AbstractFiber reinforced polymer (FRP) bars have received extensive promotion and application in the structural engineering. However, due to the limitations inherent in using single material, FRP reinforced concrete structures often encounter issues, such as brittle failure and inadequate energy dissipation, particularly in complex natural environments and under various loading conditions. In this study, the preparation of nano‐SiO2‐modified carbon/basalt hybrid FRP bars was carried out using the pultrusion‐winding process and ultrasonic treatment. The objective was to investigate the influence of the fiber volume ratio and mass fraction of nano‐SiO2 on the mechanical properties of FRP bars under drying and alkaline conditions. Molecular dynamics simulations were performed to construct interface models between fibers and epoxy resin in order to elucidate the toughening mechanism of nano‐SiO2 and the degradation mechanism in alkaline conditions. The research results show that elevating the substitution rate of carbon fibers and incorporating nano‐SiO2 doping bring about alterations in the brittle fracture characteristics of BFRP bars and enhance the post‐yield performance and interlaminar shear properties of hybrid FRP bars, concurrently mitigating the degradation of mechanical properties induced by exposure to alkaline solutions. MD simulations indicate that the addition of nano‐SiO2 improves the binding rate of hydrogen bonds between BF and epoxy resin, resulting in a higher interfacial energy between BF/epoxy resin compared to CF/epoxy resin. Moreover, nano‐SiO2 effectively mitigates the impact of alkaline solutions on the formation of interfacial hydrogen bonds. The findings of this study serve as a valuable reference for the design and application of FRP reinforced concrete structures.Highlights Nano‐SiO2 modified B/CFRP bars made via extrusion‐winding & ultrasonic treatment. Improved mechanical properties and plastic deformation in Nano‐SiO2 modified B/C FRP bars. Nano‐SiO2 inhibits B/CFRP bars degradation in alkaline solution. Nano‐SiO2 bind more at BF/epoxy than CF/epoxy interface. Nano‐SiO2 reduces alkaline solution effect on interfacial H‐bonding.
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