Formation Temperature Research Articles

Ferrochrome Production in a Submerged Electric Arc Furnace: Fundamental Analysis Based upon the FactSage‐Macro Program Approach

Around 80% of the FeCr produced worldwide is utilized in stainless steelmaking. Thus, the growth of the stainless‐steel industry is directly related to FeCr production. Although the FeCr production in submerged arc furnace (SAF) is fairly stabilized, new challenges have emerged in the furnace operation due to the depletion of lumpy ores, high SiO2 content, and lower Cr/Fe ratio in the low‐grade ores. In this regard, the addition of various fluxes such as quartz, magnesite, and bauxite are considered to improve the Cr recovery in SAF operation, particularly in the context of low‐grade ores. In this study, thermodynamic calculations are performed to discuss the effect of various additives (MgO in magnesite, Al2O3 as bauxite, and SiO2 in quartz form) on Cr recovery and slag formation temperature. In addition, a comprehensive thermodynamic‐based process model has been developed for FeCr operation that captures the most important thermochemical reactions. The modeling results are compared with the plant data, and suitable modifications in the slag compositions are made to maximize Cr recovery. Moreover, new plant trials are performed with modified slag composition, and its effect on Cr recovery is also discussed.

SUBSTANTIATION OF METHOD FOR LEVELING INJECTIVITY PROFILE UNDER CONDITIONS OF CARBONATE RESERVOIRS OF FIELD NAMED AFTER R. TREBSA

At the moment, the issue of reducing water cut during the development of carbonate fractured reservoirs is relevant. In the work, the object of the study is the carbonate deep reservoirs of the R. Trebs field. According to the field development analysis, there are production wells with sharp unpredictable breakthrough of injected water.In order to increase the coverage of pay zones by waterflooding, it is necessary to use methods aimed at limiting the filtration of injected water into water-flooded intervals.High formation temperature and mineralization of formation water are complicating factors in the selection of the injection profile alignment (runway) technology.Taking into account the criteria specified in the work, potential candidates for testing the technology were selected for the runway.The article analyzed the advantages and disadvantages of the existing runway methods used when exposed to injection wells. The criteria for the applicability of various technologies based on the use of: polymer/gel compositions, emulsion compositions, including reverse emulsions, injection of aqueous salt solutions, silicate, thermotropic and complex reagents are highlighted. Technologies and compositions based on water-soluble polymers that form viscoelastic compositions when crosslinkers of various nature are added are recognized as the most promising for the conditions of the fractured reservoir of the Trebs field.Particular attention is paid to laboratory experiments aimed at studying the physical and chemical properties of crosslinked polymer systems, conducting filtration experiments, determining the applicability of the technology for the geological and physical conditions of the study object.According to the results of physicochemical experiments, such parameters as the time of dissolution of reagents, compatibility with formation water, time and temperature of gelling were determined. Based on the shear test, rheological parameters of the investigated polymer systems are determined. Testing was carried out to determine the conditions under which the crosslinked polymer composition breaks down.Filtration experiments were carried out on linear and volumetric models of the formation using core material from the Trebs field to determine the reagent with the highest colmating abilities calculated from the residual resistance factor.

Multiple hydraulic fracture propagation simulation in deep shale gas reservoir considering thermal effects

