Block Formation Research Articles

Utilization of waste phosphogypsum and absorbent polymer in preparing hollow particles and its application in lightweight blocks

In prefabricated interior wall construction, it is necessary to reduce the material weight as much as possible without sacrificing the strength. This study proposes a novel method by shelling spherical absorbent polymer (SAP) with building phosphogypsum (BPG) to manufacture hollow particles and the associated lightweight block. The apparent density, unconfined compressive strength (UCS) and hydration heat of lightweight blocks were measured for comparative analysis, the water release mechanism of the SAP-based hollow particles was revealed by mercury intrusion porosimetry (MIP) and scanning electron microscope (SEM) tests. The results indicated that the inclusion of hollow particles reduced the apparent density of the blocks by 23.68% and 14.41% for OPC and BPG, respectively. BPG hollow particle is more effective in speeding up the block's early strength than OPC counterpart. In addition, both unshelled and shelled SAP-based blocks can delay the occurrence of the heat release peak, while the latter exhibits better mechanical properties and geometric stability than the former. SAP particles can serve as a water reservoir to facilitate internal curing, which is beneficial to the weight reduction, strength formation, and heat releasing of blocks. Microscopic tests indicated that the fraction of large pores increased while the small pores decreased in shelled hollow particle block compared with pure OPC block. Beyond which, it was noticed that the needle-shaped ettringite tends to generate between the interface of shelled hollow particle and OPC matrix, which plays a positive role in the overall strength of the block. The proposed SAP-based hollow particle block can not only reduce the overall building weight but also promotes the efficient utilization of waste phosphogypsum, resulting in both economic and environmental benefits.

Educational concepts: A longitudinal interleaved curriculum for emergency medicine residency training.

Traditionally, emergency medicine (EM) residency programs teach non-adult emergency department activities (such as pediatric EM, point-of-care ultrasound [PoCUS], emergency medical services, and others) in a block format. In this way, a resident may have a 1-month pediatric EM rotation and then not have any further pediatric EM exposure until their next pediatric rotation 6‒9 months later. Furthermore, some rotations are only allotted for 1-month during the entire residency. A first-year EM resident may have their only formal PoCUS rotation early in the first year of training when their overall skills are developing, and their level of understanding and retention of information may not be optimal at that juncture of their residency training. This is far from ideal from an educational perspective. Learning scientists have now suggested that a longitudinal interleaved curriculum has substantial advantages over the traditional block format. This curriculum allows for a "spaced retrieval" practice that enhances retention of material and develops thinking processes that are important in clinical practice. The increased continuity of clinical experience has been shown to improve educational outcome and learner satisfaction. We developed a novel longitudinal interleaved curriculum for our EM resident trainees. This curriculum encompasses the entire 3 years of residency training and has the goals of increasing EM knowledge and clinical skills and being excellent preparation for board certification examinations. This concept has clear educational benefits. While adapting an existing medical training program would be challenging, a longitudinal curriculum could be phased in to replace a traditional EM curriculum.

INTERNET RESOURCES AS A MEANS OF LEARNING THE UKRAINIAN LANGUAGE AS A FOREIGN LANGUAGE

The article is devoted to researching the relevance of Internet resources as an educational component in the system of teaching Ukrainian as a foreign language. Research and development of linguists, which were feasible in the direction of foreign language training using computer technologies and Internet tools, were studied. The work identifies the motives that encourage foreign citizens to learn the Ukrainian language. The content of popular sites was analyzed for the possibility of independent mastering of the Ukrainian language by foreign citizens with their help. Special attention is paid to researching the content of Internet resources, namely to what extent their content contributes to: mastering phonetics at the proper level, familiarization with grammatical features, mastering communication skills in accordance with modern needs, vocabulary formation. It was determined that the proposed system of interactive exercises and tasks of Internet resources allows for explanations in an interesting and accessible form, consolidation and generalization of material on the example of communicative situations from modern life, which contributes to increasing interest in the educational process. The article examines how the sociocultural and country studies component is reflected in the process of selection and formation of thematic blocks and sections of online resources. It was found that Internet resources contribute to the formation of foreign language speech competence at a sufficient level by combining theoretical knowledge and practical skills. As a result, it was concluded that the use of the Internet in the system of teaching a foreign language and Ukrainian, in particular, has a number of advantages, namely: the distance learning format allows you to independently manage the educational process, in particular, to personally determine the time and place; choose material according to your level; work on topics guided by one’s own goals and interests; students have the opportunity to learn from native speakers, not just from textbooks. The article examines the feasibility and relevance of using Internet resources in the process of learning another language. Positive prospects of using the Internet in the process of mastering the Ukrainian language as a foreign language and in raising the qualification level of teachers working in this direction were identified. Key words: Internet network, Internet resources, Internet tools, Internet technologies, Ukrainian language as a foreign language.

