Mode Frequencies Research Articles

Confinement Effects of Two-dimensional Surfaces on Water Adsorption and Dissociation over Pt(111).

It has been established that the confined space created by stacking a two dimensional (2D) surface atop a metal catalyst serves as a nano-reactor. According to recent research, when a graphene (Gr) overlayer encloses a Pt catalyst from above, the activation barrier for the water dissociation reaction, a process with major industrial significance, decreases. In order to investigate how the effect of confinement varies among different two-dimensional (2D) materials, we study the adsorption and dissociation barriers of water molecule on Pt(111) under graphene, hexagonal boron nitride (h-BN), and heptazine-based graphitic carbon nitride (g-C3N4) layers using density functional theory calculations. Our findings reveal that the strength of adsorption does not decrease consistently with a reduction in the height of the 2D overlayer. Furthermore, a smaller barrier is not always the consequence of poorer adsorption of the reactant. We also examine the effect of confinement on the shape of the reaction path, on the frequencies of vibrational modes, and on the rate constants derived using the harmonic transition state theory. Overall, all three of the 2D surfaces cause a decrease in barrier height and a weakening of adsorption, though to differing degrees due to a mix of mechanical, geometric and electronic variables.

Distribution of distance-based quantum resources outside a radiating Schwarzschild black hole

Abstract This study aims to investigate the distribution of distance-based quantum resources for fermionic fields in curved Schwarzschild spacetime (SST), as well as for bosonic fields in both flat Minkowski and curved SSTs. To achieve this, we will examine the quantum resources between an observer falling into a Schwarzschild black hole (SBH) and their stationary partner, who shares a Gisin state. Additionally, we will explore the quantum resources that arise when two uniformly accelerated detectors interact with bosonic fields in the Minkowski vacuum. Furthermore, we will investigate the interactions between these detectors and bosonic fields in the Hartle–Hawking and Boulware vacuums outside the SBH. At an infinite Hawking temperature, the quantum resources for the fermionic fields degrade; the rate of degradation is dependent on the distance between the observer and the event horizon, the fermionic frequency mode, and the Gisin state parameters. In the case of the bosonic fields, our results show that entanglement decreases monotonically, either towards zero or a constant value. Moreover, with increasing Unruh temperature, coherence and discord undergo sudden death followed by a sudden birth, and entanglement cannot be revived for a given initial state. Based on our findings, it appears that the Fermi–Dirac and Bose–Einstein statistics represent the primary differences in quantum resource distribution between the fermionic and bosonic cases. These findings may be essential for enhancing our understanding of the distribution of quantum resources in relativistic frameworks.

Exploring the Small-scale Magnetic Fields in the Atmosphere of HD 49385 by Asteroseismic Analysis

Recent asteroseismic studies have shown convincing evidence that magnetic fields may exist in the interior of some pulsating red giants. Inspired by this breakthrough, we explored the effect of small-scale magnetic fields on the p-mode oscillations in an evolved star, HD 49385. We incorporate a modified Eddington T–τ equation that phenomenologically mimics the effect of the magnetic fields in the atmosphere of HD 49385, and calculate the frequencies of p-modes with l = 0, 1, and 2. By comparing the calculated frequencies with the observed ones, we select two best-fit models with either GS98 or A09 chemical composition. Our best-fit models not only fit satisfactorily the observed frequencies but also well reproduce some spectroscopically observed stellar parameters such as effective temperature and log g. Based on the two best-fit models, we have estimated that the small-scale magnetic fields possess a strength of approximately 80 G and spread concentratively at approximately a height of 1850 km in the atmosphere. By selecting the best-fit models with a special requirement on the avoided-crossing mode, we have confirmed that the frequency of the avoided-crossing mode is tightly related to the helium core of the star, and determined the size of the helium core as 0.117 M ⊙ in mass and 0.078 R ⊙ in radius. Based on the improvements of the previous two sides, we can accurately determine the mass of HD 49385 to be 1.25 ± 0.02 M ⊙ with an age of 4.1 Gyr for GS98 composition and 4.5 Gyr for A09 composition.

