Fading Rate Research Articles

A TOC- and deposition-free electrochromic window driven by redox flow battery

Under “green architecture” principles, electrochromic smart windows are employed to adjust optical transmittance and indoor temperature, yet their high costs limit the wide application. Here, an electrochromic window is driven by a redox flow battery (RFB), where TOC and deposition layers are no longer needed. The transmittance of the electrochromic window is modulated by the state of oxidation (SOC) of aqueous posolyte Fe(phen)3Cl2, which is coupled with BTMAP-Vi negolyte in RFB. Under optimized conditions, average CE, VE, and EE reach 93.25 %, 92.61 %, and 86.35 % for RFB with a capacity fading rate of 1.57 % per cycle. 88.66 % optical modulation and 9.36 cm2/C coloration efficiency are achieved in the electrochromic process, and 72.34 % optical modulation is maintained after 12000 s. Essentially, the indoor temperature declines 3 °C for posolyte with 100 % SOC when compared with the control experiment using circulating water for a model house. This means minimum electricity of 0.0185 kWh is saved when using an air conditioner to cool a 100 m3 house, which corresponds to declined CO2 emission (COE) of 0.0185 kg. This work provides a novel and cost-efficient strategy for modulating indoor comfort via electrochromic windows driven by RFB.

Aqueous colloid flow batteries with nano Prussian blue

Flow battery is a safe and scalable energy storage technology in effectively utilizing clean power and mitigating carbon emissions from fossil fuel consumption. In the present work, we demonstrate an aqueous colloid flow battery (ACFB) with well-dispersed colloids based on nano-sized Prussian blue (PB) cubes, aiming at expanding the chosen area of various nano redox materials and lowering the cost of chemicals. Taking advantage of the two redox pairs of PB, the developed all-PB cell employing a low-cost dialysis membrane with the synthesized PB on both sides displays an open-circuit voltage (OCV) of 0.74 V. Moreover, when paired with an organic tetra pyridine macrocycle the cell with PB as positive electrolyte exhibits an OCV of 1.33 V and a capacity fade rate of 0.039 %/cycle (0.8 %/day). Redox-active colloids exhibit enduring physicochemical stability, with no evident structural or morphological changes after extensive cycling, highlighting their potential for cost-effective and reliable ACFB energy storage.

Importance of Controlling Cycling Conditions to Improve the Lifetime of Anthraquinone-Based Negolytes with a Potentially Low Cost of Manufacture

Organic redox flow batteries (RFB) in general and anthraquinones in specific have shown a great promise for developing cost-effective alternatives to vanadium RFBs. Two main hurdles, however, have been the fast fade rate and a high estimated cost of manufacture (COM) that have slowed down the scale up of organic RFBs. In this study, 1,8-dihydroxy-2,7-dicarboxymethyl-9,10-anthraquinone (1,8-DCDHAQ), 1,5-dihydroxy-2,6-dicarboxymethyl-9,10-anthraquinone (1,5-DCDHAQ) and 1,3,5,7-tetrahydroxyanthraquinone (THAQ) have been explored. These negolytes are expected to have a reasonably low COM due to their simple synthesis route. Additionally, these electroactive species have a low fade rate. Nevertheless, the fade rates are not adequately low for scaleup and commercialization purposes. Therefore, the effect of various factors including the electrolyte flow rate, cutoff voltages, SOC limits, and OH- concentration on the cycling performance have been explored in order to further reduce the fade rate.Our experimental analysis suggests that: (1) the electrolyte flow rate and the extent of mixing in the electrolyte reservoir may lead to inaccurate capacity utilizations and fade rates, (2) increasing the OH- concentration significantly lowers the fade rate and the effect continues even at concentrations higher than 1.0 M, (3) choosing an unnecessarily low discharge cutoff voltage has a detrimental effect on the fade rate of anthraquinones, (4) SOC limit is a very important tool that significantly lowers the fade rate. Through controlling these cycling conditions, the lifetime can be improved by at least a factor of 10. Under properly chosen conditions, the fade rate of 1,5-DCDHAQ and THAQ remains < 0.001%/day (< 0.4%/year). To further verify the effect of the operating conditions, cyclic voltammetry and HPLC techniques were used to identify and/or characterize the side products in the electrolyte. COM of 1,5-DCDHAQ and THAQ at scale are estimated to be 27.99 and 47.44 $/kAh (or 24.13 and 37.95 $/kWh), respectively. 1,8-DCDHAQ and 1,5-DCDHAQ are expected to have a similar COM.Due to the expected low COM for the abovementioned anthraquinones and their very low fade rate under optimum cycling conditions explored in this study, these molecules now present a distinctive prospect for developing and commercializing an affordable and long lifetime organic RFB chemistry.