Enhancing iron biogeochemical cycling for canga ecosystem restoration: insights from microbial stimuli.

The microbial-induced restoration of ferruginous crusts (canga), which partially cover iron deposits and host unique ecosystems, is a promising alternative for reducing the environmental impacts of the iron mining industry. To investigate the potential of microbial action to accelerate the reduction and oxidation of iron in substrates rich in hematite and goethite, four different microbial treatments (water only as a control - W; culture medium only - MO; medium + microbial consortium - MI; medium + microbial consortium + soluble iron - MIC) were periodically applied to induce iron dissolution and subsequent precipitation. Except for W, all the treatments resulted in the formation of biocemented blocks. MO and MI treatments resulted in significant goethite dissolution, followed by precipitation of iron oxyhydroxides and an iron sulfate phase, due to iron oxidation, in addition to the preservation of microfossils. In the MIC treatment, biofilms were identified, but with few mineralogical changes in the iron-rich particles, indicating less iron cycling compared to the MO or MI treatment. Regarding microbial diversity, iron-reducing families, such as Enterobacteriaceae, were found in all microbially treated substrates. However, the presence of Bacillaceae indicates the importance of fermentative bacteria in accelerating the dissolution of iron minerals. The acceleration of iron cycling was also promoted by microorganisms that couple nitrate reduction with Fe(II) oxidation. These findings demonstrate a sustainable and streamlined opportunity for restoration in mining areas.

Membrane fouling during the harvesting of microalgae using static microfiltration

A challenge in the filtration of algal suspensions is the reduction in filtrate flow rate with time, associated with membrane fouling and filtercake formation. These two fouling mechanisms may occur simultaneously and have different effects on the scaling relationship of filtration rate with time, making quantitative predictions of the filtration behaviour complex. The foulants include suspended microalgal cells and their presumed Extracellular Polymeric Substances (EPS). To investigate this problem, we perform static microfiltration experiments to harvest oil-rich marine microalgae Nannochloropsis oculata. Batch filtration experiments of microalgal suspensions using glass-fibre membranes are conducted under filtration pressures varying between 0.5 and 200 kPa. Here we investigate the relative importance of potential fouling mechanisms, including pore plugging, entrance blocking, and filtercake formation. We examine variations in filtrate flux, using a novel approach involving numerical differentiation of the filtrate volume to identify how its scaling relationship with time and compare with the traditional root-time behaviour. These results are analysed with reference to the blocking filtration laws to determine the potential fouling mechanism. Rheology tests of both filtration feeds and filtrate are performed, and both optical and scanning electron microscopy are used to observe the filtercake. Our results show a significant drop in the filtrate flux after a spurt loss phase under pressure. The scaling analysis demonstrates a power law relationship between cumulative filtrate volume and time in the post-spurt phase. We show here, for the first time, that the scaling exponent varies with time, approaching a value close to 0.5 (i.e. the root-time behaviour) after a long period of time. Using the analysis, we conclude that the filtration process can be divided into various stages; a spurt loss phase when the pressure is initially applied, followed by a stage in which both internal and external filtercake formation occurs, and a final stage which is dominated by external filtercake formation (at which point root-time behaviour is observed). Furthermore, our findings suggest that fresh microalgal suspensions experienced a larger spurt loss compared to aged suspensions in microfiltration. This difference may be attributed to the limited production of EPS and microalgal debris during shorter cultivation periods. The microscopic observations reveal the invasion of microalgal cells into the membrane, which verifies the formation of an internal filtercake suggested by our scaling analysis. The contamination of the membrane increases with higher filtration pressures. Finally, we demonstrate that Fe3+ coagulant can be used to increase the microalgal particulate size before filtration, resulting in a much higher filtrate flux compared to uncoagulated suspensions. This result provides opportunities to reduce membrane contamination to a negligible level.

