Flexible Thermoelectric Generator Research Articles

Aerosol Doping System for Microscale Seamless p-n Patterning of Carbon Nanotube Films.

Carbon nanotube (CNT) films are extensively researched as a promising material for wearable thermoelectric generators (TEGs) owing to their good flexibility and high thermoelectric conversion ability. Miniaturizing a pair of p- and n-type thermocouples and increasing the number of repeating elements can effectively increase the power of TEGs. However, conventional p-n patterning methods, such as dipping and printing, have a coarse resolution at the submillimeter level, thereby limiting the miniaturization rate. This study developed an aerosol doping system as a fine n-doping method. A dopant aerosol with a <3 μm diameter was formed through ultrasonic nebulization and air separation, while n-doping was achieved by exposing the CNT film to the dopant aerosol. Microscale p-n patterning of 1 μm was achieved through exposure using small-sized aerosols at an exceptionally slow rate of 3 Å/min. This resolution is 100 times higher than those of conventional p-n patterning methods. The developed aerosol doping system for CNTs can also be used on organic semiconductor materials, such as PEDOT/PSS and perovskite materials. Therefore, it has the potential to significantly impact the realization of Internet of Things (IoT) terminals, such as flexible TEGs, transistors, and solar cells.

A Waterproof Flexible Paper-Based Thermoelectric Generator for Humidity and Underwater Environments.

A thermoelectric generator (TEG) is one of the important energy harvesting sources for wearable electronic devices, which converts waste heat into electrical energy without any external stimuli, such as light or mechanical motion. However, the poor flexibility of traditional TEGs (e.g., Si-based TE devices) causes the limitations in practical applications. Flexible paper substrates are becoming increasingly attractive in wearable electronic technology owing to their usability, environmental friendliness (disposable, biodegradable, and renewable materials), and foldability. The high water-absorbing quality of paper restricts its scope of application due to water failure. Therefore, we propose a high-performance flexible waterproof paper-based thermoelectric generator (WPTEG). A modification method that infiltrates TE materials into cellulose paper through vacuum filtration is used to prepare the TE modules. By connecting the TE-modified paper with Al tape, as well as a superhydrophobic layer encapsulation, the WPTEG is fabricated. The WPTEG with three P-N modules can generate an output voltage of up to 235 mV at a temperature difference of 50 K, which can provide power to portable electronic devices such as diodes, clocks, and calculators in hot water. With the waterproof property, the WPTEG paves the way for achieving multi-scenario applications in humid environments on human skin.

Enhanced thermoelectric properties of carbon nanotubes/polyaniline fibers through engineering doping level and orientation

The rapid progress of miniaturized wearable electronics has put forward great requirements for organic fiber-based thermoelectric (TE) generators. Despite polyaniline (PANI) exhibits many outstanding attributes such as facile synthesis and low cost, as well as good environmental and thermal stability, only a few PANI-based fibers were fabricated and their TE efficiency needs to be further improved. In this work, the TE performance of wet-spun carbon nanotubes (CNTs)/PANI fibers was improved by synergistic engineering doping level of PANI and orientation of the fibers. The doping degree was optimized by varying coagulation baths, bath durations, and dopant loadings in the spinning solution, followed by fixing process during air drying to decrease shrinkage and enhance orientation of the fiber. Hexane coagulated CNTs/PANI fibers exhibited a higher doping degree of PANI compared to that of acetone and ethyl acetate, resulting in a maximum TE power factor of 77.4 μW m−1K−2 for 71 wt% CNTs/PANI fibers at PANI/dopant molar ratio of 2:1.25. Further fixing process induced a more oriented structure along the fibers, facilitating carrier transport and contributing to a significantly increased conductivity of 2155 S cm−1. Consequently, the CNTs/PANI fibers reached an optimal power factor of 91.8 μW m−1K−2. With outstanding TE performance and mechanical properties, the resultant fibers were assembled to fabricate a flexible TE generator, which generated a high output power of 2.5 nW with a temperature gradient of 10 K. These results demonstrate the potential of high-performance CNTs/PANI fibers to harvest body heat for the power supply of the wearable electronics.

High-Performance W-Doped Bi0.5Sb1.5Te3 Flexible Thermoelectric Films and Generators.

