Flame Propagation Research Articles

Effect of vent size on vented H2/N2/air deflagration

In this work, the coupling of explosion venting (vent size) and inerting (N2) on H2/air deflagration was investigated. Experiments were carried out in a vertical rectangular duct with an upper opening at an initial temperature and pressure of 280 K and 101 kPa, and a vent coefficient Kv was employed to replace the vent size to elucidate its effect on pressure buildup and flame propagation during H2/N2/air deflagration. In the present study, the internal pressure profile is monitored by three pressure sensors, PS1-3, which are installed at the bottom, center, and top of the duct, respectively, and the external pressure profile is obtained by PS4. The results show that the maximum internal overpressure (pmax) recorded by PS1-3 all increase with increasing Kv, but pmax obtained from PS2 and PS3 tend to increase linearly. For a given Kv, the maximum and minimum amplitudes of pmax are measured by PS1 and PS3, respectively. Specifically, the greater the distance between the pressure sensor and the upper opening, the greater the amplitude of pmax. The relationship between the maximum reduced explosion pressure (pred) and Kv is investigated, where pred is defined as the highest pmax for a specific Kv. As Kv increases from 2.2 to 11.9, pred increases from 26.25 kPa to 88 kPa. The maximum external flame velocity (Vext) increases from 83 m/s to 454 m/s with increasing Kv from 2.2 to 11.9. The amplitude of the maximum external overpressure (pext) first increases and decreases with an increase in Kv from 2.2 to 11.9. The formation time (Δt) of pext decreases and then increases and finally decreases with increasing Kv from 2.2 to 11.9. When Kv is increased from 2.2 to 4.1, all external fireballs are presented as mushroom shapes, but the external fireballs are gradually transformed into jet shapes for Kv ≥7.8. Two pressure oscillations, including Helmholtz oscillations and acoustic oscillations, are found. Acoustic oscillations are found in all tests, but Helmholtz oscillations are only observed for Kv ≤ 4.1.

Experimental Study on the Influence of Ignition Position on the Overpressure of Hydrogen Jet Flame.

The accidental leakage of hydrogen poses a significant barrier to the widespread adoption and development of hydrogen energy due to the potential risks of fire, explosion, and jet fire hazards. Experimental investigations have been conducted on the process of jet fires formed by igniting hydrogen jet streams after accidental releases in scenarios such as high-pressure hydrogen gas storage tanks and hydrogen transmission pipelines. These experiments utilized a release pipe with a diameter of 10 mm and a length of 0.75 m, along with three pressure sensors, to study the influence of release pressure and ignition position on jet flame overpressure and flame propagation. Extensive tests at 1.5 MPa yielded a hydrogen flammability map containing two nonflammable zones and one flammable zone, along with a graph illustrating the relationship between overpressure and ignition points. Furthermore, experiments conducted at ignition positions of 0.05, 0.5 and 1.0 m under release pressures ranging from 6 to 10 MPa revealed that release pressure had no significant effect, while ignition position notably influenced the waveform and peak of the shockwave. Additionally, a peak shockwave reaching 30 kPa was observed at the downstream of the pipe outlet when ignited at 0.05 m, far exceeding the threshold of 24 kPa associated with fatalities. This research aims to provide valuable insights for safety design and protection distance considerations in scenarios involving hydrogen release and ignition.

Effects of Fuel Bed Slope and Wind Direction on Flame Spread Characteristics Over a Bed of Pinus Silvestris Needles

ABSTRACT Important factors influencing the flame characteristics over a bed of dry pine needles from Siberian Boreal forests (Pinus silvestris) in lab-scale is provided. Factors such as slope of the fuel bed, wind velocity, and direction of spread (concurrent flow or opposed flow), which play significant roles in determining the flame spread rate, have been investigated. Systematic lab-scale experiments have been carried out in a wind tunnel with varying air velocities and on an inclined fuel bed in still air. Numerical simulations have been carried out using a three-dimensional physics-based flame spread model available in Fire Dynamics Simulator, and the results are validated against a wide range of measured flame characteristics. The validated numerical model is then used to simulate concurrent flow and opposed flow flame spread over a sloping fuel bed in the presence of wind. Gas phase temperature on and above the bed surface and total and radiative heat flux measurements for concurrent flow and opposed flow flame spread under the influence of wind as well as for upslope flame spread in still air are presented. A stationary flame propagation mode is observed for a flat fuel surface. Predicted temperature, flow, and species concentration fields have been reported for selected cases to understand the flow and flame dynamics in gas phase and within the fuel beds. These data serve as a validation of the numerical model used for simulating the experimental cases. Further, it can be used to validate popular fire models such as Fire Foam and Fire-Star 3D.