Metabolic response of endangered goats fed spineless cactus associated with Tifton-85 hay or Maniçoba hay

The aim of this study was to evaluate the effects of replacement of Tifton-85 hay by maniçoba hay, in spineless cactus-based diets, on markers of energy, protein, mineral metabolism and serum enzyme activity of Moxotó goats. Sixteen uncastrated male Moxotó breed goats, with 20 months old and initial body weight of 21.7 ± 3.92 kg were used in a randomized blocks design, using the initial weight as the criterion for the formation of blocks, with two treatments and eight replicates per treatment. The experimental treatments consisted of two diets: diets containing Miúda spineless cactus associated with Tifton-85 hay (1) or maniçoba hay (2), with roughage:concentrate ratio of 70:30. Blood samples were collected fortnightly (baseline, 15 days, 30 days and 45 days) during the feedlot period. There was a higher serum concentration of total protein and fructosamine (P < 0.05) in goats that received maniçoba hay. However, there was higher serum gamma-glutamyl transferase (GGT) enzyme activity in goats that ingested Tifton-85 hay (P < 0.05). Concerning to the profile of blood metabolites in the different fortnightly collections, it was possible to verify a significant effect for urea, fructosamine, GGT enzyme activity, K and Cl levels (P < 0.05). In conclusion, Tifton-85 hay and maniçoba hay combined with spineless cactus does not cause metabolic disorders in feedlot native goats.

Life cycle dynamics of Greenland blocking from a potential vorticity perspective

Abstract. Blocking over Greenland stands out in comparison to blocking in other regions, as it favors accelerated Greenland Ice Sheet melting and has substantial impacts on surface weather in adjacent regions, particularly in Europe and North America. Climate models notoriously underestimate the frequency of blocking over Greenland in historical periods, but the reasons for this are not entirely clear, as we are still lacking a full dynamical understanding of Greenland blocking from formation through maintenance to decay. This study investigates the dynamics of blocking life cycles over Greenland based on ERA5 reanalysis data from 1979–2021. A year-round weather regime definition allows us to identify Greenland blocking as consistent life cycles with an objective onset, maximum, and decay stage. By applying a new quasi-Lagrangian potential vorticity (PV) perspective, following the negative, upper-tropospheric PV anomalies (PVAs−) associated with the block, we examine and quantify the contribution from different physical processes, including dry and moist dynamics, to the evolution of the PVA− amplitude. We find that PVAs− linked to blocking do not form locally over Greenland but propagate into the region along two distinct pathways (termed “upstream” and “retrogression”) during the days before the onset. The development of PVAs− differs more between the pathways than between seasons. Moist processes play a key role in the amplification of PVAs− before the onset and are linked to midlatitude warm conveyor belts. Interestingly, we find moist processes supporting the westward propagation of retrograding PVAs− from Europe, too, previously thought to be a process dominated by dry-barotropic Rossby wave propagation. After onset, moist processes remain the main contribution to PVA− amplification and maintenance. However, moist processes weaken markedly after the maximum stage, and dry processes, i.e., barotropic, nonlinear wave dynamics, dominate the decay of the PVAs− accompanied by a general decrease in blocking area. Our results corroborate the importance of moist processes in the formation and maintenance of Greenland blocking and suggest that a correct representation of moist processes might help reduce forecast errors linked to blocking in numerical weather prediction models and blocking biases in climate models.