Bi-Sb-Te-based thermoelectric materials have the best room-temperature thermoelectric properties, but their inherent brittleness and rigidity limit their application in the wearable field. In this study, W-doped p-type Bi0.5Sb1.5Te3 (W-BST) thin films were prepared using magnetron sputtering on polyimide substrates to create thermoelectric generators (TEGs). Bending tests showed that the thin film has excellent flexibility and mechanical durability, meeting the flexible requirements of wearable devices. W doping can significantly increase the carrier concentration, Seebeck coefficient, and electrical conductivity of BST thin films. At 300 K, the power factor of the W-BST film is 2.25 times higher than that of the undoped film, reaching 13.75 μW cm-1 K-2. First-principles calculations showed that W doping introduces significant impurity peaks in the bandgap, in which W d electrons remarkably hybridize with the Sb and Te p electrons, leading to an improved electrical conductivity of BST films. Furthermore, W doping significantly reduces the work function of BST films, thereby improving the carrier mobility. A TEG module fabricated from four layers of W-BST thin films achieved a maximum output power density of 6.91 mW cm-2 at a temperature difference of 60 K. Application tests showed that the flexible TEG module could power a portable clock using the temperature difference between body temperature and room temperature. At a medium temperature of 439 K, the assembled TEG module can provide a stable output voltage of 1.51 V to power a LED. This study demonstrates the feasibility of combining inorganic thermoelectric materials with flexible substrates to create high-performance flexible TEGs.

Stretchable and Flexible Painted Thermoelectric Generators on Japanese Paper Using Inks Dispersed with P- and N-Type Single-Walled Carbon Nanotubes.

As power sources for Internet-of-Things sensors, thermoelectric generators must exhibit compactness, flexibility, and low manufacturing costs. Stretchable and flexible painted thermoelectric generators were fabricated on Japanese paper using inks with dispersed p- and n-type single-walled carbon nanotubes (SWCNTs). The p- and n-type SWCNT inks were dispersed using the anionic surfactant of sodium dodecylbenzene sulfonate and the cationic surfactant of dimethyldioctadecylammonium chloride, respectively. The bundle diameters of the p- and n-type SWCNT layers painted on Japanese paper differed significantly; however, the crystallinities of both types of layers were almost the same. The thermoelectric properties of both types of layers exhibited mostly the same values at 30 °C; however, the properties, particularly the electrical conductivity, of the n-type layer increased linearly, and of the p-type layer decreased as the temperature increased. The p- and n-type SWCNT inks were used to paint striped patterns on Japanese paper. By folding at the boundaries of the patterns, painted generators can shrink and expand, even on curved surfaces. The painted generator (length: 145 mm, height: 13 mm) exhibited an output voltage of 10.4 mV and a maximum power of 0.21 μW with a temperature difference of 64 K at 120 °C on the hot side.

Engineering Carbon Nanotube Yarns with Polyaniline Coating toward Enhanced Thermoelectric Performance.

The growing demand for wearable electronics has driven the development of flexible thermoelectric (TE) generators which can harvest waste body heat as a renewable power source. Despite carbon nanotube (CNT) yarns have attracted significant attention as a promising candidate for TE materials, challenges still exist in improving their TE efficiency for commercial applications. Herein, we developed high performance CNT/polyaniline (PANI) yarns by engineering the coating of polyaniline emeraldine base (PANIeb), in which CNT yarns were firstly coated by PANIeb layer and further doped by HCl vapor treatment. With the incorporation of PANIeb, σ and S were simultaneously increased to 1796 S cm-1 and 74.8 μV K-1 for CNT/PANIeb 4-2d fibers, respectively. Further HCl vapor treatment induced greatly increased σ to 3194 S cm-1, but maintained be 83 % value before doping, giving rise to the highest power factor of 1224 μW m-1K-2, higher than pristine CNT yarns of 576 μW m-1K-2. Combining outstanding high TE performance and bending durability, a flexible TE generator was constructed to deliver high out power of 187 nW with temperature gradients of about 30 K. These results demonstrate the potential promise of high-performance CNT/PANI-HCl yarns to harvest waste body heat for sustainable power supply.

