Freeze-thaw Conditions Research Articles

Potential for Recycling Metakaolin/Slag-Based Geopolymer Concrete of Various Strength Levels in Freeze-Thaw Conditions.

Geopolymer concrete (GPC) represents an innovative green and low-carbon construction material, offering a viable alternative to ordinary Portland cement concrete (OPC) in building applications. However, existing studies tend to overlook the recyclability aspect of GPC for future use. Various structural applications necessitate the use of concrete with distinct strength characteristics. The recyclability of the parent concrete is influenced by these varying strengths. This study examined the recycling potential of GPC across a spectrum of strength grades (40, 60, 80, and 100 MPa, marked as C40, C60, C80, and C100) when subjected to freeze-thaw conditions. Recycling 5-16 mm recycled geopolymer coarse aggregate (RGAs) from GPC prepared from 5 to 16 mm natural coarse aggregates (NAs). The cementitious material comprised 60% metakaolin and 40% slag, with natural gravel serving as the NAs, and the alkali activator consisting of sodium hydroxide solution and sodium silicate solution. The strength of the GPC was modulated by altering the Na/Al ratio. After 350 freeze-thaw cycles, the GPC specimens underwent crushing, washing, and sieving to produce RGAs. Subsequently, their physical properties (apparent density, water absorption, crushing index, and attached mortar content and microstructure (microhardness, SEM, and XRD) were thoroughly examined. The findings indicated that GPC with strength grades of C100, C80, and C60 were capable of enduring 350 freeze-thaw cycles, in contrast to C40, which did not withstand these conditions. RGAs derived from GPC of strength grades C100 and C80 complied with the criteria for Class II recycled aggregates, whereas RGAs produced from GPC of strength grade C60 aligned with the Class III level. A higher-strength grade in the parent concrete correlated with enhanced performance characteristics in the resulting recycled aggregates.

Application of computer technology to numerical simulation of hydrothermal variation of subgrade enhanced by seepage drainage geoglage under freeze-thaw cycle

In seasonal frozen soil areas, engineering problems are common due to the high water content of subgrade soil. In view of this phenomenon, a new type of percolating drainage geogrid (SDG) is proposed for cooling and drainage. The changes of soil temperature and moisture at different time points were analyzed through computer simulation laboratory model test, and the changes and distribution of soil temperature and moisture under freeze-thaw conditions were obtained. The temperature and moisture changes and their distribution obtained by computer modeling agree with the experimental results. By optimizing the soil materials of the model samples, the changes of temperature and moisture with time under freeze-thaw conditions were more significant. Therefore, it can be inferred that, without changing the configuration of the percolation drain grid, the cooling drainage performance of the percolation drain grid can be improved under the same conditions by changing the heat transfer coefficient or the macroporous filling material. It provides theoretical support and data guarantee for the reinforcement of subgrade percolation and drainage grid in cold area.

Hydrological responses to permafrost degradation on Tibetan Plateau under changing climate

The Tibetan Plateau (TP) has undergone significant warming and humidification in recent years, resulting in rapid permafrost degradation and spatiotemporal variations in hydrological processes, such as subsurface water transport, hydrothermal conversion, and runoff generation. Understanding the mechanisms of hydrological processes in permafrost areas under changing climate is crucial for accurately evaluating hydrological responses on the TP. This study comprehensively discusses the permafrost hydrological processes of the TP under changing climate. Topics include climate conditions and permafrost states, subsurface water transport under freeze–thaw conditions, development of thermokarst lakes and hydrothermal processes, and runoff response during permafrost degradation. This study offers a comprehensive understanding of permafrost changes and their hydrological responses, contributing significantly to water security and sustainable development on the TP.

