Efficiency Factor Research Articles

Energy and exergy analysis of a novel solar-powered passive multi-stage osmosis desalination system for sustainable water production

Climate change and population growth constantly exacerbate global water scarcity, and seawater desalination technology is crucial to addressing this crisis. Conventional fossil-fuel desalination poses environmental and economic challenges, especially in remote, water-scarce regions. Renewable energy offers sustainable options for seawater desalination; however, most related technologies face challenges in flexible deployment. Among passive technologies, interfacial evaporation still confronts issues of salt accumulation impacting desalination efficiency. Therefore, this study investigates a novel solar-powered passive multi-stage osmosis device that emulates mangroves’ transpiration and natural osmosis processes. Harnessing solar energy, it employs hydrophilic nanoporous membranes for water movement and evaporation and an osmosis membrane for solute retention, aiming for efficient seawater desalination without external power and pressure. Energy and exergy analyses reveal key efficiency factors. Results reveal significant pressure gradients across the osmosis membrane as a challenge. Optimizing salinity and adjusting the area ratio of the nanoporous membrane to the osmosis membrane is vital for stability and performance. Moreover, potential increases in water production from 0.97 kg/m2/h to 3.53 kg/m2/h with a five-stage setup, though benefits diminish with additional stages due to heat/exergy losses. The exergy efficiency increases from 0.14 % for a five-stage device to 0.18 % for a ten-stage system. This study demonstrates the solar-powered passive multi-stage osmosis device’s dependence on solar flux and highlights the importance of optimizing the air gap thickness and insulation to boost efficiency.

The effects of varying stocking densities during the first 10 days on the performance, welfare, slaughter and meat quality characteristics of broiler chickens in the subsequent period.

This study aimed to investigate the effects of varying stocking densities during the first 10 days on the performance, welfare, slaughter and meat quality characteristics of broiler chickens in the subsequent period (11-42 days). In the study, treatments representing 3 different stocking densities with the same group sizes were established and a total of 432 d-old chicks were used. In the first 10 days of the rearing period, treatments of 18 (SD18), 27 (SD27) and 36 (SD36) chicks per m2 were formed, and at 11 days of age, chicks in all treatments were reared at a density of 18 chicks/m2. Body weight differences in SD18, SD27 and SD36 treatments at 10 and 42 days of age were significant (P < 0.05), they were 252.6, 254.3 and 241.5g in SD18, SD27 and SD36 groups at 10 days and 2961.1, 2874.8 and 2842.7g at 42 days of age, respectively. In the first 10 days of growing period, SD36 showed a significant difference (P < 0.05) from the other groups in feed intake and feed conversion ratio, but this was not significant at slaughter age. The livability at 10 and 42 days was not different among treatments and was between 98.6 and 99.3% and 93.5-93.8%, respectively. The uniformity at 10 days was significant among the stocking density groups (P < 0.05) and the best uniformity level was obtained in the SD36 group, the differences in CV values at 42 days were not significant among the treatments. EPEF (European production efficiency factor) values were not different between the groups, the highest numerical value was determined in the SD36 group. Foot pad dermatitis, hock burn and breast burn levels were significantly higher in SD18 chickens (P < 0.05), however incidence of finger crookedness and valgus-varus deformity did not differ between the treatments. The litter moisture contents were similar between treatments, and ranged from 25.6 to 32.6%. Different stocking density treatments during the first 10 days of the experiment had no significant effect on slaughter, abdominal fat, carcass parts, color and pH values in the breast and thigh meat. In conclusion, rearing broiler chickens by dividing the poultry house area by half during the first 10 days (36 birds/m2) could help to improve the overall productivity (EPEF) by providing ease of maintenance, efficient heating and better control.

A combined DFT and finite difference simulation study on hybrid halide perovskite-based solar cells

This work reports the modelling and numerical estimation of the photovoltaic parameters of perovskite solar cells (PSCs) containing formamidinium lead iodide (FAPbI3) and formamidinium tin iodide (FASnI3) in the form of light active materials using SCAPS 1D software. The analysis is done by introducing diverse hole and electron transport materials and back metal contacts to identify the most appropriate device configuration that can deliver optimum photovoltaic output. The optoelectronic properties and the absorption spectra of the two compounds are estimated by DFT calculation using WIEN2k, which incorporates density functional theory (DFT) principles and are provided as input to SCAPS 1D to improve the accuracy of modelling study. For FAPbI3 as absorber material, the configuration FTO/IGZO/FAPbI3/NiO/Au shows the highest photovoltaic parameter exhibiting a power conversion efficiency (PCE) and fill factor (FF) of 19.75 % and 74.29 % respectively. With FASnI3 as the absorber material, FTO/PCBM/FASnI3/P3HT/Au gives a PCE and FF of 21.6 % and 67.74 % respectively. The work also includes the analysis of influence of defect density at the interface layers and series and shunt resistance on performance of above-mentioned device architectures to identify their limitations under real experimental conditions. The influence of various attributes of perovskite on the performance of the device is examined to determine their optimum values.

