In this study, the mechanical properties of bamboo fibers were enhanced through alkali treatment (NaOH) and graphene oxide (GO) coating to improve their potential in composite applications. The objective was to investigate the structural, thermal, and mechanical enhancements of bamboo fibers and their composites. X-ray diffraction (XRD) revealed structural alterations in NaOH-treated fibers, while FTIR analysis confirmed the presence of hydroxyl and amino groups, indicating successful functionalization. Scanning Electron Microscopy (SEM) showed increased roughness and porosity of NaOH-treated fibers, improving wettability and fiber–matrix adhesion. Thermogravimetric analysis (TGA) demonstrated that GO coating enhanced the thermal stability of the fibers. The study found that the tensile strength of the bamboo fibers increased significantly from 215 ± 13 MPa in untreated fibers to 279 ± 17 MPa after NaOH treatment, reaching 346 ± 17 MPa when combined with GO. Bamboo fiber composites (BFC) exhibited optimal mechanical properties at 1% fiber content, with AGO-BFC showing the highest performance at 319.25 ± 2.82 MPa. However, higher fiber contents (1.5%) led to fiber agglomeration, which reduced strength, particularly in A-BFC. SEM of fracture surfaces confirmed these observations, emphasizing the importance of fiber treatment and content for improving bamboo fiber composite performance. The novelty of this work lies in the synergistic effect of NaOH treatment and GO coating, significantly enhancing the mechanical properties of bamboo fibers, thereby providing insights for their use in high-performance applications, such as structural components in automotive and aerospace industries.
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