Frost Point Hygrometer Research Articles

The SPARC water vapour assessment II: biases and drifts of water vapour satellite data records with respect to frost point hygrometer records

Abstract. Satellite data records of stratospheric water vapour have been compared to balloon-borne frost point hygrometer (FP) profiles that are coincident in space and time. The satellite data records of 15 different instruments cover water vapour data available from January 2000 through December 2016. The hygrometer data are from 27 stations all over the world in the same period. For the comparison, real or constructed averaging kernels have been applied to the hygrometer profiles to adjust them to the measurement characteristics of the satellite instruments. For bias evaluation, we have compared satellite profiles averaged over the available temporal coverage to the means of coincident FP profiles for individual stations. For drift determinations, we analysed time series of relative differences between spatiotemporally coincident satellite and hygrometer profiles at individual stations. In a synopsis we have also calculated the mean biases and drifts (and their respective uncertainties) for each satellite record over all applicable hygrometer stations in three altitude ranges (10–30 hPa, 30–100 hPa, and 100 hPa to tropopause). Most of the satellite data have biases <10 % and average drifts <1 % yr−1 in at least one of the respective altitude ranges. Virtually all biases are significant in the sense that their uncertainty range in terms of twice the standard error of the mean does not include zero. Statistically significant drifts (95 % confidence) are detected for 35 % of the ≈ 1200 time series of relative differences between satellites and hygrometers.

Technical note: On HALOE stratospheric water vapor variations and trends at Boulder, Colorado

Abstract. This study compares time series of stratospheric water vapor (SWV) data at 30 and 50 hPa from 1993 to 2005, based on sets of Halogen Occultation Experiment (HALOE) profiles above the region of Boulder, CO (40∘ N, 255∘ E), and on local frost-point hygrometer (FPH) measurements. Their differing trends herein agree with most of the previously published findings. FPH trends are presumed to be accurate within their data uncertainties, and there are no known measurement biases affecting the HALOE trends. However, the seasonal sampling from HALOE is deficient at 40∘ N from 2001 to 2005, especially during late winter and springtime, when HALOE SWV time series at 55∘ N clearly show a springtime maximum. This study finds that the SWV trends from HALOE and FPH measurements nearly agree within uncertainties at 30 hPa for the more limited time span of 1993 to 2002. Yet, HALOE SWV at 50 hPa has significant and perhaps uncertain corrections for interfering aerosols from 1992 to 1994. Northern Hemisphere time series and daily SWV plots near 30 hPa from the Limb Infrared Monitor of the Stratosphere (LIMS) experiment indicate that there is transport of filaments of high SWV from polar to middle latitudes during dynamically active winter and springtime periods. Although FPH measurements sense SWV variations at all scales, the HALOE time series do not resolve smaller-scale structures because its time series data are based on an average of four or more occultations within a finite latitude–longitude sector. It is concluded that the variations and trends of HALOE SWV are reasonable at 40∘ N and 30 hPa from 1993 to 2002 and in accord with the spatial scales of its measurements and sampling frequencies.

Determination of Cirrus Occurrence and Distribution Characteristics Over the Tibetan Plateau Based on the SWOP Campaign

AbstractBalloon sounding with the Compact Optical Backscatter Aerosol Detector (COBALD) and Frost Point hygrometers (FPs) provides in situ data for a better understanding of the vertical distribution of cirrus clouds. In this study, eight summer balloon‐borne measurements in Kunming (2012, 2014, 2015, and 2017) and Lhasa (2013, 2016, 2018, and 2020) over the Tibetan Plateau were used to show the distribution characteristics of cirrus clouds. Differences of cirrus occurrence were compared by different indices: the backscatter ratio (BSR) at a 455 nm/940 nm wavelength (BSR455 > 1.2/BSR940 > 2), the color index (CI > 7), and the relative humidity with respect to ice (RHice > 70%). Analysis of the profiles indicated that BSR455 > 1.2 was the optimal criterion to identify the cirrus layer and depict the distribution of the CI and RHice within cirrus clouds. The results showed that the median CI (RHice) within the cirrus clouds at both sites was mostly in the 18–20 (90%–110%) range at pressures below 120 hPa. Furthermore, the balloon‐borne measurements combined with Cloud‐Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) measurements indicated a high frequency of cirrus occurrence near the tropopause in Kunming and Lhasa. The top height of cirrus occurrence at both sites was above the cold point tropopause and the lapse rate tropopause. Both Kunming and Lhasa had the highest frequency of thin cirrus clouds in the 0–0.4 km vertical cirrus thickness range.