Durability Evaluation of Polyurethane-Bound Porous Rubber Pavement for Sustainable Urban Infrastructure

Permeable pavements are vital in sustainable urban water management, addressing critical challenges while enhancing environmental resilience. This study focuses on the innovative polyurethane-bound Porous Rubber Pavement (PRP), which possesses high permeability and elasticity due to its unique composition of stone and crumb rubber aggregates with polyurethane binders. PRP’s useful benefits, such as noise reduction, efficient snow/ice management, and others, enhance its appeal, emphasizing the necessity for a thorough investigation into its performance and characteristics, especially in North America. To address these gaps, this paper comprehensively analyzes PRP’s durability and performance, including its strength range, failure criteria, and susceptibility to moisture-induced damage. Various testing methods are utilized, such as evaluating the abrasion loss of the stone aggregate, rutting, stripping due to moisture susceptibility, resistance to degradation from impact and abrasion, and permeability tests. This study evaluates five distinct mix compositions with varied proportions of aggregates and binders. Further, it investigates the effects of different binder types on PRP performance, such as aromatic and aliphatic binders obtained from various sources. Upon the analysis of the comprehensive test results, it was found that the mix characterized by increased rubber aggregates and a high binder content demonstrated a superior performance across various tests for PRP applications. This mix exhibited an enhanced resistance to abrasion, raveling, rutting, and permanent deformation, showcasing its durability and functionality. Additionally, when combined with an aliphatic binder, it displayed an optimal performance even in challenging freeze–thaw conditions, making it a recommended choice for long-term pavement solutions.

Risk assessment of antimony-arsenic contaminated soil remediated using zero-valent iron at different pH values combined with freeze-thaw cycles.

Soil in mining wastelands is seriously polluted with heavy metals. Zero-valent iron (ZVI) is widely used for remediation of heavy metal-polluted soil because of its excellent adsorption properties; however, the remediation process is affected by complex environmental conditions, such as acid rain and freeze-thaw cycles. In this study, the effects of different pH values and freeze-thaw cycles on remediation of antimony (Sb)- and arsenic (As)-contaminated soil by ZVI were investigated in laboratory simulation experiments. The stability and potential human health risks associated with the remediated soil were evaluated. The results showed that ZVI has a significant stabilizing effect on Sb and As in both acidic and alkaline soils contaminated with dual levels of Sb and As, and the freeze-thaw process in different pH value solution systems further enhances the ability of ZVI to stabilize Sb and As, especially in acidic soils. However, it should be noted that apart from the pH=1.0 solution environment, ZVI's ability to stabilize As is attenuated under other circumstances, potentially leading to leaching of its unstable form and thereby increasing contamination risks. This indicates that the F1 (2% ZVI+pH=1 solution+freeze-thaw cycle) processing exhibits superior effectiveness. After F1 treatment, the bioavailability of Sb and As in both soils also significantly decreased during the gastric and intestinal stages (about 60.00%), the non-carcinogenic and carcinogenic risks of Sb and As in alkaline soils are eliminated for children and adults, with a decrease ranging from 60.00% to 70.00%, while in acidic soil, the non-carcinogenic and carcinogenic risks of As to adults and children is acceptable, but Sb still poses non-carcinogenic risks to children, despite reductions of about 65.00%. These findings demonstrate that soil pH is a crucial factor influencing the efficacy of ZVI in stabilizing Sb and As contaminants during freeze-thaw cycles. This provides a solid theoretical foundation for utilizing ZVI in the remediation of Sb- and As-contaminated soils, emphasizing the significance of considering both pH levels and freeze-thaw conditions to ensure effective and safe treatment.

Damage characteristics of sandstone subjected to freeze–thaw cycles under different stress paths

