The geochemical properties of fracturing flowback fluids indirectly indicate the fracturing efficiency of the reservoir, the interaction between the reservoir and injected water, and the preservation of oil and gas, thereby offering robust data support for identifying fracturing flowback fluid sources, assessing fracturing effects, and proposing stimulation strategies. In this study, the ion characteristics, total salinity, and stable isotope ratio of fracturing flowback fluids of the Z202H1 and Z203 wells in Western Chongqing were measured. The findings suggest that with the extension of flowback time, the geochemical properties of fracturing flowback fluids evolve toward higher salinity and heavier stable isotope ratios, ultimately stabilizing. Upon comparing the water–rock reaction intensity and the rate of total salinity increase in the fracturing flowback fluids, it is concluded that fracturing flowback fluids contain a mixture of formation water. Because water–rock reactions elevate the total salinity of fracturing flowback fluids, we introduce the Water–Rock Reaction Intensity Coefficient (IR) to denote the intensity of these reactions. Based on the IR value, the binary mixture model for fracturing fluids in fracturing flowback fluids was adjusted. With the increase in flowback time, the content of fracturing fluids in fracturing flowback fluids of Z202H1 and Z203 stabilized at about 55% and 40% respectively. During the same flowback period, the fracturing flowback fluids of the Z203 well exhibit a higher total salinity, a heavier stable isotope ratio, a greater IR, and a lower fracturing fluid content in fracturing flowback fluids. This suggests that the fracturing effect of the Z203 well is superior to that of the Z202H1 well, leading to a higher production capacity of the Z203 well.
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