the reduced fracture strain and fracture toughness could be ascribed to the reduced deformation twinning and the absence of annealing twins, which produced a poor strain hardening capability. The EBWed MEA exhibited abundant dislocation networks, indicating that a high concentration of vanadium inhibited the occurrence of stacking faults and nanoscale deformation twins.

A novel method for fully penetrated U-rib-to-deck joints: Single-sided oscillating laser arc hybrid welding

U-rib-to-deck (RTD) joints represent one of the most critical and vulnerable welding details of orthotropic steel decks. Aiming for full penetration and high-level service performance, a novel method with single-sided oscillating laser-arc hybrid welding (OLAHW) technique was proposed for the RTD joint. The weld formation, microstructure and mechanical properties were extensively investigated. The results indicated that the porosity and lack of fusion (LoF) defects effectively suppressed with the beam oscillation during LAHW process. The OLAHW technique has good spatial accessibility with larger laser beam incidence angle of 20° Beam oscillation led to an increase in acicular ferrite in the fusion zone (FZ) while simultaneously a reduction of martensite in the heat effected zone (HAZ). This was related to the cooling time, and the thermal simulation results revealed that the OLAHW sample demonstrated comparable cooling times in both the Laser-FZ and arc-FZ. Consequently, beam oscillation can generated more homogeneous microstructures and microhardness. Although the microhardness of the OLAHW sample in the FZ was increased compared to the conventional arc welding (CAW) and LAHW sample, the highest microhardness value remained within acceptable limits (380 HV). Moreover, the ultimate tensile strength of the OLAHW weld sample increased by 7 % compared to the CAW weld sample. The application of the OLAHW technique demonstrates its feasibility for engineering applications in orthotropic steel decks manufacturing.

Electron Beam Welding of Copper and Aluminum Alloy with Magnetron Sputtered Titanium Filler

In this work, the results from the electron beam welding of copper and Al6082T6 aluminum alloy with a titanium filler are presented. The influence of the filler on the structure and mechanical properties of the welded joint is studied in comparison with one without filler. The X-ray diffraction (XRD) method was used to obtain the phase composition of the welded joints. Scanning electron microscopy (SEM) was used for the study of the microstructure of the welds. Energy-dispersive X-ray spectroscopy (EDX) was applied to investigate the chemical composition. The mechanical properties were studied by means of microhardness measurements and tensile tests. A three-phase structure was obtained in the fusion zone consisting of an aluminum matrix, an intermetallic compound CuAl2, and pure copper. The application of Ti filler significantly decreased the amount of molten copper introduced in the molten pool and the number of intermetallic compounds (IMCs). This improved the strength of the joint; however, some quantity of IMCs was still present in the zone of fusion (FZ), which reflected the microhardness of the samples. The application of a titanium filler resulted in refining the electron beam weld’s structure. The finer structure and the reduced amount of the brittle intermetallic phases has led to an increase in the strength of the joint.

Combined effects of local residual stresses, internal pores, and microstructures on the mechanical properties of laser-welded Ti-6Al-4V sheets

Laser-welded Ti-6Al-4 V is prone to severe residual stresses, microstructural variation, and structural defects which are known detrimental to the mechanical properties of weld joints. Residual stress removal is typically applied to weld joints for engineering purposes via heat treatment, in order to avoid premature failure and performance degradation. In the present work, we found that proper welding residual stresses in laser-welded Ti-6Al-4 V sheets can maintain better ductility during uniaxial tension, as opposed to the stress-relieved counterparts. A detailed experimental investigation has been performed on the deformation behaviours of Ti-6Al-4 V butt welds, including residual stress distribution characterizations by focused ion beam ring-coring coupled with digital image correlation (FIB-DIC), X-ray computerized tomography (CT) for internal voids, and in-situ DIC analysis of the subregional strain evolutions. It was found that the pores preferentially distributed near the fusion zone (FZ) boundary, where the compressive residual stress was up to -330 MPa. The removal of residual stress resulted in a changed failure initiation site from the base material to the FZ boundary, the former with ductile and the latter with brittle fracture characteristics under tensile deformation. The combined effects of residual stresses, microstructures, and internal pores on the mechanical responses are discussed in detail. This work highlights the importance of inevitable residual stress and pores in laser weld pieces, leading to key insights for post-welding treatment and service performance evaluations.

