Sand Fraction Research Articles

Interrelation between compressibility and permeability of reconstituted sandy clays with different sand fractions

It has been well recognized that sand particles significantly affect the mechanical properties of reconstituted sandy clays, including the hosted clay and sand particles. However, interrelation between the permeability and compressibility of reconstituted sandy clays by considering the structural effects of sand particles is still rarely reported. For this, a series of consolidation-permeability coefficient tests were conducted on reconstituted sandy clays with different sand fractions (), initial void ratio of hosted clays () and void ratio at liquid limit of hosted clays (). The roles of in both the relationships of permeability coefficient of hosted clay () versus effective vertical stress () and void ratio of hosted clay () versus were analyzed. The results show that the permeability coefficient of reconstituted sandy clays () is dominated by hosted clay (). Both and affect the of sandy clays by changing the at any given . Due to the partial contacts and densified clay bridges between the sand particles (i.e. structure effects), the in sandy clays is higher than that in clays at the same σ′v. The relationship of sandy clays is independent of and , but is a function of . The types of hosted clays affect the of sandy clays by changing the . Based on the relationship between permeability coefficient and void ratio for the reconstituted clays, an empirical method for determining the is proposed and validated for sandy clays. The predicted values are almost consistent with the measured values with = 0.6 - 2.5.

Baseline Inventory of Benthic Macrofauna in German Marine Protected Areas (2020-2022) before Closure for Bottom-Contact Fishing.

The response of benthic habitats and organisms to bottom-contact fishing intensity is investigated in marine protected areas (MPAs) of the German EEZ in the North and Baltic Seas. We examined the current state of macrofauna biodiversity in 2020-2022. Comparative analysis for macrofauna (in- and epifauna) inhabiting nine Natura 2000 MPAs constitutes a baseline to assess the effects of bottom-contact fishing exclusion in the future. Aspects of spatial and temporal variability are briefly summarized and discussed. We provide a species list for each region, including 481 taxa, of which 79 were found in both regions, 183 only in the North Sea, and 219 only in the Baltic Sea. The Baltic Sea dataset surprisingly included higher numbers of taxa and revealed more Red List species. The share of major taxonomic groups (polychaetes, bivalves and amphipods) in species richness showed peculiar commonalities between the two regions. In the North Sea, multivariate analysis of community structure revealed significantly higher within-similarity and stronger separation between the considered MPAs compared to the Baltic MPAs. Salinity, temperature and sediment fractions of sand were responsible for over 60% of the variation in the North Sea macrofauna occurrence data. Salinity, mud fraction and bottom-contact fishing were the most important drivers in the Baltic Sea and, together with other considered environmental drivers, were responsible for 53% of the variation. This study identifies aspects of macrofauna occurrence that may be used to assess (causes of) future changes.

Rates of sedimentary organic carbon preservation in the Bering Sea and Chukchi Sea, and their response to climate change over the past 75 years

The Arctic Ocean is rapidly warming. In this paper, we document changes in the source, distribution, and accumulation rate of organic matter (OM) for three sediment cores in the Bering and Chukchi seas to investigate changes to the oceanic carbon cycle over the past ∼75 years. Analyses were undertaken using bulk properties, such as total organic carbon (OC), total nitrogen (TN), stable carbon isotope (δ13C), OC to TN molar ratio (C/N), and biomarkers (lignin phenols). The OC, TN, and lignin (Σ8, in mg (g sediment)−1) contents were found to be significantly related to the fraction of sand (Sand%) as a result of sediment sorting and/or different sediment sources. Using an end-member mixing model, we estimated marine OM accounted for ∼67% of all organic matter in all cores, being the dominant source. Moreover, terrestrial OM mainly originated from angiosperm non-woody tissue, while moss contribution was negligible. In the Bering Sea shelf, OC% has not changed over time, but there have been some extreme peaks around the 1960s–1970s and in 2005, which correspond to increased terrestrial input from North American rivers. In the southern core from the Chukchi Sea, the OC% showed an apparent decrease after 2000, accompanied by an increase in sand content, likely due to enhanced delivery of volcanic rocks by the Pacific Inflow from the Bering Sea. In contrast, in the northern core from the Chukchi Sea, the OC% showed a significant increasing trend, with some peaks occurring at the same time as in the Bering Sea core. The mean increase rate was compared to the increase in Siberian riverine discharge, which both could be caused by long-term climate changes. The results highlight the regional differences in the response of OC preservation to climate change and other controlling factors. Further studies with higher spatial resolution are required to better understand the preservation of OC in response to climate change.

