Fracture Toughness KIC Research Articles

Micromechanical properties of reaction-bonded silicon carbide using atomic force microscopy and nanoindentation

Reaction-bonded silicon carbide (RB-SiC) ceramics have been produced using advanced technology for the production of space mirrors. Changing the volume content of SiC (from 78 to 93 %) in the ceramic's composition allows for improved the mechanical properties, which is achieved by a combination of the SiC and Si phases properties. In this work, a thorough study of the structure and micromechanical properties of individual SiC and Si phases for RB-SiC ceramics (with a SiC content of 78–93 vol%) was carried out at the micro- and nanolevel using atomic force microscopy and nanoindentation. The studies have shown the crack resistance limit each phase (an important factor for RB-SiC space mirrors) under mechanical loads, after which microcracks appear (sources of further degradation and destruction). The surface morphology, deformation area and crack propagation in each phase after exposure to mechanical load during indentation were studied using atomic force microscopy. Nanomechanical mapping of elastic modulus and microhardness on the surface, analysis of boundaries between phases (SiC and Si), assessment of mutual influence of phases and determination of micromechanical properties were carried out using the nanoindentation method. The fracture toughness KIC was determined using an improved indentation method with visualization of the deformation areas using atomic force microscopy. The highest values of microhardness H, elastic modulus E and fracture toughness KIC on the SiC and Si phases were obtained on a ceramic sample with 93 vol % SiC: for the SiC phase – E=486 GPa, H=35.6 GPa, KIC=5.03 MPa m1/2, for the Si phase – E=205 GPa, H=12.2 GPa, KIC=2.73 MPa m1/2. This study demonstrated the efficiency and possibility of using the atomic force microscopy and nanoindentation to determine the micromechanical properties of ceramics at the micro- and nanolevel.

Experimental study of type-I crack propagation in rock monitored by fiber Bragg grating

The occurrence of rock mass engineering disasters can be reduced significantly by obtaining the key information in the process of rock internal fracture accumulation and evolution through advanced monitoring means and taking certain preventive measures. Through fiber Bragg grating monitoring tests of the type-I crack propagation in rock, the spectral characteristics of the fiber Bragg grating in the process of rock failure were analyzed, the bandwidth expansion was extracted to characterize the local tensile strain during the crack propagation process, and the damage variable based on the bandwidth expansion was calculated to describe the type-I crack propagation process. The research results showed the following: (1) The fiber Bragg grating generated a non-uniform local tensile strain during type-I crack propagation. The bandwidth expansion of the wave spectrum was positively correlated with the local tensile strain. The change in the characteristics of the wave spectrum could provide the local real strain in the process of crack propagation. (2) During the steady propagation of the type-I crack, the bandwidth increased obviously, while the number of acoustic emission events was relatively small, and most of them were in the process zone. The gentle increase in the bandwidth corresponded to the unstable growth stage of the type-I crack, which could be used as a precursor of rock sample instability. During loading, the maximum tensile strain of the type-I crack was 6 %, while the maximum shear strain reached 1.8 %, primarily attributed to tensile failure. The average value of fracture toughness KIC, based on the equivalent linear elastic fracture mechanics model, was determined to be 1.21 MPa·m1/2, and the average value of fracture energy Gf was calculated as 57.7 N/m. The variation of peak reflectivity in fiber Bragg grating was associated with the closure of pre-existing defects and the propagation of microcracks in rocks, resulting in unstable shear strain at crack extension sites. (3) The damage variable D defined by the bandwidth broadening began to become concentrated and accumulated in the crack steady growth stage, and it increased slowly in the crack intensification and evolution stage. The grating was sensitive to changes when it was pasted to the surface at 90°, but it could easily fracture or become unable to capture spectral signals in time. Based on a comprehensive comparison, the monitoring effect was the best when the grating was pasted at 60° relative to the crack.