Deep and ultra-deep shale gas will gradually become the focus of unconventional oil and gas resources in the petroleum industry. In the development of shallow shale reservoirs, the multi-cluster hydraulic fracturing of horizontal wells is the commonly applied technique to create a network of fractures and achieve reservoir stimulation. However, for deep shale reservoirs, the behavior of multiple hydraulic fracture propagation is affected by stress interference between fractures. On the other hand, it is also influenced by the temperature disturbances caused by the injection of low-temperature fracturing fluids into high-temperature formations and the resulting thermal effects. Currently, most research on multiple hydraulic fracture propagation in shale only considers the interaction between fluids and solids while neglecting thermal effects. Therefore, based on the displacement discontinuity method, finite volume method, and finite difference method, this study established a numerical model for the non-planar propagation of multi-cluster hydraulic fractures in deep shale, considering the thermal effects. And the model was validated through numerical solutions of the temperature field and double-fracture propagation. Moreover, the number of fracture clusters, pumping rate, and formation temperature were selected as influencing factors, and the differences in multiple hydraulic fracture propagation with and without considering thermal effects were analyzed. The results show that as the formation temperature increases, the thermal effects become more significant, leading to greater differences in the morphology of multi-cluster fractures. Moreover, the thermal effects are more significant when the formation temperature exceeds 90 °C. Additionally, appropriately reducing the number of fracture clusters or increasing the pumping rate can to some extent mitigate stress interference between fractures and promote uniform fracture propagation. The findings of this study contribute to understanding the influence of thermal effects on multiple hydraulic fracture propagation and provide theoretical basis for the efficient development of deep shale gas.

Curing kinetics and plugging mechanism of high strength curable resin plugging material

Lost circulation, a recurring peril during drilling operations, entails substantial loss of drilling fluid and dire consequences upon its infiltration into the formation. As drilling depth escalates, the formation temperature and pressure intensify, imposing exacting demands on plug materials. In this study, a kind of controllable curing resin with dense cross-network structure was prepared by the method of solution stepwise ring-opening polymerization. The resin plugging material investigated in this study is a continuous phase material that offers effortless injection, robust filling capabilities, exceptional retention, and underground curing or crosslinking with high strength. Its versatility is not constrained by fracture-cavity lose channels, making it suitable for fulfilling the essential needs of various fracture-cavity combinations when plugging fracture-cavity carbonate rocks. Notably, the curing duration can be fine-tuned within the span of 3 to 7 h, catering to the plugging of drilling fluid losing of diverse fracture dimensions. Experimental scrutiny encompassed the rheological properties and curing behavior of the resin plugging system, unraveling the intricacies of the curing process and establishing a cogent kinetic model. The experimental results show that the urea-formaldehyde resin plugging material has a tight chain or network structure. When the concentration of the urea-formaldehyde resin plugging system solution remains below 30%, the viscosity clocks in at a meager 10 mPa·s. Optimum curing transpires at 60 ºC, showcasing impressive resilience to saline conditions. Remarkably, when immersed in a composite saltwater environment containing 50000 mg/L NaCl and 100000 mg/L CaCl2, the urea-formaldehyde resin consolidates into an even more compact network structure, culminating in an outstanding compressive strength of 41.5 MPa. Through resolving the correlation between conversion and the apparent activation energy of the non-isothermal DSC curing reaction parameters, the study attests to the fulfillment of the kinetic equation for the urea-formaldehyde resin plugging system. This discerning analysis illuminates the nuanced shifts in the microscopic reaction mechanism of the urea-formaldehyde resin plugging system. Furthermore, the pressure bearing plugging capacity of the resin plugging system for fractures of different sizes is also studied. It is found that the resin plugging system can effectively resident in parallel and wedge-shaped fractures of different sizes, and form high-strength consolidation under certain temperature conditions. The maximum plugging pressure of resin plugging system for parallel fractures with outlet size 3 mm can reach 9.92 MPa, and the maximum plugging pressure for wedge-shaped fractures with outlet size 5 mm can reach 9.90 MPa. Consequently, the exploration and application of urea-formaldehyde resin plugging material precipitate a paradigm shift, proffering novel concepts and methodologies in resolving the practical quandaries afflicting drilling fluid plugging.