Mechanism clarification and mitigation measures of radial deformation induced by girth welding of thin-walled pipes

Girth welding is extensively utilized in connecting pipeline structures. Excessive welding deformation may result in a decrease in ultimate bearing capacity and fatigue life. This research explores the characteristics and underlying mechanics of radial deformation in thin-walled girth welded pipes and proposes mitigation measures. Initially, several 304 stainless steel pipes were joined utilizing four distinct welding procedures. Welding deformation and residual stress distribution were measured using a 3D coordinate measuring machine (CMM) and the Cos α X-ray diffraction (XRD) method, respectively. Subsequently, numerical models were developed to simulate the welding process and verify the accuracy of the fusion zone, residual stress field, and radial deformation in the models. The mechanism of radial deformation was further elucidated based on the inherent strain method. The results show that the direction of radial deformation relies substantially on the hoop plastic strain. Hoop tensile plastic strain corresponds to radial outward deformation, while hoop shrinkage plastic strain corresponds to radial inward deformation. In addition, the influence of axial constraint on the formation process and results of hoop plastic strain, as well as the effect of heating zone width on radial deformation, was studied. Through simulation outcomes, the research suggests employing a regulated heat source method to mitigate radial deformation, which could potentially reduce deformation by 92.8%, offering considerable advantages in deformation mitigation and welding efficiency augmentation.

Investigating laser and ultrasonic welding of pouch cell multi-foil current collectors for electric vehicle battery fabrication

The escalating necessity for more efficient and defect-free joining of ‘ultra-thin foil collectors-to-tabs’ in electric vehicle (EV) Li-ion pouch cells motivates this study. The prevalent ultrasonic welding (USW) method for these joint types, faces limitations such as design constraints and access requirements, laser welding (LW) emerges as a promising alternative offering flexibility, one-side access and faster speeds with efficient heat input. This study aims to investigate the feasibility of LW as a viable alternative to USW for joining current collectors-to-tab joints. It compares the mechanical, metallurgical, electrical and thermal analysis of the joints to evaluate both welding techniques for joint defects. The comparison of solid-state material mixing during USW and the intermixing of aluminium (Al) and copper (Cu) during fusion LW using EDX analysis presents interesting observations in the study. The USW generates a thin transition layer with intermetallic compounds (IMCs) attributed to the diffusion of Cu into the Al matrix during joining, which is comparatively lower as in the case of LW with higher material mixing with brittle IMCs like Al2Cu and Al4Cu9. However, the joint strength of LW is comparatively lower than the USW joint attributed to the reduced fusion zone area. Furthermore, from the electrical contact resistance and the joint temperature analysis, it was found that the resistance and temperature vary by as much as 13% and 6%, respectively, for the 50 A and 75 A passing currents when the USW is replaced with the LW process.

Microstructure and mechanical properties in electron beam scanning welded joints of super thick titanium alloy plates

It is generally difficult to obtain good weld formation and excellent properties in super thick titanium alloy joints via conventional electron beam welding (EBW) methods due to the fact that the melt pool flow becomes more unstable as the plate thickness increases. In this study, electron beam scanning welding (EBSW) was utilized to weld 100 mm Ti–6Al–3Nb–3Zr–1Mo titanium alloy plates to improve the weld formation and impact toughness through the scanning effect. The results revealed that there were spatter and cutting defects on the surface and inner pore defect in the normal EBW joint, which could be effectively eliminated via EBSW. The decrease of the amplitude of the fluid flow rate and the change of the velocity direction were mainly responsible for this. A large amount of lamellar α phase with similar orientation was formed in the fusion zone (FZ) due to the fast cooling rate. The joint coefficient for both EBSW and EBW reached 100%, with the joint tensile strength of ∼840 MPa. The impact energy of the FZ in the EBSW joint was 70.5 J, reaching 210.4% of that of the BM (33.5 J). The impact toughness increase ratio in this study was far larger than those for Ti alloy welds ever reported, which was mainly attributed to that the high angle α colony boundaries with high preferred orientation in the FZ deflected the crack propagation direction. This study provides a reference for the strength-toughness design of EBWed joints of super thick Ti6331 titanium alloy.