Layer Exchange Synthesis of SiGe for Flexible Thermoelectric Generators: A Comprehensive Review

AbstractFlexible thermoelectric generators are leading candidates for next‐generation energy‐harvesting devices. Although SiGe, an environmentally‐friendly semiconductor, is the most reliable and widely tested thermoelectric material, it is difficult to form a SiGe layer with high thermoelectric performance at temperatures lower than the heat‐proof temperature of flexible plastic films. In this article, the synthesis of SiGe thermoelectric thin films via the metal‐induced layer exchange phenomenon is reviewed, from its mechanism to device performance. The selection of metal species allows low‐temperature formation (≤500 °C) of p‐ and n‐type SiGe on insulating substrates. Currently, the maximum power factors near room temperature are 850 µW m−1 K−2 for p‐type Si0.4Ge0.6 and 1000 µW m−1 K−2 for n‐type Si0.85Ge0.15. These values are the highest among those of Group IV semiconductor thin films formed at low temperatures. The flexible thermoelectric generator consisting of these p‐ and n‐type SiGe exhibits cross‐sectional and planar power densities of ≈3.0 mW cm−2 and 0.50 µW cm−2, respectively, at a temperature difference of 30 K. Finally, the future challenges of layer exchange for improving the performance of flexible thermoelectric generators based on Group IV semiconductors are discussed.

Carbon Nanotube Yarns Tailored Using Dispersants and Surfactants for Flexible and Wearable Thermoelectric Generators

Carbon Nanotube Yarns Tailored Using Dispersants and Surfactants for Flexible and Wearable Thermoelectric Generators

Finite Element Analysis and Design of a Flexible Thermoelectric Generator with a Rhombus Gap Structure.

Flexible thermoelectric generators (f-TEGs) offer an opportunity to realize wearable, self-powered electronic devices. A typical f-TEG consists of flexible electrodes and rigid thermoelectric (TE) legs in a flexible package. In the realm of f-TEGs utilizing flexible electrodes and TE cuboids, our unwavering objective lies in the attainment of enhanced flexibility and elevated energy conversion efficiency. In this paper, we employ a quasi-three-dimensional thermal model to design an f-TEG with a rhombus gap structure (E/A-RhTEG) with its optimized performance validated by simulation and experiment. Additionally, the lateral and vertical thermal resistances are introduced to further explain the optimizing principle in the f-TEG's output performance. Compared with the conventional TEG with a rectangular air gap structure (E/A-ReTEG), E/A-RhTEG demonstrates improved energy conversion efficiency to some extent. Simulation results indicate that the output power and energy conversion efficiency of a 25-np-pair E/A-RhTEG at a 30 K temperature gradient reach 8.45 mW and 2.55%, which represent a performance improvement of 3.09 and 6.28%, respectively, compared to E/A-ReTEG. To further elucidate the optimization principle in the performance of f-TEGs, additional considerations are given to the lateral and vertical resistances. In this study, E/A-RhTEG comprising 25 np pairs is fabricated utilizing TE cuboids. Experimental findings indicate that E/A-RhTEG exhibits a voltage output of 127.07 mV when subjected to a temperature difference of 30 K, which demonstrates a performance enhancement of 4.06% compared to E/A-ReTEG. Furthermore, this study also demonstrates its implementation when wrapped around a curved surface and successfully achieves a self-powered device system after device performance optimization.

Formulation and optimization of copper selenide/PANI hybrid screen printing ink for enhancing the power factor of flexible thermoelectric generator: A synergetic approach

The stunning thermoelectric behavior of inorganic/organic hybrids and the lack of information on screen-printed flexible thermoelectric generators based on Cu3Se2 and Polyaniline for low-temperature applications have motivated this work. The synergic influence of various acid dopants, concentration, and annealing temperature of polyaniline on the power density of Cu3Se2/PANI ink-based flexible thermoelectric generator is explored. The presence of 1.5 wt% of H2SO4-PANI, annealed at 60 °C, decreased the bandgap and electrical resistance of Cu3Se2 by 11.96 % and 29.4 %, respectively. As a result, an increase of 46.06 % in the Seebeck coefficient and 242 % in the power output is achieved, which is many folds higher than the few reported works using novel materials. In addition, the Cu3Se2/H2SO4-PANI ink-based flexible thermoelectric generator with eight legs exhibited a maximum power output, power density, and power factor of 25.69 nW, 23.79 mW/m2, and 0.77 nW/m2K2 at ΔT = 100 °C, respectively under external load.

