Flux Measurements Research Articles

Natural Gas Leakage Ratio Determined from Flux Measurements of Methane in Urban Beijing

Natural Gas Leakage Ratio Determined from Flux Measurements of Methane in Urban Beijing

Examining the Ecosystem-Scale GHG Exchange Following the Acrotelm Harvesting Method (ACM) in Eastern Quebec

Traditional horticultural peat production involves the removal of vegetation and drainage of peatlands, resulting in significant ecological disturbances and greenhouse gas (GHG) emissions. The Acrotelm Harvesting Method (ACM) was developed as a more sustainable alternative, designed to reduce these impacts by allowing peat extraction without large-scale ecosystem alterations. However, the ACM still necessitates the passage of machinery over the peat, potentially disturbing surface vegetation and altering the carbon dynamics. My project, based at a field site near Baie-Comeau, QC, represents the first comprehensive assessment of the ACM’s impact on net ecosystem exchanges of main GHGs. I focused on evaluating the ecosystem-scale effects by analyzing data collected from paired eddy covariance towers installed at both the control (unharvested) and harvested sites. These towers provide temporally continuous, spatially integrated flux measurements. Preliminary findings indicate that the site subjected to ACM exhibits altered surface topography, leading to overall wetter conditions, compaction of hummocks, and vegetation damage. These changes have resulted in reduced carbon dioxide uptake and increased methane emissions at the harvested site. Through the analysis and interpretation of this data, my research contributes to a better understanding of the ACM’s environmental impact and its potential as a sustainable peatland management strategy. This research was conducted under the supervision of Dr. Ian Strachan in the Atmospheric Environmental Research (AER) lab.

Biomethane produced from maize grown on peat emits more CO2 than natural gas

Cultivation of maize for biomethane production has expanded rapidly, including on drained peat soils. The resulting soil CO2 emissions at the point of feedstock production are largely overlooked when assessing biogas climate mitigation potential. On the basis of field-scale flux measurements, we calculate that soil CO2 emissions from biomethane feedstock production on drained peat exceed embodied emissions for an equivalent amount of natural gas by up to a factor of three.

Unexpectedly high wet mercury deposition observed in the Yarlung Tsangpo Grand canyon

Situated in the south edge of the Tibetan Plateau, the Himalayas is expected to receive direct anthropogenic Hg perturbations from South Asia, yet the measurements of atmospheric Hg deposition in the Himalayan region remain scarce. Here we report wet Hg deposition measured in the Yarlung Tsangpo Grand Canyon of the Eastern Himalayas, which is the deepest and longest canyon on earth. The precipitation Hg concentration (56.3 ng L−1) and wet Hg deposition flux (84.7 μg m−2 yr−1) from the Motuo station were observed among the highest ever reported for the Tibetan Plateau. Together with analysis of principal component suggesting Hg was mainly clustered with anthropogenic ions and backward trajectories indicating 88.8% of air masses came from South Asia, our results show that transboudary pollution influences from South Asia could be largely responsible for the unexpectedly high levels of wet Hg deposition. Moreover, the wet Hg flux measurements (84.7 μg m−2 yr−1) are found an order of magnitude (∼13 times) higher than the GEOS-Chem estimates (6.8 μg m−2 yr−1), most likely due to the underestimation of transboundary Hg pollution influence by this model. Our study has important implications for better understanding Hg dynamics and verifying atmospheric Hg models in the Tibetan Plateau and Himalayas region.

Spatiotemporal patterns of greenhouse gas fluxes in the subtropical wetland ecosystem of Indian Himalayan foothill.