The novel Vogel's approximation method integrated with a random forest algorithm in the vibration analysis of a two-directional functionally graded taper porous beam: Assessment

A functionally graded material is a class of composite materials characterized by gradual variations in composition and microstructure, which further induces the respective changes in the material properties. This study focuses on evaluating the vibration behavior of two directional functionally graded taper porous beams (FGTPB). This approach adopts a rectangular cross-section in order to deal with the challenges related to fluctuating material characteristics and geometric tapering in both thickness and width dimensions. The research employs a novel approach that merges Vogel's approximation technique with the Random Forest algorithm, an approach that has not been used in analyzing structural vibrations, establish boundary conditions and solve equations of motion. Comparative results of the suggested beam theory with the existing literature on FGTPB materials such as alumina and SUS304 at various taper, porosity, gradient and width ratios verified it. The material gradation and porosity developed a uniform pattern in the first three modes of fundamental frequencies. Higher gradient indices increased the rigidity and natural frequencies of the beams whereas the porosity index decreased the rigidity, resulting in lower natural frequencies. By combining Vogel's approximation method with machine learning techniques, the study improved vibration behavior analysis in FGTPB. The disciplines of materials and structural engineering are significantly impacted by this.

Bondi-Hoyle-Lyttleton accretion around the rotating hairy Horndeski black hole

Modeling of the shock cone formed around a stationary, hairy Horndeski black hole with Bondi-Hoyle-Lyttleton (BHL) accretion has been conducted. We model the dynamical changes of the shock cone resulting from the interaction of matter with the Horndeski black hole, where the scalar field and spacetime have a strong interaction. The effects of the scalar hair, the black hole rotation parameter, and the impacts of the asymptotic speed have been examined, revealing the influence of these parameters on the shock cone and the trapped QPO modes within the cone. Numerical calculations have shown that the hair parameter significantly affects the formation of the shock cone. As the absolute value of the hair parameter increases, the matter in the region of the shock cone is observed to move away from the black hole horizon. The rate of matter expulsion increases as h/M changes. After h/M < -0.6, a visible change in the physical structure of the shock cone occurs, ultimately leading to the complete removal out of the shock cone. On the other hand, it has been revealed that the asymptotic speed significantly affects the formation of the shock cone. As h/M increases in the negative direction and the asymptotic speed increases, the stagnation point moves closer to the black hole horizon. When the value of the hair parameter changes, the rest-mass density of the matter inside the cone decreases, whereas the opposite is observed with the asymptotic speed. Additionally, the formed shock cone has excited QPO modes. The deformation of the cone due to the hair parameter has led to a change or complete disappearance of the QPOs. Meanwhile, at asymptotic speeds of V ∞/c < 0.4, all fundamental frequency modes are formed, while at V ∞/c = 0.4, only the azimuthal mode is excited, and 1:2:3:4:… resonance conditions occur. No QPOs have formed at V ∞/c = 0.6. The results obtained from numerical calculations have been compared with theoretical studies for M87*, and it has been observed that the possible values of h/M found in the numerical simulations are consistent with the theory. Additionally, the results have been compared with those for the GRS 1915+105 black hole, and the hair parameters corresponding to the observed frequencies have been determined.

Passive control of thermoacoustic instability in a high-efficiency domestic gas stove with fine-tuning burner

Thermoacoustic oscillation is a significant challenge in the development of advanced thermal power and propulsion systems. The present work focuses on the whistling phenomenon in the practical burners of a developing high-efficiency domestic gas stove. The acoustic analysis is conducted by a Helmholtz acoustic solver, identifying the 1/2 wave longitudinal mode in the outer ring or center nozzle and its upstream pipe and estimating the modal eigenfrequencies fa=599Hz and fb=647Hz which are close to the main frequency of the whistling measured in experiments. The sequential flame images captured by a high-speed camera are processed by a dynamic mode decomposition method to illustrate flame structure oscillations at the peak frequency mode. The results verify that thermoacoustic oscillations are the generation mechanism of the whistling and display the periodic fluctuation characteristics of the flame and the spatial distribution of heat release. Moreover, both structural fine-tuning designs help to achieve better suppression for thermoacoustic oscillations and avoid the whistling phenomenon. These structural fine-tuning strategies have been researched for several decades but rarely reported to be applied to industrial burners in previous work. Motivated by this, it will provide a new insight into the investigation of burner structures on thermoacoustic behaviors and the application of these passive control strategies.