Rapid nucleation and growth of tetrafluoroethane hydrate enhanced by bubble and gas cycling

The application of hydrate technology is predominantly limited by the rapid nucleation and stable formation of hydrates, which could be promoted by the disturbance of bubbles. In this study, the effect of bubble generation and different bubble sizes on the nucleation and growth characteristics of R134a hydrates were investigated. The impact of three methods (depressurization-induced R134a vaporization, depressurization combined with stirring and gas cycling bubbling) of bubble effect and size on the nucleation, growth characteristics, and stability of R134a hydrate formation were explored. The research results indicate that utilizing only the depressurization method to induce R134a vaporization and bubble formation leads to a gas consumption rate of 19.6 mmol/min, which is 868 times higher than that in a pure water system. Furthermore, refining bubble size through stirring under depressurization conditions further augments the gas conversion rate by 8.6 %, and the optimal temperature for R134a hydrate formation is identified to be as low as 4 °C. Importantly, utilizing gas cycling as a means to generate bubbles enables uniform and rapid nucleation and growth of hydrates. Within a short 10 min, R134a hydrates was rapidly and stably formed, achieving a formation rate 35 times faster compared to the boiling-condensation method. In comparison to stirring-depressurization, the gas cycling method further increases the gas consumption rate by 10 %. The drawback of slow nucleation and growth rates in hydrates, as well as the need to enhance their stability, is addressed by the gas cycling method.

Zircon petrochronological evidences for diachronous tectonic switch and orogenic keel collapse of the Tongbai-Dabie-Sulu orogens

Migmatites can be produced in different stages of orogeny and thus have a great significance to constrain the evolution of an orogenic belt. Migmatites widely occur in the Tongbai orogen, but their formation ages and geological significance have not been well constrained. In this study, a combination of cathodoluminescence (CL) imaging, U-Pb-Hf-O isotopes and trace elements of zircons were carried for migmatites in the Tongbai orogen Most inherited cores in a melanosome show variable UPb ages and Hf isotope compositions with high δ18O values, suggesting they might be detrital zircons from its protolith. Whereas other relict cores in this sample have nebulously zoning or no zoning, flat HREE patterns with insignificant Eu anomalies and relatively low formation temperatures, indicating their formation under eclogite-facies conditions. They yield UPb ages of 228 ± 3 Ma, providing direct evidence for the involvement of Triassic subducted continental materials. The overgrowth rims and some new grown grains in the migmatites show euhedral shapes, low CL luminescence, high Th/U ratios, clear negative Eu anomalies and steep HREE patterns, suggesting they are anatectic zircons formed during partial melting. They yield UPb ages from 139 ± 2 to 132 ± 1 Ma. Combined with previous studies, we suggest that migmatization mainly occurred at 139–130 Ma in the Tongbai orogen. The anatectic zircons in the leucosomes show much lower δ18O values (5.79 ± 0.23‰ vs. 8.94 ± 0.16‰) and higher 176Hf/177Hf ratios (0.282302–0.282648 vs. 0.281728–0.282504) than the zircons in adjacent melanosomes, suggesting that the leucosomes might be externally sourced. According to a compilation of the geochronological information of migmatite and magmatism, the Tongbai-Dabie-Sulu orogens have a spatial and temporal variation of partial melting and magma activities in the post-collisional stage. These might result from the diachronical tectonic switch and collapse of the orogenic lithospheric keels caused by the subduction and rollback of the Paleo-Pacific slab.

Comparison of methanol and ethylene glycol effectiveness as chemical inhibitors in the prevention of gas hydrates in well testing barge DT-05 well Z Mahakam field

Gas hydrate is one of the production problems that are often encountered in the management of natural gas wells. Well Z is a natural gas well in the Mahakam field which routinely be tested periodically to determine the ability of flow rate and the production parameters using well testing barge. However, there are often for the formation of gas hydrate formed in several test components in well testing barge. This study aims to determine the effectiveness use of 2 inhibitor chemicals, which are methanol and glycol in handling gas hydrate in the testing barge. Natural gas flow originating from wellhead / upstream 5 MMScfd and temperature 122 °F and the operating pressure 2187 psia. From the simulation results, gas hydrate will form at 46.33 °F and it is obtained that the gas hydrate formation was predicted at the choke manifold. Fluid stream passing through the choke manifold had decreased the pressure into 254 psi and there is also a decrease in temperature from 122 °F to 41.88 °F. Methanol injection develops free of potential hydrates to form in flowlines. The temperature at which hydrates are formed changes to 33.88 °F. In the other hand, after Ethylene glycol injection in flowline, hydrates formation temperature dropped to 0.48 °F. From these results it can be resumed that the application of Ethylene Glycol injection on the process is more effective lowering the temperature of the formation of hydrates in well testing barge.