The study characterized the temporal and spatial variability in greenhouse gas (GHG) fluxes (CO2, CH4, and N2O) between December 2020 and November 2021 and their regulating drivers in the subtropical wetland of the Indian Himalayan foothill. Five distinct habitats (M1-sloppy surface at swamp forest, M2-plain surface at swamp forest, M3-swamp surface with small grasses, M4-marshy land with dense macrophytes, and M5-marshy land with sparse macrophytes) were studied. We conducted in situ measurements of GHG fluxes, microclimate (AT, ST, and SMC(v/v)), and soil properties (pH, EC, N, P, K, and SOC) in triplicates in all the habitat types. Across the habitats, CO2, CH4, and N2O fluxes ranged from 125 to 536mgm-2h-1, 0.32 to 28.4mgm-2h-1, and 0.16 to 3.14mgm-2h-1, respectively. The habitats (M3 and M5) exhibited higher GHG fluxes than the others. The CH4 flux followed the summer > autumn > spring > winter hierarchy. However, CO2 and N2O fluxes followed the summer > spring > autumn > winter. CO2 fluxes were primarily governed by ST and SOC. However, CH4 and N2O fluxes were mainly regulated by ST and SMC(v/v) across the habitats. In the case of N2O fluxes, soil P and EC also played a crucial role across the habitats. AT was a universal driver controlling all GHG fluxes across the habitats. The results emphasize that long-term GHG flux monitoring in sub-tropical Himalayan Wetlands has become imperative to accurately predict the near-future GHG fluxes and their changing nature with the ongoing climate change.

A high‐frequency greenhouse gas flux analysis tool: Insights from automated non‐steady‐state transparent soil chambers

AbstractNon‐steady‐state chambers are widely employed for quantifying soil emissions of CO2, CH4, and N2O. Automated non‐steady‐state (a‐NSS) soil chambers, when coupled with online gas analysers, offer the ability to capture high‐frequency measurements of greenhouse gas (GHG) fluxes. While these sampling systems provide valuable insights into GHG emissions, they present post‐measurement challenges, including the management of extensive datasets, intricate flux calculations, and considerations for temporal upscaling. In this study, a computationally efficient algorithm was developed to compute instantaneous fluxes and estimate diel flux patterns using continuous, high‐resolution data obtained from an a‐NSS sampling system. Applied to a 38‐day dataset, the algorithm captured concurrent field measurements of CO2, CH4, and N2O fluxes. The automated sampling system enables the acquisition of high‐frequency data, allowing the detection of episodic gas flux events. By using shape‐constrained additive models, a median percentage deviation (bias) of −1.031 and −4.340% was achieved for CO2 and N2O fluxes, respectively. Simpson's rule allowed for efficient upscale from instantaneous to diel flux values. As a result, the proposed algorithm can rapidly and simultaneously calculate CO2, CH4, and N2O fluxes, providing both instantaneous and diel values directly from raw, high‐temporal‐resolution data. These advancements significantly contribute to the field of GHG flux measurement, enhancing both the efficiency and accuracy of calculations for a‐NSS soil chambers and deepening our understanding of GHG emissions and their temporal dynamics.

Very High Energy Solar Energetic Particle Events and Ground Level Enhancement Events: Forecasting and Alerts

AbstractA Ground Level Enhancement (GLE) event can be observed as an increase in the background of ground‐based neutron monitor observations and is often associated with an increase of >500 MeV space‐based proton flux measurements. GLE events begin as very high‐energy SEP events associated with GeV protons. For such events to be detected at sea level, proton energies must exceed about 433 MeV. Since the increased flux of such particles can be a major problem to technology in space and on Earth and pose a threat for human health, developing real time warning systems is of great importance. GLE Alert++ is a product, built by the Athens Cosmic Ray Group of the National and Kapodistrian University of Athens, that issues alerts when a GLE event starts to register and is based on ground‐based neutron monitor observations. From the space‐based approach, the HESPERIA UMASEP‐500 product, jointly developed within the framework of the EU HORIZON2020 HESPERIA project by the Universidad de Malaga, Spain and National Observatory of Athens, Greece, provides forecasts of GLE events and >500 MeV protons relying on GOES satellite Soft X‐Ray and high energy proton observations. These two products are fully integrated as federated products on the ESA SWE Portal and are provided as part of the ESA Space Safety Program Space Weather Service Network. In this paper we present how the products were built, provide examples of their outputs as seen on the ESA SWE Portal, and show how the products complement each other and how using them together can in some instances provide more information for users of these services.

