In construction, coniferous wood is usually used as load-bearing and enclosing structures. Wood is characterized by the ability to ignite and spread combustion when heated in air. Wooden building structures pose a fire hazard, since with an initial impulse of external thermal energy, ignition is possible. In addition, when a fire occurs in buildings and structures where wood is located, a number of dangerous fire factors arise: flames, sparks, heat flow, toxic combustion products, extremely low oxygen concentrations, decreased visibility due to smoke. In this regard, it becomes relevant to treat wood with special compounds that increase resistance to fire. The authors examined the fire hazardous properties of building structures made of wood, analyzed the fire retardant treatment of wooden structures with a special composition; examined the fire hazardous properties of building structures made of wood, the mechanism of pyrolysis, and the effect of fire retardant treatment on the behavior of wood when exposed to fire. The use of fire retardant significantly affected the pyrolysis processes of the samples. The information obtained during the study made it possible to assess the degree of differences in the values of the average weight loss of samples treated with different fire retardants. Samples using a fire retardant composition have a shallower charring depth. Damage associated with thermal exposure is fundamentally different from untreated samples. Treated and impregnated samples exhibit rapid weight loss. This is due to the fact that in treated and impregnated samples, when exposed to high temperatures in the oven, the reactions of dehydration and cross-linking of cellulose molecules are accelerated.