Genesis of Cu-Sn Mineralization in the Shuangjianzishan Super-Large Silver Deposit, Inner Mongolia: Trace Element Constraints from Chalcopyrite and Cassiterite

The Shuangjianzishan silver polymetallic deposit is located in the copper–tin–lead–zinc–silver polymetallic metallogenic belt in the Southern Great Xing’an Range, with silver resources of more than 18,000 t, which is the largest silver polymetallic deposit in Asia. Early studies concluded that the Shuangjianzishan deposit is typically an epithermal Ag-Pb-Zn deposit that lacks a high-temperature mineralization stage. In recent years, with the deepening of research, a large amount of Cu-Sn mineralization has been found in the deep part of the Shuangjianzishan deposit, but it is less studied. The laser-ablation inductively coupled mass spectroscopy (LA-ICP-MS) technique is used to investigate the distribution and substitution of trace elements in chalcopyrite and cassiterite. In this paper, the trace element study of chalcopyrite and cassiterite from the Shuangjianzishan deposit reveals that Sn, In, As, Se, Sb, and Tl mainly exist in chalcopyrite in isomorphic form, while Pb, Bi, and Ni mainly exist in chalcopyrite in the form of mineral inclusions. The enrichment of the high-temperature elements Sn and Se in chalcopyrite, and the deficit of the middle- and low-temperature elements Ga, Sb, etc., reflect that the chalcopyrite in the Shuangjianzishan deposit was formed in a middle- and high-temperature environment, and it also indicates that the early ore-forming hydrothermal solution may be rich in Sn. Fe, In, Co, and Ni mainly exist in cassiterite in isomorphic form, and the content of W in cassiterite is high. There are two main forms, one is isomorphic and the other is wolframite inclusion. Cassiterite has Fe-rich and W-U-poor characteristics, indicating that cassiterite from the Shuangjianzishan deposit was formed under relatively oxidized conditions, and the relative enrichment of elements such as Fe, W, Zr, and Hf indicates that the temperature of cassiterite formation was high. The elemental content and inter-ionic coupling relationships suggest that the cassiterite from the Shuangjianzishan deposit may have an elemental replacement mechanism of W6+ + Fe2+ ↔ 2Sn4+ or Fe3+ + OH− ↔ Sn4+ + O2−. The trace elements in cassiterite of the Shuangjianzishan deposit are rich in Fe and Mn and depleted in Nb and Ta, according to the Fe-W diagram, and the tin mineralization of the Shuangjianzishan deposit belongs to cassiterite–sulfide-type tin mineralization. Chalcopyrite Co/Ni ratios >1 are consistent with the characteristics of chalcopyrite genesis in hydrothermal deposits.

Intermolecular Interactions between Cysteine and Aromatic Amino Acids with a Phenyl Moiety in the DNA-Binding Domain of Heat Shock Factor 1 Regulate Thermal Stress-Induced Trimerization.