Influences of root fragments on soil thermal property measurements with heat pulse method

Heat pulse (HP) method has been widely applied for measuring thermal properties, heat fluxes, and soil–water evaporation for near-surface soil layers. In topsoil layers, the presence of roots violates the underlying assumption of HP method that the soil under test is homogeneous. In this study, numerical and laboratory experiments were conducted to test the influence of root fragments on soil thermal property measurement with HP sensors. Soybean root fragments, with a water content of about 0.74 m3 m−3 and diameters ranging from 0.5 to 4 mm, were carefully repacked into soil samples that were used for HP measurements. Results showed that the effects of roots on soil thermal property measurements depended on root size, root location and directions relative to the heater probe, and the thermal property differences between soil sample and root. Roots showed negligible influence on heat pulse data when the root fragments were positioned outside the HP measurement region (more than probe space away from heater probe), or root diameters (d) were less than 1 mm, or in oven-dried soil samples. On relatively wet soils (i.e., with water content of 0.05–0.25 m3 m−3), when root fragments were located in between the heater and sensing probes (parallel to the probe planes), (1) the heat capacity (C) and thermal conductivity (λ) differences between root-free soil and root-soil mixture increased proportionally with d increased from 1 mm to 4 mm; (2) the differences in absolute values of C and λ between the root-free soil and soil-root mixture were highly dependent on soil water content. The errors in soil C and λ estimates were larger when the root fragment was parallel with than perpendicular to or inclined 45 degrees to the probe plane, and the error overall decreased with a smaller ρb and sand fraction. When the root fragments were positioned within the HP measurement region, or d were larger than 1 mm, or in relatively wet soil samples, it is important to consider root effect when interpreting HP signals.

Litho- and chronostratigraphy of the Upper Quaternary sediments from the Piedra Buena Terrace, Patagonian Continental Margin (SW Atlantic)

This paper presents a detailed description of the lithostratigraphy of mostly contouritic deposits from the Piedra Buena Terrace (PBT), collected at water depth of 2–2.5 km. It is based upon a multi-proxy investigation of five gravity cores, including visual description and scanning, grain size distributions, microfossils and sand fraction study, supported by the analysis of high-resolution sub-bottom profiles. Two older seismic units were identified in addition to those previously described in the area. The defined lithostratigraphic units were correlated to the upper seismic units, while the age of the younger units was confirmed using AMS-14C dating. In terms of the sedimentary facies, the dark quartz-glauconitic sands, which seem to be a fingerprint of the Piedra Buena Terrace, were investigated by applying the X-ray diffraction and performing grain SEM - SE images. The sandy facies correspond to sea-level low-stands during cold glacials (MIS 2 and MIS 4), when glauconite and terrigenous material were transported from the emerged shelf down and along the Patagonian continental slope by vigorous bottom currents. The latter is confirmed by an occurrence of parts of bi-gradational sequences reported from the grain-size distributions in lithostratigraphic units 2 and 4. Units 1 and 3, represented by mostly hemipelagic calcareous ooze, were formed during warm high sea-level stages (MIS 1 and 3). Unlike Unit 1, Unit 3 also demonstrates clear contourite features, similar to Units 2 and 4. They include common bioturbation, occurrence of mottles, lenses, irregular thin layers of sand, erosional boundaries and hiatuses between and within the units, good sorting of fine sands, and microfossil reworking. Together with our previous data from canyons on the Perito Moreno Terrace and the Ameghino segment, supported by available publications from the PBT and Mar del Plata areas, this study demonstrates that the Patagonian Continental Margin could be used as a natural laboratory to investigate and better understand contourite systems.