Solar Beeswax Rendering and Hints for Exhibiting Wax Blocks

The article discusses the efficiency of solar wax extractors for beeswax rendering and offers advice on constructing and using them. It outlines the basic design of a solar wax extractor, where wax and old comb are placed on a slanted tray inside a covered box, allowing the wax to melt and collect in a pan when exposed to sunlight. The piece provides a suggested plan for building such an extractor and emphasizes the importance of making it bee-tight to prevent bees from being attracted to the melting wax. Additionally, it highlights the criteria for judging rendered wax in honey shows, such as color, cleanliness, uniformity, and freedom from cracking. The article suggests methods for purifying the wax by allowing foreign materials to settle and scraping them off the bottom of the hardened wax cake. It also advises on minimizing crack formation in the final wax block by cooling it slowly in a preferred mold with slanted sides, like a bread pan. Lastly, it warns against touching the wax block before submission and suggests wrapping it in plastic for protection.

The dynamics of marsh-channel slump blocks: an observational study using repeated drone imagery

Abstract. Slump blocks are widely distributed features along marsh shorelines that can disturb marsh edge habitats and affect marsh geomorphology and sediment dynamics. However, little is known about their spatial distribution patterns or their longevity and movement. We employed an unoccupied aerial vehicle (UAV) to track slump blocks in 11 monthly images (March 2020–March 2021) of Dean Creek, a tidal creek surrounded by salt marsh located on Sapelo Island (GA, USA). Slump blocks were observed along both convex and concave banks of the creek in all images, with sizes between 0.03 and 72.51 m2. Although the majority of blocks were categorized as persistent, there were also new blocks in each image. Most blocks were lost through submergence, and both decreased in area and moved towards the center of the channel over time. However, some blocks reconnected to the marsh platform, which has not been previously observed. These blocks were initially larger and located closer to the marsh edge than those that submerged, and they increased in area over time. Only 13 out of a cohort of 61 newly created blocks observed in May 2020 remained after 5 months, suggesting that most blocks persist for only a short time. When taken together, the total area of new slump blocks was 886 m2, and that of reconnected blocks was 652 m2. This resulted in a net expansion of the channel by 234 m2 over the study period, accounting for about 66 % of the overall increase in the channel area of Dean Creek, and this suggests that slump block processes play an important role in tidal creek channel widening. This study illustrates the power of repeated UAV surveys to monitor short-term geomorphological processes, such as slump block formation and loss, to provide new insights into marsh eco-geomorphological processes.

PRIORITIES AND DISADVANTAGES OF CITY BLOCK DEVELOPMENT

The study aims to find ways to improve the efficiency of urban areas by introducing the planning structure of urban residential areas – the block type of development, taking into account the basic principles of its formation. The authors carry out an analysis of scientific and theoretical materials on etymology and historical experience of the formation of city block buildings in the context of typology of buildings according to planning and spatial characteristics with examples of the planning organisation of the cities of New York, Mexico City, Los Angeles, and Barcelona. We consider the formation of residential blocks through simple geometric shapes, such as a rectangle or a square, and concluded that using such shapes emphasises the uniformity of planning. The main principles and factors of developing city blocks are defined to identify the priorities and shortcomings of this type of building. We establish that city block development contributes to comfortable public spaces and strengthens social ties between residents. The study proves the advantages of transport accessibility in block development by placing essential infrastructure facilities within walking and cycling distance. The presence of closed yards, safety, and the absence of traffic jams form a high level of amenity and social connections; these principles contribute to creating an efficient, functional, and aesthetic urban area. City block development is a promising approach for the development of modern cities, providing residents with comfort and a quality standard of urban life. The article also analyses the main disadvantages of using block buildings, one of which is an increase in the density of buildings, which affects the distribution of sunlight and the shading of space. Despite its shortcomings, city block development remains attractive for developing high-quality and sustainable urban environments. The proposal to use city block development in the post-war reconstruction of residential areas and the use of underground space for shelter is relevant and promising for sustainable urban development in Ukraine. Keywords: city block development, residential environment, residential complex, planning methods, planning structure.

