Ferromagnetic Spin Research Articles

Investigation of structural phase stability, modified magnetic spin order and low temperature spin glass-like phase transitions in Sc-doped M-type BaFe12O19 hexaferrite

This work used two approaches of mechanical alloying before high temperature solid state reaction to synthesize BaFe12-xScxO19 (x = 0.5 to 6.0) system. Rietveld refinement of X-ray diffraction patterns showed the formation of extra phases at higher Sc doping, along with the main magnetoplumbite structure. Raman spectroscopy suggested random distribution of Sc ions at the Fe-sites of hexaferrite structure. X-ray photoelectron spectroscopy (XPS) confirmed the +3 charge state at the Fe/Sc-sites. The Fe 3s band suggested dilution of ferromagnetic 3s-3d spin exchange interactions. The neutron diffraction study re-confirmed random occupancy of the non-magnetic Sc3+ ions at Fe3+ sites of the Sc doped Ba hexaferrite system. The transformation of magnetic spin order from collinear to non-collinear state has shown spin glass-like features at low temperature regime in the dc magnetization curves. This is an effect of dilution of Fe–O–Fe ferrimagnetic super exchange interactions and spin frustration in Sc-doped samples.

Riemann–Hilbert approach, dark solitons and double‐pole solutions for Lakshmanan–Porsezian–Daniel equation in an optical fiber, a ferromagnetic spin or a protein

AbstractInverse scattering transform for the defocusing Lakshmanan–Porsezian–Daniel equation with nonzero boundary condition is constructed via the Riemann–Hilbert approach. Since poles of the associated reflection coefficient are simple, ‐dark soliton solutions corresponding to simple poles are constructed. For ‐dark soliton solutions, results show that the soliton amplitude and width are not affected by the strength of the higher‐order linear and nonlinear effects , but soliton velocity has a linear correlation with ; the interactions between the two‐dark solitons and among the three‐dark solitons are elastic and experience phase and position shifts. Besides, asymptotic analysis of the double‐pole solutions for the focusing Lakshmanan–Porsezian–Daniel equation with nonzero boundary condition is presented. Different from ‐dark soliton solutions which locate in the straight lines and experience position shift after the interaction, the double‐pole solutions diverge from each other logarithmically and experience no position shift after the interaction.

Quantum annealing of a frustrated magnet

Quantum annealing, which involves quantum tunnelling among possible solutions, has state-of-the-art applications not only in quickly finding the lowest-energy configuration of a complex system, but also in quantum computing. Here we report a single-crystal study of the frustrated magnet α-CoV2O6, consisting of a triangular arrangement of ferromagnetic Ising spin chains without evident structural disorder. We observe quantum annealing phenomena resulting from time-reversal symmetry breaking in a tiny transverse field. Below ~ 1 K, the system exhibits no indication of approaching the lowest-energy state for at least 15 hours in zero transverse field, but quickly converges towards that configuration with a nearly temperature-independent relaxation time of ~ 10 seconds in a transverse field of ~ 3.5 mK. Our many-body simulations show qualitative agreement with the experimental results, and suggest that a tiny transverse field can profoundly enhance quantum spin fluctuations, triggering rapid quantum annealing process from topological metastable Kosterlitz-Thouless phases, at low temperatures.

Tuning structure, stability and magnetism in vanadium doped zinc sulfide for spintronic applications: Insights from first-principles and Monte Carlo approaches