Investigation on sulfonated PVC/polymethyl methacrylate (PMMA)/polystyrene sulfonate (PSS) polymer blends as proton-conducting membrane

AbstractThe design and development of cost-effective and increased methanol permeable and proton-conductive membranes are critical concerns in the fabrication of polymeric electrolyte membranes (PEM). A solution-casting process was used to create a low-cost PEM based on sulfonated polyvinyl chloride (SPVC)-Polymethyl methacrylate (PMMA) blended with varying concentrations of Poly(sodium 4-styrenesulfonate) (PSS). The contact angle, oxidative stability, swelling ratio, water uptake, and methanol uptake of SPVC/PMMA/PSS membranes were investigated as a function of PSS molar ratio. FT-IR examination, 1H NMR spectra, Raman spectroscopy, X-ray diffraction, thermogravimetric analysis (TGA), and scanning electron microscope micrographs were additionally utilized for confirming the chemical structure, morphology, and thermal stability of SPVC/PMMA/PSS membranes. Furthermore, the ion exchange capacity (IEC), proton conductivity, and methanol permeability of SPVC/PMMA/PSS membranes were investigated depending on the PSS concentration. The results showed a significant increase in proton conductivity from 1.80 × 10–2 for SPVC/PMMA/1%PSS to 4.7 × 10–2 S/cm for SPVC/PMMA/5%PSS at ambient temperature. On the other hand, the methanol permeability (P = 8.53 × 10–8 cm2/s) was noticeably lower than that of Nafion 117 (3.39 × 10–6 cm2/s). Additionally, the IEC of the manufactured membrane was 1.38 ± 0.7 meq g−1 for SPVC/PMMA/5%PSS compared to 0.91 meq g−1 for Nafion 117 membranes. The maximum water uptake of the synthesized membranes was 48.37 ± 2.27%, whereas Nafion 117 membrane absorption was 65.44%. According to conductivity studies and the membrane efficiency factor, the ideal PSS content in a polymer matrix is 4 wt.%. Finally, the developed SPVC/PMMA/PSS polyelectrolytic membranes show improvements in essential properties such as methanol permeability, proton conductivity, and IEC when combined with low-cost materials, making them an attractive contender as PEM for DMFCs. Graphical abstract

Evaluation of mechanical behaviour of vegetal FRCM composites through the DIC technique: Effects of textile pre-impregnation and short flax fibres

FRCM composites are intended for the reinforcement of structural elements such as concrete and masonry. In the current environmental context, vegetal FRCM made from plant textiles such as flax, hemp or jute represent a promising alternative to synthetic FRCM typically made from carbon or glass textiles. However, the mechanical behaviour and damage mechanism of these vegetal composites are intricate and require further investigation to improve their appeal for real-world applications. This paper investigates the global and local tensile behaviour of vegetal FRCM composites using Digital Image Correlation (DIC). Three different types of textiles have been selected for Flax-FRCM (flax textile), Jute-FRCM (jute textile) and Carbon-FRCM (carbon textile) composites, which serve as references. The objective is to evaluate the influence of the physical and mechanical properties of the textiles, the addition of short flax fibres to the mineral matrix, the pre-impregnation of the plant textiles in the mineral matrix and the reinforcement ratio on the mechanical performance of the composites. The results showed that these parameters significantly affect the FRCM mechanical response in terms of the stress-strain curves, tensile properties, crack spacing, crack widths and their evolution during loading, failure mode and the exploitation rate of the textile in the composite (efficiency factor, crucial for structural applications). Furthermore, combining textile pre-impregnation with the addition of short flax fibres showed the best tensile performance for vegetal FRCM composites, notably through a significant reduction in crack widths and textile failures in the centre of the specimen.

Efficacy and Growth Performance between Two Different Ionophore Coccidiostats (Narasin and Salinomycin) in Broiler Chickens after Challenge with Eimeria spp.

