Sediment Flux Research Articles

Topography‐Based Particle Image Velocimetry of Braided Channel Initiation

AbstractRiver channels shape landscapes through gradual migration and abrupt avulsion. Measuring the motion of braided rivers, which have multiple channel threads, is particularly challenging, limiting predictions for landscape evolution and fluvial architecture. To address this challenge, we extended the capabilities of image‐based particle image velocimetry (PIV)—a technique for tracking channel threads in images of the surface—by adapting it to analyze topographic change. We applied this method in a laboratory experiment where a straight channel set in non‐cohesive sediment evolved into a braided channel under constant water and sediment fluxes. Topography‐based PIV successfully tracked the motion of channel threads if displacements between observations were less than the channel‐thread width, consistent with earlier results from image‐based PIV. We filtered spurious migration vectors with magnitudes less than the elevation grid spacing, or with high uncertainties in magnitude and/or direction. During braided channel initiation, migration rates varied with the channel planform development, showing an increase as incipient meanders developed, a decrease during the transitional braiding phase, and consistently low values during the established braiding phase. In this experimental setup, migration rates varied quasi‐periodically along stream at the half scale of initial meander bends. Lateral migration with respect to the mean flow direction was much more pronounced than streamwise migration, accounting for approximately 80% of all detected motion. Results demonstrate that topography‐based PIV has the potential to advance predictions for bank erosion and landscape evolution in natural braided rivers as well as bar preservation and stratigraphic architecture in geological records.

Modeling the Cross‐Sectional Dynamics of Tidal Sandbanks in Sediment‐Scarce Conditions

AbstractTidal sandbanks are large‐scale dynamic bedforms that consist of sandy sediment. They have been observed in shallow seas with varying sediment supply, including sediment‐scarce environments like the Flemish Banks, Zeeland Banks, and Norfolk Banks. However, we do not yet understand how scarcity affects sandbank evolution. Therefore, we have developed an idealized nonlinear process‐based model with the aim of studying cross‐sectional shape and migration under sediment‐scarce conditions. Scarcity is included through a non‐erodible layer from which no sediment can be entrained. Our results show that bank height and width decrease when the sediment budget decreases. The bank height is more sensitive to scarcity than bank width. Furthermore, sand scarcity decreases (and may even reverse) bank asymmetry and increases migration rate when a residual current is present. The migration rate attains a maximum for a specific sediment budget, which is controlled by the ratio of the cross‐sectional area of the sandbank and the tide‐averaged sediment flux. Our findings show that sandbank dynamics are strongly affected by scarcity, which is critical for seas with receding sediment stocks (e.g., through extraction).

Impact of dam construction on sediment transport capacity: A case study of the Three Gorges Reservoir

AbstractReservoir sedimentation affects lifespan, hydropower generation, water resource use, and ecosystem sustainability. In this study, using measured data from the world‐renowned Three Gorges Reservoir (TGR), sediment transport capacity was analysed from 2002 to 2020 at four TGR gauging stations (Cuntan, Qingxichang, Wanxian, and Miaohe). The result indicated that: (1) a significant decrease in sediment transport capacity occurred in the TGR before and after dam construction, with an overall reduction of 82% in the perennial backwater zone. Notably, Qingxichang, Wanxian, and Miaohe experienced reductions of 40%, 91%, and 59%, respectively. Since the initial operation phase, their maximum monthly sediment transport capacity has consistently occurred in July. (2) Changes in the water level in front of the dam, the incoming flow, and sediment influxes were the primary factors driving the annual variations in sediment transport capacity. Among the factors affecting the variation of sediment transport capacity along the TGR, the influence of the cross‐sectional morphology was more pronounced than that of the distance from the dam. Sediment transport capacities in the wide and shallow sections were considerably lower than those in the narrow and deep sections. (3) A sediment transport amplitude index () was proposed to assess the sediment dynamics within the TGR, which effectively characterized the sedimentation conditions based on the relative importance of these influencing factors. These findings provide a theoretical basis for operational strategies in the TGR and offer insights into the patterns of sediment transport capacity changes in reservoir areas before and after dam construction in other river‐type reservoirs.