Thermal-flow characteristics analysis of a novel resilient capacity ceramic insulated winding dry type transformer

With the increasing demand for the resilient capacity of transformers in high-proportion renewable energy grids, the overload capacity of transformers and the thermal conductivity of winding insulation materials have been put forward as important requirements. In response to these requirements, a novel ceramic high temperature tolerance insulation winding is proposed in this paper and is applied in a ceramic insulated winding transformer. A combination of simulation and experimentation is used to analyze the thermal-flow characteristics of this transformer. The temperature and flow field distribution characteristics of transformers with both winding insulation methods (ceramic and Nomex paper) are compared. The internal mechanism of reflux near the iron core and high voltage winding under forced air cooling is clarified. A superior outside cooling condition is obtained. A prototype ceramic insulated winding transformer is developed and tested to verify the accuracy of the simulation model. The results show that the hotspot temperature of the ceramic insulated winding transformer under natural cooling is 10.7% lower than that of the Nomex paper insulated winding transformer. With forced air cooling of 2, 3, 4, 5, and 6 m/s applied at the bottom, the hotspot temperature of the ceramic insulated winding transformer is 11.4%, 10.5%, 9.7%, 14.0%, and 17.8% lower than that of the Nomex paper insulation winding transformer, respectively. Under forced air cooling, a reflux phenomenon is observed in both transformers in the vicinity of the iron core and high voltage winding due to the formation of adverse pressure gradient region and wall viscous force blocking. The strength of the reflux is affected by the magnitude of the forced air cooling flow velocity and the construction of the transformer. The optimal range of the external cooling flow velocity for the ceramic insulated winding transformer is 3–4 m/s. The errors between the simulated temperature and the measured temperature at the nine monitoring points of the prototype are all less than 5%, which verifies the effectiveness of the simulation model. The experimental and theoretical basis for the design and application of resilient capacity dry type transformers is provided by this research.

Zircon provenances of the late Paleoproterozoic metasedimentary rock in the South Yangtze Block: Implications for paleogeographic reconstruction

ABSTRACT The zircon provenances of the late Paleoproterozoic metasedimentary rocks are important for assembling Proto-Yangtze and its reconstruction in the Nuna supercontinent. We present a dataset involving 363 detrital zircon U-Pb dating and 165 Hf isotope analyses from the Laochanghe Formation of the Dahongshan Group in the southwestern Yangtze Block. New detrital zircon U-Pb ages, combined with the heterogeneity of sedimentary strata and available magmatic age data, suggest that the maximum depositional age of the Laochanghe Formation cloud be younger than 1.81 Ga and older than 1.74 Ga. The zircon U-Pb-Hf isotope compositions of the volcanic and metamorphic rocks overlap with those of the late Paleoproterozoic metasedimentary rock, suggesting the southwestern Yangtze Block provided provenance at 1.9, 2.3, and 2.7 Ga. This characteristic is significantly different from the northern Yangtze Block only provided partial provenance at 1.9 and 2.7 Ga. The northern and southwestern of the Yangtze Block jointly provide material for the late Paleoproterozoic metasedimentary rocks, combining synchronous late Paleoproterozoic magmatism and metamorphism, indicative of the formation of the proto-Yangtze Block in response to the accumulation of the Nuna supercontinent. Additionally, the potential provenance areas of the late Paleoproterozoic metasedimentary rock in the southwestern Yangtze include the northwestern Laurentia and southern Siberia, excluding the northern Australian, and Cathaysia. These findings indicate that the southwestern Yangtze may have been located between northwestern Laurentia and southern Siberia during the partial fragmentation of the Nuna supercontinent, enhancing our understanding of changes in the Nuna supercontinent over time.

Characteristics of micron-scale pore-fracture modification in marine shale reservoirs with different combustion explosion energy