The damage characteristics and failure modes of rock specimens subjected to different freeze–thaw (FT) cycles are vital to rock engineering in cold regions. Hence, in this study, the physical and mechanical parameters of sandstone specimens under different FT cycles were measured, and their deterioration laws were analyzed. The damage features of the rocks in different FT states under loading along various stress paths, including the main-frequency variation and crack propagation path evolution, were statistically analyzed. Two damage variables, one related to the acoustic emission (AE) and the other related to the rock strength, were combined to reveal the AE characteristics and damage evolution laws in the different damage states. The results showed that FT cycling led to a decrease in the peak stress, an increase in the number of microcracks, an increase in the AE activity, a shift in the main-frequency distribution toward the low-frequency range, and a shift in the damage mode from shear damage to a mixed damage dominated by tensile damage. The degree of strength deterioration in the rock specimens was affected by FT cycling under the different stress paths in the following influence order: conventional uniaxial loading > equal-amplitude cyclic loading> multistage cyclic loading; cyclic loading was more likely to induce tensile rupture than conventional uniaxial loading. The AE characteristic parameters were consistent with the stress–strain curve variations, which could reflect the damage evolution process of the rock specimens. The main frequencies showed a band-like evolution trend with the loading process and could be divided into three bands: a low-frequency interval (0–50 kHz), a medium-frequency interval (50–150 kHz), and a high-frequency interval (150–300 kHz); the main frequencies were concentrated in the low-frequency interval. With the increase in the number of FT cycles, the main frequency in the high-frequency interval and the number of corresponding microcracks gradually decreased.

Electrical Resistivity Behavior of Saline Soil under Low-Temperature Conditions

Freeze-thaw cycling of frozen soils is known to be the cause of various engineering failures of infrastructure in cold regions. Researchers found that electrical resistivity methods outperform traditional ground surveying methods in frozen soils for their greater convenience and cost-effectiveness. However, detailed investigation into the relationship between the electrical resistivity of soil and a variety of soil properties is still needed. In this study, a series of laboratory experiments using the Wenner method were conducted to determine the relationship between soil electrical resistivity and soil geotechnical properties such as initial water content and pore fluid concentration under freeze-thaw conditions. Cylindrical soil samples undergo artificial freeze-thaw cycles to a temperature as low as −70°C, and electrical resistivity and temperature values are recorded simultaneously. Measurement results are summarized for curve fitting, and a statistical model showing relationship between electrical resistivity and temperature during freezing and thawing was given. Above freezing point, the log of electrical resistivity had a linear relationship with temperature. Below freezing point and above −15°C, the log of electrical resistivity had a square root relationship with temperature. Different trends in electrical resistivity change in extremely low-temperature regions (from −15°C to −70°C) are also discussed. In extremely low-temperature regions, the electrical resistivity of frozen soils did not monotonously increase with lower temperature, which may be because of increasing salt concentration in the unfrozen water phase. The findings of this study are expected to bring more insights to frozen soil structure, and assist in geophysical surveying in cold regions and construction methods utilizing ground freezing.

Comparative Efficacy of the Dimethyl Sulfoxide, Glycerol and Methanol on the Post-Thaw Cell Viability of HeLa Cells

Cryoprotectants are used to protect cells during freezing. The concentration, type, and freeze-thaw conditions of these substances vary depending on the type of cell to be used. It is very important to determine the appropriate cryopreservation method for the particular cell. This study aims to provide insights into the optimal cryopreservation method for HeLa cells by comparing the performance of different cryoprotectants and evaluating their effectiveness under various freezing and storage conditions. Cell suspensions were frozen with a freezing media composed of cryoprotectant + fetal bovine serum + medium at a ratio of 5:10:85 (v:v:v) and stored under the following conditions: 3 months (-20 °C), 1 month (-80 °C), and 6 months (-80 °C). Cell viability and recovery rates were analyzed immediately post-thaw and after 48 h using the trypan blue dye exclusion assay. In 3 months (-20 °C), viability and recovery rates were higher in the methanol group. Glycerol showed better performance in 1 month (-80 °C). DMSO was the most efficient in 6 months (-80 °C). Methanol failed at -80 °C storage temperature. This study demonstrates the effect of these cryoprotectants in HeLa cells on cell viability and cell recovery rates immediately after thawing and after 48 hours of cultivation.