Seasonal dynamics of water and sediment in the permafrost basin of the Qinghai‐Tibet plateau and its driving factors

AbstractClimate change has regulated cryosphere‐fed rivers and altered interannual and seasonal sediment dynamics, with significant implications for terrestrial material cycles and downstream aquatic ecosystems. However, there has been a notable scarcity of research focusing on the patterns of water–sediment transport within these permafrost zones. Integrating 6 years (2017–2022) of in‐situ observational data from FengHuoShan basin with the partial least squares‐structural equation modelling (PLS‐SEM) method, we analyse the driving factors, characteristics and seasonal patterns of the water–sediment transport process. We observed a gradual increase in both suspended sediment flux (SSF, Mt/yr) and runoff (Q, km3/yr) within the basin, with annual growth rates of 1.34%/yr and 0.75%/yr, respectively. It is worth noting that these growth rates exhibit seasonal variations, with the highest values observed in spring (SSF: 1.76%/yr, Q: 1.71%/yr). This indicates that the response to climate change is more pronounced in spring compared with summer and autumn. Through mathematical statistics and the PLS‐SEM model, we found that temperature plays a predominant role in the dynamics of water–sediment in both spring and autumn, whereas rainfall exerts a more significant impact during the summer. Most suspended sediment concentration (SSC, kg/m3) peak events throughout the year are primarily driven by rainfall. Affected by the freeze–thaw cycle of permafrost, SSC and discharge (Q, m3/s) exhibit distinct seasonality. SSC and Q demonstrate a clockwise trend; both Q and SSC begin to increase from May and peak in August before declining. The insights gleaned from this study hold significant implications for water resource management and soil conservation strategies in the region, particularly in the face of ongoing climatic changes characterized by warming and increased humidity.

The Incomplete Record of Autogenic Processes Sets Limits on Signal Detectability

AbstractSpectral analysis is a central tool regularly used by the scientific community to identify the presence of periodic processes within a time series of information, as spectral peaks at an imposed periodicity can be differentiated from internal (autogenic) variance. In scientific disciplines, such as seismology, the time series of information is of high temporal resolution. Hence, although temporal gaps are present, they do not impact the overall noise structure, meaning that the full spectrum of autogenic variance can be reconstructed. However, power spectra generated from stratigraphic information are affected by temporal incompleteness due to varying episodes of erosion and geomorphic stasis, which generate gaps over a range of scales. This removes information related to the natural and autogenic variability present within sediment‐transport systems, which makes it challenging to accurately reconstruct the structure and strength of paleo‐surface processes, which defines the detectability of past environmental signals. We explore how incompleteness impacts the temporal structure of autogenic noise within power spectra, and how this influences the detectability of spectral spikes related to environmental signals. We utilize a sediment flux time series from a physical rice pile and progressively degrade these data to mimic varying degrees of stratigraphic incompleteness. We find that incompleteness strongly influences the timescales and spectral structure of autogenic noise evident, and can render signals over all periodicities undetectable within a highly incomplete time series. This offers the ability to confidently justify the interpretation of subtle environmental signals from field measurements and understand the records that may best preserve paleoenvironmental variability.

Size Distributions and Health Risks of Particulate Polycyclic Aromatic Hydrocarbons in the Atmosphere at Coastal Areas in Ningbo, China.

Most current research focusing on the health risk assessments of particulate polycyclic aromatic hydrocarbons (PAHs) have not analyzed the size distributions and human respiratory deposition rates. In the present study, size-separated particulate matter (PM) was collected in the coastal area of Ningbo using an Anderson eight-stage air sampler over a 1-year period (2014-2015). The 16 US Environmental Protection Agency priority PAHs associated with PM were pretreated with rapid solvent extraction and analyzed by gas chromatography-mass spectrometry. The respiratory exposure assessment was determined using the multiple-path particle dosimetry (MPPD) model. The results show that all PAHs exhibited bimodal distribution with one mode peak in accumulation mode (0.43-0.65 µm) and another mode peak in coarse mode (4.7-5.8 µm). In addition, a low coefficient of divergence of PAHs between PM2.1 and PM2.1-10 indicated a high spatial heterogeneity in source factor contribution and formation mechanism. The deposition fluxes (tracheobronchial + pulmonary) of PM were highest for children in the size range of 3.3 µm < particle diameter (Dp) < 9 µm, while for males and females the highest fluxes occurred in the size range of 1.1 µm < Dp < 2.1 µm. The depositions of coarse PM in children were significantly higher than those in adults. The benzo[a]pyrene equivalent (BaPeq) depositions of dibenz[a,h]anthracene ranged from 1.4e-04 to 0.015 ng h-1, which were highest among the PAHs. The PAHs on particles with Dp >4.7 µm contributed approximately three times more to children than to males and females. Therefore, the toxicity of coarse PM to children needed attention. The incremental lifetime cancer risks (ILCR) for children, males, and females were estimated to be 2.92 × 10-7, 1.82 × 10-7, and 2.38 × 10-7, respectively, which were below the cancer risk guideline value (10-6). These ILCR values were much lower than the risks calculated without considering particle size distributions and respiratory depositions. The combination of the size-segregated sampling technique and the MPPD model can effectively avoid the overestimation of human respiratory exposure. Environ Toxicol Chem 2024;43:1364-1377. © 2024 SETAC.