The combustion explosion fracturing of shale with in-situ methane is a revolutionary fracturing technique, but the modification characteristics of reservoir pores and fractures by combustion explosion energy level are still unclear. In order to study the transformation characteristics of micron-scale pore-fracture systems of marine shale reservoirs with different combustion explosion energies, this study selected a section of shale samples from the Longmaxi Formation in the Luzhou block in the southern Sichuan Basin to carry out different energy gradient combustion explosion test, named W1∼W5 (25–91 MPa). Based on micron CT scanning technology, the three-dimensional reconstruction of shale samples before and after combustion explosion was carried out to analyze the effect of combustion explosion energy on the transformation of the pore-fracture system characteristics. The results show that at the energy between 25 MPa and 45 MPa, the variation characteristics of cracks before and after explosion are not obvious. When the energy of the explosion is in the range of 61 MPa–91 MPa, the cracks gradually extend and become longer, and the distribution density of cracks becomes higher and more interconnected. After the explosion at 91 MPa, it can be seen that a number of annular cracks are generated at the edge of the sample, which are interconnected with radial cracks. Total porosity, connected porosity, pore number, and total pore volume of the shale increased after combustion explosion, where the total porosity at the combustion explosion energy of 91 MPa have the largest increment, while the connected porosity, pore number, and total pore volume in the combustion explosion energy of 71 MPa have the largest relative increments, indicating that there is a fracturing pressure value that strongly breaks through the bottleneck when the explosion pressure is between 61 MPa and 71 MPa. A comparison of different pore size sections before and after the combustion explosion pore volume share found that the explosion pressures of 25 MPa, 45 MPa and 91 MPa tend to expand from 100 to 200 μm pore size to form a larger volume share of >200 μm cracks, while at the explosion pressure of 71 MPa, more inclined to transform the 0–100 μm pores, so that the pores gradually transition to the 100–200 μm. Analysis shows that the gas explosion generates a large pressure, release a large amount of heat. Due to the high temperature and high pressure coupling effect, the pore-fracture in the shale changes significantly. Strong stress waves lead to stress concentration at the tip of shale and crack expansion and extension. At the same time, the local expansion force causes “pore expansion effect”. Various mineral particles in the shale undergo differential expansion, along the crystal rupture or through the crystal rupture. New pore fractures are also generated when the original pores keep expanding, which improves the shale pore connectivity. This understanding can provide a theoretical basis for the selection of the energy level of the in-situ methane combustion explosion in shale.

Research on the Process of Laser Cladding Ni60 Coating on High-Nickel Cast Iron Surfaces

In order to achieve high-performance coatings on the surface of electric submersible pump impellers, it is crucial to optimize the laser cladding process parameters. Using Ansys 2021 R1 commercial software, a numerical simulation of laser cladding Ni60 powder on high nickel cast iron was conducted. The simulation utilized a 3D Gaussian heat source, parametric language, and life–death unit technology to replicate the characteristics of synchronous powder delivery laser cladding. The study focused on analyzing the temperature field cloud map and molten pool size under different laser power and scanning speeds, narrowing down the process parameter window, selecting optimized laser power and scanning speed, and assessing the changes in surface morphology, melting height and width, dilution rate, microhardness, and microstructure of the laser cladding coating. Results indicate that the coating width and thickness increase with higher laser power and lower scanning speeds. The microstructure consists primarily of dendritic, block, short rod, and long strip formations, and exhibits a tightly distributed and uniform grain structure. Furthermore, the microhardness of the coating shows a negative correlation with laser power and scanning speed. The optimal process parameters were determined to be a laser power of 1100 W and a scanning speed of 6 mm/s. A comparison with the simulation confirmed the effectiveness of the simulation in effectively guiding actual production.

Comparative clinical study of phosphorous necrosis and medical-related osteonecrosis of the jaws.

Phosphorous necrosis of the jaw (PNJ) exhibits similar clinical and pathological features as medical-related osteonecrosis of the jaw (MRONJ). This study aims at comparing the similarities and differences between PNJ and MRONJ regarding pathological features and to provide a theoretical basis for the clinical diagnosis and management of PNJ. A retrospective analysis was conducted to assess clinical differences among 38 PNJ patients and 31 MRONJ patients, who were diagnosed and treated between January 2009 and October 2022. Pathological alterations in bone tissue were evaluated using EDS, H&E, Masson, and TRAP staining on five specimens from both MRONJ and PNJ cases; furthermore, immunohistochemistry was used to determine the expression levels of OPG, RANKL, and Runx2. The mandibular coronoid process was removed from individuals with temporomandibular joint ankylosis to serve as a control. CBCT imaging demonstrated necrotic bone formation in block, strip, or plaque shapes. EDS analysis showed that the calcium/phosphorus ratio in the bone tissue of PNJ and MRONJ was significantly lower than that of the control group (P < 0.05). Additionally, staining indicated reduced osteoblast counts, disrupted bone trabecular structure, and decreased collagen fiber content in the bone tissues of PNJ and MRONJ. Immunohistochemistry demonstrated that RANKL expression was significantly lower in MRONJ compared to PNJ and control groups (P < 0.05). Conversely, Runx2 expression was significantly higher in PNJ than in MRONJ and control groups (P < 0.05), and there was no significant difference in OPG expression. PNJ and MRONJ demonstrate comparable clinical manifestations and pathological traits, although disparities may exist in their underlying exhibit comparable clinical manifestations, pathological traits, and molecular mechanisms.