Fracture properties of carbon/glass fiber composite laminates with surface scratch damage

Carbon/glass fiber reinforced polymer composite panels may experience minor surface scratches during processing or use. These shallow scratches can expand and potentially lead to dangerous fracture failure as the specimens are continually loaded. This study presents a closed form non-LEFM model for predicting the fracture performance of materials with slight scratches. First, 3-p-b tests and direct tensile tests were conducted on 115 carbon/glass fiber composite laminated panel specimens. A comparison of the two test methods revealed that 3-p-b tests were more suitable for analyzing quasi-brittle fracture in carbon/glass fiber composites. The tensile strength ft and fracture toughness KIC of 3-p-b specimens with and without notched were discussed using the weighted average calculation method to determine the thickness of the “composite” single-layer prepreg as the characteristic composite unit Cch. A normal distribution method was also introduced to analyze the experimental discrete points, covering almost all the experimental scatterers with desired reliability. Furthermore, the same method was applied to specimens with different layup methods, and the data analysis confirmed its effectiveness. As the seam-thickness ratio α increases within a certain range, the tensile strength ft showed an overall increasing trend and the peak load Pmax showed a decreasing trend. Additionally, the laboratory routine dimensions can be utilized to efficiently predict the fracture of large size members with defects at the same thickness, which is significant for the safe design of composite structures.

Improved mechanical properties of 3YSZ ceramics prepared by pressure-less sintering assisted by cold sintering under mild conditions

It is an effective method to prepare ZrO2 ceramics by cold sintering (CS) and the subsequent pressure-less sintering (PLS), while the compacting problems are serious during the CS process with high pressure and high temperature, such as delamination, cracking and sticking to steel mold. To solve these problems, polyacrylic acid (PAA) is utilized as the organic binder, with the aid of which the 3 mol% yttrium-doped zirconia (3YSZ) nanopowder can be well compacted by CS under mild conditions (200 MPa, 100 °C). Compared to the conventional dry-pressed compacts, the particle agglomerations are observed in cold-sintered compacts as well as the slightly increased relative density, which lead to a significant improvement of Vickers Hardness (Hv) by 78 %. Consequently, the CS-PLS ceramics sintered at 1400 °C also exhibit a higher relative density (99.76 %) and better mechanical properties (Hv = 14.8 GPa, fracture toughness KIC = 6.49 MPa m1/2, flexural strength σ = 380.64 MPa) than the PLS ones without cold sintering, indicating that the CS-PLS process with mild conditions for CS is promising for preparing the denser and stronger YSZ ceramics.

Effect of aging temperatures on the microstructure and mechanical properties of TC21 forgings with basket–weave microstructure

This study aims to explore the influence of various aging temperatures on the microstructure and mechanical properties of TC21 forgings. Basket-weave microstructures were prepared via quasi-β forging followed by annealed at 900 °C for 1.5 h and aged at 530 °C, 560 °C, and 590 °C for 4 h, and then their tensile performance, impact toughness, and fracture toughness were examined. Results indicate that higher aging temperatures not only facilitate the segregation of Al element, resulting in a reduction in the effective size (dαlaths, the width/length ratio) of primary α laths (αlaths) and their amount, but also promote phase transition, inducing an increase in the effective size (dαfine) of secondary fine α (αfine) lamellae. While both dαlaths−1/2 and dαfine−1/2 have a linear relationship with the strength, which was analyzed using the Hall–Petch relationship, the more pronounced interface strengthening effect and hindering crack propagation mainly results from the αlaths. Moreover, the plasticity declines significantly as the proportion of the αlaths phases decreases. Thus, for strength and plasticity, the αlaths are a much more important factor than the αfine lamellae. However, although the synergistic deformation and fracture of both the αlaths and αfine phases can consume a larger impact initiation energy, the enhancement of the impact energy of the alloy is primarily related to a high precipitation amount of the αfine lamellae. Furthermore, the decrease in dαlaths promotes the misorientation and accumulation of dislocations between αlaths interfaces, hindering the enhancement of KIC (fracture toughness) by forming transgranular fractures. Conversely, the increase in KIC attributed to the energy consumed in the plastic deformation region at the crack tip, due to the αfine lamellae compensates for the energy, resulting in a reduction in the crack propagation path. Therefore, the αfine lamellae may play a more crucial role in increasing the toughness of alloys, in particular the impact toughness of the TC21 alloy.