(Invited) Low Cost in Situ Electrosynthesis and Cycling of Quinone Negolytes in a Commercial Flow Battery Stack

Aqueous organic redox flow batteries (RFBs) potentially offer greatly lower capital cost relative to vanadium RFBs or even lithium-ion batteries, as they use no critical materials and are instead derived from very inexpensive precursors. To date, the success of organic RFBs as a whole has been hampered by two factors. The first is the high cost of scaling up a new chemistry, as every synthetic step adds cost and complexity and creates waste that must be disposed of. The second is fast degradation of the reactants and has been largely mitigated through various strategies that have recently been reported. The recent results mean that low-cost compounds that may intrinsically have a fast degradation rate, now merit consideration since their fade rate can be lowered significantly.We report the development of an in situ electrosynthesis process, from the lab scale to the ton scale, that creates the organic RFB negolyte from the starting reactants using commercial RFB stacks that have been repurposed as chemical reactors. The yield and purity are even higher than the equivalent chemical process and no further purification or downstream processing is required; the entire process is self-contained and produces zero waste which greatly simplifies scaleup, permitting, and implementation. Moreover, the as-produced material can be immediately cycled as a drop-in replacement for vanadium in RFBs with minimal modification of existing vanadium RFB designs.This unique in situ strategy enables rapid scaling of a new chemistry in a way that supports local manufacture, which is of strategic importance to many governments. Further cost reductions are envisioned if it can be implemented at the customer site -- inside a completed flow battery system -- rather than at a centralized facility.When combined with previous results on reversing the degradation of quinone RFB reactants, the electrosynthetic pathway to producing organic RFB negolytes is the final missing piece of the puzzle in the commercialization of an affordable, practical, and viable organic RFB chemistry.

Suppressing Shuttle Effect in Lithium-Sulfur Batteries Using Perovksite Lead Zirconate Titanante Nanofibers

Rapid capacity fade and untimely failure caused by the infamous “shuttle effect” prevents the commercialization of Lithium-sulfur batteries (LSB). In this work, Lead Zirconate Titanate (PZT) nanofibers have been employed as polysulfide immobilizer in LSB. Ferroelectric materials possess a unique domain structure where each individual domain carries a dipole moment. The dipole-dipole interaction between the domains of the ferroelectric PZT nanofibers and polysulfides inhibits the diffusion of polysulfides from the cathode. In addition to electrostatic interactions, the 1-dimensional nanofibers with large specific surface area are accompanied by lithiophilic and sulfiphilic heteroatoms which act as anchoring points for chemically binding the polysulfides. Moreover, the enhanced wettability of the electrode arising from the favorable affinity of PZT nanofibers towards the electrolyte along with lithiophilic heteroatoms aids the diffusion of Lithium-ions. This enhanced wettability and the presence of lithiophilic surface promotes the diffusion of lithium ions which boosts the reaction kinetics. Briefly, the synergy of physical and chemical interaction of PZT nanofibers towards the polysulfide species is found to mitigate the shuttle effect and improve electrochemical performance of LSB. Further, a promising long-term cycling over 200 cycles for LSB cell with PZT interlayer is observed with 98 % Coulombic efficiency and slow fade rate of 0.08 % per cycle. Moreover, cells with higher sulfur loading and lower electrolyte to sulfur ratio reveal superior electrochemical performance with 80.8 % capacity retention over 100 cycles. Figure 1

High-Performance Lithium-Sulfur Batteries with Atomic V- and Co-Modified Ketjen Black-Sulfur Composite Cathode