Insights into glacial processes from micromorphology of silt-sized sediment

Abstract. Silt-rich meltwater plume deposits (MPDs) analyzed from marine sediment cores have elucidated relationships that are clearly connected, yet difficult to constrain, between subglacial hydrology, ice-marginal landforms, and grounding-zone retreat patterns for several glacial catchments. Few attempts have been made to infer details of subglacial hydrology, such as flow regime, geometry of drainage pathways, and mode(s) of sediment transport through time, from grain-scale characteristics of MPDs. Using sediment samples from MPD, till, and grounding-zone proximal diamicton collected offshore of six modern and relict glacial catchments in both hemispheres, we examine grain shape distributions and microtextures (collectively, grain micromorphology) of the silt fraction to explore whether grains are measurably altered from their subglacial sources via meltwater action. We find that 75 % of all imaged grains (n = 9400) can be described by 25 % of the full range of measured shape morphometrics, indicating grain shape homogenization through widespread and efficient abrasive processes in subglacial environments. Although silt grains from MPDs exhibit edge rounding more often than silt grains from tills, grain surface textures indicative of fluvial transport (e.g., v-shaped percussions) occur in only a modest number of grains. Furthermore, MPD grain surfaces retain several textures consistent with transport beneath glacial ice (e.g., straight or arcuate steps, (sub)linear fractures) in comparable abundances to till grains. Significant grain shape alteration in MPDs compared to their till sources is observed in sediments from glacial regions where (1) high-magnitude, potentially catastrophic meltwater drainage events are inferred from marine sediment records and (2) submarine landforms suggest supraglacial melt contributed to the subglacial hydrological budget. This implies that quantifiable grain shape alteration in MPDs could reflect a combination of high-energy flow of subglacial meltwater, persistent sediment entrainment, and/or long sediment transport distances through subglacial drainage pathways. Integrating grain micromorphology into analysis of MPDs in site-specific studies could therefore aid in distinguishing periods of persistent, well-connected subglacial discharge from periods of sluggish or disorganized drainage. In the wider context of deglacial marine sedimentary and bathymetric records, a grain micromorphological approach may bolster our ability to characterize ice response to subglacial meltwater transmission through time. This work additionally demonstrates that glacial and fluvial surface textures are retained on silt-sized quartz grains in adequate amounts for microtexture analysis, which has heretofore been conducted exclusively on the sand fraction. Therefore, grain microtextures can be examined on silt-rich glaciogenic deposits that contain little to no sand as a means to evaluate sediment transport processes.

A Quantitative Provenance Analysis (QPA) Approach to Quantify Controls on Sediment Generation and Sediment Flux in the Upper Reaches of the Magdalena River (Colombia): 1. Natural and Anthropic Controls on the Sand Fraction

AbstractThis study investigates the upper Magdalena river basin (Colombia), which is characterized by tectonic activity, tropical climate, heterogeneous lithological assemblages, and anthropic influence. It aims to comprehend factors controlling sediment generation, flux, and composition by incorporating petrographic data from 27 recent fluvial samples along with geochemistry, geomorphological parameters, historical precipitation, land cover, landsliding and suspended sediment load data. The analysis shows mismatches between sand composition and drainage lithology distribution. A new set of endmember mixing models is presented, quantifying the impacts of erodibility, sand generation potential (related to lithology), and sediment connectivity between hillslopes and river outlets (related to geomorphology). Results show enhanced sediment generation from sedimentary rocks (up to 40%) due to high erodibility, and decreased sediment flux from low‐ to medium‐grade metamorphic rocks (up to 60%) due to controlling morphometric parameters. Overrepresentation of plutonic and high‐grade metamorphic rocks and underrepresentation of volcanic rocks (up to 100%) are controlled by mineralogical and textural parameters. Enhanced landsliding activity in areas with volcanic activity occasionally overshadows basin‐wide compositional trends driven by morphological and lithological characteristics, as it controls rare overrepresentation of volcanic and low‐grade metamorphic detritus in the sand fraction. Sediment retention by hydroelectric dams significantly decreases suspended sediment flux by 30%, while deforestation plays a minor role in sediment flux. This study underscores the importance of coupling sediment generation, geomorphology and the distribution of stochastic events related to seismic activity in any sediment production‐focused study and for developing numerical models in Quantitative Provenance Analysis (QPA).