A facile approach for enhancing mechanical resilience, and corrosion protection in epoxy coatings using bismuthene nanosheets

AbstractThis study presents novel mechanochemical methods for the synthesis and chemical modification of bismuthene nanosheets (BINS) using a high‐speed blender and planetary ball milling. Atomic force microscopy (AFM) measurements confirmed successful exfoliation of 1.5‐nm BINS. Epoxy/BINS nanocomposites exhibited enhanced mechanical properties, thermal stability, and chemical resistance. Chemical modification via ball milling improved the interface and dispersion of BINS within the epoxy matrix, leading to significant enhancements in mechanical performance and chemical resistance. Compared to neat epoxy, at 0.75 vol% m‐BINS, Young's modulus, impact strength and fracture toughness KIC were respectively enhanced by 30%, 88.6%, and 144.4% while these increments were 10%, 55.7%, and 97.8% for pristine BINS‐based epoxy nanocomposite. A 3D finite element model of the impact test of the nanocomposite was developed to predict its behavior under high‐strain rate loadings; the numerical model showed high agreement with experimental measurements. Epoxy/m‐BINS nanocomposites demonstrated exceptional chemical resistance, attributed to the small lateral dimensions of m‐BINS, which fill the spaces between cross‐linked epoxy molecules and uniformly distribute within the matrix. These findings highlight the crucial role of interface and dispersion in defining the mechanical properties of nanocomposites. Overall, this study provides a facile and scalable method for synthesizing and modifying bismuthene, showcasing its potential for developing functional polymer nanocomposites.Highlights Bismuthene nanosheets & modified BINS (m‐BINS) are prepared by eco‐friendly method. m‐BINS is ~1.5 nm thick and ~0.5 μm wide. m‐BINS shows good dispersion and strong interface adhesion within epoxy matrix. Impact strength and KIC of epoxy/m‐BINS nanocomposite are enhanced by 88.6% and 144.4%. Numerical model for impact strength is developed to predict behavior at high‐strain rate.

Thickness Effect of 2195 Al-Li Alloy Friction Stir Weld Fracture Toughness.

For damage tolerance design in engineering components, the fracture toughness value, KIC, of the material is essential. However, obtaining specimens of sufficient thickness from stir friction welded plates is challenging, and often, the experimental test values do not meet the necessary criteria, preventing the experimental fracture toughness, Kq, from being recognized as plane strain fracture toughness KIC. The fracture toughness Kq of 2195 Al-Li alloy welding seams with different thicknesses was measured on the forward and backward sides. Microstructure characterization was conducted by scanning electron microscope (SEM). The results indicated minimal significant differences in grain size between the advancing and retreating sides of the weld nugget zone. In specimens of the same thickness, fracture toughness measurements along the normal direction of the joint cross-section showed a high similarity between the advancing and retreating sides of the weld nugget zone. Utilizing the quantitative relationships between fracture toughness and sample thickness derived from both the fracture K and G criteria, it is possible to predict the fracture toughness of thick plates using thin plates. This study employs these relationships to calculate the fracture toughness KIC of 2195 aluminum-lithium alloy friction stir welds. The KIC values obtained are 41.65 MPa·m1/2 from the fracture K criterion and 43.54 MPa·m1/2 from the fracture G criterion.

Influence of specimen configuration on mode I and mode II fracture toughness of sandstone

In order to investigate the impact of cracked specimen configurations on the apparent fracture toughness of the green sandstone, a series of fracture experiments were conducted utilizing four distinct types of specimens. The experimental results show that the cracked straight-through Brazilian disk (CSTBD) specimens observed the minimum mode I fracture toughness KIC and the maximum mode II fracture toughness KIIC. The KIC measured by notched semi-circular bending (NSCB) specimens is nearly twice that of CSTBD specimens, while the KIIC is only 77% of CSTBD specimens. It indicates that both the specimen configurations and loading conditions are significant factors influencing the apparent fracture toughness, which may be attributed to the different T-stress for different specimens. Furthermore, several fracture criteria were employed to evaluate the experimental results. Simultaneously, a theoretical framework based on the generalized maximum tangential strain (GMTSN) criterion was proposed to investigate the impact of T-stress on apparent fracture toughness. The results indicate that positive T-stress can improve the KIC, while negative T-stress can decrease the KIC. In addition, we also found that the dependence of KIIC on T-stress is exactly opposite to that of KIC. The study provides theoretical references for systematically evaluating experimental results and selecting specimens reasonably.