Estimation of Urban Greenhouse Gas Fluxes from Mole Fraction Measurements Using Monin–Obukhov Similarity Theory

Abstract The purpose of this study is to determine whether urban greenhouse gas (GHG) fluxes can be quantified from tower-based mole fraction measurements using Monin–Obukhov similarity theory (MOST). Tower-based GHG mole fraction networks are used in many cities to quantify whole-city GHG emissions. Local-scale, micrometeorological flux estimates would complement whole-city estimates from atmospheric inversions. CO2 mole fraction and eddy-covariance flux data at an urban site in Indianapolis, Indiana, from October 2020 through January 2022 are analyzed. Using MOST flux–variance and flux–gradient relationships, CO2 fluxes were calculated using these mole fraction data and compared to the eddy-covariance fluxes. MOST-based fluxes were calculated using varying measurement heights and methods of estimating stability. The MOST flux–variance relationship method showed good temporal correlation with eddy-covariance fluxes at this site but overestimated flux magnitudes. Fluxes calculated using flux–gradient relationships showed lower temporal correlation with eddy-covariance fluxes but closer magnitudes to eddy-covariance fluxes. Measurement heights closer to ground level produce more precise flux estimates for both MOST-based methods. For flux–gradient methods, flux estimates are more accurate and precise when low-altitude measurements are combined with a large vertical separation between measurement heights. When stability estimates based on eddy-covariance flux measurements are replaced with stability estimates based on the weather station or net radiation data, the MOST-based fluxes still capture the temporal patterns measured via eddy covariance. Based on these results, MOST can be used to estimate the temporal patterns in local GHG fluxes at mole fraction tower sites, complementing the small number of eddy-covariance flux measurements available in urban settings.

Electrocaloric effect in chemically modified barium titanate ferroelectric ceramics

Electrocaloric (EC) refrigeration offers superior energy-conversion efficiency, miniaturization, and environmental benefits compared to compression refrigeration. However, its practical application is limited by the challenge of aligning the adiabatic temperature change (ΔT) with the operational temperature range. In this study, we have tailored the EC characteristics of BaTiO3 (BT)-based Ba(Ti0.9Sn0.1)O3 (BTS) ferroelectric ceramics using Bi(Mg0.5Ti0.5)O3 (BMT). We provide a comprehensive analysis of the microstructure, electrical properties, and EC behavior of the (1–x)BTS-xBMT system. Our results indicate that the incorporation of BMT establishes a broad platform in the dielectric spectrum while maintaining high polarization. This improvement potentially increases the electrocaloric effect (ECE) and expands the operating temperature range. Direct heat flux measurements reveal that the x = 0.02 composition achieves a maximum ΔT (ΔTmax) of 0.41 K with a temperature span (Tspan) of 68 °C under an intermediate electric field of 50 kV/cm. Moreover, the x = 0.01 sample exhibits a room-temperature ΔT of 0.33 K and relatively good temperature stability within 30–130 °C. These findings indicate that chemical modification methods have the potential to optimize the cooling capacity of refrigerants.

Comprehensive Analysis of Magnetic Flux Density and RF-EMF Exposure in Electric Buses: A Case Study from Samsun, Turkey.

This study investigates magnetic flux density (B) and radiofrequency electromagnetic field (RF-EMF) measurements on electric buses operating in Samsun, Turkey, focusing on two bus routes (called E1 and E4) during the morning and evening hours. Measurements were taken under diverse operational conditions, including acceleration, cruising, and braking, at locations of peak passenger density. Along the E1 route, the magnetic field intensity varied significantly based on the bus position, road slope, and passenger load, with notable increases during braking. In contrast, the E4 route showed a lower magnetic field intensity and RF-EMF values due to its straighter trajectory and reduced operational stops. The highest RF-EMF measurement recorded was 6.01 V/m, which is below the maximum levels established by the ICNIRP guidelines. In 11 out of the 12 different band-selective RF-EMF measurements, the highest contribution came from the downlink band of the base stations, while in only one measurement, the highest contribution originated from the uplink bands of the base stations. All data were subject to the Anderson-Darling test, confirming the generalized extreme value distribution as the best fit for both B and RF-EMF measurements. Additionally, the study assessed B levels inside and outside the bus during charging, revealing heightened readings near the pantograph. These findings significantly contribute to our understanding of electromagnetic field exposure in electric bus environments, highlighting potential health implications and informing the development of targeted mitigation strategies.