Proximal sensors for modeling clay mineralogy and characterization of soil textural fractions developed from contrasting parent materials

Proximal sensors combined with X-ray diffraction (XRD) have optimized soil characterization, but scarce studies have focused on predicting the contents of minerals under this scope. The objectives herein were to: a) use the portable X-ray fluorescence (pXRF) spectrometry, diffuse reflectance spectroscopy in the range of visible and near-infrared (Vis-NIR), magnetic susceptibility (χ) and XRD to characterize the mineralogy of soils derived from representative Brazilian soil parent materials, and b) create models to quantify the minerals obtained via XRD. Twenty-two soil profiles developed from gabbro, gneiss, quartzite, mineral and organic sediments were described with 53 soil horizons sampled. Each sample had the sand, silt and clay fractions separated and analyzed with XRD, pXRF, χ, and Vis-NIR. Models were created using the Random Forest algorithm permuting the following predictor variables (separately and combined): pXRF, parent material (PM), χ, soil texture (sand, silt, and clay content), and Vis-NIR. Models’ accuracy was calculated using the leave-one-out cross-validation method. Si, Al, Fe, Ca, K, and Ti contents obtained by pXRF and the χ discriminated the soil particle size fractions according to the parent material. XRD analysis allowed the evaluation of the pedogenetic development of soils and their relation to the respective parent material. The best models for mineral contents were found for hematite (Hm) (104)+(Gt) (130) (R2 = 0.85), Hm (110) + Mh (131) (R2 = 0.76), kaolinite (Kt) (001) (R2 = 0.73), Kt (002) (R2 = 0.80), mica (Mc) (001) (R2 = 0.77), and Mc (020) + Kt (020) (R2 = 0.81). Clay mineralogy content was accurately modeled using only pXRF and parent material data. This approach can facilitate and speed up detailed soil mineralogy characterization. Further studies are encouraged to model the content of minerals found in the sand and silt fractions of soils with diverse mineralogy via proximal sensors and using larger data sets.

Evaluating consistency across multiple NeoSpectra (compact Fourier transform near‐infrared) spectrometers for estimating common soil properties

AbstractRapid and cost‐effective techniques for soil analysis are essential to guide sustainable land management and production agriculture. This study aimed at evaluating the performance and consistency of portable handheld Fourier‐transform near‐infrared spectrometers and the NeoSpectra scanners in estimating 12 common soil physical and chemical properties including pH; organic carbon (OC); inorganic carbon (IC); total nitrogen (TN); cation exchange capacity (CEC); clay, silt, and sand fractions; and exchangeable potassium (K), phosphorus (P), calcium (Ca), and magnesium (Mg). A diverse set of samples (n = 600) were retrieved from a national‐scale soil archive of the Kellogg Soil Survey Laboratory of USDA‐NRCS and scanned with five NeoSpectra scanners. Predictive models for the soil properties were developed using partial least squares regression (PLSR), Cubist, and memory‐based learning (MBL). Cubist outperformed PLSR and MBL, with the best prediction performance for clay, OC, and CEC (R2 > 0.7), followed by IC, sand, silt, and Mg (R2 > 0.6), and then pH, TN, and Ca (R2 > 0.5). K and P were predicted somewhat poorly with R2 of 0.48 and 0.22. All five NeoSpectra yielded comparable near‐infrared (NIR) spectral data and the PLSR models for the soil properties (in terms of model regression coefficients). However, the consistency assessment showed that the model performance was significantly decreased when the training and testing spectra were from different NeoSpectra scanners. It is concluded that NeoSpectra scanners could be rapid and cost effective for estimating certain soil properties, and calibration transfer should be considered for applications where multiple devices are involved and high estimation accuracy from NIR data is required.

Diatom record the holocene marine facies deposition history in inner bay of Pearl River Estuary, South China