The Implementation of National Defense Policy: Understanding the Concept in the Millennial Era

Purpose: This research aims to comprehensively examine the implementation of national defense policy in the millennial era, explicitly focusing on the conceptual understanding within the framework of the National Defense program in the Republic of Indonesia. The study aims to shed light on the challenges and implications of the evolving threat landscape, globalization, and technological advancements, emphasizing the necessity for a strategic and well-utilized defense strategy. Theoretical Reference: This research is grounded in the theoretical framework of state defense, emphasizing its significance as a mindset and pattern of action aligned with the values of Pancasila. The study draws on the context of Indonesia's pluralistic and multicultural conditions, exploring how these factors contribute to the complexity of implementing state defense. The theoretical foundation is further supported by critical variables, including government leadership, the formation of reserve component blocks, and citizenship education, all crucial in shaping a robust national defense strategy. Method: This qualitative case study explores the implementation of state defense policies in the millennial era. Key aspects include assessing the government's role, National Defense program effectiveness, and community participation. Respondent selection involves stakeholders, ensuring diverse perspectives. Data collection comprises in-depth interviews and document analysis. Results and Conclusion: The results of this research highlight the intricate nature of implementing state defense in the millennial era, considering the challenges arising from globalization, technological advancements, and internal conflicts. The study underscores the importance of genuine role models among national leaders and stakeholders, especially in fostering a paternalistic culture for the younger generation. The conclusion emphasizes the constructive nature of defending the country as a strategy for maintaining national integrity and empowering the Republic of Indonesia in the face of evolving threats. Implications of research: The implications of this research extend to various sectors, including government policy-making, defense program development, and societal awareness. The study provides insights into the urgency of aligning government programs with the dynamic needs of the millennial era. Originality/value: This research uniquely explores the implementation of national defense policy in Indonesia's millennial era, integrating theory, qualitative analysis, and critical variables. It enriches the discourse on state defense by addressing challenges and opportunities in the evolving global and technological landscape. A valuable resource, it benefits scholars, policymakers, and practitioners.

Formation of misoriented blocks during single-crystal CVD diamond growth

This paper presents the results of a CVD diamond crystal growth experiment on an HPHT type IIa substrate (9 × 9 mm). Data acquired through cathodoluminescence and EBSD methods shed light on the aspects of the formation of a polycrystalline shell around a single crystal of CVD diamond. CVD diamond exhibits orientation features of the polycrystalline shell, microblocks, low-angle boundaries, and linear hexagonal macrostructures of dislocation origin. Crystal splitting occurs when the dislocation density increases from the geometric center to the periphery. Such CVD diamonds exhibit a continuous transition from single crystal to polycrystal through a block-type crystal.

Application of a Finite-Discrete Element Method Code for Modelling Rock Spalling in Tunnels: The Case of the Lyon-Turin Base Tunnel

Brittle failure, or spalling, occurs around openings excavated in hard rock masses with high in situ stresses. It takes place due to the nucleation and growth of cracks around the excavation boundary, induced by the redistribution of stresses following the excavation. Modelling this failure process is a tough challenge. The hybrid finite-discrete element method (FDEM) can overcome the boundary between continuum and discontinuum, capturing emergent discontinuities associated with brittle fracturing processes. In this study, FDEM is applied using a commercial code to show its applicability to model brittle behaviour around deep underground excavations in the case of the Torino-Lyon Base tunnel in three different stress conditions. Except for the hydrostatic condition, cracking is triggered immediately after the excavation. Spalling occurring around the tunnel is quite extended; therefore, an accurately designed support must be installed to prevent blocks from falling from the tunnel boundary. The obtained results are aligned with previous results existing in the literature. However, in this case, a deeper spalling is caused by the shape change due to the gradual stress redistribution. Such a phenomenon underlines the importance of using a code able to identify crack propagation, opening, and the formation of loose blocks that progressively modify the tunnel contour.