Considering the Size Distribution of Elements in Particle Matter and Oxidation Potential: Association before and after Respiratory Exposure

Oxidation potential (OP), reflecting the redox activities of particle matter (PM), is considered an optimal measure to explain the biological effects of PM exposure. However, the size resolution of the relationship between OP and chemical composition in PM, especially how the relationship changes after respiratory exposure, has not been well investigated. In this study, size-resolved indoor PM10 samples were collected from a waste recycling plant from November to December 2021 using an Anderson eight-stage cascade impactor. OP, measured by a dithiothreitol (DTT) assay (defined as OPDTT), and elements, determined by inductively coupled plasma–mass spectrometry (ICP-MS) in size-resolved PM, were determined to check their relationships and the related human exposure risk. The results indicated that compared with PM0.4 and PM0.4–2.1, PM2.1–10 contributed the most to total OPDTT and its bound elements contributed the most to potential health risks, both before and after respiratory exposure. The association between OPDTT and the elements varied with PM size. Pearson correlation analysis showed that the PM0.4- and PM0.4–2.1-bound elements were moderate-to-strongly positively correlated with OPvDTT (r: 0.60–0.90). No significant correlation or dose–response relationship was found in PM2.1–10. After respiratory exposure, several PM0.4- and PM0.4–2.1-bound elements had a moderate-to-strongly positive correlation with deposition fluxes of OP (defined as OPFlux) (0.69–0.90). A generalized linear model analysis showed that the interquartile range (IQR) increase in the PM-bound elements (ng h−1) was associated with a 41.7–58.1% increase in OPFlux. Our study is a special case that enriches the knowledge of the association between OPDTT and the chemical composition of PM of different sizes, especially after respiratory exposure, but the generalizability of the findings to other settings or types of PM may be limited. The associations among OPDTT, other chemical compositions of PM, and human exposure risk merit further research.

Ca isotopic gradients in epeiric marine carbonates: Diagenetic origins of and significance for Ca cycle reconstructions