Numerical and experimental investigation of silo vibration of sulfur storage

PurposeDue to the abundant use of granular materials in chemical industries, it is inevitable to store raw materials and products in bulk in silos. For this reason, much research has been carried out in the field of construction, operation and maintenance of silos. One of the important issues that must be investigated in silos is the behavior of their structure when the materials inside them are unloaded. Structural vibrations and the creation of normal noise usually discharge the granular of material from the silo. Both of phenomena are undesirable due to the problems they can cause to the structure and its surroundings. According to the said issues, this paper aims to investigate the vibration problem of the sulfur storage silo of the first refinery during discharge with the help of measuring experimental vibration data and simulating the silo model.Design/methodology/approachIn the experimental investigation, the main cause of the vibration of the 400-ton silo in the refinery is used. The mass asymmetry phenomenon when the silo is filled is also considered. The experimental results are authenticated by software analysis too.FindingsThe results showed that the natural frequency of the ninth mode is almost equal to the natural frequency of sulfur discharge from the silos and has the largest shape change in the structure and vibration range. It is also concluded that the larger sulfur silo (400 tons) should be prioritized over the smaller sulfur silo (200 tons) in the emptying program, and the 400 tons silo should never be emptied even through the 200 tons silo is empty.Originality/valueAn attempt is made to investigate the issue of vibration in sulfur storage silos in the first refinery of South Pars in the form of experimental investigation and modal analysis.

New high-field side magnetic probe array system for three-dimensional magnetic fluctuation measurements on EAST

To better study the magnetic fluctuations in the high-field side of EAST tokamak, a new high-field side magnetic probe array (HFS-MPA) has been developed on EAST recently. The HFS-MPA consists of 12 identical three-dimensional (3D) magnetic probes, which are mounted on the HFS wall with carefully designed arrangement. The HFS-MPA magnetic probes bring additional toroidal magnetic fluctuation measurements compared with the HFS regular magnetic probes which can only provide poloidal and radial magnetic fluctuation measurements. The upper limits of frequency and toroidal mode number (n) measurements of the magnetic fluctuations have been improved by comparing HFS-MPA with the HFS regular magnetic probes, i.e., 650 kHz vs 100 kHz and n = 23 vs n = 1. In developing the HFS-MPA diagnostic system, many practical challenges have been overcome and many special designs have been developed. These will be mentioned in the main subsystem description of the HFS-MPA diagnostic in this paper, which might be useful for developing new magnetic probe diagnostics in the future on EAST or other magnetically confined fusion devices. The calibration of the effective area and frequency response of the HFS-MPA is also described. The preliminary application in studying the frequency and propagation characteristics of the magnetic fluctuations with HFS-MPA compared with EAST regular magnetic probes shows that the HFS-MPA is well developed for plasma physics studies.

Weyl fermions in a (2+1)-dimensional gravitational wave spacetime

In this study, we work on understanding the behavior of relativistic fermions within the framework of a (2+1)-dimensional gravitational wave environment. Our main objective is to uncover an analytical solution for the massless Dirac equation in this particular scenario. Initially, we derive a set of coupled equations that describe the quantum dynamics of the system under consideration. Subsequently, we embark on finding an analytical solution for the resulting wave equation governing Weyl fermions by utilizing the generators associated with the [Formula: see text] algebra. This approach enables us to determine the relativistic frequency modes of the system. We then delve into examining how the parameters of the gravitational wave spacetime influence the real oscillation modes of Weyl fermions. Our findings highlight the sensitivity of Weyl fermions to the specific gravitational wave spacetime background being considered.

Modifiable and Non-Modifiable Factors That Affect Human Milk Oligosaccharides Composition.