This work utilizes a multi-scale computational approach combining first-principles density functional theory (DFT) and Monte Carlo statistical simulations to provide fundamental insights into the impacts of vanadium (V) doping on the structural, electronic, magnetic, and thermodynamic properties of wurtzite zinc sulfide (ZnS). 2 × 2 × 2 ZnS supercells with controlled V doping concentrations from 12.5%–25% substituting zinc sites were constructed. The introduction of V dopants induces systematic expansions in lattice parameters and cell volume, attributed to the larger ionic radius of V2+ than Zn2+, while the average compressibility shows minimal variation. However, V incorporation is found to soften ZnS by over 15% at higher dopant contents, increasing compliance and anisotropy. Stable ferromagnetic spin couplings emerge, mediated by host carriers without precipitating V secondary phases. The band structure develops half-metallic electronic properties with the lifting of spin degeneracy and preferential spin-up band metallicity induced by V-3d and S-3p hybridization effects. This results in 100% spin polarization at the Fermi level. Monte Carlo simulations based on a tight-binding Hamiltonian constructed from maximally localized Wannier functions to accurately calculate the exchange interactions between V spins successfully reproduce the magnetic phase transition behavior. The results confirm high Curie temperatures exceeding 300 K at 25% V, attributable to the significant strengthening of short-range ferromagnetic couplings over antiferromagnetic interactions. The integrated computational approach provides fundamental insights into the microscopic origin of carrier-mediated ferromagnetism in V-doped wurtzite ZnS dilute magnetic semiconductors. The systematic first-principles calculations and statistical mechanics modeling establish clear structure–property relationships linking V doping configurations and concentrations to tuned mechanical response, enhanced stability, electronic structure modifications, spin polarization, and magnetic ordering temperatures in ZnS. The results present design pathways and predictive capabilities to guide experimental efforts toward emerging high-performance magnetic materials for spintronic technologies.

Discontinuous phase transition from ferromagnetic to oscillating states in a nonequilibrium mean-field spin model.

We study a nonequilibrium ferromagnetic mean-field spin model exhibiting a phase with spontaneous temporal oscillations of the magnetization, on top of the usual paramagnetic and ferromagnetic phases. This behavior is obtained by introducing dynamic field variables coupled to the spins through nonreciprocal couplings. We determine a nonequilibrium generalization of the Landau free energy in terms of the large deviation function of the magnetization and of an appropriately defined smoothed stochastic time derivative of the magnetization. While the transition between paramagnetic and oscillating phase is continuous, the transition between ferromagnetic and oscillating phases is found to be discontinuous, with a coexistence of both phases, one being stable and the other one metastable. Depending on parameter values, the ferromagnetic points may either be inside or outside the limit cycle, leading to different transition scenarios. The stability of these steady states is determined from the large deviation function. We also show that in the coexistence region, the entropy production has a pronounced maximum as a function of system size.

Magnetization reversal phenomenon of higher-order lump and mixed interaction structures on periodic background in the (2+1)-dimensional Heisenberg ferromagnet spin equation

This paper mainly researches a useful model that can describe the rapid magnetization reversal process, namely the (2+1)-dimensional Heisenberg ferromagnet spin equation. Based on its Lax pair, we construct the iterative generalized (r,N−r)-fold Darboux transformation (DT), and obtain new position-controllable higher-order lump, periodic wave and rich mixed lump–breather interaction structures on periodic background. In particular, with the increase of N in the iterative generalized (r,N−r)-fold DT, we find that the structure of the lump and periodic wave can flip over with respect to the background. Moreover, we also find a bright lump structure with two peaks and two valleys, which does not flip with the increase of N. We study the magnetization trajectory and magnetization on the Bloch sphere, from which we discover that the magnetization is distributed in an incomplete unit sphere for the flipped case, while the magnetization is distributed in a complete unit sphere for the non-flipped case. These magnetization reversal phenomena are expected to have potential applications in understanding the rapid magnetization reversal process.

Single-hole spectra of Kitaev spin liquids: from dynamical Nagaoka ferromagnetism to spin-hole fractionalization

The dynamical response of a quantum spin liquid upon injecting a hole is a pertinent open question. In experiments, the hole spectral function, measured momentum-resolved in angle-resolved photoemission spectroscopy (ARPES) or locally in scanning tunneling microscopy (STM), can be used to identify spin liquid materials. In this study, we employ tensor network methods to simulate the time evolution of a single hole doped into the Kitaev spin-liquid ground state. Focusing on the gapped spin liquid phase, we reveal two fundamentally different scenarios. For ferromagnetic spin couplings, the spin liquid is highly susceptible to hole doping: a Nagaoka ferromagnet forms dynamically around the doped hole, even at weak coupling. By contrast, in the case of antiferromagnetic spin couplings, the hole spectrum demonstrates an intricate interplay between charge, spin, and flux degrees of freedom, best described by a parton mean-field ansatz of fractionalized holons and spinons. Moreover, we find a good agreement of our numerical results to the analytically solvable case of slow holes. Our results demonstrate that dynamical hole spectral functions provide rich information on the structure of fractionalized quantum spin liquids.