In this study, we investigated the trimerization mechanism and structure of heat shock factor 1 (HSF1) using western blotting, tryptophan (Trp) fluorescence spectroscopy, and molecular modeling. First, we examined the DNA-binding domains of human (Homo sapiens), goldfish (Carassius auratus), and walleye pollock (Gadus chalcogrammus) HSF1s by mutating key residues (36 and 103) that are thought to directly affect trimer formation. Human, goldfish, and walleye pollock HSF1s contain cysteine at residue 36 but cysteine (C), tyrosine (Y), and phenylalanine (F), respectively, at residue 103. The optimal trimerization temperatures for the wild-type HSF1s of each species were found to be 42, 37, and 20 °C, respectively. Interestingly, a mutation experiment revealed that trimerization occurred at 42 °C when residue 103 was cysteine, at 37 °C when it was tyrosine, and at 20 °C when it was phenylalanine, regardless of the species. In addition, it was confirmed that when residue 103 of the three species was mutated to alanine, trimerization did not occur. This suggests that in addition to trimerization via disulfide bond formation between the cysteine residues in human HSF1, trimerization can also occur via the formation of a different type of bond between cysteine and aromatic ring residues such as tyrosine and phenylalanine. We also confirmed that at least one cysteine is required for the trimerization of HSF1s, regardless of its position (residue 36 or 103). Additionally, it was shown that the trimer formation temperature is related to growth and survival in fish.

Development of Selenium-Silica Nanocomposites By Sol-Gel Process Utilizing Three Different Reducing Agents and Its Characterization

Nanocrystalline Selenium was synthesized within a silica matrix using a sol-gel method with high-purity SeO2, ethyl alcohol, distilled water, and TEOS (Tetraethyl orthosilicate). This process encapsulated the selenium dioxide in the silica matrix, which was then reduced at about 100°C using an oil bath. Three reducing agents were employed: acetone vapor, and sodium borohydride (NaBH4) and hydrazine (N2H4) in liquid form. DSC-TGA analyses of the precursor mixture determined the crystallization temperature for selenium nanoparticle formation within the matrix to be around 100°C. Post-heating phase analysis via XRD revealed hexagonal structures, with crystallite sizes between 33 and 43 nm determined using Debye-Scherrer's formula. Morphological studies showed irregular polygonal shapes with rough surfaces, with particulate sizes under 0.2µ for acetone vapor, around 0.1µ for hydrazine, and slightly over 0.1µ for sodium borohydride. Time variations were explored to observe phase and crystallite size changes. FTIR analysis was conducted for bonding assessment, revealing M-O coordination. The composite's absorbance was examined through UV-VIS spectroscopy, and its morphological attributes were investigated using FESEM analysis, complemented by EDX to determine elemental composition

Improved thermodynamic properties of (Sc, V, Ti, Fe, Mn, Co, and Ni) doped NaBH4 for hydrogen storage: First-principal calculation

Sodium borohydride (NaBH4) shows promise as a hydrogen storage option, but its substantial thermodynamic stability limits its practical application. Enhancing NaBH4 by introducing transition metals is an effective approach to enhance its hydrogen-related characteristics. Nevertheless, even with the most successful additives, the temperatures needed for hydrogen release remain too elevated, exceeding 400 °C, which hinders its practical utility. Using first-principles density functional, we have investigated the potential of sodium borohydride as a hydrogen-based fuel source. Our focus has been on the stable α-phase NaBH4 structure with space group symmetry F-43m (216), aiming to understand the impact of 3d transition metal (Sc, V, Ti, Fe, Mn, Co, and Ni) doping on the structural, electronic, and dehydrogenation properties of the NaBH4 system. Furthermore, the heat of formation and desorption temperature values obtained align with the stability and volumetric capacity criteria set by the U.S. Department of Energy (DOE). Our findings indicate that doping transition metals at the Na site weakens the B–H bonds, thereby enhancing the dehydrogenation performance. Among the various systems studied, those doped with Sc and Ti exhibit the most favorable dehydrogenation properties.