Block Copolymers of Polyolefins with Polyacrylates: Analyzing and Improving the Blocking Efficiencies Using MILRad/ATRP Approach.

Despite their industrial ubiquity, polyolefin-polyacrylate block copolymers are challenging to synthesize due to the distinct polymerization pathways necessary for respective blocks. This study utilizes MILRad, metal-organic insertion light-initiated radical polymerization, to synthesize polyolefin-b-poly(methyl acrylate) copolymer by combining palladium-catalyzed insertion-coordination polymerization and atom transfer radical polymerization (ATRP). Brookhart-type Pd complexes used for the living polymerization of olefins are homolytically cleaved by blue-light irradiation, generating polyolefin-based macroradicals, which are trapped with functional nitroxide derivatives forming ATRP macroinitiators. ATRP in the presence of Cu(0), that is, supplemental activators and reducing agents , is used to polymerize methyl acrylate. An increase in the functionalization efficiency of up to 71% is demonstrated in this study by modifying the light source and optimizing the radical trapping condition. Regardless of the radical trapping efficiency, essentially quantitative chain extension of polyolefin-Br macroinitiator with acrylates is consistently demonstrated, indicating successful second block formation.

Lower Cisuralian brachiopod faunas from the Lhasa and South Qiangtang blocks in Tibet and their biostratigraphical and palaeobiogeographical implications

The opening time of the Bangong-Nujiang Ocean (BNO, also known as the Meso-Tethys Ocean) remains controversial. It was documented to have opened during the Permian, Early Palaeozoic or Mesozoic times. The Permian faunas and their palaeobiogeographical affinities of the Lhasa and South Qiangtang blocks bordered by the Bangong-Nujiang Suture Zone are crucial for reconstructing the tectonic evolution of both blocks and determining the opening time of the BNO. This paper describes two new lower Cisuralian brachiopod faunas from the uppermost Yunzhug Formation of the Lhasa Block and the Zhanjin Formation of the South Qiangtang Block. These two faunas exhibit a high similarity in composition, both containing species of Bandoproductus, Spirelytha and Sulciplica thailandica. Comparable brachiopod faunas are found from the glaciomarine diamictites in the blocks of the eastern Cimmerian belt including the Baoshan, Irrawaddy and Sibuma, as well as the Tethys Himalaya and the Gondwanaland. They are herein named the Bandoproductus-Spirelytha association, which exhibits apparent Gondwanan affinities. Cluster analysis and principal components analysis are employed to conduct a palaeobiogeographical reconstruction of the Asselian–Sakmarian brachiopod faunas primarily from the aforementioned tectonic units. A single palaeobiogeographical unit, the Indoralian Province, is recognised and represented by the unified brachiopod association. This suggests that most of the Cimmerian blocks, including the Lhasa and South Qiangtang blocks, were attached to the northern Gondwanan margin during the early Cisuralian. This is in contrast to our previous results revealed by multiple quantitative analyses for the Kungurian–Roadian brachiopod faunas in the Tethys, which show distinct faunal differences between the Lhasa and South Qiangtang blocks. This palaeobiogeographical discrepancy suggests that the two blocks probably had varying northward drifting tempos after they detached from the Gondwanaland, that is, the South Qiangtang Block drifted faster and incorporated into the temperate-warm region of the Northern Cimmerian Subprovince; whereas the Lhasa Block drifted relatively slowly and retained to be close to the northern Gondwanan margin and belonged to the Southern Cimmerian Subprovince during the late Cisuralian. The faunal differences provided critical implications that the BNO probably had opened in the Artinskian and reached a certain width with distinct faunal differences during the Kungurian.