M2‐SCREAM: A Stratospheric Composition Reanalysis of Aura MLS Data With MERRA‐2 Transport

AbstractThe MERRA‐2 Stratospheric Composition Reanalysis of Aura Microwave Limb Sounder (M2‐SCREAM) is a new reanalysis of stratospheric ozone, water vapor, hydrogen chloride (HCl), nitric acid (HNO3) and nitrous oxide (N2O) between 2004 and the present (with a latency of several months). The assimilated fields are provided at a 50‐km horizontal resolution and at a three‐hourly frequency. M2‐SCREAM assimilates version 4.2 Microwave Limb Sounder (MLS) profiles of the five constituents alongside total ozone column from the Ozone Monitoring Instrument. Dynamics and tropospheric water vapor are constrained by the MERRA‐2 reanalysis. The assimilated species are in excellent agreement with the MLS observations, except for HNO3 in polar night, where data are not assimilated. Comparisons against independent observations show that the reanalysis realistically captures the spatial and temporal variability of all the assimilated constituents. In particular, the standard deviations of the differences between M2‐SCREAM and constituent mixing ratio data from The Atmospheric Chemistry Experiment Fourier Transform Spectrometer are much smaller than the standard deviations of the measured constituents. Evaluation of the reanalysis against aircraft data and balloon‐borne frost point hygrometers indicates faithful representations of small‐scale structures in the assimilated water vapor, HNO3 and ozone fields near the tropopause. Comparisons with independent observations and a process‐based analysis of the consistency of the assimilated constituent fields with the MERRA‐2 dynamics and with large‐scale stratospheric processes demonstrate the utility of M2‐SCREAM for scientific studies of chemical and transport variability on time scales ranging from hours to decades. Analysis uncertainties and guidelines for data usage are provided.

The SPARC Water Vapor Assessment II: assessment of satellite measurements of upper tropospheric humidity

Abstract. Nineteen limb-viewing data sets (occultation, passive thermal, and UV scattering) and two nadir upper tropospheric humidity (UTH) data sets are intercompared and also compared to frost-point hygrometer balloon sondes. The upper troposphere considered here covers the pressure range from 300–100 hPa. UTH is a challenging measurement, because concentrations vary between 2–1000 ppmv (parts per million by volume), with sharp changes in vertical gradients near the tropopause. Cloudiness in this region also makes the measurement challenging. The atmospheric temperature is also highly variable ranging from 180–250 K. The assessment of satellite-measured UTH is based on coincident comparisons with balloon frost-point hygrometer sondes, multi-month mapped comparisons, zonal mean time series comparisons, and coincident satellite-to-satellite comparisons. While the satellite fields show similar features in maps and time series, quantitatively they can differ by a factor of 2 in concentration, with strong dependencies on the amount of UTH. Additionally, time-lag response-corrected Vaisala RS92 radiosondes are compared to satellites and the frost-point hygrometer measurements. In summary, most satellite data sets reviewed here show on average ∼30 % agreement amongst themselves and frost-point data but with an additional ∼30 % variability about the mean bias. The Vaisala RS92 sonde, even with a time-lag correction, shows poor behavior for pressures less than 200 hPa.