Toughness enhancement in TiN/Zr0.37Al0.63N1.09 multilayer films

The hardness and fracture toughness of high-temperature wear-resistant transition metal aluminum nitride multilayer films depend largely on the constituting layer's structure, compositional modulation, morphology, and interface coherency. We present a study on 1-micron thick multilayered films consisting of stacked layers of TiN and Zr0.37Al0.63N1.09, each layer being 10 nm thick. The films were grown using ion-assisted reactive magnetron sputtering on MgO(001) and Si(001) at substrate temperatures ranging from ambient to 900°C. By increasing growth temperature, we found that the ZrAlN layers transition from near amorphous to nanocrystalline wurtzite to decomposed c-ZrN and w-AlN domains. Concurrently, the TiN layers exhibit strong fiber texture, polycrystallinity, and epitaxial growth carried by the ZrN domains. Both hardness and fracture stress, evaluated by nanoindentation and micromechanical tests, increase with temperature from H=24 GPaMgO, 23 GPaSi to 36 GPaMgO, 30 GPaSi, and σFSi= 6.1-7.7 GPa, respectively. An improved fracture toughness of KIC=2.4-2.8 MPa√m is related to different toughening mechanisms for the various microstructures. The difference in hardness between the substrates is related to compressive stress due to the deposition conditions and thermal contraction. The superior fracture stress is attributed to dense multilayers, free from macroscopic defects due to ion-assisted growth. After being deposited at 200°C, the multilayers remained thermally stable when vacuum annealed for 15 hours at 900°C, with no significant change in phase composition or hardness. The improved hardness, toughness, and temperature stability of the otherwise brittle nitrides are promising for industrial applications.

Fracture Toughness, Radiation Hardness, and Processibility of Polymers for Superconducting Magnets.

High fracture toughness at cryogenic temperature and radiation hardness can be conflicting requirements for the resins for the impregnation of superconducting magnet coils. The fracture toughness of different epoxy-resin systems at room temperature (RT) and at 77 K was measured, and their toughness was compared with that determined for a polyurethane, polycarbonate (PC) and poly(methyl methacrylate) (PMMA). Among the epoxy resins tested in this study, the MY750 system has the highest 77 K fracture toughness of KIC = 4.6 MPa√m, which is comparable to the KIC of PMMA, which also exhibits linear elastic behaviour and unstable crack propagation. The polyurethane system tested has a much higher 77 K toughness than the epoxy resins, approaching the toughness of PC, which is known as one of the toughest polymer materials. CTD101K is the least performing in terms of fracture toughness. Despite this, it is used for the impregnation of large Nb3Sn coils for its good processing capabilities and relatively high radiation resistance. In this study, the fracture toughness of CTD101K was improved by adding the polyglycol flexibiliser Araldite DY040 as a fourth component. The different epoxy-resin systems were exposed to proton and gamma doses up to 38 MGy, and it was found that adding the DY040 flexibiliser to the CTD101K system did not significantly change the irradiation-induced ageing behaviour. The viscosity evolution of the uncured resin mix is not significantly changed when adding the DY040 flexibiliser, and at the processing temperature of 60 °C, the viscosity remains below 200 cP for more than 24 h. Therefore, the new resin referred to as POLAB Mix is now used for the impregnation of superconducting magnet coils.

Prediction of crack initiation for notched concrete beam from FPZ at maximum load

The initial cracking load (Pi) of a notched concrete beam, difficult to measure, has been predicted from the maximum fracture load (Pmax) together with the notch-tip fracture process zone (FPZ) at Pmax. A simple analytical model is used to link Pi and Pmax together through the FPZ. The corresponding initiation and unstable fracture toughness, Ki and Kun, have also been determined. The model assumes that the lower limit of Pmax from a group of identical notched concrete beams corresponds to the lower limit of the FPZ length FPZL, so that the lowest limit Pmax = Pi is established for FPZL = 0. Detailed FPZ measurements before and at Pmax using a digital image correlation technique were analysed and used to predict the initial cracking load Pi. Six different specimens with various sizes (W = 40, 60 and 80 mm), initial notches (a0 = 12 to 48 mm) and FPZL (7 to 13 mm) at Pmax showed the average ratio of FPZL/(W – a0) was around 0.25, indicating the Pi/Pmax ratio was around 0.67 based on the analytical model. The crack growth resistance KR-curve between the crack initiation toughness Ki at Pi and the unstable fracture toughness Kun at Pmax was also established approximately by the simple model. Estimated intrinsic fracture toughness KIC was compared with Ki and Kun. The influence of average aggregate size dav on Pi and FPZL at Pmax was also discussed.