Spin dynamic soliton in ferromagnetic materials over the (2 + 1)-dimensional beta fractional HFSC model

Ferromagnetic materials have important exploitation practice in permanent information in electromagnets, electric motors, generators, recording in thin film etc. This research explores spin dynamic soliton in Ferromagnetic materials via the (2 + 1)-D Heisenberg ferro-magnetic Spin Chains (HFSC) model. The Extended (I,R) and Extended Simple schemes treatment are applied to integrate the model. Through the technique, various novel dynamical wave solutions afford as optical dark and bright soliton envelope, spin wave envelope Black soliton, optical bell-shock interaction, optical bell-anti-shock wave, optical Dark-bright bell soliton and optical bright periodic waves from modulus plots, besides these real and imaginary profiles exhibits bright periodic wave with dark bell wave, periodically increasing–decreasing carrier wave, periodic carrier wave increase its amplitude by shock, periodic carrier wave suddenly decrease its amplitude by shock waves. The effect of fractional derivative, neighboring interaction as well as uniaxial crystal field anisotropy parameters is explored on the envelope soliton and amplitude of carrier waves. The changing value of neighboring interaction parameters are exhibited as increases wave height with the increases of parametric values, but while increasing values of the uni-axial crystal arena anisotropy factor causes the reduction of wave heights.

Influence of interlayer exchange coupling on ultrafast laser-induced magnetization reversal in ferromagnetic spin valves

Influence of interlayer exchange coupling on ultrafast laser-induced magnetization reversal in ferromagnetic spin valves

Metal vs Ligand Oxidation: Coexistence of Both Metal-Centered and Ligand-Centered Oxidized Species.

A series of two-electron-oxidized cobalt porphyrin dimers have been synthesized upon controlled oxidations using halogens. Rather unexpectedly, X-ray structures of two of these complexes contain two structurally different low-spin molecules in the same asymmetric unit of their unit cells: one is the metal-centered oxidized diamagnetic entity of the type CoIII(por), while the other one is the ligand-centered oxidized paramagnetic entity of the type CoII(por•+). Spectroscopic, magnetic, and DFT investigations confirmed the coexistence of the two very different electronic structures both in the solid and solution phases and also revealed a ferromagnetic spin coupling between Co(II) and porphyrin π-cation radicals and a weak antiferromagnetic coupling between the π-cation radicals of two macrocycles via the bridge in the paramagnetic complex.

The magneto thermoelectric coefficients of double quantum dots in series connected to ferromagnetic electrodes

In this paper, the charge and spin magneto coefficients of a double quantum dots system coupled in series connected to ferromagnetic electrodes with collinear magnetic alignments at finite bias voltage are theoretically investigated based on Green’s functions in a linear response regime. Magneto and spin magneto thermopower are estimated as a function of the thermal gradient and quantum dot energy levels. Magneto conductance and spin magneto conductance are also studied. The results showed that the positions of the peaks can be controlled for each value of polarization, and the magneto conductance is negative where the charge conductance for parallel alignment is lesser than that for antiparallel alignment except in the case of high spin polarization and ferromagnetic spin exchange. Enhancing the magneto thermoelectric coefficients of double quantum dots is a promising step in creating adaptable magnetic switching for thermoelectric generations, which could find use in thermal energy-based logic circuits or heat control applications.

Thermal transitions in a one-dimensional, finite-size Ising model

We revisit the one-dimensional ferromagnetic Ising spin chain with a finite number of spins and periodic boundaries, deriving analytically and verifying numerically its various stationary and dynamical properties at different temperatures. In particular, we determine the probability distributions of magnetization, the number of domain walls, and the corresponding residence times for different chain lengths and magnetic fields. While we study finite systems at thermal equilibrium, we identify several temperatures similar to the critical temperatures for first-order phase transitions in the thermodynamic limit. We illustrate the utility of our results by their application to structural transitions in biopolymers having non-trivial intermediate equilibrium states.