Analysis of fracture toughness deterioration and instability model of dangerous rock masses under freeze–thaw cycles

The instability of dangerous rock masses is primarily caused by the stress intensity factor at the primary structural plane exceeding the fracture toughness of the rock bridge section, which results in the propagation of fractures. Additionally, in cold regions, the fracture toughness of these rock masses gradually decreases due to freeze–thaw cycles. Initially, considering the deterioration of type I and type II fracture toughness in the rock bridge section and the frost heaving force between structural planes, an assessment model for the stability of dangerous rock mass under freeze–thaw cycles is established. Secondly, utilizing the theory of circular hole expansion, along with the Mohr-Coulomb yield criterion and maximum tensile stress criterion, a model is constructed to simulate the degradation of type I and type II fracture toughness in rock bridge segments under the influence of freeze–thaw cycles. The validity of this model was subsequently verified through experimental validation. Finally, through engineering case studies, the degradation pattern of the stability of dangerous rock formations under the action of freeze–thaw cycles was analyzed. The study reveals that the decreasing stability of dangerous rock mass under freeze–thaw conditions is intricately linked to the internal friction angle, elastic modulus, and initial tensile strength of the rocks. Notably, the long-term stability of hard and coarsely textured dangerous rock mass under such conditions generally improves. Conversely, the tensile strength of the rock bridge segment elevates, which is beneficial for the long-term stability of the rock mass. When the residual debris ratio exceeds 0.25, the instability of the rock mass deteriorates more modestly. To maintain long-term stability, managing debris loss or injecting fillers into the pores can be effective strategies.

Cracking behaviour of concrete with superabsorbent polymer (SAP) under rolling fatigue load and temperature coupling

ABSTRACT To explore the long-term crack resistance of pavement concrete containing superabsorbent polymer (SAP), a fatigue test was designed with the consideration of rolling fatigue load and temperature coupling. The four-point fracture and acoustic emission tests were combined to evaluate the evolution of crack resistance. Additionally, the enhancement mechanism was revealed through scanning electron microscopy and mercury intrusion porosimetry experiments. The results indicate that the coupling effects of rolling fatigue load and temperature accelerate the deterioration of the fracture performance of concrete, particularly the freeze–thaw conditions. The concrete with SAP had greater fracture toughness, with improvements of 9.3%, 11.9%, and 58.1% under the coupling rolling fatigue loading and high temperatures, low temperatures, and freeze‒thaw cycles, respectively. The fracture process of concrete with SAP includes fluctuation, fatigue accumulation, and fatigue failure periods, and the SAP delays the arrival time of cumulative ring count and energy, significantly reducing the rate of concrete damage. More fibrous C-S-H and ettringite were generated at the interface microcracks in the concrete containing SAP, confirming the greater degree of hydration. Moreover, the SAP reduced the porosity and average pore size, which enabled the concrete to better resist the impact of rolling fatigue loading and adverse environmental temperatures.

Evolution and prediction of static and seismic properties in diatomite-incorporated concrete members exposed to freeze-thaw cycles

Freeze-thaw cycles induce substantial durability concerns for concrete infrastructures in cold regions. Traditional approaches to assess freeze-thaw degradation in concrete necessitate extensive environmental and mechanical testing, which are both resource-intensive and time-consuming. This paper introduces a concrete freeze-thaw damage constitutive model, designed for the accurate and efficient quantitative evaluation and prediction of the evolution in concrete's mechanical properties post freeze-thaw cycles. This model specifically considers the impact of supplementary cementitious materials, like diatomite. A numerical program was then developed to simulate the stress-strain responses of both diatomite-enhanced and ordinary concrete under freeze-thaw conditions. Based on these insights, the model was extended to structural members, creating a seismic and static finite element simulation methodology. The findings demonstrate the improvements in the mechanical performance of diatomite- incorporated concrete subjected to both static and seismic loads. This model offers theoretical support for predicting the mechanical behavior evolution of concrete materials and structures in cold climate regions.