Microstructural analysis and mechanical characterization of dissimilar welds between nickel-based and steel-based superalloys post-cryogenic treatment using hotwire GTAW

This study explores the dissimilar welding of nickel superalloy 59 with Fe-Ni superalloy 904 L using the Gas Tungsten Arc Welding with Hot Wire technique (HW-GTAW). The HW-GTAW process produced defect-free weldments with complete penetration, as confirmed by macroscopic analysis. Microstructural analysis using FESEM and EDS revealed fine equiaxed and columnar dendrites in the fusion zone and identified a secondary phase enriched with chromium. XRD analysis supported the presence of predominant austenitic phases and indicated the formation of Cr23C6-type carbide. The grain size of the weld joint, determined using the Gaussian method and Scherer formula, was 44.53 nm, slightly smaller than base metals. Microhardness tests revealed values ranging from 226 ± 5 HV 10 to 243 ± 5 HV 10, with the highest values observed in the deep cryogenic treatment (DCT). The Mo in the ERNiCrMo-13 filler and the effects of DCT, which promote grain refinement, are responsible for this increase in hardness. Residual stress measurements revealed a maximum tensile stress of 315 MPa along the longitudinal axis and a maximum compressive stress of 355 MPa along the transverse axis. DCT enhanced the weldment’s tensile strength by up to 12% compared to as-welded samples, with a 6% increase compared to shallow cryogenic-treated (SCT) samples. Charpy impact testing indicated a value of 88 J in the fusion zone, which is 1.2% less than alloy 59 and 9% higher than 904 L. Tensile fracture analysis revealed ductile dimples, while impact fractography showed a mix of ductile dimples and brittle, glassy cleavage facets.

Effect of building orientation on weld characteristics of additively manufactured 316L stainless steel: Microstructure and mechanical properties

In this study, the influence of building orientation of additively manufactured 316L stainless steel (SS) welded joints was investigated. Laser powder bed fusion (LPBF) technique was employed to print 316L SS plates in three different building orientations (BO): horizontal, inclined at 45°, and vertical directions. Subsequently, the welding processing of the printed 316L plates were conducted in various directions to the building orientations, i.e., the weld directions were perpendicular to the built layer (W90D) in horizontal specimens, parallel (W0D) in the vertical specimens, and oriented with 45° (W45D) to the inclined layers. The microstructure features were characterized using electron backscattered diffraction (EBSD) and laser confocal scanning microscopy (LCSM). The mechanical properties were evaluated through tension tests and hardness measurements. Fracture mode after tensile testing was examined by scanning electron imaging.The microstructural analysis revealed that the fusion zone (FZ) consisted of a predominantly austenitic matrix with the presence of 1–4% δ-ferrite. The FZ of the W0D joints exhibited fine grain structure and lowest dendrites arm spacing as compared to W90D and W45D. The hardness measurements in the FZ of W90D and W45D are 143 ± 5 and 155 ± 6 HV, respectively. These values were lower than the hardness of W0D joints, which measured 180 ± 7 HV. During tensile testing, the W90D and W45D joints were observed to fracture at the FZ, recording ultimate tensile strength (UTS) of 531 and 548 MPa, respectively. In contrast, the W0D joints fractured outside the FZ, displaying a lower UTS of 492 MPa. Furthermore, the welded joints displayed a ductile fracture mode, while W0D joints showed a very fine dimple structure, indicative of a different failure mechanism.