Marine carbonates record geochemical information on the state of Earth’s surface environment in the geological past, but recrystallization during burial can make the records difficult to interpret. Here, we report shore to basin gradients in δ44Ca values in matrix limestone and burrow dolomite across a sequence of Late Ordovician (Katian Stage) burrow-mottled carbonates in the Williston Basin, an intracratonic epeiric marine basin in North America. Both gradients are interpreted to have diagenetic origins. The gradient in limestone δ44Ca values developed in a bathymetrically controlled sediment- to fluid-buffered diagenetic system operating between the center and the edges of the basin. Two dolomitizing events formed the gradient in dolomite δ44Ca values. The sediment-buffered end of the limestone gradient preserves the δ44Ca value of the original carbonate mud (∼–1.28 ± 0.10 ‰). The fluid-buffered end of the gradient conserves the δ44Ca value of contemporaneous seawater (–0.47 ± 0.10 ‰), because: (1) pore water exchange drivers operated with greater variety and intensity in shallow water settings, (2) shallow nearshore deposits exchanged more Ca with seawater during recrystallization to diagenetic calcite than deeper offshore deposits, and (3) diagenetic calcite formed with negligible fractionation under equilibrium conditions. The gradient conserves the local value of Δsed (–0.81 ± 0.20 ‰) despite its diagenetic origin, and the magnitude of Δsed is consistent with primary calcite precipitation in a ‘calcite sea’. Field assessment of the equilibrium Ca isotope fractionation factor between calcite and dolomite of –0.41 ± 0.17 ‰ at ambient temperature is applied to correct basin-centered dolomite for fractionation, yielding –1.62 ± 0.27 ‰, which is very different from the –0.25 ± 0.07 ‰ value of Ca in evaporatively concentrated seawater from which the dolomite originally formed. Applying the same fractionation factor to correct literature data on early diagenetic dolomite in the Great Basin, North America, yields –0.69 ± 0.22 ‰ for the δ44Ca value of seawater, which is ∼0.2 ‰ lower than ‘normal marine’ waters in stratigraphically equivalent deposits in the Willison Basin, and 0.44 ‰ lower than evaporatively concentrated seawater during a brief period of basin restriction and anhydrite deposition. The nearly 0.5 ‰ variation in the δ44Ca value of Katian seawater falls within the range of scatter in the brachiopod reconstruction of seawater Ca isotopes. Here, we propose that the true ocean record of secular change lies towards the bottom of the range of scatter, and that the higher values in the record reflect local Ca cycling and circulation restriction in epeiric seas. Epeiric seas cultivate the fluid-buffered diagenetic conditions required to promote Ca isotope exchange between reactive carbonate sediments and seawater through carbonate mineral dissolution/recrystallization, crystal coarsening by way of Ostwald ripening, and replacive dolomitization. It is not the apportioning of kinetically fractionated aragonite and calcite in the carbonate deposition flux that drove secular changes in global value of Δsed between ‘calcite’ and ‘aragonite’ seas, but rather the replacement of kinetic fractionations with equilibrium fractionations during fluid-buffered diagenesis with seawater.

Production of oxygenated volatile organic compounds from the ozonolysis of coastal seawater

Abstract. Dry deposition of ozone (O3) to the ocean surface and the ozonolysis of organics in the sea surface microlayer (SSML) are potential sources of volatile organic compounds (VOCs) to the marine atmosphere. We use a gas chromatography system coupled to a Vocus proton-transfer-reaction time-of-flight mass spectrometer to determine the chemical composition and product yield of select VOCs formed from ozonolysis of coastal seawater collected from Scripps Pier in La Jolla, California. Laboratory-derived results are interpreted in the context of direct VOC vertical flux measurements made at Scripps Pier. The dominant products of laboratory ozonolysis experiments and the largest non-sulfur emission fluxes measured in the field correspond to Vocus CxHy+ and CxHyOz+ ions. Gas chromatography (GC) analysis suggests that C5–C11 oxygenated VOCs, primarily aldehydes, are the largest contributors to these ion signals. In the laboratory, using a flow reactor experiment, we determine a VOC yield of 0.43–0.62. In the field at Scripps Pier, we determine a maximum VOC yield of 0.04–0.06. Scaling the field and lab VOC yields for an average O3 deposition flux and an average VOC structure results in an emission source of 10.7 to 167 Tg C yr−1, competitive with the DMS source of approximately 20.3 Tg C yr−1. This study reveals that O3 reactivity to dissolved organic carbon can be a significant carbon source to the marine atmosphere and warrants further investigation into the speciated VOC composition from different seawater samples and the reactivities and secondary organic aerosol (SOA) yields of these molecules in marine-relevant, low NOx conditions.

Temporal-spatial characteristics and sources of heavy metals in bulk deposition across China