Lithium-sulfur (Li-S) batteries are potential alternatives to lithium-ion batteries, which are known to have certain drawbacks. This has drawn special technological attention. Sulfur’s low electrical conductivity, shuttling of the intermediate polysulfides, the slow conversion reaction kinetics of various lithium polysulfides (LiPS), and the major volume change of sulfur in the lithiation reaction are some of the main issues that still need to be resolved before Li-S batteries can be used in practical applications. Additionally, it is likely because there are not enough prognostic models determining energy densities at the cell and pack level based on materials and cell design, most of the articles do not report system-level metrics, specific energy (Wh kg-1), and energy density (Wh L-1).To overcome these problems, atomic vanadium (V) and cobalt (Co) modified ketjen black-sulfur composite (VCKBS) was prepared and used as a cathode in Li-S batteries. The synthesized composite was characterized by various techniques, e.g., XRD, Raman, SEM, HR-TEM, HAADF-STEM, and XPS spectra. The polysulfide adsorption test showed that V had increased the adsorption ability, and cyclic voltammetry displayed the increased catalytic activity resulting from Co, offering a large number of interfacial active sites and ensuring smooth electron transfer. Cycling performance tests showed an initial specific capacity of 1329 mAh g−1, maintained at 1249 mAh g−1 after 100 cycles. Under a higher sulfur loading (2.4 mg cm−2), at 0.2 C, Li-S cells demonstrated an initial specific capacity of 1201 mAh g−1 and retained 985 mAh g−1 after 300 cycles with a low fading rate of 0.059% per cycle. The rate performance tests showed that the prior capacity is nearly recovered, going from 1C back to 0.1C, demonstrating the superiority of the VCKBS material.In addition to the experimental characterization of the Li-S cell performance, energy densities were also predicted by a proposed system-level performance model. The 1st and 100th discharge capacities were used to forecast the system-level specific energies and energy densities. The system-level specific energies and energy densities based on the 100th discharge capacity of VCKBS cathodes had improvements of 1342 and 568%, respectively. This suggests that an easy route to construct the highly stable cathode material may pave the way for the development of highly efficient Li-S batteries. Acknowledgments Hira Fazal acknowledges support from the Türkiye Scholarship/Research Fellowship Program sponsored by the Prime Ministry of Turkey Presidency for Turks Abroad and Related Communities (21PK070917). Damla Eroglu acknowledges support from the Istanbul Development Agency (Award No: TR10/21/YEP/0001). We also thank the National Natural Science Foundation of China (22171180) and the Science and Technology Commission of Shanghai Municipality (20520710400).

(Invited) Recent Progress in Organic-Based Aqueous Flow Batteries

We have developed high performance flow batteries based on the aqueous redox behavior of small organic and metalorganic monomers composed of earth-abundant elements. These redox active materials can be inexpensive and exhibit rapid redox kinetics and high solubilities, potentially enabling rapid scaling of flow batteries at reduced cost. Adequate molecular lifetime has been one of the most challenging requirements to satisfy. We have shown that the amount of lost capacity is determined by the molecular calendar life, which can depend on state of charge, but is independent of the number of charge-discharge cycles imposed. I will discuss recent progress in molecule development and in measuring extremely small capacity fade rates and will discuss how an understanding of molecular decomposition mechanisms has permitted us to design molecules with decadal projected lifetimes and even to reverse capacity fade by recomposing decomposed molecules within the functioning battery electrolyte.

Electrochemically Active MoO3/TiN Sulfur Host Inducing Dynamically Reinforced Built-in Electric Field for Advanced Lithium-Sulfur Batteries.

Although various electrocatalysts have been developed to ameliorate the shuttle effect and sluggish Li-S conversion kinetics, their electrochemical inertness limits the sufficient performance improvement of lithium-sulfur batteries (LSBs). In this work, an electrochemically active MoO3/TiN-based heterostructure (MOTN) is designed as an efficient sulfur host that can improve the overall electrochemical properties of LSBs via prominent lithiation behaviors. By accommodating Li ions into MoO3 nanoplates, the MOTN host can contribute its own capacity. Furthermore, the Li intercalation process dynamically affects the electronic interaction between MoO3 and TiN and thus significantly reinforces the built-in electric field, which further improves the comprehensive electrocatalytic abilities of the MOTN host. Because of these merits, the MOTN host-based sulfur cathode delivers an exceptional specific capacity of 2520mA h g-1 at 0.1 C. Furthermore, the cathode exhibits superior rate capability (564mA h g-1 at 5 C), excellent cycling stability (capacity fade rate of 0.034% per cycle for 1200 cycles at 2 C), and satisfactory areal capacity (6.6mA h cm-2) under a high sulfur loading of 8.3mg cm-2. This study provides a novel strategy to develop electrochemically active heterostructured electrocatalysts and rationally manipulate the built-in electric field for achieving high-performance LSBs.