Optical study on spray mixing, flame propagation and jets evolution within visible methanol active pre-chamber for turbulent jet ignition

Methanol spray impingement, mixing, flame propagation and jet evolution within the narrow-confined active pre-chamber (APC) with complex walls were experimentally observed by optical method for the first time. The effects of injection pressure and duration was investigated on an actual-geometry optical APC assembled in constant volume combustion chamber (CVC). Exploration on APC internal processes within static environments forms the basis for optimization of APC and analysis of jet formation. Mie scattering coupled with flame natural luminosity imaging were used to record spray mixing and combustion. The results show that in the APC with narrow-confined space, methanol spray undergoes three wall impingements, inducing a tumble that promotes mixing. High injection pressure enhances rapid spray tip penetration, while long injection duration slows methanol diffusion. In longer injection duration cases, the spray tip after the third impingement interferes with subsequent sprays. For higher injection pressure, this interference occurs in the APC cone section due to a larger spray cone angle, whereas for lower pressure, it happens in the APC duct section. Higher injection pressure also causes more spray to impact the APC bottom after the first wall impingement, hindering flame acceleration in the duct section. Irregular flame propagation is observed in the APC cone section due to wider space and uneven mixture conditions, while the convergent geometry from the APC throat to the duct section significantly accelerates flame propagation. The APC jet appears due to the pressure difference between the APC and the main chamber, with the brightness and length of the visible flame jet increasing with APC flame luminosity and pressure difference. A Mach ring structure is observed initially, but the jet velocity decreases as the Mach ring disappears during the APC inner flame extinguishing process. Through this study, the actual spraying and combustion process in APC is experimentally captured and revealed, which are an important contribution for APC optimization and development.

Study on the combustion characteristics and reaction mechanism of aluminum/alcohol-based nanofluid fuel

Enhancing the volumetric energy density of fuels is a crucial approach in the exploration of efficient energy sources. As a commonly used high-energy additive, Aluminum nanoparticles (Al NPs) holds broad application prospects. This study delves into the effects of Al NPs on the combustion characteristics of methanol and ethanol fuels through in-depth analysis of single droplet combustion and spray combustion experiments involving alcohol-based nanofluid fuels. The experiments revealed that adding Al NPs significantly enhances fuel combustion efficiency, shortening both the combustion life and ignition delay time. Spray combustion tests demonstrated that adding 2 wt% Al NPs increased the maximum and average flame propagation speeds of ethanol fuel spray by 48.93 % and 47.94 %, respectively, while the maximum explosion pressure rose from 0.66MPa to 0.83MPa, with a reduced time to reach peak explosion pressure by 106ms. Based on the SEM and XRD characterization results of the combustion residues and the analysis of flame morphology, a physical model of the alcohol-based nanofluid fuel spray combustion flame was established. Numerical simulations of the gas-phase kinetics model showed that the generation rates of radicals such as H, O, and OH were significantly increased with the addition of Al NPs, intensifying the combustion reaction. The findings provide a theoretical basis for future fuel design and combustion performance optimization.

The effect of jet disturbance on flame propagation characteristics of multi-component natural gas/hydrogen mixed fuel

