Abstract
In-situ High-Temperature Environmental Scanning Electron Microscopy (HT-ESEM) is used to characterize the transient phases formed during the melting of complex glass batch mixtures representing simulated nuclear waste feeds. The first phenomenon that occurs is the formation of oxyanionic salt melt, followed by the reaction of oxyanionic salts with refractory grains containing Si, Al, or Mg through surface reactions to form a molten alkali-alumino-boro-silicate phase. The onset temperatures of gas bubble formation and primary foaming are directly determined from the HT-ESEM measurements. The formation of sulfate lakes as well as the formation of high-temperature transient phases floating at the sample surface are also directly observed and identified. Convection currents are observed and their consequences on glass homogenization are discussed.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