Optimization of geometric configurations for enhanced thermal performance in microchannel finned plates

This study investigates the thermal performance of microchannel finned plates by comparing various geometric configurations and operating conditions. Twelve models (a to l) were evaluated by varying parameters such as fin height, fin spacing, and channel width, as well as operating factors like inlet velocity and heat flux. The results reveal that increasing the fin height and decreasing the fin spacing enhance heat transfer by expanding the surface area, though at the cost of increased pressure drops and higher pumping power requirements. Variations in channel width impact flow characteristics, with wider channels reducing temperature but potentially lowering convective efficiency. Higher inlet velocities improve convective cooling but increase pressure drops, while elevated heat fluxes lead to steeper temperature gradients. Model k was found to provide an optimal balance between heat transfer efficiency and pressure drop, while Model l’s novel fin geometry showed unique temperature distributions warranting further exploration. Temperature contours and volume renders demonstrated air temperature increases across the models, ranging from 4.78 K to 17.36 K, and surface heat flux measurements confirmed the significant influence of fin configuration on thermal performance. The findings offer valuable insights for optimizing the design of microchannel finned plates for enhanced heat transfer and effective thermal management in various applications.

Surface energy fluxes in a drip-irrigated agroecosystem: Unique advection effect of oasis

Surface energy fluxes, mainly encompassing the net radiation (Rn), latent heat flux (LE), sensible heat flux (Hs), and soil heat flux (Gs), play an important role in the land-atmosphere interactions. However, almost all sites face the problem of energy imbalance, and advection fluxes associated with large inhomogeneous surfaces have been ignored, especially in arid oasis areas. In this study, a three-year continuous measurement of energy fluxes with an eddy covariance system was conducted in a drip-irrigated oasis agroecosystem in Northwest China. Reanalysis data including air temperature (Ta), soil moisture (θ), and leaf area index (LAI) in our cropland and surrounding deserts were also collected. The results showed that multi-year mean turbulent fluxes (LE+Hs) accounted for 75 ± 8 % (mean ± standard deviation) of available energy (Rn–Gs). To be precise, LE took up 72 ± 10 % of available energy, and 7.8 ± 2.8 % of it was induced by higher sensible heat advection, proving a pronounced advection effect in this study. When advection was present, most likely during the heading stage, the threshold value for the Priestley–Taylor parameter α, an indicator to reflect the advection effect, fell in the range of 0.88–1.34. Additionally, after a significant irrigation event, α showed a good linear relationship with differences in air temperature (ΔTa), soil moisture (Δθ), and leaf area index (ΔLAI) between our cropland and surrounding deserts. It's worth mentioning that Δθ was the most significant factor, showing a negative correlation with the advection effect. This study has deepened our understanding of the energy balance in oasis agriculture, emphasizing that the advection effect should not be overlooked.

Development of an integrated online deposition and corrosion monitoring system in a full-scale solid waste CFB boiler

Solid waste incineration is a clean and sustainable approach for solid waste management. However, ash deposition and corrosion remain a critical issue due to fuel’s inherent enrichment of alkali chlorine. This study develops an integrated online deposition and corrosion monitoring system to enhance the operational safety and efficiency of solid waste incineration boilers. This system combines linear polarization resistance (LPR) for corrosion rate estimation with heat flux measurements for ash deposition analysis. It can offer a novel approach for real-time monitoring of heat exchangers’ safety during solid waste combustion. It was deployed in a full-scale circulating fluidized bed (CFB) boiler that purely combust solid wastes. Key findings demonstrate the system’s capability to deliver continuous, real-time data, crucial for the dynamic control of combustion processes and the maintenance of heat transfer surfaces. Its robust diagnostic capabilities were evident across various scenarios. Specially, initial corrosion rates sharply increase with deposition rates due to the enrichment of alkali chlorine on inner deposit layer, in which chlorine serves as a catalyst, facilitating the rapid penetration and aggravation of corrosion by other agents. As deposit further buildup, the corrosion rate steadily decreases along with surface temperature, highlighting a dynamic interaction. Moreover, measured corrosion rates can quickly response to temperature variations. Such multi-process online monitoring system provide more possibilities to investigate the inherent interaction between deposition and corrosion. Therefore, this work offers insights that could significantly influence operational strategies, maintenance protocols, and the overall reliability of waste-to-energy technologies.