Gas explosions mostly occur in turbulent environments in practical situations. Meanwhile, the current research on the explosion characteristics of hydrogen-doped natural gas is mostly methane/hydrogen mixed fuel, ignoring the influence of other components of natural gas on the explosion characteristics of the actual situation. Therefore, the effects of different jet intensities (Pjet), hydrogen-doping ratios (XH2) and equivalence ratios (φ) on the explosion characteristics of multi-component natural gas/hydrogen mixed fuel are experimentally investigated in cylindrical tanks of 30 L. Additionally, it extensively explored the dual influence of jet disturbance and gas inerting effect on the flame propagation characteristics of multi-component natural gas/hydrogen mixed fuel. With the increase of Pjet, both Pmax and (dp/dt)max initially increase and then decrease, while τ continuously decreases. When Pjet = 0.4 MPa, the promotion effect on Pmax and (dp/dt)max is most significant. The lifting of XH2 leads to a gradual increase in Pmax and decreasing τ. (dp/dt)max exhibits a trend of initially increasing and then decreasing with the elevation of XH2, reaching its maximum at XH2 = 40%. The introduction of jet flow significantly reduces the promotion or inhibition effect on explosions of high hydrogen blending ratio mixtures. Furthermore, the introduction of jet flow is more effective in promoting the explosive performance of multi-component natural gas/hydrogen mixed fuel with high equivalence ratios and low hydrogen doping ratios under rich fuel conditions. This study can provide a key reference for the explosion hazard assessment during the practical application of natural gas/hydrogen mixed fuel.

Experimental Study of the Effect of CO/H2 Ratio and Release Pressure on Syngas Jet Flame Propagation and Overpressure.

Syngas, composed of hydrogen and carbon monoxide, serves as an alternative fuel for hydrogen energy and a key raw material for chemical synthesis. However, due to its flammable nature, syngas poses risks of forming explosive mixtures in the event of a leak. This study explores potential accident scenarios in coal chemical environments involving syngas reaction vessels. Experimental investigations focus on the overpressure and propagation dynamics of jet flames resulting from syngas leakage, with CO volume fractions ranging from 50 to 80% and release pressures between 2 and 5 MPa. Results reveal that maximum flame overpressure occurs within a CO volume fraction range of 55-65%, with no consistent relationship observed between overpressure and CO fraction at fixed release pressures. During our experiments, the maximum recorded overpressure of 28.4 kPa was reached during vented explosions. Additionally, ignition outcomes categorize into three types based on flame propagation speed: combustion/flare, resembling normal deflagration; and high-velocity deflagration, characterized by rapid propagation and potential for steady jet fire formation. While shockwave-like features may be observed, these do not indicate true detonation. These findings offer insights for the safe handling and storage of syngas.

Experimental Study on Explosion Characteristics and Consequences for Homogeneous and Inhomogeneous Methane-Air Mixtures within a Kitchen

ABSTRACT Owing to the effect of a non-uniform concentration distribution, natural gas leakage explosion accidents usually cause different degrees of damage inside residential kitchens. According to the similarity principle, a reduced-scale experiment setup of a kitchen was established. Uniform and non-uniform explosion experiments for methane-air mixtures with concentrations of 7.7%, 9.5%, and 11.2% were performed. The flame propagation behavior and pressure evolution characteristics were analyzed for homogeneous and inhomogeneous methane-air mixtures. In addition, two dimensionless coefficients, namely macroscopic and directional non-uniformity coefficients, were introduced to quantify the uneven distribution of gas concentration within the kitchen. Furthermore, the flame development process and pressure evolvement characteristics were compared between homogeneous and inhomogeneous methane-air mixtures in a fuel-lean, chemical equivalence concentration and fuel-rich state. The results show that the macroscopic non-uniformity coefficients are 0.0998, 0.0653, and 0.0571 on the fuel-lean, chemical equivalence concentration and fuel-rich conditions, respectively. It indicates that the greatest non-uniformity of methane concentration distribution within the kitchen is represented on the fuel-lean condition. The concentration gradient could obviously reduce the explosion overpressure in the fuel-lean condition, whereas it would not significantly decrease the explosion overpressure in the chemical equivalence concentration or fuel-rich condition. It means that the greater the non-uniformity coefficient is, the more significant the effect on the overpressure peak is.