Human milk, the gold standard in infant nutrition, is a unique fluid that provides essential nutrients such as lactose, lipids, proteins, and free oligosaccharides. While its primary role is nutritional, it also protects against pathogens. This protection mainly comes from immunoglobulins, with human milk oligosaccharides (HMOs) providing additional support by inhibiting pathogen binding to host cell ligands. The prebiotic and immune-modulatory activity of HMOs strongly depends on their structure. Over 200 individual structures have been identified so far, with the composition varying significantly among women. The structure and composition of HMOs are influenced by factors such as the Lewis blood group, secretor status, and the duration of nursing. HMO profiles are heavily influenced by maternal phenotypes, which are defined based on the expression of two specific fucosyltransferases. However, recent data have shown that HMO content can be modified by various factors, both changeable and unchangeable, including diet, maternal age, gestational age, mode of delivery, breastfeeding frequency, and race. The first part of this overview presents the historical background of these sugars and the efforts by scientists to extract them using the latest chromatography methods. The second part is divided into subchapters that examine modifiable and non-modifiable factors, reviewing the most recent articles on HMO composition variations due to specific reasons and summarizing potential future challenges in conducting these types of studies.

A stochastic Schrödinger equation and matrix product state approach to carrier transport in organic semiconductors with nonlocal electron-phonon interaction.

Evaluation of the charge transport property of organic semiconductors requires exact quantum dynamics simulation of large systems. We present a numerically nearly exact approach to investigate carrier transport dynamics in organic semiconductors by extending the non-Markovian stochastic Schrödinger equation with complex frequency modes to a forward-backward scheme and by solving it using the matrix product state (MPS) approach. By utilizing the forward-backward formalism for noise generation, the bath correlation function can be effectively treated as a temperature-independent imaginary part, enabling a more accurate decomposition with fewer complex frequency modes. Using this approach, we study the carrier transport and mobility in the one-dimensional Peierls model, where the nonlocal electron-phonon interaction is taken into account. The reliability of this approach was validated by comparing carrier diffusion motion with those obtained from the hierarchical equations of motion method across various parameter regimes of the phonon bath. The efficiency was demonstrated by the modest virtual bond dimensions of MPS and the low scaling of the computational time with the system size.

Multi-method piecewise low-frequency identification

Inter-area frequency modes of electromechanical oscillations are decisive factors that influence the performance of electrical power systems. However, the accurate estimation of these frequencies remains a challenge due to the non-linear behavior of the response system following a disturbance and the strong coupling among the frequencies. This work describes a curve fitting and electromechanical frequency estimation algorithm, called Multi-method Piecewise Identification (MPI), based on a combination of the Matrix Pencil Method (MPM), the Prony method, and Subspace Identification (SSI), choosing the best approximation of an interval basis according to the model accuracy index (MAI) and the mean square error (MSE). The advantages and limitations of MPI were analyzed by computational analyses that were carried out with Python-based code that estimates the low frequencies for several ringdown signals, including oscillating signals from Australian and Brazilian systems that arise after large disturbances. To ensure robustness to random and noisy conditions, the method was tested with a synthetic signal with Gaussian white noise and time-variant frequencies, and compared to the methods mentioned above, the Hilbert–Huang Transform (HHT), and Eigensystem Realization Algorithm (ERA). The MPI has shown robust results and is capable of obtaining a better fitting for the signal than the other methods.

Practice-oriented numerical model for seismic response of cold-formed steel-framed mid-rise buildings

Cold-formed steel (CFS) framed buildings are becoming increasingly common, notably in the high seismic regions of the United States (US). However, research to understand the seismic performance of CFS-framed buildings specifically using large-scale (building-level) specimens has begun only recently. Therefore, efforts to validate and improve numerical modeling of whole building systems have been limited due to this lack of experimental data. A recently completed experimental program, conducted at the Large High-Performance Outdoor Shake Table at the University of California, San Diego, involved earthquake testing of a full-scale 6-story CFS-framed building. The test building adopted an assembly of continuous tie-rod and built-up compression stud pack at the ends of individual shear walls to resist seismic overturning moment and uplift forces within the building. The objective of this paper is to present a practice-oriented phenomenological finite element modeling approach intended for design engineers and compare the predictions from this model against the measured seismic response of the 6-story building. The model aims to provide a robust, yet computationally efficient approach, with minimal degrees-of-freedom, while also capturing the salient features of seismic response of mid-rise CFS-framed buildings suitable for nonlinear time history analyses-based design. The building model, developed within the OpenSeesPy finite element platform, includes the shear walls and gravity walls as well as the lateral strength and stiffness contribution from exterior and interior gypsum sheathing. The continuous tie-rod system is also modeled to capture the cumulative floor displacements caused by the axial elongation in the steel rods. The effect of built-up compression stud packs on the lateral behavior of a shear wall was estimated using available experimental data and a detailed numerical model of an isolated shear wall, then subsequently incorporated in the nonlinear hysteretic material model. The numerical model captured the natural frequencies of the translation modes of the building in its undamaged state with <3% error. It also predicted the peak roof drift ratio within an error of 0.03% drift ratio under the design earthquake event. These results provide confidence in the proposed numerical modeling approach as a tool for seismic response prediction of mid-rise CFS-framed buildings with similar structural detailing features.