Stratospheric Moistening After 2000

AbstractThe significant climate feedback of stratospheric water vapor (SWV) necessitates quantitative estimates of SWV budget changes. Model simulations driven by the newest European Centre for Medium‐Range Weather Forecast reanalysis ERA5, satellite observations from the Stratospheric Water and OzOne Satellite Homogenized data set, Microwave Limb Sounder, and in situ frost point hygrometer observations from Boulder all show substantial and persistent stratospheric moistening after a sharp drop in water vapor at the turn of the millennium. This moistening occurred mainly during 2000–2006 and SWV abundances then remained high over the last decade. We find strong positive trends in the Northern Hemisphere and weak negative trends over the South Pole, mainly during austral winter. Moistening of the tropical stratosphere after 2000 occurred during late boreal winter/spring, reached values of ∼0.2 ppm/decade, was well correlated with a warming of the cold point tropopause by ∼0.4 K/decade and can only be partially attributed to El Nino‐Southern Oscillation and volcanic eruptions.

Investigation and amelioration of long-term instrumental drifts in water vapor and nitrous oxide measurements from the Aura Microwave Limb Sounder (MLS) and their implications for studies of variability and trends

Abstract. The Microwave Limb Sounder (MLS), launched on NASA's Aura spacecraft in 2004, measures vertical profiles of the abundances of key atmospheric species from the upper troposphere to the mesosphere with daily near-global coverage. We review the first 15 years of the record of H2O and N2O measurements from the MLS 190 GHz subsystem (along with other 190 GHz information), with a focus on their long-term stability, largely based on comparisons with measurements from other sensors. These comparisons generally show signs of an increasing drift in the MLS “version 4” (v4) H2O record starting around 2010. Specifically, comparisons with v4.1 measurements from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) indicate a ∼ 2 %–3 % per decade drift over much of the stratosphere, increasing to as much as ∼ 7 % per decade around 46 hPa. Larger drifts, of around 7 %–11 % per decade, are seen in comparisons to balloon-borne frost point hygrometer measurements in the lower stratosphere. Microphysical calculations considering the formation of polar stratospheric clouds in the Antarctic winter stratosphere corroborate a drift in MLS v4 water vapor measurements in that region and season. In contrast, comparisons with the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) instrument on NASA's Thermosphere Ionosphere Mesosphere Energetics and Dynamics (TIMED) mission, and with ground-based Water Vapor Millimeter-wave Spectrometer (WVMS) instruments, do not show statistically significant drifts. However, the uncertainty in these comparisons is large enough to encompass most of the drifts identified in other comparisons. In parallel, the MLS v4 N2O product is shown to be generally decreasing over the same period (when an increase in stratospheric N2O is expected, reflecting a secular growth in emissions), with a more pronounced drift in the lower stratosphere than that found for H2O. Comparisons to ACE-FTS and to MLS N2O observations in a different spectral region, with the latter available from 2004 to 2013, indicate an altitude-dependent drift, growing from 5 % per decade or less in the mid-stratosphere to as much as 15 % per decade in the lower stratosphere. Detailed investigations of the behavior of the MLS 190 GHz subsystem reveal a drift in its “sideband fraction” (the relative sensitivity of the 190 GHz receiver to the two different parts of the microwave spectrum that it observes). Our studies indicate that sideband fraction drift accounts for much of the observed changes in the MLS H2O product and some portion of the changes seen in N2O. The 190 GHz sideband fraction drift has been corrected in the new “version 5” (v5) MLS algorithms, which have now been used to reprocess the entire MLS record. As a result of this correction, the MLS v5 H2O record shows no statistically significant drifts compared to ACE-FTS. However, statistically significant drifts remain between MLS v5 and frost point measurements, although they are reduced. Drifts in v5 N2O are about half the size of those in v4 but remain statistically significant. Scientists are advised to use MLS v5 data in all future studies. Quantification of interregional and seasonal to annual changes in MLS H2O and N2O will not be affected by the drift. However, caution is advised in studies using the MLS record to examine long-term (multiyear) variability and trends in either of these species, especially N2O; such studies should only be undertaken in consultation with the MLS team. Importantly, this drift does not affect any of the MLS observations made in other spectral regions such as O3, HCl, CO, ClO, or temperature.

Fluid dynamics analysis and experimental study for solar radiation error correction of sounding humidity sensor.