Effects of explosion-venting interlayer within utility tunnels on the characteristics of natural gas explosions

With the rapid expansion of the national economy and strategic adjustments to the energy structure, natural gas, a crucial clean energy source, encounters significant safety challenges during transportation in utility tunnels, owing to its flammable and explosive nature. To effectively address the current issues in response technologies for gas explosions in utility tunnels, such as inadequate control over the flame propagation range, limited attenuation of overpressure, and the mechanical impact damage effects on the internal structures of the utility tunnels and surrounding buildings, a small-scale experimental platform was constructed independently. This platform is designed to explore how the area and position of vents affect the characteristics of methane explosions within tunnels, utilizing the explosion venting mechanism. The results indicate that, for the same venting position, the maximum flame propagation distance, speed, and peak overpressure all decrease as the venting area increases. When the vent is located at position 1 in each compartment, the reduction in maximum flame propagation distance and speed is the most significant. The maximum decrease in peak overpressure occurs at venting position 2. When the venting position is closer to the ignition source, the rate of explosion overpressure rise and the explosion index both decrease with an increase in venting area, with the most significant reduction occurring at venting position 1. Conversely, when the venting position is farther from the ignition source, the rate of explosion overpressure rise and the explosion index actually increase, with the most significant increase occurring at venting position 4. The research findings offer a theoretical foundation and scientific guidance for developing new technologies aimed at mitigating gas explosion disasters in utility tunnels through internal venting.

Effects of position layout and length gradient of two side ducts of on methane/air explosion in a tube

ABSTRACT In order to examine how two side ducts affect the dynamic behavior of a gas explosion in a tube, two side ducts were added to a tube containing a mixture of 9.5% methane and air. An experiment was conducted to release the explosion pressure and study how the position and length gradient of the side ducts influence the explosion’s overpressure and the speed at which the flame spreads. Based on the data, it was found that the most effective pressure release occurred at a length of 0.2 m for the front side duct and 0.1 m for the end side duct. Additionally, the greatest explosive overpressure recorded was 2.54 kPa. A double driving effect was created between the two side ducts when they were put in the front and middle and the middle and end locations. This increased the flame propagated speed. The greatest acceleration effect on the flame front occurred at 0.2 m of side duct length. When the two side ducts were placed at the front and end of the tube, the length gradient did not have any impact on flame propagation. Instead, it was predominantly the length of the front side duct that controlled flame propagation. The pressure relief effect was more pronounced when the two side ducts had a downward gradient; however, it was affected by the length of the end side duct. A relationship equation was established between the lengths of the two side ducts (d 1 and d 2), positioned at the front and end locations, and the maximum flame velocity (Vmax). The analysis results of the impact of different positioning layouts and length gradients of two side ducts on flame propagation and pressure release within the tube were instrumental in ensuring the safety of personnel, equipment, and environment during energy utilization processes.

Experimental and Numerical Study on the Plasma-Laser-Induced Ignition of Strut Stabilizer at Different Locations

The minimum ignition equivalence ratio of the strut stabilizer is an important parameter in the design of integrated afterburners. The ignition location significantly affects the ignition equivalence ratio and flame propagation, and therefore, it should be deeply studied. The ignition equivalence ratio and flame propagation at different axial ignition locations downstream of the strut stabilizer are studied in this paper. When the ignition distance is approximately the bluff body trailing edge width, a lower ignition equivalence ratio is required for ignition, and the flame propagates faster through the entire combustion chamber. For different ignition locations, the generated flame kernel at different locations all first propagates to the shear layer. Subsequently, the unilateral flame rapidly extends, ultimately igniting the entire combustion chamber. The flame propagation trajectory depends on the ignition location controlled by the non-reacting flow field and the distribution of kerosene concentration. The flame propagation trajectory mainly includes three paths: (1) the flame kernel is directly downstream the shear layer when the ignition location is close to the tail edge of the stabilizer, (2) the flame propagates upstream into the shear layer in a U-shape when the ignition location is far from the stabilizer but still in the recirculation zone, and (3) the flame propagates upstream into the recirculation zone and shear layer in a U-shape when the ignition location is outside the recirculation zone. In addition, the time for flame propagation to the shear layer is directly related to the ignition performance when the ignition location is within the recirculation zone. If the flame reaches the shear layer in a longer time, there will be more energy loss during the flame propagation process, and the ignition performance will deteriorate. The speed of the flame-trailing edge extension is directly related to the ignition fuel-air ratio, and the downstream extension of the flame is mainly affected by the turbulence velocity in the shear layer.

