MECHANICAL PROPERTIES OF POROUS SILICON CARBIDE CERAMICS: A REVIEW

Abstract

Porous silicon carbide (SiC)-based ceramics exhibit exceptional structural and functional properties, such as excellent mechanical, chemical, and thermal stability, and controlled electrical resistivity. Owing to their superior properties, porous SiC ceramics are suitable for various industrial applications, including heatable filters, heating elements, thermoelectric energy converters, fusion reactors, thermal insulators, water purifiers, molten metal and hot gas filters, diesel particulate filters, membrane supports, and catalyst supports. A deeper understanding of the mechanical properties of porous SiC ceramics, coupled with the development of new strategies for tuning these properties, will enable the realization of numerous new applications. In this review, important factors known to determine the mechanical strength of porous SiC ceramics, such as microstructures (necking area) and pore characteristics (porosity, pore size), have been analyzed. With increasing porosity and pore size of porous SiC ceramics, the flexural strength tends to decrease. The flexural strength increases with decreasing pore size at a constant porosity, whereas the flexural strength decreases with increasing porosity at a constant pore size. In addition, the flexural strength of porous SiC ceramics is primarily influenced by the developed necking area between SiC grains, which can be obtained through the doping of soluble atoms into the SiC lattice. Based on these critical factors affecting the mechanical properties, a novel strategy for tuning the flexural strength of porous SiC ceramics is proposed.