The objective of this study was primarily to assess the different performance impacts of two ionophore coccidiostats (narasin and salinomycin) used to manage coccidiosis. While both products may be efficacious in controlling disease challenges, previous literature has suggested that some ionophores are less well tolerated by the broiler chickens. In this study, we were particularly interested to know how the use of different coccidiostat programs translates into broiler health and performance, as measured by zootechnical parameters such as the feed conversion ratio, average daily gain, and final body weight. A total of 352 male Ross 308 one-day-old broilers were randomly divided into two treatment groups (T1 and T2). Treatment 1 included a basal diet (BD) + nicarbazin/narasin (Maxiban®, Elanco) at 100 ppm 0-24 days, narasin at 70 ppm 25-42 days, and (2) Treatment 2 included basal diet + nicarbazin/narasin at 100 ppm 0-24 days, salinomycin (Sacox®, Huvepharma) at 70 ppm 25-42 days. Efficacy and performance parameters, slaughter analysis, dry matter (DM) in litter, and intestinal integrity (I2) were measured for the broilers from both treatment groups. The findings demonstrated more favorable results for broilers reared in the group diet fed with narasin (in the finisher phase), including higher daily body weight gain, higher final body weight, lower feed conversion ratio value (improved feed efficiency), and higher European Production Efficiency Factor value, compared with the salinomycin-supplemented group.

Evaluation of golfers’ performances in the ladies professional golf association tour based on bootstrapped data envelopment analysis and latent growth curve model

A latent growth curve model and bootstrapped data envelopment analysis were used to examine the performance and changes in professional golfers on the Ladies Professional Golf Association tour. The panel data for both analyses were obtained for the last three seasons (from 2020 to 2022). The dependent variable was the official money list of players, whereas the independent variables consisted of efficiency factors, technical factors (number of birdies, eagles, and hole-in-ones), mental factors (driving and putting accuracies), and career length. Each factor, other than the efficiency factor, was determined by the weighted combination of parenthesized variables using principal component analysis and was measured as two latent variables of the intercept and the slope of the growth pattern for the three seasons. The efficiency factor was measured using data envelopment analysis and its z with the output factors of scoring average and the percentage of rounds in the 60s, and the input factors of driving distance, greens in regulation, number of putts per green hit in regulation, and sand savings. The results confirm the homogeneity in players’ efficiency and prove Penick’s claim that golf performance is dependent on various factors and that golf is psychological.

Enhancing Circularly Polarized Luminescence Dissymmetry Factor of Chiral Cylindrical Molecules to -0.56 through Intramolecular Short-Range Charge Transfer.

High-performance circularly polarized luminescent (CPL) materials have received wide attention recently by virtue of broad application in circularly polarized light-emitting diodes, 3D display, and encryption. Reaching both high luminescence efficiency and strong luminescence dissymmetry factor (glum) is still a challenging goal that requires continuous efforts. Herein, we performed a systematic theoretical investigation on the chiroptical properties of helical cylindrical molecules (-)-[4]cyclo-2,6-anthracene [(-)-[4]CA2,6] and (P)-[4]cyclo-2,8-chrysenylene [(P)-[4]CC2,8], and found that the unique and symmetric cylindrical structure could make the transition dipole moment components offset along the cylindrical surface but concentrated along the vertical central axis. This structural superiority contributes the collinear electric and magnetic transition dipole moment vectors and thus the large glum. Based on the results of decomposed transition dipole moment vectors to individual atoms, an effective strategy to enhance the glum through introducing intramolecular short-range charge transfer by embedding B,N atoms is proposed. The decreased electric transition dipole moment and well-kept magnetic transition dipole moment enable the glum of B,N-embedded designed molecules (-)-[4]CA2,6-4BN and (P)-[4]CC2,8-4BN up to -0.31 and -0.56, respectively. This molecular-insight investigation deepens the understanding of the structure-property relationship and provides efficient guidance for improving glum of CPL materials.

Analysis of the Spatiotemporal Differentiation and Influencing Factors of Land Use Efficiency in the Beijing–Tianjin–Hebei Urban Agglomeration

Optimizing urban land use is of significant practical importance for promoting economic development, enhancing the standard of living for individuals residing in metropolitan areas, enhancing urban infrastructure and public services, driving urban transformation and upgrading, and attaining synchronized progress of the economy, society, and environment. This paper uses the super-efficiency SBM model to measure the urban land use efficiency (ULUE) of 13 cities in the Beijing–Tianjin–Hebei (BTH) urban agglomeration from 2005 to 2020 and explores the spatiotemporal evolution characteristics and influencing factors of ULUE in this urban agglomeration using analysis of spatial data and application of geographic detector methods. The results show that (1) from 2005 to 2020, the ULUE of the BTH urban agglomeration had an initial rise followed by a decline; however, the overall efficiency score is above 1, suggesting an overall effective state; (2) a distribution pattern with Beijing as its core was established, exhibiting greater ULUE in the northern region and poorer efficiency in the southern region, with significant correlation characteristics in efficiency values between adjacent cities; and (3) capital input, labor input, social welfare, and ecological environment are all influencing factors that promote the improvement in ULUE in the BTH region, and the interaction of any two factors explains the ULUE in this region better than a single factor. The empirical research results can provide useful references for improving the input–output ratio of land units and further spatial planning and policy formulation in the BTH region.