Synergistic enhancement of oil-water separation and flame retardant properties of melamine sponges based on 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and perfluorinated compounds

Facing the escalating issue of industrial wastewater discharge and its profound environmental repercussions, the creation of novel sponge materials that excel in oil-water separation while incorporating flame retardancy becomes critically urgent. Despite their superior absorption capabilities, conventional oil-water separation sponges typically overlook flame retardant features, a limitation that curtails their applicability. To address this gap, we have developed a multifunctional hydrophobic sponge through a sophisticated multi-step chemical self-assembly process. This method grafts 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and perfluorinated compounds onto melamine foam (MF), yielding a composite material designated as DOPO-PF@MF. DOPO-PF@MF boasts a dual functionality of hydrophobicity and flame retardance. Its modified surface exhibits a pronounced hydrophobic-lipophilic balance, with a static water contact angle of 134°. It also displays favorable wetting characteristics towards various organic solvents, such as methanol, ethanol, dimethylformamide, dichloromethane, and hexane. This material demonstrates an impressive adsorption capacity for these solvents, with the adsorption-desorption capacity for ethanol remaining consistent over ten cycles. Furthermore, DOPO-PF@MF efficiently separates emulsions of methylene chloride and water, showcasing its versatility. Moreover, DOPO-PF@MF exhibits commendable chemical resilience under extreme temperatures, ranging from 0 °C to 100 °C, and withstands both acidic and alkaline conditions (pH 1–14), preserving its structural integrity against corrosive substances. Most notably, it surpasses unmodified melamine foam in flame retardancy. The incorporation of DOPO fortifies the material's resistance to high-temperature ignition, effectively inhibiting flame propagation and reducing burn rate, enhancing safety measures.

Modeling and Experimental Validation of Pre-Chamber Jet Penetration Considering Jet Density and Ejection Pressure Variations

Abstract Although pre-chamber (PC) is regarded as a promising solution to enhance ignition in lean-burn gas engines, a lack of comprehensive understanding of PC jet penetration dynamics remains. This study proposed a zero-dimensional (0-D) model for PC jet penetration, considering the mixing of combustion products and unburned gases and floating ejection pressure. A combustion completion degree was defined employing fuel property and heat release to estimate varying jet density. Pressure differences between PC and the main chamber (MC) were referred to as the ejection pressure. Then, this model was validated against experiments from a constant volume chamber and a rapid compression and expansion machine with CH4-H2 blends at different equivalent ratios. Results showed that the proposed model can provide a good prediction in stationary and turbulent fields with the calibrated model coefficient. The overall jet penetration exhibits a t0.5 dependence due to its single-phase characteristic and the relative lower density compared to ambient gas in MC. The flame propagation speed and heat release in PC influence the combustion completion degree at the start of jet ejection, the mass fraction of burned gas in jet increases with the equivalent ratio. Jet penetration is primarily driven by ejection pressure, with tip dynamics barely affected by the pressure difference after the peak. Tip penetration intensity increases with increased fuel equivalent ratio and H2 addition, owing to the faster flame propagation. These findings can offer useful suggestions for model-based design and combustion model development for gas engines.

Dynamics of fuel-lean and stoichiometric methane-air explosion venting: Experiments and simulations

The computational explosion venting analyzer (EVA), a zero-dimensional (0D) model based on the conservation of mass and energy, is being developed to model centrally- and rear-ignited explosions. For this purpose, a series of explosion venting experiments in a cylinder with vent areas of 132.7, 86.6, 67.9 cm2 (corresponding to the vent area ratios of K=0.47,0.31,0.24, respectively) is performed. Two equivalence ratios of ϕ=0.8 and 1 are considered to represent the fuel-lean and stoichiometric methane-air mixtures, respectively. The dynamics of explosions is studied through the observation of flame propagation and pressure measurements. In rear ignition experiments, laminar, so-called “finger flame” propagation is observed, while in the case of center ignition, a flame initially expands spherically and then is pulled by the vent, acquiring a half-elliptical and half-spherical shape. The peak pressures obtained from rear ignition exceed their counterparts in the center ignition experiments. The EVA is compared with the experimental matrix. No turbulence is implemented in stoichiometric simulations, and slight turbulence has been accounted for in the lean mixture simulations. It is found that the large vent, generally, imposes more disturbances on the flame shape and the fuel-lean mixtures are more prone to the diffusional-thermal instabilities. It is shown that such a simple numerical tool, as the EVA is, can estimate a complicated problem such as pressure evolution resulted from a vented gas explosion.