With the rapid development of industries, agriculture, and urbanization (including transportation and population growth), there has been a significant alteration in the emission and atmospheric deposition of heavy metal pollutants. This has consequently given rise to a range of ecological and environmental health issues. In this study, we conducted a comprehensive two-year investigation on the temporal and spatial distribution characteristics of heavy metals in atmospheric deposition across China based on the Nationwide Nitrogen Deposition Monitoring Network (NNDMN). The atmospheric bulk deposition of Lead (Pb), Arsenic (As), Nickel (Ni), Selenium (Se), Chromium (Cr) and Cadmium (Cd) were 6.32 ± 1.59, 4.49 ± 0.57, 1.31 ± 0.21, 1.05 ± 0.16, 0.60 ± 0.06 and 0.21 ± 0.03 mg m−2 yr−1, respectively, with a large variation among the different regions of China. The order for atmospheric deposition flux was Southwest China > Southeast China > North China > Northeast China > Qinghai-Tibet Plateau and rural area > urban area > background area. The concentrations of heavy metals in bulk deposition exhibit seasonal variation with higher levels observed during winter compared to summer and spring, which are closely associated with anthropogenic activities. The Positive Matrix Factorization (PMF) results indicated that combustion, industrial emissions and traffic are the primary contributors to atmospheric deposition of heavy metals. The single factor pollution index (Pi) of heavy metals is consistently below 1, and the composite pollution index (Ni) is 0.16 across China, indicating that atmospheric heavy metal deposition is at a pollution-free level. The comprehensive potential ecological risk index of heavy metals is 11.8, with Cd exhibiting the highest single factor potential ecological risk index at 7.09, suggesting that more attention should be paid to Cd deposition in China. The present study reveals the spatial-temporal distribution pattern of atmospheric heavy metals deposition in China, identifying regional source characteristics and providing a theoretical foundation and strategies for reducing emissions of atmospheric pollutants.

Observation of ozone deposition flux and its contribution to stomatal uptake over a winter wheat field in eastern China

Ground-level ozone (O3) poses a significant threat to food security in China. Therefore, it is imperative to conduct a comprehensive scientific evaluation of the potential hazards posed by O3 to agricultural crops. This study continuously observed variation in meteorological factors, O3 concentration, O3 deposition rate and flux, and quantified the distribution characteristics of O3 deposition flux in stomatal and non-stomatal pathways. Results suggested that the O3 dry deposition rate and flux in winter wheat fields exhibited relatively stable variations at night but pronounced fluctuations during the day. Their mean values were 0.31 cm s−1 and -0.0044 μmol m−2·s−1, respectively, with peak values occurring at 08:30 and 14:00. The cumulative O3 total flux during the main growth season of winter wheat was 26.1 mmol m−2, with stomatal and non-stomatal fluxes accounting for 7.7 mmol m−2 and 18.4 mmol m−2, respectively. The proportions of total O3 flux in stomatal and non-stomatal channels were 29.5% and 70.5%, respectively, with daytime proportions being 39.7% and 60.3%, respectively. These findings provide crucial insights for future accurate assessments of crop yield loss due to O3 at the earth's surface.

Emissions and Atmospheric Dry and Wet Deposition of Trace Metals from Natural and Anthropogenic Sources in Mainland China

Trace metals from natural and anthropogenic sources impact the atmospheric environment and enter the soil through dry and wet atmospheric deposition, ultimately affecting human health. In this study, we established an emission inventory of Pb, As, Cr, and Cd in East Asia (80° E–140° E, 15° N–50° N) for the year 2017, including dust and anthropogenic sources from both land and marine. We modified the Community Multiscale Air Quality (CMAQ) model to provide gridded data on concentrations, as well as dry and wet atmospheric deposition fluxes of metals, with a focus on mainland China. The emissions of Pb, As, Cr, and Cd in East Asia were 19,253, 3415, 3332, and 9379 tons, respectively, in 2017, with 55%, 69%, 25%, and 58% distributed in the fine mode. The spatial distribution of atmospheric concentrations and dry deposition of trace metals was similar to that of emissions, while the spatial distribution of precipitation-related wet deposition was further east and greater in the south than in the north. In mainland China, the average bulk-deposition fluxes of Pb, As, Cr, and Cd were 1036.5, 170.3, 465.9, and 185.0 μg·m−2·year−1, respectively. Our study provides gridded data on trace metals in mainland China, which can be used for assessing air quality, human exposure risks, and metal inputs to soils.