Study on the Quasi-Ductile Fracture Behavior of Glubam: The Role of Fiber Distribution.

Cracking in fibrous composites is inevitable, and the fracture pattern is influenced by its fiber distribution. Bamboo fibrous composites have a distinct fiber distribution, which makes them an excellent material for studng the relationship between fiber distribution and fracture mode. Glued laminated bamboo is a bi-directional bamboo fibrous composite, which is called glubam for short. Its vertical thickness is about 28 mm, and the ratio of the number of longitudinal fiber layers to the number of transverse fiber layers is 4:1. This study conducted three-point bending fracture tests on single-edge notched specimens of glubam to investigate its mode-I fracture characteristics in the transverse vertical direction. The deformation curves show that the specimens still have the load-carrying capacity after reaching the maximum load, and the load shows a trend of step-like decrease, exhibiting a quasi-ductile fracture behavior. Overall, the fracture process can be divided into four stages, including linear, softening, quasi-ductile, and failure stages. In this study, based on certain assumptions, the prefabricated notch length a0 was adjusted according to the position of the transverse fibers. Subsequently, the non-linear elastic fracture mechanics method was employed to calculate the fracture parameters of glubam during the softening and quasi-ductile stages, including the fracture toughness KIC* and fiber tensile strength ft. The deviation of the fracture parameters between the two stages is within 10%, indicating that the correction of the a0 is correct. This indirectly proves that the staggered structure formed by longitudinal and transverse fibers is responsible for the quasi-toughness fracture of glubam. Finally, this study summarized and analyzed the quasi-ductile fracture behavior and found that materials or structures exhibiting quasi-ductile fracture behavior often possess a staggered structure. This staggered structure makes the crack in the form of semi-stable propagation, while the load decreases in a step-like manner.

Investigation on the size effect of compacted clay mode I fracture based on NDB specimens

The size effect is closely related to the cracking resistance of compacted clay, which is crucial in engineering applications, but little attention has been given to it in previous studies. This study investigated the size effect on mode I fracture behaviors of compacted clay using single-edge notched deep beam (NDB) specimens. Through the digital image correlation (DIC) method, the crack initiation mechanism of compacted clay was analyzed. The results showed that the specimen size and dimensionless crack length did not change the failure pattern, while peak load, peak displacement, and fracture energy gradually increased with the increase of specimen size. Based on the load–displacement curves and the horizontal strain evolution laws, the three horizontal strain stages at the crack tip crack initiation point were defined, i.e., the steady strain growth stage, the nonlinear strain growth stage, and the nonlinear strain intensification stage. Through the Bažant size effect model (SEM), the fracture process zone length Cf and mode I fracture toughness KIC of compacted clay without the size effect were inferred. The separated form of SEM was applied, and the contribution ratios of the strength criterion and linear elastic fracture mechanics were quantitatively analyzed. Combing the characteristics of the NDB specimens, a prediction model considering the support spacing, specimen structure parameters, and fracture toughness was established.

A Strategy to Enhance the B-Solubility and Mechanical Properties of Ti–B–N Thin Films

The Ti–B–N system offers a wide range of possible meta(stable) phases, making it interesting for science and industry. However, the solubility for B within the face-centered cubic (fcc)-TiN lattice is rather limited and less studied, especially without forming B-rich phases. Therefore, we address how chemistries along the TiN–TiB2 or TiN–TiB tie-line influence this B-solubility. The variation between these two tie-lines is realized through non-reactive co-sputtering of a TiN, TiB2, and Ti target. We show that for variations along the TiN–TiB tie-line, even 8.9 at.% B (equivalent to 19.3 at.% non-metal fractions) can fully be incorporated into the fcc-TiNy lattice without forming other B-containing phases. The combination of detailed microstructural characterization through X-ray diffraction and transmission electron microscopy with ab initio calculations of fcc-Ti1-xNBx, fcc-TiN1-xBx, and fcc-TiN1-2xBx solid solutions indicates that B essentially substitutes N.The single-phase fcc-TiB0.17N0.69 (the highest B-containing sample along the TiN–TiB tie-line studied) exhibits the highest hardness H of 37.1±1.9 GPa combined with the highest fracture toughness KIC of 3.0±0.2 MPa·m1/2 among the samples studied. These are markedly above those of B-free TiN0.87 having H = 29.2±2.1 GPa and KIC = 2.7±<0.1 MPa·m1/2.