To understand the evolution of river mouth systems under natural and human being forces is a critical task in coastal and marine science studies. We present a new sedimentary record with diatom, grainsize analysis and radiocarbon age dating, recovered from a drilling core in an inner bay of the Pearl River Estuary, South China, in order to describe marine facies depositional history and to examine relative palaeoclimatic and palaeoenvrionmental changes during the Holocene. The occurrence of marine diatoms at ca. 9,000 cal. yr. BP provides marine facies starting point at this core profile in the shoal area, west of the Pearl River Estuary. Three fossil diatom units were distinguished following the early to late Holocene epoch division. The changed diatom bio-facies before and after ca. 8,200 cal. yr. BP, especially in coastal and neritic species relative abundances contrast, offers a diatom floral response to the "8.2 kyr" event. In middle Holocene, enhanced diatom absolute abundances of tropical open-sea water species and increased neritic species number and relative abundances, with more sand fractions, provide evidences of diatom bio-facies response to higher sea-level and strong hydrodynamic clearly. Following the regression, fossil diatom flora experienced a long-term decline after ca. 5,500 cal. yr. BP, until to ca. 1,400 cal. yr. BP. In the past ca. 1,400 years, there has been a clear increase in the absolute abundances and biodiversity of diatoms, along with a greater presence of coarse granularity fractions. This is a strong signal that human activities influenced local environmental change, combined with natural forces.An interesting phenomenon of higher sedimentation rate was observed in three periods as a millennial-scale pulse, at ca. 9,000–8,000 cal. yr. BP, ca. 6,500 - 5,500 cal. yr. BP, and ca. 1,000 - 0 cal. yr. BP. Meanwhile, two periods of lower sedimentation rate over longer time interval occurred during those pulses. Through regional correlation, this study presents a record of deposition after ca. 9,000 cal. yr. BP in Holocene marine facies, provide improved understanding of the west shoal evolution history in Pearl River Estuary, and natural and human being impact on diatom flora and coastal geo-environment in low latitude river mouth systems in Asian Monsoon realm.

Conversion of Natural Soil to Paddy Promotes Soil Organic Matter Degradation in Small-Particle Fractions: δ13C and Lipid Biomarker Evidence

The stabilization mechanism of soil organic matter (SOM) has received considerable attention. It is widely accepted that mineral sorption/protection is important for SOM stabilization. However, it remains unclear which organic carbon component is beneficial for mineral protection. We collected soil samples from a paddy field (TP) to compare with natural soil (NS). To illustrate the behavior of different SOM pools and their protection by particles, we separated the soils into different particle-size fractions and then removed the active minerals using an acid mixture (1 M HCl/10% HF). The different carbon pools were analyzed using stable carbon isotopes and lipid biomarkers. Our study showed that acid treatment evidently increased the extractability of free lipids, usually over 60%, which confirmed the predominant role of minerals in SOM protection. For NS, the δ13C values increased with decreasing soil particle sizes and soil depths, indicating that 13C-enriched SOM was selectively preserved. However, this trend disappeared after cultivation, which was mainly attributed to the combined effects of the input of 13C-depleted fresh SOM and decomposition of the preserved 13C-enriched SOM. Meanwhile, based on the degradation parameters of the overall lipid biomarkers, SOM showed higher degradation states in clay and silt fractions than in the sand fraction before cultivation. It is possible that the small particle-size fractions could selectively absorb highly degraded SOM. The clay-associated SOM showed a low degradation state, but its carbon content was low after cultivation. We propose that the previously protected SOM was degraded after cultivation and was replaced by relatively fresh SOM, which should be carefully monitored during SOM management.

Relationships between soil compaction and soil physical-chemical-biological characteristics: A case study from volcanic agricultural soils of Entisol and Ultisol in North Maluku Province of Indonesia

Soil compaction has been recognized as a form of soil degradation that mostly deteriorates agricultural soil health worldwide from various climatic conditions and soil management. Heavy compaction can occur in agricultural soils due to intensive tillage, where its effects on soil properties have been the focus of many studies. The present study was undertaken to assess whether soil compaction occurs in agricultural soils adopting no-tillage systems and how the link between soil compaction and chemical-biological characteristics could be. A field investigation was carried out in two different locations that have different soil types, Entisol in Maitara Island and Ultisol in Halmahera Island, North Maluku Province. Sixteen undisturbed and disturbed soil samples were collected from each location grown with cassava and taken to the laboratory for analysis. Soil components observed included soil texture, bulk density, particle density, total porosity, soil permeability, soil organic matter (SOM), total nitrogen (N), phosphorous (P) availability, and phosphate-solubilizing bacteria (PSB). The findings revealed linear relationships between soil compaction and sand fraction, SOM, PSB, and available P, but none were found in soil total N. These results confirmed the importance of soil compaction management in food crop agricultural systems, particularly when soil carbon is low, to promote soil health. As the inconsistent correlation of soil compaction and chemical-biological properties was found in these two soil types, further investigation is necessary.