One-Pot Hydrothermal-Derived rGO/MXene/Sulfur Composite Aerogels as Free-Standing Cathodes in Lithium-Sulfur Batteries.

The confinement and high utilization of sulfur in the cathodes is critical for improved cycling performance of lithium-sulfur batteries. In this case one-pot hydrothermal strategy is developed to produce rGO/MXene/sulfur composite aerogels where sulfur is in situ trapped in the 3D rGO/MXene conductive skeleton. The optimized composite aerogels as free-standing cathodes delivery a specific capacity of 951 mAhg-1 after 100 cycles at 0.2 C with a low fading rate of 0.062 % per cycle. The excellent cycling performance is correlated with highly oxidized MXene and in situ formed sulfate/thiosulfate complex layer in the long-term cycles.

Engineering d-p Orbital Hybridization with P, S Co-Coordination Asymmetric Configuration of Single Atoms Toward High-Rate and Long-Cycling Lithium-Sulfur Battery.

Single-atom catalysts (SACs) have been increasingly explored in lithium-sulfur (Li-S) batteries to address the issues of severe polysulfide shuttle effects and sluggish redox kinetics. However, the structure-activity relationship between single-atom coordination structures and the performance of Li-Sbatteries remain unclear. In this study, a P, S co-coordination asymmetric configuration of single atoms is designed to enhance the catalytic activity of Co central atoms and promote d-p orbital hybridization between Co and S atoms, thereby limiting polysulfides and accelerating the bidirectional redox process of sulfur. The well-designed SACs enable Li-S batteries to demonstrate an ultralow capacity fading rate of 0.027% per cycle after 2000 cycles at a high rate of 5 C. Furthermore, they display excellent rate performance with a capacity of 619 mAh g-1 at an ultrahigh rate of 10 C due to the efficient catalysis of CoSA-N3PS. Importantly, the assembled pouch cell still retains a high discharge capacity of 660 mAh g-1 after 100 cycles at 0.2 C and provides a high areal capacity of 4.4 mAh cm-2 even with a high sulfur loading of 6mg cm-2. This work demonstrates that regulating the coordination environment of SACs is of great significance for achieving state-of-the-art Li-S batteries.

A New High-Performance Porous Carbon-Coated Mn3O4/Na2CO3 Cathode for Suppressing Mn2+Dissolution in Aqueous Zinc Ion Batteries.

Manganous-manganic oxide (Mn3O4), akin to other manganese-based oxides, faces several critical challenges such as substantial capacity fading and limited rate performance due to its inferior electrical conductivity, in addition to the inevitable dissociation of Mn2+. To address these issues, we introduce for the first time a novel carbon-coated Mn3O4/Na2CO3 (Mn3O4/Na2CO3/C) composite material. Comprehensive characterizations indicate that Na2CO3 effectively curtails Mn2+dissolution, enhances carbon encapsulation throughout charging/discharging cycles, and exposes additional active sites on the Mn3O4/Na2CO3/C composite. Electrochemical assessments confirm that the Mn3O4/Na2CO3/C-2 cathode exhibits exceptional electrochemical performance, outperforming other cathodes in the ZnSO4 system. Moreover, the Mn3O4/Na2CO3/C-2 cathode delivers a high specific capacity of ~550 mAh gM-1 at 0.1 A g-1 and maintains a significant capacity of ~230 mAh g-1 after 360 cycles at 1.0 A g-1 within the 2.0 M ZnSO4+0.2 M MnSO4 electrolyte system, demonstrating its potential as a high-performance cathode material for aqueous zinc-ion batteries.