Investigation of cabin heating in electric vehicles with integrating solar cells and heat storage systems

In recent years, the production and usage of electric vehicles have been encouraged due to zero emissions, efficiency, and economic factors. Efficient cabin heating and thermal management in electric vehicles are crucial for enhancing passenger comfort, extending battery life, and optimizing overall energy usage, thus contributing to the sustainability and practicality of electric transportation. Heating the cabin of electric vehicles in winter has a negative effect on range. Therefore, methods are being researched to use energy efficiently without sacrificing passenger comfort and minimizing the effect on the vehicle's range. This study presents an innovative radiator design specifically crafted for Electric Vehicles (EVs), leveraging solar panels to heat water for the radiator. This system enables the vehicle to harness solar energy for heating a water tank while stationary, effectively serving as an energy storage reservoir. Upon vehicle movement, the radiator system activates to disperse the stored thermal energy throughout the cabin, ensuring superior thermal comfort. Consequently, optimizing battery range is achieved as the heating load typically leads to significant range reductions. From the obtained results in experiment 2, the results indicated that the cabin temperature rose from 3 °C to around 15 °C within a few minutes, reflecting an increase of approximately 12 °C. According to the results, this indicates that there will be a reduction in energy consumption of between 1.9 % and 3 % for a one-hour travel range in this electric vehicle. The findings of this investigation demonstrate that utilizing warm water energy storage effectively enhances cabin thermal management.

Greenhouse gas emissions from Chinese livestock sector can be decreased by one third in 2030 by the improvement in management

China is one of the largest contributors to global greenhouse gas (GHG) emissions, and the livestock sector is a major source of non-CO2 GHG emissions. Mitigation of GHG emissions from the livestock sector is beneficial to the sustainable development of the livestock sector in China. This study investigated the provincial level of GHG emissions from the livestock sector between 2000 and 2020 in China, to determine the driving factors affecting the provincial-level GHG emissions from the livestock sector, based on the logarithmic mean Divisia index (LMDI) model, which took into account of technological progress, livestock structure, economic factor, and agricultural population. Moreover, a gray model GM (1, 1) was used to predict livestock GHG emissions in each province until 2030 in China. The results showed that the GHG of Chinese livestock sector was decreased from 195.1 million tons (MT) CO2e in 2000 to 157.2 MT CO2e in 2020. Henan, Shandong, and Hebei provinces were the main contributors to the reduction in Chinese livestock GHG emissions, with their livestock GHG emissions reduced by 60.1%, 53.5% and 45.5%, respectively, in 2020 as compared to 2000. The reduction in GHG emissions from the Chinese livestock sector can be attributed to two main factors: technological progress and the shrinking of the agricultural laborers. In contrast, the agricultural economic development model with high input and high emissions showed a negative impact on GHG emission reduction in China’s livestock sector. Furthermore, the different livestock structure in each province led to different GHG reduction effects on the livestock sector. Under the gray model GM (1,1), the GHG emissions of the livestock sector will be reduced by 33.7% in 2030 as compared with 2020 in China, and the efficiency factor will account for 76.6% of the positive effect of GHG reduction in 2030. The eastern coastal region will be the main contributor to the reduction of GHG emissions from the Chinese livestock sector in 2030. Moreover, recommendations (such as upgrading livestock management methods and promoting carbon emission mitigation industries) should be proposed for the environmentally sustainable development of the livestock sector in the future.

Thermal energy resource utilization and sample image restoration technology based on Machine vision simulation in interior design

With the rise of sustainable building design, the traditional design methods are often unable to fully consider the optimal allocation and application of thermal energy resources. This study aims to explore the application of heat resource utilization and sample image restoration technology based on machine vision simulation technology in interior design, and provide practical solutions for optimizing indoor environment. In this paper, machine vision technology is used to monitor and model indoor space in real time, and heat energy flow and distribution under different design schemes are simulated. At the same time, the influence of different designs on thermal energy utilization efficiency is analyzed by using sample image restoration technology. In the study, a set of comprehensive evaluation indexes was established, which comprehensively considered the factors of heat efficiency, indoor comfort and energy consumption. The experimental results show that the simulation technology based on machine vision can accurately predict the indoor heat distribution and identify the best design scheme. At the same time, the sample image restoration technology significantly improves the evaluation accuracy of heat utilization efficiency. Through these methods, the optimized design scheme has higher thermal energy utilization than the traditional design, and significantly improves the indoor comfort. This study shows that the combination of machine vision simulation and sample image restoration technology can effectively improve the utilization efficiency of thermal energy resources in interior design, and provide new ideas and methods for sustainable building design.