Development of Readily Available & Robust High Heat Flux Gardon Gauges

Concentrated solar power (CSP) technologies deliver concentrated solar energy as a heat source to industrial processes, power generation cycles, and chemical cycles. CSP systems require accurate and reliable high flux measurements, and next generation CSP systems will require flux measurement up to 1000 W/cm2. Existing flux measurement devices do not comprehensively meet the flux rating, cycle life, cost, and lead-time needs of stakeholders, necessitating the development of an improved flux sensor. In this study, Sandia National Laboratories (SNL) partnered with Hukseflux Thermal Sensors to develop a low-cost, short lead-time, and robust flux sensor rated to 250 W/cm2. Three prototype circular foil gauge designs were assessed for performance at the National Solar Thermal Test Facility (NSTTF) at SNL. Each gauge design measured flux up to 250 W/cm2 with <5% measurement error. Following baseline error quantification, gauges were exposed to flux above 500 W/cm2 to assess gauge failure mechanisms. Gauges physically survived >500 W/cm2 flux exposure, but measurement error was found to increase after foil coatings reached 400 °C. The results of this study suggest that coating optical properties change at excessive temperatures and that foil coating temperature, rather than heat flux level, dictates the acceptable gauge measurement range.

Advanced Feedforward Controller for a Molten Salt Receiver in Star Design Based on Real-Time Flux Measurement

This paper presents a control system with a panel-wise applied feedforward temperature controller for a molten salt receiver in star design utilizing temperature measurements in the connecting pipes between the panels and a real-time flux density measurement as inputs. It is tested in realistic cloud passage scenarios and the results are compared to the results from an earlier developed control system for the same receiver, in which the temperature controller is based on a simple feedback controller (PID) supported by a simple feedforward controller. The results show that the performance of the new feedforward controller is outstanding and could be applied to common cylindrical receiver designs as well. Nevertheless, the highly increased actuator movement of the control valves is to be further investigated.

Pulsar Population Synthesis with Magnetorotational Evolution: Constraining the Decay of the Magnetic Field

We present a population synthesis model for normal radio pulsars in the Galaxy incorporating the latest developments in the field and the magnetorotational evolution processes. Our model considers spin-down with a force-free magnetosphere and the decay of the magnetic field strength and its inclination angle. The simulated pulsar population is fit to a large observation sample that covers the majority of radio surveys using the Markov Chain Monte Carlo technique. We compare the distributions of four major observables—spin period (P), spin-down rate ( Ṗ ), dispersion measure, and radio flux density—using accurate high-dimensional Kolmogorov–Smirnov statistics. We test two B-field decay scenarios, an exponential model motivated by ohmic dissipation and a power-law model motivated by the Hall effect. The former clearly provides a better fit, and it can successfully reproduce the observed pulsar distributions with a decay timescale of 8.3−3.0+3.9 Myr. The result suggests that significant B-field decay in aged pulsars and ohmic dissipation could be the dominant process.

The Universe SPHEREx Will See: Empirically Based Galaxy Simulations and Redshift Predictions

We simulate galaxy properties and redshift estimation for SPHEREx, the next NASA Medium Class Explorer. To make robust models of the galaxy population and test the spectrophotometric redshift performance for SPHEREx, we develop a set of synthetic spectral energy distributions based on detailed fits to COSMOS2020 photometry spanning 0.1–8 μm. Given that SPHEREx obtains low-resolution spectra, emission lines will be important for some fraction of galaxies. Here, we expand on previous work, using better photometry and photometric redshifts from COSMOS2020 and tight empirical relations to predict robust emission-line strengths and ratios. A second galaxy catalog derived from the GAMA survey is generated to ensure the bright (m AB < 18 in the i band) sample is representative over larger areas. Using template fitting to estimate photometric continuum redshifts, we forecast the recovery of 19 million galaxies over 30,000 deg2 with redshifts better than σ z < 0.003(1 + z), 445 million with σ z < 0.1(1 + z), and 810 million with σ z < 0.2(1 + z). We also find through idealized tests that emission-line information from spectrally dithered flux measurements can yield redshifts with accuracy beyond that implied by the naive SPHEREx channel resolution, motivating the development of a hybrid continuum–line redshift estimation approach.