Exploring Machine Learning Techniques for Accurate Prediction of Methane Hydrate Formation Temperature in Brine: A Comparative Study

AbstractAccurate estimation of formation conditions plays a pivotal role in effectively managing various processes related to hydrates, including flow assurance, deep-water drilling, and hydrate-based technology development. The formation temperature of methane hydrates in the presence of brine greatly affects the efficacy and accuracy of these processes. This work presents a comprehensive and novel comparative analysis of nine distinct machine learning models for accurate prediction of formation temperatures of methane hydrate. This study investigated the application of major machine learning (ML) algorithms including multiple linear regression (MLR), long short-term memory (LSTM), radial basis function (RBF), support vector machine (SVM), artificial neural network (ANN), gradient boosting regression (GBR), gradient process regression (GPR), random forest (RF), and K-nearest neighbor (KNN). The model accuracy was validated against a large dataset comprising of over 1000 data points with diverse range of salt concentrations. In this regard, model accuracies were compared using several metrics including R2, ARD, and AARD. The experimental results exhibited KNN algorithm to be fast-converging, accurate, and consistent over the entire range of data points with an R2 score of 0.975 and AARD of 0.385%. The results enable efficient and accurate temperature estimation with ML algorithms for multiple hydrate-related processes.

Typomorphic and Technological Characteristics of Quartz of the Mica-Pegmatite Formation on the Example of the Berkutinskaya Vein (South Urals)

Abstract ––Understanding the origin of quartz veins of the mica-pegmatite formation is of great importance for deciphering the emplacement conditions for the of commercially prospective quartz targets. On the example of the Berkutinskaya vein, which is the typical metamorphogenic quartz deposit of the mica-pegmatite formation of the South Urals, we study the source and origin of the mineral-forming fluid, temperatures of quartz formation, the structure of intergranular boundaries, their morphometric feature, the fractal dimension of quartz grains and commercial characteristics of quartz grit. An integrated approach to the study of the typomorphic features of quartz allowed us to assess their impact on the technological characteristics of quartz concentrates. Comparison of data on the content of impurity elements in the Berkutinskaya quartz vein with quartz of the vein No. 175 of OOO Russian Quartz and IOTA-std (Sibelco) showed that the Berkutinskaya quartz vein is promising for commercial development.

The Success of Fabrication of Pure SmFe2 Phase Film with Outstanding Perpendicular Magnetic Anisotropy.

This study used DC magnetron sputtering technology to fabricate Sm-Fe films and systematically investigated the phase transition behavior of Sm-Fe films with different Fe ratios. It was found that at higher Fe content, the films consisted of Sm2Fe17 or SmFe7 phases; as Fe content decreased, the films were mainly composed of SmFe3 or SmFe2 phases; at higher Sm content, the films primarily consisted of Sm phase. Sm is prone to volatilization at high temperatures, so Ta was used as a capping layer to effectively suppress Sm volatilization, successfully synthesizing pure SmFe2 phase films at a nearly 1:2 ratio. The magnetic properties and magnetostrictive behavior of the SmFe2 films were investigated, revealing that pure-phase SmFe2 films exhibit good perpendicular magnetic anisotropy and magnetostriction properties. The larger stress along the perpendicular-to-film direction, resulting from the absence of substrate-induced constraints, contributes to the excellent perpendicular magnetic anisotropy of the films. This study successfully synthesized pure-phase SmFe2 films and discovered a new method for fabricating perpendicularly anisotropic films. The research findings are of great significance for the efficient synthesis of desired films with high phase formation temperatures containing volatile elements.

Стадийность формирования кварц-альбит-алланит-фукситовых прожилков на Au-Pd-месторождении Чудное (Приполярный Урал)