A Review of Durability of New and Old Concrete Joints

The purpose of this study is to explore the durability of the new and old concrete joints, including chloride ion erosion, freeze-thaw phenomena, and the influence of aggregates. Firstly, taking into account the difference in material properties between the old and new concrete, this study analyzes the chloride ion transport characteristics of the joints in detail, focusing on the key areas of the joints, that is, the areas where the old concrete may have been eroded by chloride ions. Secondly, this study explores the change in the properties of the joints under freeze-thaw conditions, and the influence of different interface treatment methods on the properties of the joints. Finally, this study examines the influence of the type and content of aggregates on the durability of the joints. Through the above research, this paper aims to provide some useful guidance and suggestions for the durability design of the old and new concrete structures.

Spatial and Temporal Changes in Soil Freeze-Thaw State and Freezing Depth of Northeast China and Their Driving Factors

It is necessary to further investigate the spatial considerations, temporal characteristics, and drivers of change affecting the beginning and end of soil freezing and thawing, including the maximum depth of the seasonal freezing (MDSF) and the active layer thickness (ALT) in Northeast China. Hourly soil temperature, among other data, from 1983–2022 were investigated, showing a delay of about 6 days in freezing. In contrast, thawing and complete thawing advanced by about 26 and 20 d, respectively. The freezing period and total freeze-thaw days decreased by about 29 and 23 days, respectively. The number of complete thawing period days increased by about 22 days, while the MDSF decreased by about 25 cm. The ALT increased by about 22 cm. Land Surface Temperature (LST) is the main factor influencing the beginning and end of soil freezing and thawing, MDSF and ALT changes in Northeast China; air temperature, surface net solar radiation, and volumetric soil water content followed. The influence of the interacting factors was greater than the single factors, and the interactive explanatory power of the LST and surface net solar radiation was highest when the soil started to freeze (0.858). The effect of the LST and the air temperature was highest when the soil was completely thawed (0.795). LST and the volumetric soil water content interacted to have the first explanatory power for MDSF (0.866) and ALT (0.85). The results of this study can provide scientific reference for fields such as permafrost degradation, cold zone ecological environments, and agricultural production in Northeast China.

A Spatiotemporal Enhanced SMAP Freeze/Thaw Product (1980–2020) over China and Its Preliminary Analyses

The soil freeze/thaw (FT) state has emerged as a critical role in the ecosystem, hydrological, and biogeochemical processes, but obtaining representative soil FT state datasets with a long time sequence, fine spatial resolution, and high accuracy remains challenging. Therefore, we propose a decision-level spatiotemporal data fusion algorithm based on Convolutional Long Short-Term Memory networks (ConvLSTM) to expand the SMAP-enhanced L3 landscape freeze/thaw product (SMAP_E_FT) temporally. In the algorithm, the Freeze/Thaw Earth System Data Record product (ESDR_FT) is sucked in the ConvLSTM and fused with SMAP_E_FT at the decision level. Eight predictor datasets, i.e., soil temperature, snow depth, soil moisture, precipitation, terrain complexity index, area of open water data, latitude and longitude, are used to train the ConvLSTM. Direct validation using six dense observation networks located in the Genhe, Maqu, Naqu, Pali, Saihanba, and Shandian river shows that the fusion product (ConvLSTM_FT) effectively absorbs the high accuracy characteristics of ESDR_FT and expands SMAP_E_FT with an overall average improvement of 2.44% relative to SMAP_E_FT, especially in frozen seasons (averagely improved by 7.03%). The result from indirect validation based on categorical triple collocation also shows that ConvLSTM_FT performs stable regardless of land cover types, climate types, and terrain complexity. The findings, drawn from preliminary analyses on ConvLSTM_FT from 1980 to 2020 over China, suggest that with global warming, most parts of China suffer from different degrees of shortening of the frozen period. Moreover, in the Qinghai–Tibet region, the higher the permafrost thermal stability, the faster the degradation rate.