Oscillations of a fluid in a circular cylinder with bottom elevation

The problem of standing waves in a circular cylindrical vessel with an elevation on the bottom is formulated and numerically solved in the long wave approximation using an accelerated convergence algorithm. As a result of the calculations, the natural frequency of the fundamental wave mode is determined with a high accuracy. To compare the theoretical results, new experimental data on the excitation of standing surface gravity waves in a circular cylindrical vessel with parabolic and conical elevations at the bottom are presented. It is shown that the calculated and measured natural frequencies of the fundamental wave mode in vessels with the profiled bottom coincide between themselves.

Intercalation-enhanced topological material Bi2Se3: Tuning charge carrier and phonon dynamics for advanced optoelectronic and terahertz applications

The field of topological materials (TMs) is experiencing significant advancements due to their unique surface states, which offer considerable potential for optoelectronics and terahertz (THz) applications. Intercalation in TMs can effectively modulate these surface states, thereby altering electronic and optical properties and enhancing functionalities. This approach enables the tailoring of material properties for specific applications, broadening the utility of TMs across various technological domains. This study focuses on understanding the charge carrier and phonon dynamics in bismuth selenide (Bi2Se3) intercalated with various metals (AxBi2Se3, where A = Ag, Cr, Ni, Mn, Sm, Zn). We examine carrier trapping, carrier relaxation through optical and acoustic phonons, charge recombination processes, and variations in carrier temperature with probe delay lifetimes. Additionally, we explore coherent optical phonons (COPs) in MIBS, which oscillate at THz frequencies and have potential applications in THz generation and detection. Achieving tunability in the THz frequency of COP modes is a significant challenge; however, our research establishes a correlation between optical and structural properties and the dependence of COP frequencies on effective metal intercalation. This comprehensive investigation elucidates the intricate interplay between surface carriers and phonon dynamics in intercalated TMs, highlighting promising advancements for diverse technological applications, including spintronics, optoelectronics, and THz technology.

Emergent symmetry in TbTe3revealed by ultrafast reflectivity under anisotropic strain.

We report ultrafast reflectivity measurements of the dynamics of the order parameter of the charge density wave (CDW) in TbTe3under anisotropic strain. We observe an increase in the frequency of the amplitude mode with increasing tensile strain along thea-axis (which drives the lattice intoa > c, withaandcthe lattice constants), and similar behavior for tensile strain alongc(c > a). This suggests that both strains stabilize the corresponding CDW order and further support the near equivalence of the CDW phases oriented ina- andc-axis, in spite of the orthorhombic space group. The results were analyzed within the time-dependent Ginzburg-Landau framework, which agrees well with the reflectivity dynamics. Our study presents an ultrafast approach to assess the stability of phases and order parameter dynamics in strained systems.

Characterization of Catheter-Type Tactile Sensor Using Polyvinylidene Fluoride (PVDF) Film

To enable quantitative palpation in vivo, we previously developed a catheter-type tactile sensor with an outer diameter of 2 mm composed of a polyvinylidene fluoride (PVDF) film for minimally invasive surgery. However, our previous studies did not evaluate the effect of the PVDF film shape on the sensor output. In this study, we fabricated three types of prototype sensors with different PVDF film shapes and sizes using a simple cutting method. One of the films had the same shape as that used in one of our previous studies. We also prepared two types of PVDF film with a wide base and a narrow tip because we assumed that the deformation of the sensor gradually decreases from the root to the tip, similar to the first mode of the natural frequency. We evaluated the frequency response of the proposed sensors by vibrating the sensor tip and compared the results with the theoretical values. It was confirmed that the sensor output increased with PVDF film size. Although this tendency was observed for both the measured and theoretical values, the measured values were smaller than the theoretical values. Moreover, the effect of film size was larger than that of film shape. Improvements in the sensor structure and the theoretical equation and better evaluation methods are required in order to optimize the film shape and size.