The gold-palladium mineralization of the Chudnoe deposit is represented by mineralized veined zones in fractured and brecciated rhyolites of the Riphean-Vendian age. Native gold and palladium minerals are concentrated mainly in veins of Cr-containing muscovite (fuchsite), in which allanite is present in small amounts; quartz, albite, calcite, potassium feldspar, titanite, apatite, zincochromite and other minerals are also found. Veins of allanite-albite-quartz composition are found in ore zones, in some cases containing abundant fuchsite secretions. It has been established that quartz-albite-allanite-fuchsite and other fuchsite-containing veins are the result of the superposition of quartz-albite vein execution on previously formed gold-bearing fuchsite veins. Quartz-albite vein material fills central parts of the combined veins and cements fragments (xenoliths) of fuchsite, while in some cases part of the gold was redeposited and fixed in the quartz-albite part of the veins. Based on the study of the decomposition structures of solid solutions in native gold, it was previously established that the temperature of gold formation in fuchsite veinlets exceeded 220 °C. The deposition temperature of the main part of the quartz-albite veins was noticeably lower. The homogenization temperature of fluid inclusions in vein minerals (quartz, albite, allanite, calcite) was mainly in the range of 96—168 °C, solutions were enriched with magnesium and calcium chlorides. Under these conditions, allanite, apatite, monazite, xenotime, and molibdosheelite were formed and redeposited, and fuchsite recrystallized.

Effect of melt temperature on the quasi-equilibrium solidification of K465 Ni-based superalloy

The solidification process of Ni-based superalloy K465 was examined using DTA and X-ray diffraction. The impact of melt structure on solidification process and the morphology of MC carbide and γ′-phase was analyzed. It was observed that an increase in melt peak temperature led to a significant decrease in precipitation temperature for carbides, but only a slight increase in the formation temperature of matrix and eutectic microstructure. The X-ray diffraction results showed that some ordered structures were detected in the sample with melt peak temperature of 1450 °C and 1500 °C, but not in the sample with melt peak temperature of 1360 °C. Furthermore, the ordered structure displayed similar crystalline features with M6C carbide. As the melt peak temperature increased, the carbides changed from block type to script type morphology. This phenomenon was likely caused by the formation of ordered structures at high temperatures. However, the microstructure of γ matrix and γ′ precipitates remained unaffected by the melt peak temperature.

Heavy oil removal using modified polyacrylamide and SDS

Composite systems of surfactants have been extensively applied in the recovery and removal of heavy oil. In this work, the characteristics and mechanisms of heavy oil removal in surfactant-polymer systems (SP) were investigated. The effects of the main factors, including the oil-to-water ratio, washing temperature, washing time, and shear rate, on the oil washing rate (OWR) were analyzed through the response surface methodology (RSM). The results demonstrated the ratio of oil to water had the most significant impact on the OWR compared to other factors. Based on the experimental data and the analysis of variances, a high-precision model was established, and the predicted OWR value was 42.0 % at the formation temperature (50 °C). In addition, the adsorption process of the SP molecules onto quartz silica was well represented by the pseudo-second-order kinetic model and the Freundlich isotherm. This indicates that the SP system has the characteristics of multilayer rebinding and heterogeneous adsorption. On the other hand, the adsorption thermodynamics identified that the adsorption was endothermic and unspontaneous. The dynamic experiments showed that the removal of heavy oil was clean and efficient without secondary adsorption and contamination on the solid surface. Furthermore, the oil removal of the SP system was determined by the mechanism of wettability alteration, utilizing the adsorption of SP molecules onto the solid surface to displace the adsorbed heavy oil molecules. The findings enhance the understanding of heavy oil removal by the surfactant-polymer composite system, which is frequently overlooked in conventional methodologies.

The In-Ga-Sb association of the post-Variscan Zn-Pb-Ag vein deposit at Lautenthal, Upper Harz Mountains, Germany: sphalerite mineral chemistry