Study of the mechanical behavior and multiscale simulation of the crack propagation in a bilinga wooden beam

The mechanical behavior of local wood species (Bilinga) in the south west region in Cameroon during rainy and dry seasons and the mechanical behavior of wooden beam under bend loading are studied. The three points flexural tests were used to determine the mechanical properties of the wood under study. ANSYS 2020 R1 finite element (FE) software is used for numerical simulations at a macroscopic level using one of the newer technologies called Smart crack growth, which was introduced in the 2019 version. The geometry was modeled in SolidWorks with an initial crack length of 4 and 8 mm introduced in each sample and then imported to ANSYS workbench for further analysis with ANSYS which has all the tools to perform linear fracture. The stress intensity factor (SIF) determines the fracture toughness of a material which is subjected to linear-elastic fracture mechanics (LEFM) where a variable of the critical stress intensify is denoted as KIc. The fatigue crack growth was modeled using Paris’ law. The crack growth was simulated based on Mode I crack specimen with an initial crack length of 4 and 8 mm, respectively. The stochastic multiscale modeling of crack growth on meso- and microscale is used to compare the crack growth rate in the approach of a heterogeneous material and taking into account the microstructure and fracture mechanism of the Bilinga wood. The results of stochastic modeling of the crack growth in the array of cracks and pores of a characteristic size shows that the simulation is close to FE-modeling results. Therefore, the stochastic simulation of the crack growth in wood at meso- and microscale shows the lower local stress intensity factors and slower crack growth due to the existence of the scale-time hierarchy. The crack growth rate vcr at a macroscale ranges within 0.845 – 0.9 × 10–3 m/sec which corresponds to the macroscopic value of the fracture toughness KIc.

Micromechanical characterization of zirconia and silicon nitride ceramics using indentation and scratch methods

Micromechanical characterization of brittle ceramics remains challenging due to the difficulty in sample preparation required by conventional tests. The micromechanical properties (e.g., elastic modulus EIT, indentation hardness HIT, and fracture toughness KIC) of ZrO2 and Si3N4 were investigated by indentation and scratch tests with different indenters (e.g., Vickers, Knoop, and Berkovich indenters) under various loads. The ratio of the true hardness by the Vickers indenter over that by the Knoop indenter is approximately a constant of 1.13 and independent of material. Elastic recovery of residual imprint by the Knoop indenter was also used to assess elastic modulus of ZrO2 and Si3N4, and modified equations were proposed. The length of Vickers indenter-induced cracking was found to be proportional to the applied load under large loads, and a modified formula for calculating fracture toughness was proposed for ZrO2 and Si3N4, which have relatively large fracture toughness of about 9 MPa⋅m1/2. The critical void volume fraction f* in the nanoindentation energy-based methods was found to linearly decrease with the exponent mf of the power-law equation used for curve fitting of the degradation of HIT or EIT with hmax. The determination of fracture toughness by scratch methodology was found to be affected by mechanical properties of material, indenter geometry, and data range.

The Influence of Glass Fiber and Copper Wire z-Binder on the Mechanical Properties of 3D Woven Polymeric Composites

AbstractThree-dimensional composites (3D) have potential applications in various fields due to their enhanced properties compared to conventional two-dimensional composites (2D). This study investigates the effect of different volumes of z-binder made from copper wire and E-glass fiber on the mechanical properties of 3D woven polymeric composites. The tensile, flexural, and fracture toughness behavior of four types of 3D orthogonal woven composites were studied in addition to a comparative 2D composite. The creation of the 3D orthogonal single-ply fabrics involved weaving z-binders using two different copper wire diameters, single fiber bundles, and double fiber bundles, each combined with four layers of woven E-glass fiber. The consolidation process for both 2D fabric and single-fabric 3D woven composites was executed using the hand lay-up technique. The results showed that most 3D woven composites outperformed 2D composites in terms of fracture toughness (stress intensity factor KIC and energy release rate GIC) and flexural strain. However, a decrease in flexural strength and tensile properties was observed for all 3D composites. The specimen with a small copper diameter had the smallest decrease of 5% in tensile strength. Furthermore, a decrease of 9% and 21% was attained by reinforcing with double and single glass fiber bundle z-binders, respectively, as compared with 2D composites. The highest enhancement of 92.5% in flexural failure strain was attained with double glass fiber bundles of z-binder. The maximum improvement in KIC fracture toughness, reaching 126% and 101.5%, was observed in specimens with a single glass fiber bundle z-binder and those with a large copper wire diameter, respectively.