In order to correct the solar radiation error of relative humidity, the mainstream capacitive sounding humidity sensor HC103M2 is selected and investigated by simulation analysis and experimental verification. First, the basic theories for solar radiation error and sensor error itself are elaborated, and simulational and experimental platforms are introduced. The computational fluid dynamics (CFD) method is utilized to theoretically investigate the dry error of the humidity sensor caused by solar radiation heating, which is related to radiation intensity, altitude, and solar elevation angle as well as reflectivity, thickness, and shape of the shield. Then, in order to verify the accuracy of the simulation, an experimental platform including a humidity sensor and two temperature sensors to measure the solar radiation heating is built to analyze the relative error of humidity obtained by the CFD simulation and experiment. It is found that their maximum deviation is 3.30% and the average error is 1.94%, which indicates that the calculation using the CFD method is accurate and feasible. In order to easily and operationally predict the solar radiation heating of the humidity sensor, a back propagation (BP) neural network fusion algorithm based on three inputs of radiation intensity, air pressure, and solar elevation angle is proposed. Compared with the solar radiation heating obtained by CFD simulation, the maximum absolute error is about 0.2K, and the relative error of humidity is about ±1.30%. Finally, a case of vertical humidity profile correction considering the temperature-sensitive error of HC103M2 is analyzed. The response time of sensor measurement and the airflow into the shield are discussed as well. The corrected results after taking solar radiation heating into account are more similar to those measured by RS92 and cryogenic frost point hygrometer (CFH). This result shows that the prediction model is accurate, which may be applied to correct the dry error and further improve the accuracy of humidity measurement.

Compact and lightweight mid-infrared laser spectrometer for balloon-borne water vapor measurements in the UTLS

Abstract. We describe the development, characterization, and first field deployments of a quantum cascade laser direct absorption spectrometer (QCLAS) for water vapor measurements in the upper troposphere and lower stratosphere (UTLS). The instrument is sufficiently small (30×23×11 cm3) and lightweight (3.9 kg) to be carried by meteorological balloons and used for frequent soundings in the UTLS. The spectrometer is a fully independent system, operating autonomously for the duration of a balloon flight. To achieve the required robustness, while satisfying stringent mass limitations, the concepts for optics and electronics have been fundamentally reconsidered compared to laboratory-based spectrometers. A significant enhancement of the mechanical and optical stability is achieved by integrating a newly designed segmented circular multipass cell which allows for 6 m optical path length in a very compact fashion. The H2O volume mixing ratio is retrieved by calibration-free evaluation of the spectral data, i.e., only relying on SI-traceable measurements and absorption line parameters. The open-path design reduces the risk of contamination and allows for fast response and thus high vertical resolution. Laboratory-based characterization experiments show an agreement within 2 % of reference measurements and a precision of 0.1 % under conditions comparable to the UTLS. The instrument successfully performed two balloon-borne test flights up to 28 km altitude. In the troposphere, the retrieved spectroscopic data show an excellent agreement with the accompanying measurements by a frost point hygrometer (CFH). At higher altitude, the quality of the spectral data remained unchanged, but outgassed water vapor within the instrument enclosure was hindering an accurate measurement of the atmospheric water vapor. Despite this limitation, these test flights demonstrated the operation of a compact laser spectrometer in the UTLS aboard a low-volume meteorological balloon, opening the perspective for future highly resolved, accurate, and cost-efficient soundings.

Unprecedented Observations of a Nascent In Situ Cirrus in the Tropical Tropopause Layer

AbstractA nascent in situ cirrus was observed on January 11, 2019 in the tropical tropopause layer (TTL) over the southwestern Indian Ocean, with the use of balloon‐borne instruments. Data from cryogenic frost point hygrometer (CFH) and Compact Optical Backscatter and AerosoL Detector (COBALD) instruments were used to characterize the cirrus and its environment. Optical modeling was employed to estimate the cirrus microphysical properties from the COBALD backscatter measurements. Newly fomed ice crystals with radius <1 μm and concentration ∼500 L−1 were reported at the tropopause. The relatively low concentration and CFH ice supersaturation (1.5) suggests a homogeneous freezing event stalled by a high‐frequency gravity wave. The observed vertical wind speed and temperature anomalies that triggered the cirrus formation were due to a 1.5‐km vertical‐scale wave, as shown by a spectral analysis. This cirrus observation shortly after nucleation is beyond remote sensing capabilities and presents a type of cirrus never reported before.