Discovery and Characterization of Antiferromagnetic UFe5As3.

This work presents a study on a new uranium iron arsenide UFe5As3. By implementing Bi-flux synthesis, we were able to grow mm-sized single crystals of this compound, which show twinning. UFe5As3 is one of only two known uranium iron arsenides. It adopts a monoclinic, UCr5P3-type crystal structure (space group P21/m, Pearson symbol mP18, a = 7.050(2) Å, b = 3.8582(9) Å, c = 9.634(1) Å, β = 100.25(1)°). The magnetic susceptibility of UFe5As3 indicates it to be an antiferromagnet with TN = 47 K and μeff = 4.94 μB per formula unit, signaling that both U and Fe are likely magnetic in this material. The material appears to be anisotropic, with a small (likely ferromagnetic) spin reorientation transition around T = 29 K. The Sommerfeld coefficient γ0 = 135 mJ mol-1 K-2 suggests enhanced effective electron mass in UFe5As3, while electrical resistivity indicates metallic, Kondo-like behavior.

Real-space spectral simulation of quantum spin models: Application to generalized Kitaev models

The proliferation of quantum fluctuations and long-range entanglement presents an outstanding challenge for the numerical simulation of interacting spin systems with exotic ground states. Here, we present a toolset of Chebyshev polynomial-based iterative methods that provides a unified framework to study the thermodynamical properties, critical behavior and dynamics of frustrated quantum spin models with controlled accuracy. Similar to previous applications of the Chebyshev spectral methods to condensed matter systems, the algorithmic complexity scales linearly with the Hilbert space dimension and the Chebyshev truncation order. Using this approach, we study two paradigmatic quantum spin models on the honeycomb lattice: the Kitaev-Heisenberg (K-H) and the Kitaev-Ising (K-I) models. We start by applying the Chebyshev toolset to compute nearest-neighbor spin correlations, specific heat and entropy of the K-H model on a 24-spin cluster. Our results are benchmarked against exact diagonalization and a popular iterative method based on thermal pure quantum states. The transitions between a variety of magnetic phases, namely ferromagnetic, Néel, zigzag and stripy antiferromagnetic and quantum spin liquid phases are obtained accurately and efficiently. We also determine the temperature dependence of the spin correlations, over more than three decades in temperature, by means of a finite temperature Chebyshev polynomial method introduced here. Finally, we report novel dynamical signatures of the quantum phase transitions in the K-I model. Our findings suggest that the efficiency, versatility and low-temperature stability of the Chebyshev framework developed here could pave the way for previously unattainable studies of quantum spin models in two dimensions.

Effectiveness of the recursive-lattice technique in the investigation of magnetic systems with the pyrochlore structure.

A well-defined higher recursive approximation of the pyrochlore lattice is introduced and its relevance and effectiveness for the systematic investigation of magnetic systems with the pyrochlore structure is studied within the classical antiferromagnetic as well as ferromagnetic spin-1/2 Ising model in the presence of the external magnetic field. The exact solution of the model is found with the explicit analytic expression for the free energy per site of the lattice. The magnetization and entropy properties of all ground states of the antiferromagnetic model are determined and compared to those obtained within the lower recursive approximation of the model on the recursive tetrahedral lattice. The exact analysis of the residual entropies of the model on the introduced recursive lattice explicitly shows that the well-known Pauling entropy of the water ice cannot represent the true residual entropy of the antiferromagnetic model on the regular pyrochlore lattice in the zero external magnetic field. The improvement of the value of the critical temperature of the ferromagnetic model obtained within the introduced higher recursive approximation is also discussed. The analysis performed demonstrates the great efficiency of recursive approximations in the investigation of various magnetic systems with the pyrochlore structure, especially for frustrated antiferromagnetic systems.