Development of pressure-temperature limit curves considering unified constraint for reactor pressure vessel

In this work, the pressure-temperature (P-T) limit curves considering unified constraint for a typical large-sized reactor pressure vessel (RPV) with axial surface cracks have been investigated and developed based on the KJ-Ad* two-parameter and the Master Curve (MC) method. The ASME fracture toughness KIc curve and the MC with and without considering unified constraint for irradiated RPV steel were used in the constructions of the P-T limit curves. The effects of crack sizes (constraint levels) and fracture toughness curves on the P-T limit curves have been analyzed for the RPV under heatup and cooldown conditions. The results further show that the P-T limit curves based on traditional ASME KIc curve has the highest degree of conservatism and the use of the MC method can significantly increase the safety margin of P-T limit curves. With increasing crack sizes (increasing constraint levels), the safety region in P-T limit curves reduces, which may lead to the decrease of operating flexibility for nuclear power plants. The accuracy of the P-T limit curves can be improved by considering unified constraint. For smaller size cracks with lower constraint in the RPV, the consideration of constraint can reduce conservatism of the P-T limit curves, and for larger size cracks with higher constraint, it can avoid the non-conservatism. It is recommended to obtain more accurate P-T limit curves based on the MC with considering unified constraint and finite element analysis for RPVs under various operating conditions.

Effect of silanization of poly (urea-formaldehyde) microcapsules on the flexural strength and self-healing efficiency of an experimental self-healing dental resin composite (An in-vitro study)

ObjectivesThis study investigated the impact of using γ-methacryloxypropyl trimethoxy silane (MPS) for surface silanization of poly (urea-formaldehyde) (PUF) microcapsules which enclose a healing liquid of “triethylene glycol dimethacrylate (TEGDMA) and N,N dihydroxyethyl-p-toluidine (DHEPT)” on some mechanical properties of an experimental dental composite as well as its self-healing efficiency. MethodsSynthesis of PUF microcapsules was done via in situ polymerization, followed by silanization with MPS silane. Silanized and non-silanized microcapsules were incorporated into a composite containing 30% polymer matrix and 70% fillers at different weight percentages (0%, 5%, 7.5% and 10%). The composite strength and elastic modulus were evaluated by Flexural testing. Fracture toughness KIc and self-healing efficiency were assessed by utilizing the “single edge notched beam” method. ResultsFlexural strength of all groups containing silanized microcapsules was non-significantly different from control group without microcapsules. However, in contrast to control group, all groups containing non-silanized microcapsules displayed considerably decreased flexural strength. Adding silanized and non-silanized microcapsules didn't show a significant change in the KIc-virgin. The silanized microcapsules' groups achieved a self-healing efficiency of about 49–77% recovery in KIc-virgin compared to 38–69% for their non-silanized counterparts. SignificanceIn order to increase the interfacial adhesion with the polymer matrix, improve the mechanical properties, and increase the efficiency of self-healing of dental resin composite, PUF microcapsules were silanized for the first time in the dental field using MPS silane. This innovative silanized microcapsule-containing self-healing composite may hold promise for repairing the damage caused by restorative cracks and extending their service life.

Dy2O3–MgO composite ceramics: Fabrication and properties

An IR-transparent magneto-optical Dy2O3–MgO compositeceramics was fabricated by vacuum hot pressing of glycine-nitrate self-propagating high-temperature synthesized nanopowders. Composites significantly outperform dysprosium sesquioxide ceramics in terms of thermal conductivity and mechanical properties.The HV1 microhardness of the Dy2O3–MgO composite is 9.9 GPa and the fracture toughnessKIC, calculated by the Palmquist method, is 1.7 MPa m½. The thermal conductivity of the composite was measured in the range of 50–300 K and is 10.6 W/(m K) at room temperature. The transmittance of 1.5 mm thick Dy2O3–MgO sample is about 70 % in the wavelength range ∼2.1–2.2 μm and more than 80 % in the range ∼3.6–6.5 μm, which is close to the theoretical value for dysprosium sesquioxide.The value of Verdet constant of Dy2O3–MgO composite ceramics is 7.0 ± 0.3 rad/(T∙m)at 1940 nm.