Pitting behavior of austenitic stainless-steel welded joints with dense inclusions and methods to enhance pitting resistance

PurposeThis study aims to assess the pitting resistance of austenitic stainless steel welded joints fusion zone (FZ) with high density of inclusions before and after surface treatment, including potentiostatic pulse technique (PPT) and pickling.Design/methodology/approachThe potentiodynamic polarization tests and critical pitting temperature tests were carried out for estimating pitting resistance. The PPT and pickling were performed as surface treatment. Scanning electron microscope (SEM) and energy dispersive spectrometer were used for characterize the microstructure and elemental distribution. Electron back-scattered diffraction (EBSD) was used to assess the portion of phases and morphology of grains.FindingsThe weld metal exhibits a higher degree of alloying compared to the base metal, and it contains d-phase and sulfur-containing inclusions. Sulfur-containing inclusions serve as initiation sites for pitting, and they diminish the pitting resistance of weld metal. Both PPT and pickling can remove sulfur-containing inclusions, but PPT causes localized dissolution of the weld metal matrix around the inclusions, while pickling does not. Because of the high density of inclusions, certain pits initiated by PPT are significantly deeper, which makes the formation of stable pitting easier. Because of the high density of inclusions, certain pits initiated by the PPT are deeper. This characteristic facilitates the progression of these initial defects into fully developed, stable pits.Originality/valueAnalysis of pitting initiation in shielded metal arc welding FZ with PPT and ex situ SEM tracking observation. Explanation of why the PPT surface treatment is not able to enhance the pitting resistance of stainless steel with a high inclusion density.

Study on Microstructure and Properties of LZ50 Axle Steel Repaired by Laser Additive Remanufacturing

ER308L stainless steel welding wire was used for laser repair of LZ50 train axle steel sample. A large number of defects, such as microcracks, pore shrinkage and porosity, can be found in the re-manufacturing sample. A wave-like structure was formed at the boundary of the fusion zone between the augmented repair material and the base material, and the structure in this zone was consist of about 83% martensite and about 17% austenite, In the ER308L stainless steel welding wire repair zone, columnar equiaxed crystals with different lengths and morphology were formed, all of which pointed to the center of the molten pool. After repair, the tensile strength of the specimens decreased from 601.34MPa to 427.81MPa, and the elongation decreased from 16% to 5%, The fracture mode was a combination of ductile fracture and brittle fracture.

Effect of Swing Amplitude on Microstructure and Properties of TC4 Titanium Alloy in Laser Welding

The welding of TC4 titanium alloy sheets with a thickness of 1 mm was successfully accomplished by a swinging laser. The microstructure and mechanical properties of the welding seam under different swing amplitudes were studied. In this paper, the microstructure, phase composition, mechanical properties, and fracture morphology of the weld with swing frequency of 50 Hz and different swing amplitudes (0.2 mm, 1 mm, 2 mm, and 3 mm) were tested and analyzed. The results show that basket-weave microstructures are present in the fusion zone of welds under different oscillation amplitudes, but the morphology of martensite within the basket-weave differs. The weld microstructure is mainly composed of acicular α′ martensite, initial α phase, secondary α phase, and residual β phase. The hardness of the weld is higher than that of the base metal, and the overall hardness decreases from the weld center to the base metal. When the oscillation amplitude A = 1 mm, the weld microstructure has the smallest average grain size, the highest microhardness (388.86 HV), the largest tensile strength (1115.4 MPa), and quasi-cleavage fracture occurs. At an oscillation amplitude of A = 2 mm, the tensile specimen achieves the maximum elongation of 14%, with ductile fracture as the dominant mechanism.

Flux-cored arc welding of 316L austenitic stainless steel: the effect of different shielding gas mixtures on microstructural features and weld performance

ABSTRACT Double-pass flux cored arc welding (FCAW) of 316 L austenitic stainless steel was performed using different shielding gas mixtures. Microstructural features and weld performance were evaluated. Based on the Creq/Nieq ratio of fusion zone and cooling rate, different morphologies of ferrite (skeletal, lathy, and dendritic) and austenite with various volume fractions were produced. An increase in Creq/Nieq ratio can increase the strength level because the presence of ferrite in the weld metal acts as a second-phase strengthening agent. On the other hand, ferrite is a suitable place for sigma phase precipitation. Highest joint efficiency resulted in the specimen welded via GTAW. The ductility of welds was ranked as CO2 +Ar shielded FCAW > GTAW > CO2 shielded FCAW > self-shielded FCAW. At room temperature, variation of delta-ferrite content (Creq/Nieq ratio) does not affect toughness. However, an increased amount of CO2 in shielding gas will result in decreased toughness values because of the enhanced formation of oxide inclusions. Increasing CO2 content of shielding gas from 0% to 18% and finally to 100% will result in decreasing toughness values from the highest value of 76J to 40 J and finally the lowest value of 38J.