Thermal Runaway Characteristics of Ni-Rich Lithium-Ion Batteries Employing Triphenyl Phosphate-Based Electrolytes

Abstract Enhancing the safety performance of high-energy-density lithium-ion batteries is crucial for their widespread adoption. Herein, a cost-effective and highly efficient electrolyte additive, triphenyl phosphate (TPP), demonstrates flame-retardant properties by scavenging hydrogen radicals in the flame, thereby inhibiting chain reactions and flame propagation to enhance the safety performance of graphite/LiNi0.8Co0.1Mn0.1O2 (Gr/NCM811) pouch cells. The results reveal that the capacity retention of cells without flame retardants, and those with the addition of 1 wt%, 3 wt%, 5 wt%, and 10 wt% TPP is 96.4%, 92.1%, 84.15%, 40.8%, and 12.4% (at 1/2C 300 cycles), respectively. Furthermore, compared to cells without flame retardants, the highest temperature during thermal runaway (TR) decreases by 8.3%, 26.9%, 35.1%, and 38.8% with the addition of 1 wt%, 3 wt%, 5 wt%, and 10 wt% TPP, respectively. Through comprehensive analysis of the impact of flame-retardant additives on battery electrochemical performance and safety, it is determined that the optimal addition amount is 3 wt%. At this level, there are no significant flames during battery abuse, the triggering temperature for TR increases by 26.6 ℃, and the maximum temperature decreases by 157 ℃. Moreover, even after 300 cycles at 1/2C, a capacity of 814.5 mAh is retained, with a capacity retention rate of 84.1%. This study provides valuable insights into mitigating TR in high-energy-density power batteries.

Characteristics analysis of flame propagation and its coupling effect with other parameters in LPG pipeline

AbstractTo study the flame propagating characteristic and its coupling effect with other parameters in the LPG pipeline, a typical pipeline model with two equal‐length branches perpendicular to each other is designed for experiment and simulation. Then, gas explosion scenarios are experimentally tested and numerically simulated, which is followed by the analysis of flame shape changing with time and peak temperature changing with space. Results show that when passing through the bifurcation, flame propagates to vertical branch B in a sharp knife shape affected by the strong vortex, reflected airflow, and compressed pressure wave in the pipeline with a diameter of 0.125 m. At the monitoring point that is 0.4 m away from the bifurcation point, the peak temperature of the vertical branch B is 57.87% bigger than that of the horizontal branch C, and its arrival time is 80% longer than that of the horizontal branch C, due to the existence of flame in vertical branch B. What's more, in both branches, the coupling results between peak temperature and peak velocity agree very well with the growth function, while the coupling results between peak temperature and peak pressure agree well with the decay function, providing aids to the optimal layout design of industrial pipeline branches as well as to the explosion suppression measures.

Spatiotemporal Surface Temperature Measurements Resolving Flame-Wall Interactions of Lean H2-Air and CH4-Air Flames Using Phosphor Thermometry

AbstractSpatiotemporal wall temperature (Twall) distributions resulting from flame-wall interactions of lean H2-air and CH4-air flames are measured using phosphor thermometry. Such measurements are important to understand transient heat transfer and wall heat flux associated with various flame features. This is particularly true for hydrogen, which can exhibit a range of unique flame features associated with combustion instabilities. Experiments are performed within a two-wall passage, in an optically accessible chamber. The phosphor ScVO4:Bi3+ is used to measure Twall in a 22 × 22 mm2 region with 180 µm/pixel resolution and repetition rate of 1 kHz. Chemiluminescence imaging is combined with phosphor thermometry to correlate the spatiotemporal dynamics of the flame with the heat signatures imposed on the wall. Measurements are performed for lean H2-air flames with equivalence ratio Φ = 0.56 and compared to CH4-air flames with Φ = 1. Twall signatures for H2-air Φ = 0.56 exhibit alternating high and low-temperature vertical streaks associated with finger-like flame structures, while CH4-air flames exhibit larger scale wrinkling with identifiable crest/cusp regions that exhibit higher/lower wall temperatures, respectively. The underlying differences in flame morphology and Twall distributions observed between the CH4-air and lean H2-air mixtures are attributed to the differences in their Lewis number (CH4-air Φ = 1: Le = 0.94; H2-air Φ = 0.56: Le = 0.39). Findings are presented at two different passage spacings to study the increased wall heat loss with larger surface-area-to-volume ratios. Additional experiments are conducted for H2-air mixtures with Φ = 0.45, where flame propagation was slower and was more suitable to resolve the wall heat signatures associated with thermodiffusive instabilities. These unstable flame features impose similar wall heat fluxes as flames with 2–3 times greater flame power. In this study, these flame instabilities occur within a small space/time domain, but demonstrate the capability to impose appreciable heat fluxes on surfaces.