Synergistic effects of cold rolling and age hardening on the hardness and tensile characteristics of AA6061 hybrid composites

The present study involves the fabrication of aluminium alloy 6061 matrix hybrid composites with varying weight fractions of silica sand and copper particles by employing the conventional stir casting method. The combined influence of age hardening (AH) and low temperature thermomechanical treatment (LTMT) on the hardness and tensile properties of AA6061 hybrid composites was investigated. The uniform dispersion of the particles in the matrix was confirmed by microstructure analysis and the improvement of Brinell hardness values. The composites exhibited higher tensile strength and hardness than the base alloy. Both AH and LTMT enhanced the properties of the hybrid composites and a comparison between them revealed the best results for LTMT hybrid composites. The LTMT hybrid composite with 3 wt% silica sand and 3 wt% copper (3S3C) subjected to 12% rolling deformation and aged at 100 °C had the highest hardness and tensile strength of 144.26 HV and 290 MPa respectively. The hardness and tensile strength of AA6061-3S3C hybrid composite subjected to LTMT in peak aged condition showed an improvement of 125 and 97% respectively when compared with those of AA6061 alloy. Fracture surface analysis of the thermomechanical treated composites in peak aged condition showed a mixed mode of failure dominant with the ductile fracture.

Assessing the Impact of Gully Erosion on Soil Fertility in Ankpa Local Government Area of Kogi State

This study explores the impact of gully erosion on soil fertility in Ankpa Local Government Area, Kogi State, Nigeria. A systematic sampling procedure was employed, involving composite soil samples collected at varying depths (0 – 15 cm, 15 – 30 cm, and 30 – 45 cm). Physical and chemical analyses were conducted on these samples, and statistical analysis, utilizing the coefficient of variation (CV), was applied to the data. Results revealed that sand fractions dominated the surface horizons in all pedons studied, ranging from 74.10% to 80.60%. Silt content showed irregular accumulation down the profile depth, ranging from 5.00% to 6.00%. Clay content, ranging from 14.40% to 20.40%, decreased down the profile depth, indicating potential illuviation and pedoturbation processes. Bulk density values within the rooting zone were optimal for plant production. Particle size distribution suggested that the studied soils fell within the sandy loam textural class, except for one profile identified as sandy clay loam. Soil pH (H2O) and pH (KCl) indicated highly acidic conditions. Organic carbon content was critically low, and total nitrogen levels were also critically low according to fertility ratings. Available phosphorus ranged from low to moderate levels, while calcium dominated the exchange complexes. Magnesium levels were high, potentially contributing to unstable soil structural arrangements. Potassium content was categorized as moderate, while sodium content was rated moderate with implications for soil fertility. Cation Exchange Capacity (CEC) was moderate, reflecting the general low organic matter content in the soil series. Base saturation indicated high values, suggesting minimal leaching of plant nutrients. In conclusion, the study identifies the complex interplay of soil properties affected by gully erosion, emphasizing the need for targeted interventions to improve soil fertility.

Magnesium Addition and Treatment of Reinforcement Particles in Al6061 – Sea Sand Composite on Coefficients Friction and Wear Rate

Aluminium matrix composite is a composite material that can be used as reinforcement to increase the tribological properties of composite. The process of manufacturing the Al6061-Sea sand composite used the stir casting method with stirring time of 10 minutes and speed of 600 rpm. Stir casting specimens were manufactured with height dimension of 20 mm and diameter of 10 mm. After that, the specimen was friction tested using the pin on disc method. The highest coefficient of friction was the specimen without electroless coating with the addition of 2 wt% Mg of 0.634. The more mass fraction of sea sand, the higher the porosity, and the lower the density. An electroless coating process can be carried out on reinforcing particles. This study aims to determine the effect of addition of Mg and treatment of reinforcing particles on the Al6061-Sea sand composite on the coefficient of friction and wear rate. The coefficient of friction, the specimen density increased, the porosity and the wear rate, decreased. This occurred because the reinforcement particle size of sea sand bonded strongly to aluminium matrix. The highest coefficient of friction was the electroless coating with the addition of 2 wt% Mg of sea sand, which was 0.646.