Study on freeze-thaw deterioration model of new-to-old concrete based on pore surface fractal characteristics

New-to-old concrete (NTOC) structures are widely used in engineering practice, the adhesive interface as a weak part is easily damaged under freeze-thaw environment. At present, most of NTOC deterioration models are grounded in the empirical summary of experiment data. In this paper, the bonding and durability of NTOC adhesive interface under different freeze-thaw cycles were investigated by splitting tensile test and ultrasonic nondestructive test, and the pore distribution characteristics of adhesive interface were obtained by mercury intrusion porosimetry. Based on the S-N equation and the constitutive relationship of damaged concrete, the phenomenological freeze-thaw damage model of NTOC was established. According to the fractal analysis of the effective bearing area of the pores, the freeze-thaw deterioration model of NTOC adhesive interface was further established, which was named PDM model. The splitting tensile strength (macroscopic mechanical properties) and ultrasonic wave velocity (microscopic defects) of the concrete repaired by four kinds of alkali activated slag-fly ash were used to verify PDM model. The results showed that PDM model could reflect the change of bonding properties and the defects of NTOC adhesive interface under freeze-thaw conditions. The microscopic pore evolution characteristics reflected the macroscopic mechanical properties. With a restricted number of monitoring sites, the PDM model could n forecast the changing trend of the whole freeze-thaw degradation process of NTOC.

Performance and Heavy Metal Analysis of Graphite Tailings Cured Using Cementitious Materials

The massive accumulation of graphite tailings causes serious environmental pollution, mainly from heavy metal pollution. Therefore, this article introduces a method of using graphite tailings as a high-content main material, cement as a small component of the auxiliary cementitious material, and clay as a substitute for cement. The compressive strength and permeability of graphite tailing–solidified material (GT, GT–Clay) were tested, and the effect of clay partially replacing cement as an auxiliary cementitious agent on GT–Clay performance was compared. In addition, inductively coupled plasma mass spectrometry (ICP) was used to analyze the effect of the graphite tailing placement time on the heavy metal content, as well as the changes in the GT heavy metal leaching concentration and its heavy metal content under outdoor freeze–thaw conditions. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to elucidate the microstructural changes in the GT–Clay. The experimental results show that, as the substitution of clay for cement increased from 0 to 50%, the compressive strength of the 90% GT–Clay gradually decreased, and the permeability also increased. The compressive strength of 95% GT–Clay did not show significant changes, but the permeability increased, and when mixed with quicklime, gypsum, and silica fume, the permeability decreased. The Ni and As in graphite tailings fluctuated significantly with the placement time. The heavy metal leaching concentrations of the 90% GT and 95% GT were below the standard limit, and Cd, As, and Ni in GT were potential sources of pollution. The analysis of the microscopic test results showed that the hydration products of the GT–Clay included ettringite, Ca(OH)2, and calcium silicate hydrates. The hydration product stabilized and filled the gaps between the tailing particles, thereby cementing them together. Not only did it improve the mechanical strength of GT, it also reduced the permeability and heavy metal leaching rate. This study provides a new analytical approach to applying graphite tailings for environmental treatment.

Factors affecting the sediment concentration in runoff from a slope during the spring thawing period

AbstractSediment concentration (S) is vital in soil erosion models. However, research on estimating S at different positions on slopes in the spring thaw period is difficult. Thus, in this research, four flow discharges, two slope gradients, and four initial thawing depths were used in combination with Rare Earth Elements (REEs) tracing techniques to investigate the effects of hydraulic parameters at different locations of freeze–thaw rill flows on S. The results show that the S on the freeze–thaw slope gradually increases from the first section to the third section of the slope, with an increase of 43.99% from the first slope section to the third slope section. The flow velocity is the most critical factor to affect the S (R2 > 0.7). The prediction equation of S on the entire slope under freeze–thaw conditions was established based on the flow turbulence intensity and relative gravity (R2 = 0.769). This study examined the S and hydraulic parameters of the freeze–thaw rill flow, which provided a reference for further research on the soil erosion model during the spring thawing period.