Study on the effect of Sc and Zr addition on microstructure, mechanical property and fracture behavior of electron beam welded Be-Al alloys

Because of various excellent properties of low density, high specific strength and stiffness, high modulus, good thermal stability and corrosion-resistant, beryllium-aluminum (Be-Al) alloys have shown great potential to be used in nuclear industries. However, Be-Al alloys suffer from the bottlenecks of low solubility between Be and Al and the lack of effective technology for fabricating large-sized products. Herein, based on Sc and Zr addition, Be-Al-Sc-Zr alloys are successfully fabricated by conducting the electron beam welding (EBW) technology, and the effect of Sc and Zr addition on microstructure, mechanical property and fracture behavior of Be-Al-Sc-Zr alloys are studied. Microstructural characterizations show that both the EBWed Be-Al and Be-Al-Sc-Zr alloys exhibit two distinct zones of substrate zone (SZ) and fusion zone (FZ). Compared to grain size of the SZ and FZ in Be-Al alloys, grain sizes of these two zones in Be-Al-Sc-Zr alloys are significantly refined, thus leading to ultimate tensile strength (UTS) of the Be-Al-Sc-Zr alloys (∼176 MPa) approximately 150 % higher than that of the Be-Al alloys (∼118 MPa). Besides, a newly generated third phase (TP), which is confirmed as Be13(Scx, Zr1-x), forms within Al phase in both SZ and FZ of the Be-Al-Sc-Zr alloys. Different from fracture behavior of Be-Al alloys that preferentially fractures within Al phase or near the Be/Al interface, fracture of the Be-Al-Sc-Zr alloys is prone to occur within Be phase. As revealed by the calculation results of finite element method (FEM), the underlying mechanism for different fracture behaviors mainly ascribe to that the reinforcement of Al phase and existence of the newly formed TP can greatly increase the internal stress and even causes stress concentration within Be phase of the Be-Al-Sc-Zr alloys. The present findings may provide more insights to the micro-alloying and deformation mechanism of Be-Al alloys that with enhanced mechanical properties.

Microstructural investigation of nanocrystalline Nd-Fe-B magnets fabricated by laser powder bed fusion

Nd-Fe-B magnets were manufactured by laser powder bed fusion (LPBF) using commercially available spherical powder (MQP-S-11-9). The magnets were manufactured at four different volume energy densities but similar relative densities to investigate the relations between the process, structure, and characteristics. Unlike the nanocomposite microstructure of the initial powder, the microstructure of the LPBF samples had (Nd, Pr)2Fe14B grains separated by grain boundary phases through the remelting and solidification of the initial powder. The cooling rate of the melt pool increased as the volume energy density decreased, suppressing the crystallization of α-Fe in the grain boundary phase. When the volume energy density was less than 86 J/mm3, the crystallization of α-Fe was fully suppressed, and the grain boundary phases became amorphous, resulting in higher coercivity than that of the initial powder. The magnet with the strongest magnetic properties of Hci = 10.3 kOe, Br = 6.2 kG, and (BH)max = 7.5 MGOe was produced when LPBF was performed under the conditions of P90, V500, H70, and L30 (volume energy density = 85.7 J/mm3). The solidification behavior of Nd-Fe-B magnets during LPBF was analyzed in detail using thermodynamic simulations. In this study, the microstructure of the fusion zone (FZ) and the heat affected zone (HAZ) according to process parameters was analyzed, and the effect of the solidification microstructure on the magnetic properties of Nd-Fe-B magnets was reported.