Coordination and light modulated dynamic optical switches of terpyridine-derived spiropyran for time-resolved information encryption

The development of the light-controlled assembly of smart materials for advanced information encryption with time-dependent optical characteristics is essential to meet the increasing demand on fabricating multiple optical materials for encryption security. In this work, the integration of terpyridine-derived photochromic spiropyran (Tpy-SP) as Zn2+ ion chelating agent and photo-regulator building blocks endows the materials with dynamic assembly-induced optical functionality. Under UV light irradiation, the Tpy-Zn2+-SP will be transformed into Tpy-Zn2+-MC, which forms coordinated architecture with distinct optical properties from that of Tpy-MC form. Modulated by the coordination, Tpy-Zn2+-MC and Tpy-MC show obviously different fading rate with the achievement of time-resolved multicolor optical switches. The temporal multioptical features promote the light-controlled switches as a promising candidate for time-dependent confidential materials, including dynamic optical patterns and multilevel encryption, and the relative encrypted data that could only be identified at a specified time.

Ultra-Stable Sodium-Ion Battery Enabled by All-Solid-State Ferroelectric-Engineered Composite Electrolytes

HighlightsThe capacity fading mechanism of the conventional Na3V2(PO4)3//Na3V2(PO4)3 (NVP//NVP) cell has been investigated.All-solid-state ferroelectric-engineered composite electrolyte could improve the electrolyte–electrode interfacial stability as well as the interfacial ion conduction of the Na-ion battery using the NVP anode.Outstanding cyclic stability has been achieved in the all-solid-state Na-ion battery using the NVP anode, with a capacity fading rate as low as 0.005% per cycle.

Tellurium doped sulfurized polyacrylonitrile nanoflower for high-energy-density, long-lifespan sodium-sulfur batteries

Sodium-sulfur (Na−S) batteries are promising energy storage devices for large-scale applications due to their high-energy-density and abundant material reserve. However, the practical implementation of room temperature (RT) Na−S batteries faces challenges, including low-energy-density and limited lifespan, particularly attributed to the properties of sulfurized polyacrylonitrile (SPAN). In this study, we address these challenges by introducing tellurium doping into SPAN nanoflowers, enhancing their performance for Na−S batteries. The resulting material exhibits high sulfur loading as well as superior electron and ion transport properties, leading to enhanced redox kinetics and improved battery performance. The tellurium-doped SPAN nanoflower electrode delivers an exceptional composite capacity of 700 mAh g−1 at 0.1 C and demonstrates stable cycling over 2400 cycles with minimal capacity fade (0.01 % average fading rate). Even under challenging conditions (24.0 mg cm−2, E/S=5 mg μLS−1, N/P=2.1), the Na−S battery achieves a high areal capacity of 16.1 mAh cm−2, resulting in an impressive energy density of 340.9 Wh kg–1 based on cathode and anode. This work presents a promising approach to designing high-energy-density, long-lifespan RT Na−S batteries, with potential applications for other metal-sulfur battery systems.

How old are the Mojave topographic dunes? The implications of new luminescence dating analyses from the Cady Mountains, Mojave Desert, southwest USA

The aeolian landforms of the Mojave Desert in the SW USA have been studied in detail over the last three decades, particularly in terms of their relationship to the region's topography and Pleistocene climate / sediment supply histories, as well as wider developments, such as the aeolian “sediment state” concept. In this context, the evolution of the Mojave River and its associated palaeolakes is thought to have been a key control on long-term sediment supply to aeolian systems, and luminescence dating chronologies for a range of (resulting) aeolian landforms have been related to these hydrological changes. Here we argue that at least some of these aeolian chronologies need to be re-assessed.We focus on luminescence chronologies for aeolian landforms within and marginal to the Cady Mountains, a mountain block adjacent to the Mojave River and palaeolake Manix, east of Barstow, California. We demonstrate that quartz in this locale exhibits several malign luminescence properties, and that low temperature K-feldspar infrared stimulated luminescence (IRSL) consistently exhibits high anomalous fading rates. Both contribute to age underestimation. We address these issues via post-infrared IRSL (pIRIR) and post-isothermal post-IR (pIt-IR) analyses of K-feldspars. The resulting ages span the last ~120 ka and imply phases of aeolian activity of a substantially greater antiquity than previously inferred. Notably, at one well-studied site – the Soldier Mountain sand ramp – the new ages suggest a landform dating not to Marine Isotope Stage (MIS) 1 or 2, as previously suggested, but more likely to MIS 5. The Cady Mountain record indicates that the only period of the last glacial cycle lacking evidence for aeolian sedimentation is ~40–9 ka, broadly consistent with expectations of increased regional humidity. These results also suggest that site topographic context may influence the age structure of aeolian deposits. In this instance, sand ramps consistently represent the oldest type of deposit (range ~ 40–120 ka), while early-mid Holocene dune accumulation is associated with sandsheets and valley-fill sands. Based on these findings, we argue that there is a need to critically re-assess the existing regional luminescence age database, and that there is potential to significantly revise our understanding of the region's aeolian system responses, and associated paleoenvironmental interpretations.