Investigation on damage creep constitutive model of rock under the coupled effect of freeze–thaw cycles and loading

AbstractThe investigation on damage creep properties of rock under freeze–thaw conditions are essential for assessing the long‐term stability of rock mass engineering in cold regions. This research analyzed the damage characteristics of rock under the coupled effect of freeze–thaw cycles and loading; the damage variable under the coupled effect of freeze–thaw cycles and loading was proposed. A damage creep constitutive model was developed, and the determination method for the model parameters was proposed. The rationality of the model was calibrated using test data, and the calculation results of the proposed model were compared with classical Nishihara model. Additionally, the research analyzed the variation of model parameters with the number of freeze–thaw cycles and discussed the damage creep mechanisms of rock under the coupled effect of freeze–thaw cycles and loading.

Experimental study on bond durability of GFRP bar/engineered cementitious composite exposed to freeze-thaw environments

Glass fiber reinforced polymer (GFRP) bars and engineered cementitious composites (ECC) present better structural performance as compared to conventional concrete with reinforcing steel bars. However, the bond behavior of the GFRP bar to ECC matrix under freeze-thaw (FT) cycles in cold climates remains underexplored. Therefore, this study aims to investigate the bond durability of GFRP bars and ECC under FT conditions. An experiment was conducted with 33 pullout specimens, categorized according to concrete types (normal concrete and ECC), compressive strengths (30 MPa and 50 MPa) and the number of FT cycles (0, 100, 150, and 200 cycles). Assessment parameters included surface degradation, failure modes, mean bond strength, weight loss, and the relative dynamic modulus of elasticity. Results indicated ECC specimens exhibited greater durability compared to normal concrete specimens, with no significant improvement in durability observed with increased compressive strength. Specifically, the mean bond strengths of N30 (30 MPa normal concrete) specimens, E30 (30 MPa ECC) specimens, and E50 (50 MPa ECC) specimens decreased by 88.41 %, 38.86 %, and 58.21 % after 150 FT cycles, respectively. Failure modes correlated strongly with concrete type and the number of FT cycles. SEM and composition analyses revealed the effects of FT cycles on the concrete matrix, the bond interface, and the GFRP bars. The ascending branches in the bond stress-slip curves of specimens subjected to FT cycles were effectively modeled using Malvar's model. Based on the declining relative dynamic modulus of elasticity and the correlation between laboratory and natural FT cycles, the estimated fatigue lives for GFRP bar/E30 specimens subjected to 250 FT cycles are 35.7, 71.4, and 46.2 years in Beijing, Detroit, and Vancouver, respectively. This research provides insights on GFRP bar/ECC's longevity in practical engineering contexts.

Tendon biomechanical properties are altered by storage duration but not freeze-thaw temperatures or cycles.

Tendon allograft and xenograft processing often involves one or more steps of freezing and thawing. As failure strength is an important graft consideration, this study aimed to evaluate effects on failure properties when varying freeze-thaw conditions. Kangaroo tendons, a potential xenograft source, were used to evaluate changes in ultimate tensile strength (UTS), failure strain and elastic modulus after exposure to different freezer-storage temperatures (-20°C vs.-80°C), storage durations (1, 3, 6, 9, or 12 months), number of freeze-thaw cycles (1, 2, 3, 4, 5, or 10), or freeze-thaw temperature ranges (including freezing in liquid nitrogen to thawing at 37°C). Tendons stored for 6 or more months had significantly increased UTS and elastic modulus compared with 1 or 3 months of storage. This increase occurred irrespective of the freezing temperature (-20°C vs.-80°C) or the number of freeze-thaw cycles (1 vs. 10). In contrast, UTS, failure strain and the elastic modulus were no different between storage temperatures, number of freeze-thaw cycles and multiple freeze-thaw cycles across a range of freeze and thaw temperatures. Common freeze-thaw protocols did not negatively affect failure properties, providing flexibility for graft testing, storage, transportation and decellularisation procedures. However, the change in properties with the overall storage duration has implications for assessing the consistent performance of grafts stored for short versus extended periods of time (<6 months vs. >6 months), and the interpretation of data obtained from tissues of varying or unknown storage durations.