A powerful lidar system capable of 1 h measurements of water vapour in the troposphere and the lower stratosphere as well as the temperature in the upper stratosphere and mesosphere

Abstract. A high-power Raman lidar system has been installed at the high-altitude research station Schneefernerhaus (Garmisch-Partenkirchen, Germany) at 2675 ma.s.l., at the side of an existing wide-range differential absorption lidar (DIAL). An industrial XeCl laser was modified for linearly polarized single-line operation at an average power of about 180 W. This high power and a 1.5 m diameter receiver allow us to extend the operating range for water-vapour sounding to 20 km for a measurement time of just 1 h, at an uncertainty level of the mixing ratio of 1 to 2 ppm. This was achieved for a vertical resolution varied between just 0.2 and 0.6 km in the stratosphere. The lidar was successfully validated with a balloon-borne cryogenic frost-point hygrometer (CFH). In addition, temperature measurements up to altitudes of around 87 km were demonstrated for 1 h of signal averaging. The system has been calibrated with the DIAL, the CFH and radiosondes.

Understanding balloon-borne frost point hygrometer measurements after contamination by mixed-phase clouds

Abstract. Balloon-borne water vapour measurements in the upper troposphere and lower stratosphere (UTLS) by means of frost point hygrometers provide important information on air chemistry and climate. However, the risk of contamination from sublimating hydrometeors collected by the intake tube may render these measurements unusable, particularly after crossing low clouds containing supercooled droplets. A large set of (sub)tropical measurements during the 2016–2017 StratoClim balloon campaigns at the southern slopes of the Himalayas allows us to perform an in-depth analysis of this type of contamination. We investigate the efficiency of wall contact and freezing of supercooled droplets in the intake tube and the subsequent sublimation in the UTLS using computational fluid dynamics (CFD). We find that the airflow can enter the intake tube with impact angles up to 60∘, owing to the pendulum motion of the payload. Supercooled droplets with radii > 70 µm, as they frequently occur in mid-tropospheric clouds, typically undergo contact freezing when entering the intake tube, whereas only about 50 % of droplets with 10 µm radius freeze, and droplets < 5 µm radius mostly avoid contact. According to CFD, sublimation of water from an icy intake can account for the occasionally observed unrealistically high water vapour mixing ratios (χH2O > 100 ppmv) in the stratosphere. Furthermore, we use CFD to differentiate between stratospheric water vapour contamination by an icy intake tube and contamination caused by outgassing from the balloon and payload, revealing that the latter starts playing a role only during ascent at high altitudes (p < 20 hPa).

Effect of monsoon dynamics and deep convection on the upper troposphere lower stratosphere water vapour over Indian monsoon region

Balloon-borne cryogenic frost-point hygrometer (CFH) observations conducted over three stations Trivandrum, Hyderabad and Kolkata in the Indian region during the period 2014–2017 are used to study the influence of deep convection and monsoon dynamics on the distribution of water vapour in the upper troposphere and lower stratosphere (UTLS) and to quantify the amount of water vapour transported to the lower stratosphere (LS) during summer-monsoon (June to September). In summer monsoon season, CFH observations show a water vapour enhancement of ~40–250% in the upper troposphere (UT) and 0.5–1 ppmv (10–40%) in the LS compared to pre-monsoon. In this season, the spatial pattern of Microwave Limb Sounder (MLS) derived water vapour mixing ratio (WVMR) at 100 hPa peaks north of the deep convection core over the head Bay of Bengal (BoB). In the LS, the water vapour maximum shows a south westward shift with altitude in accordance with the anticyclonic circulation flow. The maximum altitude of deep convective cloud top increases north eastward in accordance with the peak in tropical easterly jet (TEJ) causing the altitudinal shift in water vapour enhancement in the UT. The probability of dehydration (WVMR<3 ppmv) maximizes west of the deep convective core over Head BoB. During summer-monsoon, the day-to-day variability of water vapour in the tropical tropopause layer (TTL) is mainly controlled by the dehydration of air due to freeze drying (temperature dependent) and rehydration due to recurrent overshooting deep convections. Direct injection of water vapour into the LS region is probable when the tropopause is relatively warm (>192 K).