The pace of global river meandering influenced by fluvial sediment supply

Meandering rivers move gradually across the floodplains, and this river movement presents socioeconomic risks along river corridors and regulates terrestrial biogeochemical cycles. Experimental and field studies suggest that fluvial sediment supply can exert a primary control on lateral migration rates of rivers. However, we lack an understanding of the relative importance of environmental boundary conditions, such as floodplain vegetation and sediment supply, in setting the pace of river meandering across different environmental settings. Here, we combine the analysis of satellite imagery and global-in-scale sediment and water discharge models to evaluate the controls on lateral migration rates of 139 meandering rivers that span a wide range in size, climate, and bank vegetation. We show that migration rates normalized by the channel width monotonically increase with the volumetric sediment flux normalized by the characteristic size of the river. This relation is consistent across rivers in vegetated and unvegetated catchments, indicating that enhanced lateral migration rates in unvegetated basins is likely not only facilitated by lower bank mechanical strength, but also by higher normalized sediment supply in ephemeral rivers. Using three case examples, we also demonstrate that width-normalized meander migration rates respond to spatial gradients in sediment supply caused by river impoundments, highlighting the prominent role of sediment supply in setting the pace of meander migration. Our results suggest that sediment-supply variations caused by climate, land-cover and land-use changes can lead to predictable changes in meandering river evolution and ultimately drive architectural changes in sedimentary stratigraphy.

Long-term trends and response of wet ammonia deposition to changes in anthropogenic emissions in the Pearl River delta of China

The Pearl River Delta (PRD) region has been identified as a significant hotspot of wet ammonium deposition. However, the absence of long-term monitoring data in the area hinders the comprehension of the historical trends and changes in wet NH4+-N deposition in response to emissions, which interferes with the ability to make effective decisions. This study has analyzed the long-term trends of wet NH4+-N deposition flux and has quantified the effect of anthropogenic emissions and meteorological factors at a typical urban site and a typical forest site in the PRD region from 2009 to 2020. It revealed a significant decreasing trend in wet NH4+-N flux in both the typical urban and forest areas of the PRD region, at -6.2%/year (p < 0.001) and -3.3%/year (p < 0.001), respectively. Anthropogenic emissions are thought to have contributed 47–57% of the wet NH4+-N deposition trend over the past 12 years compared to meteorological factors. Meteorological conditions dominated the inter-annual fluctuations in wet NH4+-N deposition with an absolute contribution of 46%–52%, while anthropogenic emissions change alone explained 10%–31%. NH3 emissions have the greatest impact on the urban area among anthropogenic emission factors, while SO2 emissions have the greatest impact on the forest area. Additionally, precipitation was identified as the primary meteorological driver for both sites. Our findings also imply that the benefits of NH3 emissions reductions might not immediately emerge due to interference from weather-related factors.

Spatial and temporal distribution of physicochemical parameters of water in Gorgan Bay (the southeast of the Caspian Sea - Iran): Fundamentals for the monitoring of the Caspian Sea coastal areas

Gorgan Bay as a main part of the Miankaleh (a natural biosphere reserve registered by UNESCO) is one of the richest ecological area in the West Asia and very important internationally recognized refuge for the wildlife. To date, multi physicochemical parameters have not been examined on a large scale. To fill this knowledge gap, the present study aimed to explore the seasonal and spatial variability of water quality parameters of the bay. The results showed that except for depth and transparency, there are significant variations in most parameters across the four seasons. The patterns of these changes in the bay vary, as evidenced by a comparison of the distribution maps of the various factors throughout the year. Notably, alkalinity declined from east to west, reaching its highest levels at important entry points such as the Qarasu River, Bandar-Gaz, and the pier. TDS, on the other hand, increased westward, reaching its highest concentration in the shallow western regions. Maximum depth (310 cm) and transparency (250 cm) were observed in the central bay. While the pH was higher in deeper areas, the distribution of PO4 was more uniform. With lower levels in the east (salinity = 0.40 ‰) and higher levels in the west (salinity = 28.9 ‰), the salinity showed a coherent gradient. Agricultural land use in the basin of the bay and fluxes of nutrients and sediments of the rivers entering the bay has significant contribution to the bay pollution situation. These results will serve as a guide for improving our understanding of the Gorgan Bay ecosystem. They also have implications for informed conservation and management plans adapted to the specifics of this special region within the Caspian Sea.