Evolutionary distribution and mode transition in medium frequency from 50 kHz to 5 MHz of argon atmospheric pressure dielectric barrier discharge plasma

Dielectric barrier discharges (DBDs) provide a promising technology for generating non-equilibrium cold plasmas at atmospheric pressure. For both application-focused and fundamental research, it is important to explore the discharge mode transition and electron heating mechanism to enable effective independent tuning of key plasma parameters in a DBD system. In this work, we report numerical studies of the effects of single-frequency excitation on atmospheric argon DBDs, which are carried out in the medium driving frequency (MF) range from 50 kHz to 5 MHz by using a one-dimensional hydrodynamics coupling model. The spatio-temporal evolution of particle density associated with the discharge mode transition and electron dynamic behavior has been investigated. By tuning different components of a single frequency, we observe the electron heating behaviors of the individual modes and mode transitions from the Townsend discharge to the glow discharge in the low frequency to the Ω mode and the hybrid mode in the medium frequency to the α-mode and the γ-mode in the radio frequency. The physical analysis is understood based on these fundamental insights into the plasma physics.

Characteristics of Existing Online Patient Navigation Interventions: Scoping Review.

Patient navigation interventions (PNIs) can provide personalized support and promote appropriate coordination or continuation of health and social care services. Online PNIs have demonstrated excellent potential for improving patient knowledge, transition readiness, self-efficacy, and use of services. However, the characteristics (ie, intervention type, mode of delivery, duration, frequency, outcomes and outcome measures, underlying theories or mechanisms of change of the intervention, and impact) of existing online PNIs to support the health and social needs of individuals with illness remain unclear. This scoping review of the existing literature aims to identify the characteristics of existing online PNIs reported in the literature. A scoping review based on the guidelines outlined in the Joanna Briggs Institute framework was conducted. A search for peer-reviewed literature published between 1989 and 2022 on online PNIs was conducted using MEDLINE, CINAHL, Embase, PsycInfo, and Cochrane Library databases. Two independent reviewers conducted 2 levels of screening. Data abstraction was conducted to outline key study characteristics (eg, study design, population, and intervention characteristics). The data were analyzed using descriptive statistics and qualitative content analysis. A total of 100 studies met the inclusion criteria. Our findings indicate that a variety of study designs are used to describe and evaluate online PNIs, with literature being published between 2003 and 2022 in Western countries. Of these studies, 39 (39%) studies were randomized controlled trials. In addition, we noticed an increase in reported online PNIs since 2019. The majority of studies involved White females with a diagnosis of cancer and a lack of participants aged 70 years or older was observed. Most online PNIs provide support through navigation, self-management and lifestyle changes, counseling, coaching, education, or a combination of support. Variation was noted in terms of mode of delivery, duration, and frequency. Only a small number of studies described theoretical frameworks or change mechanisms to guide intervention. To our knowledge, this is the first review to comprehensively synthesize the existing literature on online PNIs, by focusing on the characteristics of interventions and studies in this area. Inconsistency in reporting the country of publication, population characteristics, duration and frequency of interventions, and a lack of the use of underlying theories and working mechanisms to inform intervention development, provide guidance for the reporting of future online PNIs.

Theoretical velocity of an object frictionally coupled to a two-mode vibrating plate.

Net velocity has been demonstrated for objects frictionally coupled to a flat plate that oscillates periodically in-plane with two frequencies, provided plate displacement is nonantiperiodic: the ratio of frequencies γ cannot be the ratio of two odd integers. We give a mathematical derivation of the experimentally determined dependence of mean velocity on the relative amplitudes of the two frequency modes, and the phase lag between the modes, when γ=2, and when the magnitude of plate acceleration is much larger than the magnitude of acceleration by static friction. The approach uses an analysis of the symmetry properties of the roots of trigonometric polynomials, without explicit determination of those roots. The behavior when γ=1/2, and specific phase lags that inhibit net velocity for general γ, are also determined.