Far‐Ranging Impact of Mountain Waves Excited Over Greenland on Stratospheric Dehydration and Rehydration

AbstractIn situ observations of reduced stratospheric water vapor combined with those of ice particle formation are rarely conducted. On the one hand, they are essential to broaden our knowledge about the formation of polar stratospheric clouds (PSCs). On the other hand, the observed profiles allow the comparison with global circulation models. Here we report about a balloon‐borne observation above Sodankylä, Finland on 26 January 2005. The frostpoint hygrometer detected layers of reduced water vapor by up to 2 ppmv from 18.5 to 23 km. Beneath, a 1‐km‐deep layer of increased water vapor was identified. An aerosol backscatter sonde measured the presence of stratospheric ice clouds. According to meteorological analysis the PSCs were formed upstream above the east coast of Greenland due to mountain wave‐induced cooling. The inertia‐gravity waves generated a large and persistent stratospheric wake far downstream of Greenland and led to the observed dehydration. Comparing the most recent ERA5 data with operational analyses from 2005, we find an improved representation of mesoscale internal gravity waves, dehydration and PSC formation for this particular event.

Effect of deep convection on the tropical tropopause layer composition over the southwest Indian Ocean during austral summer

Abstract. Balloon-borne measurements of cryogenic frost-point hygrometer (CFH) water vapor, ozone and temperature and water vapor lidar measurements from the Maïdo Observatory on Réunion Island in the southwest Indian Ocean (SWIO) were used to study tropical cyclones' influence on tropical tropopause layer (TTL) composition. The balloon launches were specifically planned using a Lagrangian model and Meteosat-7 infrared images to sample the convective outflow from tropical storm (TS) Corentin on 25 January 2016 and tropical cyclone (TC) Enawo on 3 March 2017. Comparing the CFH profile to Aura's Microwave Limb Sounder's (MLS) monthly climatologies, water vapor anomalies were identified. Positive anomalies of water vapor and temperature, and negative anomalies of ozone between 12 and 15 km in altitude (247 to 121 hPa), originated from convectively active regions of TS Corentin and TC Enawo 1 d before the planned balloon launches according to the Lagrangian trajectories. Near the tropopause region, air masses on 25 January 2016 were anomalously dry around 100 hPa and were traced back to TS Corentin's active convective region where cirrus clouds and deep convective clouds may have dried the layer. An anomalously wet layer around 68 hPa was traced back to the southeast Indian Ocean where a monthly water vapor anomaly of 0.5 ppmv was observed. In contrast, no water vapor anomaly was found near or above the tropopause region on 3 March 2017 over Maïdo as the tropopause region was not downwind of TC Enawo. This study compares and contrasts the impact of two tropical cyclones on the humidification of the TTL over the SWIO. It also demonstrates the need for accurate balloon-borne measurements of water vapor, ozone and aerosols in regions where TTL in situ observations are sparse.

Increasing Water Vapor in the Stratosphere and Mesosphere After 2002

AbstractWater vapor (H2O) measurements made by the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) instrument between 2002 and 2018 and by the Aura Microwave Limb Sounder (MLS) instrument between 2004 and 2018 are analyzed to determine the linear trend and solar cycle response of H2O in the stratosphere and mesosphere. Both SABER and MLS show a rapid global H2O increase of 5–6% per decade in the lower stratosphere after the 2001 drop. The increasing zonal mean H2O at 40°N in SABER and MLS is consistent with the Boulder frost point hygrometer data in the lower stratosphere. The global distribution of SABER and MLS H2O trends are positive at most altitudes and latitudes, and they peak in the tropical lower stratosphere. In the mesosphere the SABER H2O trend is 0.1–0.2 ppmv per decade and the MLS H2O trend is 0.2–0.3 ppmv per decade. The trend and solar cycle response derived from the observations are compared against the Whole Atmosphere Community Climate Model (WACCM). The solar cycle response of H2O from WACCM agrees with SABER and MLS. The linear H2O trend from WACCM does not show the observed increase in the lower stratosphere.