Performance evaluation of four sampling techniques and source apportionment for the atmospheric deposition fluxes of polycyclic aromatic hydrocarbons

Polycyclic aromatic hydrocarbons (PAHs) are primarily emitted into the atmosphere through anthropogenic activities and can be transported to receptor sites at varying distances. In this study, the atmospheric PAH deposition was investigated using a dry deposition plate (DDP) with Mylar, a dry deposition disk (DDD) with Velcro, a resin bulk deposition sampler (Resin-BDS), and a water bulk deposition sampler (Water-BDS) in Ulsan, South Korea, during May–October 2013. Additionally, ambient PAH concentrations were monitored using high-volume air samplers. The mean deposition fluxes of Σ13 PAHs were 8.62 ± 1.44, 36.9 ± 6.81, 56.9 ± 9.74, and 63.8 ± 8.04 μg/m2/d for the DDP, DDD, Resin-BDS, and Water-BDS, respectively. The DDD was more effective than the DDP because it could collect high molecular weight (HMW) PAHs from dry deposition, which are more toxic than low molecular weight PAHs. The Water-BDS had the highest fluxes of Σ13 PAHs; however, the Resin-BDS may be more suitable for collecting HMW PAHs from both dry and wet deposition due to relatively constant values for the deposition velocity of PAHs. Furthermore, the PAH fluxes in the Resin-BDS samples were significantly positively correlated with the gaseous and total (gaseous + particulate) concentrations of ambient PAHs. Hence, the fluxes obtained by the Resin-BDS were further used to apply principal component analysis, multiple linear regression, and backward air trajectory simultaneously to identify the emission sources of the deposited PAHs. The results indicate that the combustion of fossil fuels and biomass was the major source. In particular, the industrial complexes using petroleum and coal on the city's east coast and vehicular exhausts were the main local sources. Meanwhile, long-range sources may be forest fires, harbors, and industrial activities in nearby countries. Our study suggests that BDS, considering both dry and wet deposition, can be selectively used for research on PAH deposition.

Mesoscale structure of the atmospheric boundary layer across a natural roughness transition

The structure and intensity of turbulence in the atmospheric boundary layer (ABL) drive fluxes of sediment, contaminants, heat, moisture, and CO[Formula: see text] at the Earth's surface. Where ABL flows encounter changes in roughness-such as cities, wind farms, forest canopies, and landforms-a new mesoscopic flow scale is introduced: the internal boundary layer (IBL), which represents a near-bed region of transient flow adjustment that develops over kilometers. Measurement of this new mesoscopic scale lies outside present observational capabilities of ABL flows, and simplified models fail to capture the sensitive dependence of turbulence on roughness geometry. Here, we use large-eddy simulations, run over high-resolution topographic data and validated against field observations, to examine the structure of the ABL across a natural roughness transition: the emergent sand dunes at White Sands National Park. We observe that development of the IBL is triggered by the abrupt transition from smooth playa surface to dunes; however, continuous changes in the size and spacing of dunes over several kilometers influence the downwind patterns of boundary stress and near-bed turbulence. Coherent flow structures grow and merge over the entire [Formula: see text]10 km distance of the dune field and modulate the influence of large-scale atmospheric turbulence on the bed. Simulated boundary stresses in the developing IBL counter existing expectations and explain the observed downwind decrease in dune migration, demonstrating a mesoscale coupling between flow and form that governs landscape dynamics. More broadly, our findings demonstrate the importance of resolving both turbulence and realistic roughness for understanding fluid-boundary interactions in environmental flows.

Multivariate analysis of inlet morphodynamics: The mixed sand-gravel ebb-tidal delta of Deben Estuary, Suffolk

The morphodynamics of inlets and ebb-tidal deltas often exhibit cyclic behaviour, controlled by wave-tide interactions and the influence of these on sediment-bypassing processes. Variation in the form and timing of inlet dynamics can occur in response to changes in the key sediment transport processes and sediment supply, and particularly the relative dominance of differential wave direction driving alongshore sediment transport. This paper investigates the morphodynamics of the Deben ebb-tidal delta through multivariate analysis of multi-annual bathymetry and metocean parameters covering the period 1991 to 2023. Results show that sediment bypassing and associated morphological change in this ebb-tidal delta follows variable behaviour mid-cycle, leading to change in the morphology and configuration of the ebb-delta from cycle to cycle. In the most recent cycle (since 2003), delta volume followed a stepwise growth driven by sediment influx periods, evident primarily in the updrift shoal, followed by cross-shore redistribution. Interannual variability in wave climate was clustered into four groups that capture the relative balance between the dominant NE and SW forcing. Sediment influx periods are mostly associated with subdued SW and increased NE forcing, but the summer and winter NE wave climate play different roles on the up- and downdrift, and upper and lower components of the ebb-delta system. Tide level has increased in the last 33 years, which is strongly correlated with ebb-delta volume increase. Wave and tide conditions have discrete and independent effects on the ebb-tidal delta, whereas wave-tide interactions do not significantly change these underlying influences.