AbstractThe Lautenthal sphalerite-galena vein deposit is part of the world-class Upper Harz Pb-Zn-Ag district in the Harz uplift block of the Paleozoic Variscan fold belt in Germany. Its sphalerite-dominated mineral association was studied using bulk-ore chemistry, electron probe microanalysis, and laser ablation-ICP-mass spectrometry. Gallium and locally In are the main high-tech-relevant trace elements hosted by sphalerite, with up to 150 ppm Ga and up to 380 ppm In in hand-picked sphalerite samples (mean In/Zn, 0.70 × 10−3). Ore concentrates (≤ 50 kg) contain up to 65 ppm Ga and up to 109 ppm In (mean In/Zn, 0.36 × 10−3). Accessory Fe-Co-rich gersdorffite-1 occurs in the earlier quartz-sulfide ore stage and Sb-rich gersdorffite-2 in the later carbonate-sulfide stage. Enrichment patterns of In are either defined by overprinting textures in the Fe-richer sphalerite-1 of the earlier stage, or relate to primary growth zoning in Fe-poor sphalerite-2 of the later stage. Using the sphalerite geothermometer GGIMFis, formation temperatures (median) of sphalerite-1 were estimated at ~ 230 °C for the Lautenthal orebody and at ~ 175 °C for the Bromberg orebody, which may indicate lateral T-zonation for the earlier ore stage. Sphalerite-2 data indicate formation temperatures of ~ 185 °C (median). Copper-bearing brines of the carbonate-sulfide stage with assumed temperatures of ~ 250 °C initiated replacement of In-poor sphalerite-1 by chalcopyrite and remobilization of Zn and trace elements. Indium-rich sphalerite-2 occurs associated with calcite and fine-grained galena. A direct spatial or temporal link of ore formation to a magmatic-hydrothermal system is unlikely, which contrasts to In-rich epithermal and tin-polymetallic vein deposits worldwide.

Dynamic coupling between cementation and porosity evolution of the Chang 8 tight sandstone reservoir, Ordos Basin: Insights from in-situ microanalysis

Understanding cement paragenesis is crucial to the study of the porosity evolution in low-permeability sandstone reservoirs. Carbon and oxygen isotope analysis with micro-drilling sampling, electron probe microanalysis, and laser Raman spectroscopy microanalysis was used to clarify the origin of cements and their relationship with reservoir quality of the Chang 8 tight sandstone reservoir in the Longdong area of the Ordos Basin. The predominant cements are chlorite, illite, kaolinite, quartz, and carbonate, which occur in 3 forms: grain rim, overgrowth, and filling of intergranular pore and intragranular dissolved pore. The quantitative paragenesis of the cements is established based on the formation temperature of cements obtained through fluid inclusion, oxygen isotope, chemical composition and Raman parameters. The main source of carbon for carbonate cements is the decarboxylation of organic matter in the adjacent mudstone interlayers. The conversion of smectite to illite and the dissolution of feldspar and previous carbonates provide Ca2+, Mg2+, and Fe3+ ions for carbonate cements and authigenic chlorite, and the authigenic chlorite rim continuously grows from the grain surface outward. The porosity reduction by the cements mainly occurs during the main hydrocarbon filling period (80–120 °C), and the reservoir belongs to the type of “hydrocarbon accumulation prior to significant porosity reduction”. This study provides a new approach for studying the temporal and spatial evolution of clastic rock diagenesis.

The Average Symmetry Index of Minerals Co-Varies with Their Hydrogen Content, Rarity, and Paragenetic Mode

Variations in the Dolivo-Dobrovol’sky symmetry index for minerals through time reveal several factors that influence the emergence of crystalline symmetry in natural processes. Of special interest in this regard are the numerous paragenetic modes—different processes of mineral genesis that reflect changes in physical, chemical, and ultimately biological environments that foster the emergence of new mineral species. Here, we consider the roles of hydrogen content, rarity, formation temperature and pressure, and age on the average symmetry of minerals from 57 different modes of formation (i.e., paragenetic modes). We find four significant trends in the average mineral symmetry index for all minerals in each paragenetic mode: specifically, this average index is (1) lower for minerals with greater hydrogen content; (2) greater for minerals formed at higher pressure; (3) lower for minerals of greater rarity; and (4) greater for older paragenetic modes. These findings elucidate some of the intricate relationships among paragenetic modes, average mineral attributes, and the Dolivo-Dobrovol’sky symmetry index, providing insights into the geological processes governing mineral formation.