Performance evaluation of flexible thermoelectric generator with Bi2Te3 thin-film

In the information society, carrying devices such as smartphones and tablets is crucial, and ensuring their power supply is essential. Furthermore, from the perspective of energy security, being able to secure their power supply from low-quality energy sources could reduce dependence on fossil fuels. In this study, we fabricated a flexible thermoelectric generator capable of harvesting energy from a low-temperature difference between a low-temperature heat source and room or outdoor temperature and evaluated its performance. The device was fabricated by depositing an n-type Bismuth telluride (Bi2Te3) film onto a polyimide film substrate using radio frequency (RF) magnetron sputtering. A 3D printer was used to fabricate flexible fins for attaching and bonding the films. Owing to their adaptability, these flexible models can be installed on heat sources of different shapes. The experimental conditions for this study were as follows: the temperature in the test chamber was maintained at 25 ± 1 °C and that of the heat source ranged from 35 to 75 °C; further, thermoelectric elements in numbers varying from 1 to 6 were installed. The maximum open-circuit output voltage |E| and power generation (Pmax) were determined to be 11.4 mV and 69 nW, respectively. The fins with the Bi2Te3 thin film maintained a temperature of approximately 25 to 30 °C at the tip of the fin, even when exposed to the highest temperature (75 °C) of the heat source during the experiment. As a result, the thermoelectric device developed in this study has demonstrated the potential to power sensors operating in the tens of nW range.

Two-dimensional van der Waals stack heterostructures for flexible thermoelectrics

The incorporation of disparate materials into heterostructures has arisen as a formidable technique for modulating interfaces and electronic configurations. The introduction of two-dimensional (2D) materials has unveiled unparalleled prospects for generating innovative heterostructures in the guise of van der Waals stacks. Tantalum sulfide (TaS2), a prominent 2D material, has been extensively studied across various domains, faces constraints in thermoelectric conversion attributed to its diminished absolute Seebeck coefficient below 10 μV K−1. By constructing a two-dimensional van der Waals stack heterostructure, TaS2/organics/TiS2, a significantly enhanced absolute Seebeck coefficient of 38.3 μV K−1 was obtained, mostly attributed to the induced interfacial effect. The power factor reached 87.6 μW m−1 K−2, marking a sevenfold increase compared to the original. The thermoelectric generator demonstrated a maximum power of 86.4 nW at a temperature difference of 40 K. Employing such heterostructure films in tactile and respiration sensors demonstrated encouraging prospects for aiding the visually impaired with language assistance and facilitating real-time monitoring of respiratory rates for health monitoring purposes. This study highlights the expansive potential of two-dimensional van der Waals stack heterostructure technology for use in flexible thermoelectric generators, wearable sensors, and beyond.

Fully Screen‐Printed, Flexible, and Scalable Organic Monolithic Thermoelectric Generators

AbstractEnergy‐harvesting technologies offer a sustainable, maintenance‐free alternative to conventional energy‐storage solutions in distributed low‐power applications. Flexible thermoelectric generators (TEGs) can generate electric power from a temperature gradient, even on complex surfaces. Organic materials are ideal candidates for flexible TEGs due to their good solution‐processability, natural abundance, low weight, and flexibility. Electronic and thermoelectric properties of organic materials have steadily progressed, while device architectures leveraging their advantages are largely missing. Here, a design and fabrication method are proposed for producing fully screen‐printed, flexible monolithic organic TEGs scalable up to m2, compatible with any screen‐printable ink. This approach is validated, along with its scalability, by printing TEGs composed of two different active inks, in three configurations, with up to 800 thermoelements, with performances well matching simulations based on materials parameters. It is demonstrated that by using an additive‐free graphene ink, a remarkable power density of 15 nW cm−2 at ΔT = 29.5 K can be achieved, with an estimated weight‐normalized power output of 1 µW g−1, highlighting a strong potential in portability. Owing to such power density, only limited areas are required to generate microwatts, sufficient for operating low‐power electronic devices such as sensors, and wearables.

