The emerging multi-axis fused deposition modeling (FDM) printing process is a powerful technology for fabricating complicated 3D models that otherwise would require extensive support structures or suffer the severe stair-case effect if printed on a conventional three-axis FDM printer. However, because of the addition of two rotary axes which enables the printing nozzle to change its orientation continuously, and the fact that the printing layer is now curved, determining how a nozzle printing path to cover the layer becomes a non-trivial issue, since the rotary axes of the printer in general have a much worse kinematic capacity than the linear axes. In this paper, specifically targeting robotic printing, we first propose an efficiency indicator called the material deposition rate which considers both the local geometry of the layer surface and the kinematic capacities of the printer. By maximizing this indicator globally, a best drive plane direction is found, and then the classic iso-planar method is adopted to generate the printing path for the layer, which not only upholds the specified printing quality but also strives to maximize the kinematic capacities of the printer to minimize the total printing time. Preliminary experiments in both computer simulation and physical printing are carried out and the results give a positive confirmation on the proposed method.