Deciphering the eg occupancy descriptor on perovskite oxides for lithium-sulfur batteries

The partially filled d orbital of transition metal-based catalysts demonstrate excellent catalytic activity against polysulfides. However, an appropriate descriptor to reveal their structure-activity relationship is lacked. This study proposes a quantitative relationship between the eg occupancy of perovskite oxides and polysulfide catalytic activity, serving as an activity descriptor. LaCoO3, with a moderate eg occupation (t2g5eg1.08), demonstrates effective polysulfide anchoring and facilitated redox kinetics conversion compared to LaCrO3 (t2g3eg0) and LaFeO3 (t2g3eg2), showcasing exceptional catalytic performance. The degree of eg occupancy significantly influences the polysulfides adsorption strength, with empty or fully filled eg orbitals resulting in either strong or weak adsorption, respectively. LaCoO3-based batteries exhibit remarkable reversible capacity over 700 cycles at 1.0C, with a minimal capacity fading rate of 0.065 % per cycle. This work elucidates the crucial role of eg descriptor for evaluating the adsorption and conversion on polysulfides, offering insights into the development of innovative lithium-sulfur electrocatalysts.

Fading suppression and noise reduction of a DAS system integrated multi-core fiber.

Multi-core fiber (MCF) has attracted increasing attention for application in distributed fiber sensing owing to its unique properties of independent light transmission in multiple spatial channels. Here, we report a distributed acoustic sensing (DAS) system integrated MCF to suppress coherent fading, which overcomes an inevitable challenge in DAS systems. Because the parallel spatial cores in MCF allow the use of space-division multiplexed (SDM) technology, we propose that fading can be effectively suppressed by merging different signals with the spatial rotated-vector-average (SRVA) method. We theoretically analyze the principle of SRVA in fading suppression, and identify that it can effectively reduce phase noise with preventing phase unwrapping failures. In our experiment, a DAS system with 2.58-km length MCF have been investigated, the fading rate of Rayleigh backscattered signals is effectively reduced by three orders of magnitude and the amplitude fluctuation range is decreased by 21.9 dB. Compared with the conventional spectrum extraction and remix method (SERM), SRVA reduces the noise level by 9.5 dB, which also shows excellent low-frequency signal recovery ability. Benefiting from its fading suppression, the false alarm of localization is mitigated and the phase recovery can be distortionless. The proposed and verified method is helpful for the application of SDM-based MCF in long-distance distributed fiber sensors and accelerates the progress of integrated sensing and communication.

Efficient in Situ One-Pot Synthesis of Water-Soluble Hydroxynaphthoquinones for Redox Flow Batteries.

Given the importance of energy storage and its hybridization with renewable technologies for the energy transition, the development of redox flow batteries (RFB) is receiving particular attention. Among the various emerging technologies, aqueous organic redox flow batteries (AORFBs) are of particular interest, as the objectives in terms of durability, cost, and safety can be achieved thanks to the possibilities offered by molecular engineering. While anthraquinones have been widely explored as negolytes, few works report the use of naphthoquinones. This work aims to exploit an innovative in situ and cost-effective method for the one-pot synthesis of water-soluble naphthoquinones for application as a negolyte in redox flow batteries. As exemplified with alizarin, the energy of the naphthoquinone synthetic reaction in fuel cell mode can be recovered and the electrolyte solution used directly in redox flow batteries without purification. A 0.3 M naphthoquinone solution paired with 0.6 M ferrocyanide demonstrated good stability compared with other naphthoquinones, with a capacity fade rate of 0.017%/cycle (0.84%/day) over 320 cycles. Additionally, the system exhibited one of the highest energy efficiencies (82%) and a power density of 80-105 mW cm-2 at 50% SOC. These first results are promising for further exploration of new water-soluble naphthoquinones efficiently synthesized from hydroxyanthraquinones for application in AORFBs.