Largely enhanced performance of Cu2Se film by doping sulfur for flexible thermoelectric generators

Herein, a facile method to prepare flexible S-doped Cu2Se thermoelectric films on porous nylon membranes is developed. First, S-doped Cu2Se powders with nominal compositions of Cu2Se1-xSx (x = 0, 0.02, 0.04, or 0.06) are synthesized by a hydrothermal method. Then, the as-prepared powders are deposited onto nylon substrates by vacuum-assisted filtration and hot-pressing. By adjusting the amount of S doping, the carrier concentration and mobility of the films are tuned, and the thermoelectric properties of the films are effectively optimized. As a result, the Cu2Se0.96S0.04 film displays a highest power factor of ∼662.2 μW m−1 K−2 at 300 K, representing one of the highest values reported for Cu2Se-based flexible films. The film also exhibits excellent flexibility (after 1500 bending cycles around a 4 mm radius rod, 90.8% of the initial electrical conductivity is retained). Additionally, a six-leg flexible thermoelectric generator is assembled with the Cu2Se0.96S0.04 film and outputs a peak power of 1.89 μW at a temperature difference of 23.1 K. This work presents a new method for preparing cost-effective and high-performance Cu2Se flexible thermoelectric films.

Phase-Transition-Promoted Thermoelectric Textiles Based on Twin Surface-Modified CNT Fibers.

With the fast development of new science and technology, wearable devices are in great demand in modern human daily life. However, the energy problem is a long-lasting issue to achieve real smart, wearable, and portable devices. Flexible thermoelectric generators (TEGs) based on thermoelectric conversion systems can convert body waste heat into electricity with excellent flexibility and wearability, which shows a new direction to solving this issue. Here in this work, polyethylenimine (PEI) and gold nanoparticles (Au NPs) twin surface-modified carbon nanotube fibers (CNTFs) were designed and prepared to fabricate thermoelectric textiles (TET) with high performance, good air stability, and high-efficiency power generation. To better utilize the heat emitted by the human body, microencapsulated phase change materials (MPCM) were coated on the hot end of the TET to achieve the phase-transition-promoted TET. MPCM-coated TET device could generate 25.7% more energy than the untreated control device, which indicates the great potential of the phase-transition-promoted TET.

Developing Air-Stable n-Type SWCNT-Based Composites with High Thermoelectric and Robust Mechanical Properties for Wearable Electronics.

Flexible organic thermoelectric generators are gaining prominence in wearable electronics, leveraging body heat as an energy source. Their advancement is hindered by the scarcity of air-stable n-type organic materials with robust mechanical properties. This study introduces two new polymers (HDCN4 and HDCN8), created through polycondensation of paraformaldehyde and diamine-terminated poly(ethylene glycol) (PEGDA) with molecular weights of 4000 and 8000 g/mol into single-walled carbon nanotubes (SWCNTs). The resulting HDCN4/SWCNT and HDCN8/SWCNT composites show impressive power factors of 225.9 and 108.2 μW m-1 K-2, respectively, and maintain over 90% in air for over four months without encapsulation. The HDCN4/SWCNT composite also demonstrates significant tensile strength (33.2 MPa) and flexibility (up to 10% strain), which is currently the best mechanically n-type thermoelectric material with such a high power factor reported in the literature. A thermoelectric device based on HDCN4/SWCNT generates 4.2 μW of power with a 50 K temperature difference. Additionally, when used in wearable temperature sensors, these devices exhibit high mechanical reliability and a temperature resolution of 0.1 K. This research presents a viable method to produce air-stable n-type thermoelectric materials with excellent performance and mechanical properties.

A Novel PDMS-Based Flexible Thermoelectric Generator Fabricated by Ag2Se and PEDOT:PSS/Multi-Walled Carbon Nanotubes with High Output Performance Optimized by Embedded Eutectic Gallium-Indium Electrodes.

Flexible thermoelectric generators (FTEGs), which can overcome the energy supply limitations of wearable devices, have received considerable attention. However, the use of toxic Te-based materials and fracture-prone electrodes constrains the application of FTEGs. In this study, a novel Ag2Se and Poly (3,4-ethylene dioxythiophene): poly (styrene sulfonate) (PEDOT:PSS)/multi-walled carbon nanotube (MWCNT) FTEG with a high output performance and good flexibility is developed. The thermoelectric columns formulated in the work are environmentally friendly and reliable. The key enabler of this work is the use of embedded EGaIn electrodes, which increase the temperature difference collected by the thermoelectric column, thereby improving the FTEG output performance. Additionally, the embedded EGaIn electrodes could be directly printed on polydimethylsiloxane (PDMS) molds without wax paper, which simplifies the preparation process of FTEGs and enhances the fabrication efficiency. The FTEG with embedded electrodes exhibits the highest output power density of 25.83 μW/cm2 and the highest output power of 10.95 μW at ΔT = 15 K. The latter is 31.6% higher than that of silver-based FTEGs and 2.5% higher than that of covered EGaIn-based FTEGs. Moreover, the prepared FTEG has an excellent flexibility (>1500 bends) and output power stability (>30 days). At high humidity and high temperature, the prepared FTEG maintains good performance. These results demonstrate that the prepared FTEGs can be used as a stable and environmentally friendly energy supply for wearable devices.