Characterization of carbon dioxide emissions from late stage windrow composting

As organic waste is converted to usable amendments via composting, there are large CO2 emissions associated with the decomposition of organic matter via microorganisms. While the active composting phase produces the largest emissions over a short duration, compost can often be stored during and after the maturation phase for much longer periods of time, increasing cumulative emissions. As such, the objectives of this study were to examine the spatial and temporal variability associated with in situ emissions sampling while identifying the environmental and chemical controls on emissions in windrow composting facilities during and after the maturation phase. A total of 665 flux measurements were taken from four windrows representing different ages and compositions between June and November 2020. Factorial analysis of covariance (ANOVA) was used to determine the variability between sampling locations, while multiple linear regression was used to identify those parameters which had the most influence on CO2 flux. Emissions showed significant variability over time that were attributed to ambient temperatures. During the summer, each windrow reached peak emissions between 5.0 and 32.3 g CO2 m-2 hr-1. As temperatures cooled, the windrows saw a 62%–86% decline in emissions, generally falling below 2 g CO2 m-2 hr-1. Significant differences occurred between the top-most sampling location and all others on the windrow, emitting between 33%–100% more CO2. The environmental controls of surface temperature, moisture content, and internal temperature showed the highest influence on emissions (R2 = 0.62). Chemical properties including organic nitrogen, carbon, pH, magnesium, and nitrate also showed significant influence (R2 = 0.43). This research has shown that environmental factors including temperature and moisture show the strongest influence over emission rates in mature compost. A significant negative effect of organic nitrogen on CO2 flux was found, indicating that increased presence of organic nitrogen would aid in the retention of carbon after the maturation phase, acting to lower total emissions.

Temporal Variations in Methane Emissions from a Restored Mangrove Ecosystem in Southern China

The role of coastal mangrove wetlands in sequestering atmospheric carbon dioxide has been increasingly investigated in recent years. While studies have shown that mangroves are weak sources of methane (CH4) emissions, measurements of CH4 fluxes from these ecosystems remain scarce. In this study, we examined the temporal variation and biophysical drivers of ecosystem-scale CH4 fluxes in China’s northernmost mangrove ecosystem based on eddy covariance measurements obtained over a 3-year period. In this mangrove, the annual CH4 emissions ranged from 6.15 to 9.07 g C m−2 year−1. The daily CH4 flux reached a peak of over 0.07 g C m−2 day−1 during the summer, while the winter CH4 flux was negligible. Latent heat, soil temperature, photosynthetically active radiation, and tide water level were the primary factors controlling CH4 emissions. This study not only elucidates the mechanisms influencing CH4 emissions from mangroves, strengthening the understanding of these processes but also provides a valuable benchmark dataset to validate the model-derived carbon budget estimates for these ecosystems.

Effects of Fuel Bed Slope and Wind Direction on Flame Spread Characteristics Over a Bed of Pinus Silvestris Needles

ABSTRACT Important factors influencing the flame characteristics over a bed of dry pine needles from Siberian Boreal forests (Pinus silvestris) in lab-scale is provided. Factors such as slope of the fuel bed, wind velocity, and direction of spread (concurrent flow or opposed flow), which play significant roles in determining the flame spread rate, have been investigated. Systematic lab-scale experiments have been carried out in a wind tunnel with varying air velocities and on an inclined fuel bed in still air. Numerical simulations have been carried out using a three-dimensional physics-based flame spread model available in Fire Dynamics Simulator, and the results are validated against a wide range of measured flame characteristics. The validated numerical model is then used to simulate concurrent flow and opposed flow flame spread over a sloping fuel bed in the presence of wind. Gas phase temperature on and above the bed surface and total and radiative heat flux measurements for concurrent flow and opposed flow flame spread under the influence of wind as well as for upslope flame spread in still air are presented. A stationary flame propagation mode is observed for a flat fuel surface. Predicted temperature, flow, and species concentration fields have been reported for selected cases to understand the flow and flame dynamics in gas phase and within the fuel beds. These data serve as a validation of the numerical model used for simulating the experimental cases. Further, it can be used to validate popular fire models such as Fire Foam and Fire-Star 3D.