High resolution luminescence and radiocarbon dating of Holocene Aeolian silt (loess) in west Greenland

Loess–palaeosol sequences serve as valuable archives of changes in climate and atmospheric mineral dust deposition. However, little work has been conducted on Holocene loess in the Arctic, despite the sensitivity of this region to climate changes. Aeolian silt/loess profiles in the ice-free region of western Greenland near Kangerlussuaq were sampled to develop a robust age framework using both luminescence and bulk organic matter radiocarbon dating. Radiocarbon ages generally show consistent age increases with depth but are likely offset to younger ages due to sediment mixing in the upper 10–20 cm of the profiles. Quartz OSL signals exhibit insensitivity, while low-temperature infrared stimulated luminescence performed at 50 °C (IR50) and the post-IR IRSL at 180 °C (pIRIR180) signals of polymineral fine grain revealed a consistent natural inherited dose of approximately 5 Gy for pIRIR180 and an unbleachable residual of around 2 Gy for IR50, with substantial fading rates in the latter. This led to a notable age overestimation when compared with bulk organic matter radiocarbon ages. To develop an appropriate dating approach, we evaluated the differential bleaching rates of feldspar IR50 and pIRIR180 signals, and corrected for modern inherited doses. Radiocarbon ages measured on the bulk organic carbon oxidised at 400 °C (LT 14C) increased very consistently with depth, allowing calculation of accumulation rates. The presence of the atmospheric radiocarbon bomb signal at depth indicated down-mixing of surface material into the profile, which caused negative (younger) age offsets. The offset-corrected radiocarbon-based age-depth model could be compared to the luminescence results.We show that a combination of LT 14C with polymineral pIRIR180 dating allows the development of age models for these deposits. This multi-chronological approach reveals that loess accumulation in the region was initiated around 4 ka, probably consisting of two main phases of loess accumulation at 4–3 ka and <1 ka. The initial phase matches the proposed onset of aeolian sand activity in the wider region, but post-dates local ice retreat by c. 3 kyr. The more recent phase of accumulation also matches the timing of increased sand accumulation in the region and likely coincides with Neoglacial to Little Ice Age ice advances, or even enhanced dust activity in the last decades.

The post-IR IRSL dating of an ancient dammed lake upstream of the Ganglai gorge in the upper-middle reaches of Yarlung Tsangpo

The middle reaches of Yarlung Tsangpo, situated on the southern Tibetan Plateau, have experienced extensive river damming events due to glacier advances, resulting in the formation of several ancient dammed lakes. These palaeolakes offer invaluable insights into past hydrological and geomorphological dynamics on the Tibetan Plateau. In this study, we reported a newly identified ancient dammed lake, named the Xiaru palaeolake, located upstream of the Ganglai Gorge in the uppermost segment of the middle reaches of Yarlung Tsangpo, and conducted a pioneer chronological investigation of the lake using K-feldspar post-IR IRSL (pIRIR) dating. Quartz minerals from most lacustrine and fluvial sediments can not provide reliable ages characterized with low intensity and large inter-aliquot scatter in equivalent doses (De). In contrast, the K-feldspar exhibited much greater luminescence intensity and narrower De distribution using the pIRIR225 dating protocol. Residual, dose recovery, and fading tests demonstrated that the pIRIR225 signals are well bleached with a relatively low fading rate, making it a more suitable dosimeter for dating applications in the study area. The pIRIR225 ages, derived through single aliquots, standard growth curve (SGC), and single grain measurements, reveal a major phase of the Xiaru Lake between 24.1 ± 1.0 ka and 15.8 ± 1.1 ka, that commenced aligning with the global Last Glacial Maximum. Furthermore, one lacustrine sample dated to 29.9 ± 2.2 ka suggests the possibility of multiple damming events in Ganglai Gorge during the last glacial period, although further evidence is required for a comprehensive interpretation.