Multi-material Directed Energy Deposition of new high-performance components is limited by phase incompatibilities between metals and by the composition variations which complicate parameter optimization. In this work, a methodology of incorporation of a graded Multi-Material Compatibility Interface (MMCI) was employed to allow deposition of tungsten layers (melting at 3410 °C) on a much less refractory metal, copper (boiling at 2562 °C). The manufacturing of parts combining tungsten and copper is of interest for components designed to dissipate heat in extreme environments, such as the divertor for tokamak fusion reactors. A succession of miscible filler metals rationally selected from thermodynamics were printed by laser and powder injection, with optimization of energy and material inputs for each layer, supported by material characterization and physical numerical analysis of the process phenomenology. 90 %wt. tungsten layer deposition on a copper initial substrate is achieved using an MMCI with 6 intermediate layers and 1.6 mm total thickness. The results reveal the importance of controlling the dilution ratio to achieve stable depositions of multi-material with compositional gradients, with a progressive increase in melt pool temperatures. The numerical analysis highlighted the important role of the dissolution and mixing of partially melted refractory powders, and the selective vaporization of volatile elements.
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