A Study on the Influence of Radial Spoiler Arrangement on the Combustion Process of Wankel Rotor Engines

Wankel rotor engines are widely used in various fields due to their high power density and simple structure. This paper presents the optimisation of the Wankel rotor engine by simple modifications of the structure. We propose a radial spoiler arrangement scheme that can affect the flame propagation speed and reaction severity by altering the flow field distribution and pre-reaction distribution in the cylinder. By comparing the effects of four layout schemes on flame propagation speed and reaction intensity, including no spoilers, radial spoilers deflected at an angle of 10° in the negative direction of the Z-axis, radial spoilers deflected at an angle of 10° in the positive direction of the Z-axis, and radial spoilers arranged at the centre of the rotor combustion chamber, the benefits of different layout schemes were evaluated. We conducted a study on the influence of the arrangement of radial spoilers on the combustion process of a Wankel rotary engine through theoretical calculations. This helps to reduce engine vibration, improve engine operation stability, and enhance engine performance.

Enhanced Fire Safety of Energy-Saving Foam by Self-Cleavage CO2 Pre-Combustion and Phosphorus Release Post-Combustion.

Rigid polyurethane foam (RPUF) is widely utilized in construction and rail transportation due to its lightweight properties and low thermal conductivity, contributing to energy conservation and emission reduction. However, the inherent flammability of RPUF presents significant challenges. Delaying the time to ignition and preventing flame spread post-combustion is crucial for ensuring sufficient evacuation time in the event of a fire. Based on this principle, this study explores the efficacy of using potassium salts as a catalyst to promote the self-cleavage of RPUF, generating substantial amounts of CO2, thereby reducing the local oxygen concentration and delaying ignition. Additionally, the inclusion of a reactive flame retardant (DFD) facilitates the release of phosphorus-oxygen free radicals during combustion, disrupting the combustion chain reaction and thus mitigating flame propagation. Moreover, potassium salt-induced catalytic carbonization and phosphorus derivative cross-linking enhance the condensed phase flame retardancy. Consequently, the combined application of potassium salts and DFD increases the limiting oxygen index (LOI) and reduces both peak heat release rate (PHRR) and total heat release (THR). Importantly, the incorporation of these additives does not compromise the compressive strength or thermal insulation performance of RPUF. This integrated approach offers a new and effective strategy for the development of flame retardant RPUF.

Comparison of fluid structure downstream of an evaporative flameholder with subsonic uniform and subsonic-supersonic inflows

Subsonic uniform and supersonic mixing flows are widely present in the combustion chamber of a multi-mode combined scramjet engine, where the significant pressure, velocity, and temperature gradients of the two impose severe limitations on flame propagation. The vortex structures downstream of an evaporative flameholder were experimentally measured under subsonic-supersonic mixing inflow and subsonic uniform inflow. Results indicate that, under subsonic-supersonic mixing inflow conditions, an asymmetric vortex structure in the recirculation zone is formed due to the presence of a subsonic-supersonic shear layer, which exerts compressive or stretching effects on the recirculation zone downstream of the flameholder, in contrast to the symmetric dual-vortex structure observed under subsonic uniform inflow conditions. The asymmetric recirculation zone displays fluid being entrained from one vortex to another, with the degree and direction of entrainment dependent on the supersonic expansion state. Additionally, a simplified flow field structure is proposed for comparing the differences between the subsonic-supersonic mixing inflow and subsonic uniform inflow, along with the introduction of five regions and two stages to describe the flow field structure downstream of the flameholder under subsonic-supersonic mixing inflow. Analysis of the flow characteristics downstream of the flameholder under subsonic-supersonic mixing inflow and subsonic uniform inflow conditions can offer design insights for the combustion scheme of aerospace-integrated propulsion systems.