A complex case of thermal maturity assessment in a terrigenous sedimentary system: The Northwestern Black Sea basin

An integrated approach combining fluorescence spectrometry, pyrolysis geochemistry, and dispersed organic matter (DOM) maceral analysis has been used to determine the thermal maturity of Oligocene source rocks in two neighboring offshore wells within the complex deep-sea system of the Northwestern Black Sea. The samples contain predominantly immature Type II kerogen, including a mixture of marine liptinite (alginite, liptodetrinite), degraded liptinite, primary vitrinite, and reworked vitrinitic macerals. The occurrence of several vitrinite reflectance (VRo) populations in the samples is attributed to a high influx of reworked vitrinite transported to the marine basin from multiple terrestrial sources with diverse degrees of degradation. The presence of multiple VRo populations complicates the application of VRo for determining the thermal maturity of the organic matter. Further, the VRo measurements on the primary vitrinite population show only a subtle increasing trend with depth. A significantly improved thermal maturity resolution was obtained using the red to green quotient (R/G). R/G was measured on the autochthonous unicellular Tasmanites-type alginite under UV-excitation. In contrast to VRo the results show a significant correlation between increasing R/G values with increasing depth. This indicates that the R/G quotient is a better maturity proxy for the studied low maturity marine system with a large influx of sediments. The beginning of the downward declining trend in the temporal variation of liptinite is regarded as the onset of catagenesis. This occurs at a burial depth of 2.5 km and a R/G value of 0.50, corresponding to a VRo equivalent (VRo Eq) of 0.44%. At a burial depth of 3.2 km and a R/G value of 0.57 (VRo Eq = 0.57%), the onset of the oil window is marked by an increase in the amount of solid bitumen (initial oil solid bitumen). The observed alterations in maceral composition with burial depth align with the thermal maturity of the wells. However, the data suggest that the thermal evolution of the organic matter is out of sync with the surrounding formation temperature, possibly due to rapid burial induced by a high sedimentation rate.

Refining the roles of productivity, redox, and remineralization on the cadmium isotope composition of marine sediments

Cadmium (Cd) has a nutrient-like distribution in the ocean, similar to the macronutrient phosphate. Significant isotope fractionation induced by the biological cycling of Cd makes it a potential tracer for nutrients and productivity. However, the Cd flux and Cd isotope composition of marine sediments may also be influenced by local redox conditions and partial remineralization of organically hosted Cd. These confounding factors are under-constrained and render it challenging to use Cd as a reliable paleoproxy. To understand the relative importance of each of these processes, we examined the Cd isotope systematics of 69 modern sediments deposited across a wide range of environments. We complement these data with four profiles of particulate Cd isotope compositions from the Southern Ocean. We report three main results. First, we show that the sedimentary flux of Cd is tightly coupled to that of organic matter. Second, most Cd burial occurs in regions with some bottom-water oxygen, and the flux of CdS to anoxic regions is, globally, minor. Finally, we find that remineralization can substantially modify sedimentary Cd isotope compositions, though it is challenging to relate pelagic and sedimentary processes. For example, we find that the relationship between sedimentary Cd isotope compositions and surface seawater [Cd] is the reverse of that predicted by isotope reactor models. Likewise, sedimentary Cd isotope compositions are anti-correlated with bottom-water oxygen. While this pattern is consistent with preferential remineralization of isotopically heavy Cd, profiles of marine particulate matter reveal the reverse, whereby the Cd isotope composition of large particles, which are most likely to reach the seafloor, becomes increasingly ‘heavy’ with depth. These results highlight how productivity, redox, and remineralization all influence the flux and isotope composition of Cd to marine sediments. While our study suggests that there is no simple way to relate sedimentary Cd isotopes to surface nutrient utilization, our data point toward several potential controls that could form the basis of novel proxies for local redox conditions and remineralization.