Analytical approaches to the (2+1)-dimensional Heisenberg Ferromagnetic Spin Chain equation and their applications for optical devices

Analytical approaches to the (2+1)-dimensional Heisenberg Ferromagnetic Spin Chain equation and their applications for optical devices

Properties and applications of two-dimensional quantum materials beyond carbon

Two-dimensional quantum materials are currently a hot research area in the field of materials. These unique materials allow electrons to move freely in only two dimensions and the other dimension is limited within the atom scale. The isolation of Graphene in 2004 showed the advantages of two-dimensional (2D) materials and led a rapid development in this field. Meanwhile, it stimulates the synthesis and research of the materials beyond carbon. 2D materials beyond carbon have different components and structures, showing a broader range of remarkable properties and applications than traditional graphene. This article will pay attention to the phenomenon and mechanism of these exceptional properties, including superconductivity, ferromagnetism, antiferromagnetism, and quantum spin liquid phase. Additionally, potential applications and future prospects of 2D materials beyond carbon will be explored. With the progress of technology, 2D materials beyond carbon are expected to have exciting developments in various fields, leading to significant changes in human life and production

Exploring Spin Distribution and Electronic Properties in FeN4-Graphene Catalysts with Edge Terminations.

Understanding the spin distribution in FeN4-doped graphene nanoribbons with zigzag and armchair terminations is crucial for tuning the electronic properties of graphene-supported non-platinum catalysts. Since the spin-polarized carbon and iron electronic states may act together to change the electronic properties of the doped graphene, we provide in this work a systematic evaluation using a periodic density-functional theory-based method of the variation of spin-moment distribution and electronic properties with the position and orientation of the FeN4 defects, and the edge terminations of the graphene nanoribbons. Antiferromagnetic and ferromagnetic spin ordering of the zigzag edges were considered. We reveal that the electronic structures in both zigzag and armchair geometries are very sensitive to the location of FeN4 defects, changing from semi-conducting (in-plane defect location) to half-metallic (at-edge defect location). The introduction of FeN4 defects at edge positions cancels the known dependence of the magnetic and electronic proper-ties of undoped graphene nanoribbons on their edge geometries. The implications of the reported results for catalysis are also discussed in view of the presented electronic and magnetic properties.

Exact solutions, symmetry groups and conservation laws for some (2+1)-dimensional nonlinear physical models

In this paper, the Bernoulli sub-equation function method is used to construct new exact travelling wave solutions for two important physical models: (2+1)-dimensional hyperbolic nonlinear Schrödinger (HNLS) equation and (2+1)-dimensional Heisenberg ferromagnetic spin chain (HFSC) equation. These solutions provide valuable insights into the behavior of these models, described in terms of exponential and hyperbolic tangent (tanh) functions. The study also involves an exploration of the infinitesimal generators and symmetry groups through the Lie symmetry method. In addition, by using multiplier approach, the conservation laws are established for these models. Graphical simulation of some solutions in the form of two-dimensional and three-dimensional are plotted to understanding of the underlying physical phenomena and mathematical properties of the (2+1)-dimensional HNLS and HFSC equations. The solutions and graphing are performed using Maple software.

Structural and Electrochemical Properties of F-Doped RbTiOPO4 (RTP:F) Predicted from First Principles

Batteries based on heavier alkali ions are considered promising candidates to substitute for current Li-based technologies. In this theoretical study, we characterize the structural properties of a novel material, i.e., F-doped RbTiOPO4 (RbTiPO4F, RTP:F), and discuss aspects of its electrochemical performance in Rb-ion batteries (RIBs) using density functional theory (DFT). According to our calculations, RTP:F is expected to retain the so-called KTiOPO4 (KTP)-type structure, with lattice parameters of 13.236 Å, 6.616 Å, and 10.945 Å. Due to the doping with F, the crystal features eight extra electrons per unit cell, whereby each of these electrons is trapped by one of the surrounding Ti atoms in the cell. Notably, the ground state of the system corresponds to a ferromagnetic spin configuration (i.e., S=4). The deintercalation of Rb leads to the oxidation of the Ti atoms in the cell (i.e., from Ti3+ to Ti4+) and to reduced magnetic moments. The material promises interesting electrochemical properties for the cathode: rather high average voltages above 2.8 V and modest volume shrinkages below 13% even in the fully deintercalated case are predicted.