The Stability of Aggregates in Different Amazonian Agroecosystems Is Influenced by the Texture, Acidity, and Availability of Ca and Mg in the Soil

The processes of occupation and exploitation in the Amazon have been increasing, and as a consequence, forest areas are being replaced by agroecosystems. As a consequence of this change, changes have been occurring in the soil attributes, and consequently, in the stability of aggregates in these environments. Thus, this work had two objectives: the first was to evaluate the impacts generated by the conversion of forests into agroecosystems on the soil attributes that are related to aggregates, in the southwestern region of the Amazon; the second objective was to evaluate the roles of pedophysical and pedochemical parameters on the stability of soil aggregates. The study was carried out on rural properties located in the southern part of Amazonas State, Brazil. Eight areas under different agroecosystems were selected: in the municipality of Canutama: (i) annatto, (ii) guarana, and (iii) cupuassu; in the municipality of Humaitá: (iv) cassava, (v) agroforestry, and (vi) sugarcane; and in the municipality of Manicoré: (vii) pasture and (viii) native forest. Unformed soil samples were collected from the 0.00–0.10 m layer and analyzed for aggregate stability, bulk density, soil organic carbon, and soil organic carbon stock. Univariate, bivariate, and multivariate analyses were performed. The largest soil aggregations occurred in the annatto, guarana, sugarcane, and pasture agroecosystems. We associate the greater aggregation capacity of soils with factors that are inherent to the cultivated species and soil properties. The first factor corresponds to the adaptability of the Amazonian and grass species and their ability to produce biomass. The second factor is related to the physical and chemical properties of Amazonian soils, largely influenced by the sand fraction, soil organic carbon, soil acidity, and availability of exchangeable Ca and Mg.

Mineralogical compositions of soils under three geological formations in some parts of Ogun state, Nigeria and their agricultural potentials

Investigating the mineralogical compositions of soils under different geological formations becomes imperative for maximizing agricultural productivity and ensuring the long-term viability of agricultural practices. Therefore, studies were carried out on mineral compositions and diversities of soils developed over the Basement complex rock, Coastal plain sands and Ewekoro formations in Ogun state Nigeria. A total of nine profile pits (three per location) of 2 m × 1 m × 2 m size were dug in all the three locations. Soil samples were collected from the pedogenic horizons of each profile pits in replicates into a well labeled polyethylene bag. Using X-ray diffractometry (XRD) and scanning electron microscopy (SEM) the mineral contents and their relative abundance, elemental compositions and morphologies of the fine sand, coarse silt and clay fractions of the soils at different topographic positions were identified, described and compared. Results obtained from XRD and SEM analyses exhibited similarities. The most abundant elements in the basement complex and Ewekoro pedon were oxygen, carbon and silicon whereas in the coastal plain sand pedon, oxygen, carbon and aluminum were the most abundant element. The presence of mixed-layer illite, mica, kaolinite, quartz, hematite, anatase, goethite, and chlorite at varying degrees was observed in the pedons developed on these geological formations, although kaolinite and quartz dominated the soil matrix. The mineralogical complexity of the pedons followed the order of basement complex > coastal plain sand > Ewekoro formation. Profiles developed on the Ewekoro formation exhibited the highest degree of weathering, as evidenced by their chemical properties and mineralogical compositions. The petrographic evaluation of the three geological formations revealed that all pedons were rich in quartz and exhibited varying degrees of mineral complexity and maturation. The overlapping and distinct characteristics among the geologies indicated different stages of weathering. By using the mineral maturity index, profiles developed over the basement complex rock and the coastal plain sand could be regarded as sub-matured and this could have contributed significantly to the native fertility of these soils and profiles from the Ewekoro formation were the most weathered. The use of Ewekoro formation for agriculture would necessitate significant investments in agro-inputs and sound principles of soil management through integrated soil fertility management.

SOC bioavailability significantly correlated with the microbial activity mediated by size fractionation and soil morphology in agricultural ecosystems