Vertically designed high-performance and flexible thermoelectric generator based on optimized PEDOT:PSS/SWCNTs composite films

To solve the long-lasting challenge of low thermoelectric performance of flexible thermoelectric device (F-TEG), in this work, we report a three-dimensional vertically structured F-TEG composed of flexible, stable, and high-performing p- and n-type single-walled carbon nanotube (SWCNT)-based composite films. The p-type SWCNT-based composite film exhibits a high room-temperature power factor of >500 μW m−1 K−2, benefiting from the effective de-doping of the hybridized poly(3,4-ethylenedioxythiophene)–poly(styrenesulfonate) (PEDOT:PSS) using a binary co-doping agent composed of NaHCO3 and the polar solvent ethylene glycol (EG). Simultaneously, the n-type SWCNT-based film doped with the amine-rich electron donor polyethyleneimine (PEI) is prepared, exhibiting a high room-temperature power factor of 185.4 μW m−1 K−2 and excellent air stability. By employing flexible supporting foam, vertical p-n thermoelectric legs are realized, and the F-TEG based on these legs exhibits a maximum open-circuit voltage of 23.2 mV and a maximum output power of 2.6 μW at a temperature difference of 48 K, demonstrating a competitive normalized power density of >2.5 μW cm−2 K−2, which advances the low-power flexible wearable field.

Correlating framework structures and thermoelectric performance of metal–organic framework/carbon nanotube thermoelectric hybrids with n–p type inversion

Metal–organic frameworks (MOFs) show considerable promise as thermoelectric materials due to the inherently low thermal conductivities provided by their unique porous frameworks. Nevertheless, their applications are impeded by poor electrical conductivities and processabilities. Herein, novel n–p type carrier transport inversion MOF/carbon nanotube (CNT) thermoelectric hybrids are developed via controlled adjustment of the MOF/CNT composition. The low thermal conductivities of the MOFs provide optimized (zT) values of 0.071 and 0.025 for the n- and p-type thermoelectric hybrids, respectively. Moreover, a flexible thermoelectric generator consisting of seven p-n junction pairs in series provides a maximum open-circuit voltage of 11.2 mV and a maximum power of around 165.5 nW at a temperature difference of 20 K. This study introduces an alternative approach to creating high zT p- and n-type thermoelectric hybrids near room temperature by manipulating the composite ratio, and establishes a correlation between the framework structure and the thermoelectric performance, thereby supporting the development of MOF-based thermoelectric materials.

Investigations of Morphology and Carrier Transport Characteristics in High‐Performance PEDOT:PSS/Tellurium Binary Composite Fibers Produced via Continuous Wet‐Spinning

AbstractFiber‐based flexible thermoelectric (TE) generators are highly desirable due to their capability to convert thermal energy into electricity and their potential applications in wearable electronics. High‐performance poly(3,4‐ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS)/Tellurium (Te) composite TE fibers have been successfully developed via a continuous wet‐spinning approach followed by sulphuric acid treatment. With a simple pre‐modification to Te nanowires, the inorganic Te fillers form uniform distribution in PEDOT:PSS. At the optimal condition, the composite fibers exhibit a power factor of 233.5 µW m−1 K−2 and mechanical strength of 205 MPa, which are among the highest values reported so far for the PEDOT:PSS‐based TE fibers. From the viewpoint of TE property enhancement mechanism, understanding the morphology and carrier transport behavior in the 1D organic/inorganic composite fibers remains still challenging. On basis of a series of PEDOT:PSS/Te composite fibers with varying Te fractions, orientations of both the inorganic and organic constituents are quantitatively evaluated. Their electrical conductivities and Seebeck coefficients are also analyzed with modified series‐parallel models and energy filtering theory. This work may not only provide a universal approach to produce high‐performance organic/inorganic composite TE fibers for various wearable applications, but also help to understand the morphology and charge transport between heterogeneous phases in a 1D composite.