Validation of the Water Vapor Profiles of the Raman Lidar at the Maïdo Observatory (Reunion Island) Calibrated with Global Navigation Satellite System Integrated Water Vapor

The Maïdo high-altitude observatory located in Reunion Island (21 ∘ S, 55.5 ∘ E) is equipped with the Lidar1200, an innovative Raman lidar designed to measure the water vapor mixing ratio in the troposphere and the lower stratosphere, to perform long-term survey and processes studies in the vicinity of the tropopause. The calibration methodology is based on a GNSS (Global Navigation Satellite System) IWV (Integrated Water Vapor) dataset. The lidar water vapor measurements from November 2013 to October 2015 have been calibrated according to this methodology and used to evaluate the performance of the lidar. The 2-year operation shows that the calibration uncertainty using the GNSS technique is in good agreement with the calibration derived using radiosondes. During the MORGANE (Maïdo ObservatoRy Gaz and Aerosols NDACC Experiment) campaign (Reunion Island, May 2015), CFH (Cryogenic Frost point Hygrometer) radiosonde and Raman lidar profiles are compared and show good agreement up to 22 km asl; no significant biases are detected and mean differences are smaller than 9% up to 22 km asl.

Water Vapor in the Asian Summer Monsoon Anticyclone: Comparison of Balloon‐Borne Measurements and ECMWF Data

AbstractWater vapor (H2O) is the strongest greenhouse gas in our atmosphere. Hence, accurate measurements and a correct representation in global models of H2O in the upper troposphere/lower stratosphere (UTLS) are important for understanding and projecting climate. Here we compare balloon‐borne measurements of UTLS H2O, performed by cryogenic frostpoint hygrometers (CFH) and meteorological radiosondes (Vaisala RS41) during two intensive field campaigns in the Asian summer monsoon anticyclone region, with humidity data from three products of the European Centre for Medium‐range Weather Forecasts (ECMWF): operational analysis and forecast (termed OPERA), ERA‐Interim reanalysis, and the newly released ERA5 reanalysis. Taking CFH as a reference, we show that OPERA and ERA5 provide a more accurate representation of UTLS H2O than ERA‐Interim. In particular, OPERA and ERA5 similarly overestimate H2O mixing ratios by on average 0.7–0.8 ppmv (14–15%) and 0.7–0.9 ppmv (15–17%) at pressures 60–100 hPa, respectively, and both provide a good representation of the observed vertical distribution (including fine structures) and natural variability of UTLS H2O. In contrast, ERA‐Interim underestimates UTLS H2O by 0.6–1.7 ppmv (14–30%), and it fails to capture relevant features of the vertical distribution of UTLS H2O. At pressures (p) lower than 60 hPa, all three ECMWF products are in good agreement with CFH. Humidity measurements by RS41 show an average dry bias of 0.1–0.5 ppmv (3–9%) compared to CFH for 60–100 hPa, and a moist bias increasing with altitude for p &lt; 60 hPa, exceeding 100% for p &lt; 40 hPa.

Tropospheric water vapor profiles obtained with FTIR: comparison with balloon-borne frost point hygrometers and influence on trace gas retrievals