Despite the fact that physical and chemical processes have been widely proposed to explicate the stabilization mechanisms of soil organic carbon (SOC), thebioavailability of SOC linked to soil physical structure, microbial community structure, and functional genes remains poorly understood. This study aims to investigate the SOC division based on bioavailability differences formed by physical isolation, and to clarify the relationships of SOC bioavailability with soil elements, pore characteristics, and microbial activity. Results revealed that soil element abundances such as SOC, TN, and DOC ranked in the same order as the soil porosity as clay > silt ≥ coarse sand > fine sand in both top and sub soil. In contrast to silt and clay, which had reduced SOC bioavailability, fine sand and coarse sand had dramatically enhanced SOC bioavailability compared to the bulk soil. The bacterial and fungal community structure was significantly influenced by particle size, porosity, and soil elements. Copiotrophic bacteria and functional genes were more prevalent in fine sand than clay, which also contained more oligotrophic bacteria. The SOC bioavailability was positively correlated with abundances of functional genes, C degradation genes, and copiotrophic bacteria, but negatively correlated with abundances of soil elements, porosity, oligotrophic bacteria, and microbial biomass (p < 0.05). This indicated that the soil physical structure divided SOC into pools with varying levels of bioavailability, with sand fractions having more bioavailable organic carbon than finer fractions. Copiotrophic Proteobacteria and oligotrophic Acidobacteria, Firmicutes, and Gemmatimonadetes made up the majority of the bacteria linked to SOC mineralization. Additionally, the fungi Mortierellomycota and Mucoromycota, which are mostly involved in SOC mineralization, may have the potential for oligotrophic metabolism. Our results indicated that particle-size fractionation could influence the SOC bioavailability by restricting SOC accessibility and microbial activity, thus having a significant impact on sustaining soil organic carbon reserves in temperate agricultural ecosystems, and provided a new research direction for organic carbon stability.

Geochemical base for As, Co, Cu, Ni, P, Pb, S, V and Zn in road dust collected in areas of oil industry activity in the Metropolitan Region of Salvador, Bahia, Brazil

Road dust collection was carried out in Salvador and some municipalities in the Metropolitan Region of Salvador (MRS), such as Simões Filho, Candeias, Madre de Deus and São Francisco do Conde, situated within an area of oil activity. In the chemical-physical characterisation of the road dust collected, the average fractions of coarse sand (17.44 %), medium (27.15 %), fine (32.63 %) and very fine (15.54 %) were found in the 17 samples collected. The samples underwent an acid extraction procedure in a closed digester block, with the mixture HCl + HNO3 + H2O2. The extract was analysed and concentrations of Al, As, Co, Cu, Fe, Ni, Pb, P, Sb, V and Zn were determined. Linear regression analysis was applied to the concentrations of As, Co, Cu, Ni, Pb, P, V and Zn, generating the equations of the straight lines, which served as a geochemical baseline for the region of road dust samples. For the enrichment factor (EF), most chemical elements showed values lower than < 1 at the collection points, except for Cu, Mn, and P (10 < EF < 25) and for Co, Cu, P and Ni (5 < EF < 10), in the regions of Candeias and Simões Filho. On the other hand, the geoaccumulation index (Igeo) of most points were evaluated as uncontaminated (class 0) and moderate or uncontaminated (class 1) for Igeo, except for P (class 4) and Mn (class 5). Principal component analysis (PCA) showed accumulated total variance corresponding to 76.45 %. For the hierarchical cluster analysis (HCA), the results agree with those found in the PCA. Points P3 (Candeias) and P16 (Simões Filho) were the points that showed less dissimilarity with the other points analysed, indicating possible enrichment of the chemical elements found at these points, confirmed by the EF values.

Using the surface scattering mechanism from dual-pol SAR data to estimate topsoil particle-sizefractions

Data extracted from Synthetic Aperture Radar (SAR) have been widely employed to estimate soil properties. However, these studies are typically constrained to bare soil conditions, as soil information retrieval in vegetated areas remains challenging. Polarimetric decomposition has emerged as a potentially useful method to separate the scattering contributions of different targets (e.g. canopy/leaves and the underlying soil), which is of significance for areas that are near-permanently covered in low-lying vegetation (e.g. grass) like Ireland – the study area for this investigation. Here, we test the surface scattering mechanism, derived from H-alpha dual-pol decomposition, together with other covariates, to estimate percentages of sand, silt, and clay, over vegetated terrain, using Sentinel 1 data (dual-pol C-band SAR). The statistical modelling approaches evaluated – linear regression (LRM) and tree-based regression models (machine learning) – explicitly consider the compositional nature of soil texture. When compared to the models fitted without surface scattering data, results showed that the inclusion of the surface scattering data improved estimates of silt and clay, with the compositional linear regression model, and estimates of sand and silt fractions with different tree-based models. While not without limitations, our study demonstrated that the polarimetric decomposition method, which is typically used for classification and segmentation purposes, could also be used for soil property estimation, broadening the application of this technique in microwave remote sensing studies.