Abstract. Retrievals of vertical profiles of key atmospheric gases provide a critical long-term record from ground-based Fourier transform infrared (FTIR) solar absorption measurements. However, the characterization of the retrieved vertical profile structure can be difficult to validate, especially for gases with large vertical gradients and spatial–temporal variability such as water vapor. In this work, we evaluate the accuracy of the most common water vapor isotope (H216O, hereafter WV) FTIR retrievals in the lower and upper troposphere–lower stratosphere. Coincident high-quality vertically resolved WV profile measurements obtained from 2010 to 2016 with balloon-borne NOAA frost point hygrometers (FPHs) are used as reference to evaluate the performance of the retrieved profiles at two sites: Boulder (BLD), Colorado, and at the mountaintop observatory of Mauna Loa (MLO), Hawaii. For a meaningful comparison, the spatial–temporal variability has been investigated. We present results of comparisons among FTIR retrievals with unsmoothed and smoothed FPH profiles to assess WV vertical gradients. Additionally, we evaluate the quantitative impact of different a priori profiles in the retrieval of WV. An orthogonal linear regression analysis shows the best correlation among tropospheric layers using ERA-Interim (ERA-I) a priori profiles and biases are lower for unsmoothed comparisons. In Boulder, we found a negative bias of 0.02±1.9 % (r=0.95) for the 1.5–3 km layer. A larger negative bias of 11.1±3.5 % (r=0.97) was found in the lower free troposphere layer of 3–5 km attributed to rapid vertical change of WV, which is not always captured by the retrievals. The bias improves in the 5–7.5 km layer (1.0±5.3 %, r=0.94). The bias remains at about 13 % for layers above 7.5 km but below 13.5 km. At MLO the spatial mismatch is significantly larger due to the launch of the sonde being farther from the FTIR location. Nevertheless, we estimate a negative bias of 5.9±4.6 % (r=0.93) for the 3.5–5.5 km layer and 9.9±3.7 % (r=0.93) for the 5.5–7.5 km layer, and we measure positive biases of 6.2±3.6 % (r=0.95) for the 7.5–10 km layer and 12.6 % and greater values above 10 km. The agreement for the first layer is significantly better at BLD because the air masses are similar for both FTIR and FPH. Furthermore, for the first time we study the influence of different WV a priori profiles in the retrieval of selected gas profiles. Using NDACC standard retrievals we present results for hydrogen cyanide (HCN), carbon monoxide (CO), and ethane (C2H6) by taking NOAA FPH profiles as the ground truth and evaluating the impact of other WV profiles. We show that the effect is minor for C2H6 (bias &lt;0.5 % for all WV sources) among all vertical layers. However, for HCN we found significant biases between 6 % for layers close to the surface and 2 % for the upper troposphere depending on the WV profile source. The best results (reduced bias and precision and r values closer to unity) are always found for pre-retrieved WV. Therefore, we recommend first retrieving WV to use in subsequent retrieval of gases.

Intercomparison of Cryogenic Frost-Point Hygrometer Observations With Radiosonde, SAPHIR, MLS, and Reanalysis Datasets Over Indian Peninsula

This paper assesses the performance of water vapor measurements by Sondeur Atmospherique du Profild’ Humidite Intertropicale par Radiometrie (SAPHIR), microwave limb sounder (MLS), and the global reanalysis water vapor data [Modern Era Retrospective analysis for Research and Applications (MERRA) and European Center for Medium-Range Weather Forecasts reanalysis (ERA) interim] by comparing with water vapor-measured in situ by cryogenic frost-point hygrometer (CFH) at two tropical stations, Trivandrum (8.5°N, 76.9°E) and Hyderabad (17.47°N, 78.58°E). The iMet-1 radiosonde though overestimates frost-point temperature (3%–5%) in the 4–10-km altitude region with respect to CFH, it agrees well with CFH observations in the upper troposphere and the lower troposphere with a mean difference <2% and ~1%, respectively. SAPHIR–CFH intercomparison is done for the troposphere region, and MLS, MERRA, and ERA interim are compared with CFH in the lower stratosphere region. SAPHIR and CFH comparison shows a reasonable agreement between both the datasets with a relative humidity difference of about 15% in the lower and middle troposphere and a dry bias of ~40% in the upper troposphere. Intercomparison between CFH and MLS water vapor mixing ratios (WVMRs) shows a small wet bias (−10% to −20%) for the MLS in the lower stratospheric region between 100 and 50 hPa and a small dry bias (<10%) above that region. This paper shows that the MLS always underestimates when the CFH WVMR is greater than 6 ppmv and overestimates when the WVMR is less than 2 ppmv. The intercomparison of CFH with MERRA and ERA interim specific humidity shows results similar to that with MLS.