Adsorption characteristics and separation behavior of binder and binderless zeolite LiX Pellets: O2, N2, and CO2

In adsorptive gas separation process design, optimal adsorbent selection acts as a critical factor in process efficiency. This study investigated the adsorption equilibria and kinetics of O2, N2, and CO2 (weak, medium and strong affinity, respectively) and the breakthrough performance of four commercial zeolite LiX pellets (one binderless and three binder zeolite LiX pellets) because the performance of pelletized zeolites becomes different by adding binders and pelletizing methods. The adsorption isotherms at 293–323 K and up to 100 kPa were correlated with the dual-site Langmuir and Sips models. For all adsorbents, the order of adsorption amount and isosteric heat of adsorption was CO2 ≫ N2 > O2. However, differences among the four zeolite pellets were also observed, showing the highest values of the binderless zeolite LiX pellet. Furthermore, the adsorption capacity was 20–25 % smaller for CO2 and 40–50 % smaller of N2 and O2 at 100 kPa compared to pure zeolite LiX powder. According to kinetic analysis using a non-isothermal diffusion model, the adsorption rate of N2 was faster than that of CO2 for all adsorbents, showing the order difference in the low-pressure range. The kinetic difference among the zeolite pellets resulted from the effects of heat of adsorption, heat dissipation, and thermal resistance. The breakthrough performance using N2 and O2 was mainly controlled by the adsorption capacity, showing almost constant breakthrough pattern regardless of the samples. This study suggests that detailed evaluation of pelletized adsorbent is essential before designing adsorptive processes because performance of adsorbent powder would lead to under-design of the process. (255 words)

Revolutionizing PV grid integration: Metaheuristic optimization of fractional PI controllers in T-type neutral point piloted inverters for enhanced performance

This study investigates the efficacy of FOPI regulators as a substitute for conventional proportional integral (PI) controllers in grid-connected PV inverters. The research's objective is to improve the dynamic efficiency of these systems by integrating intelligent optimization techniques that utilize both PI and FOPI controllers and employing different metaheuristic optimization procedures. The study introduces four new optimization algorithms: the Tyrannosaurus Optimization Algorithm (TROA), the Nutcracker Optimization Algorithm (NOA), the Golden Eagle Optimizer (GEO), and the Jellyfish Search Optimizer (JSO). These are made to meet the needs of multi-objective optimization. The proposal suggests using two PI/FOPI regulators to regulate both voltage and amperage provided by the multilayer inverter. The proposal employs a T-type three-level inverter, known for its superior conversion efficiency over conventional inverters. Matlab-Simulink simulations demonstrate that the Nutcracker optimization algorithm (NOA) outperforms other metaheuristic techniques for optimizing dynamic behavior, such as overshoot, settling time, execution, and rising time. Comparisons with existing methods, such as the Manta Rays Foraging Optimization (MRFO) and Grey Wolf Optimizer (GWO), show that all four new algorithms consistently outperform these existing algorithms. The data suggest that using NOA improves stability, efficiency, and power factor while reducing the inverter's THD.

Dissecting the characteristics and driver factors of potential vegetation water use efficiency in China

While large-scale vegetation greening in China has substantially influenced global vegetation dynamics, the specific impact of this restoration on water use efficiency (WUE) remained inadequately understood. This study employed both the Geodetector and structural equation modeling (SEM) methods, utilizing the Lund-Potsdam-Jena (LPJ) Global Dynamic Vegetation Model, to explore the contributions of various driving factors to China's potential vegetation WUE from 1982 to 2019. The results indicated: (1) there existed considerable further potential for vegetation recovery nationwide. Among them, the Loess Plateau, Inner Mongolia Plateau, and northern Xinjiang had relatively high potential for vegetation recovery. This potential was further amplified by the significant prospects for enhancing WUE in these areas; (2) The application of the Geodetector method revealed that the normalized difference vegetation index (NDVI) explained over 40 % of the variation in potential vegetation WUE in China, exerting a greater influence than climatic factors. In arid/semi-arid regions, precipitation (PRE), NDVI, and vapor pressure deficit (VPD) significantly influenced WUE. Temperature (TEM) was the dominant factor affecting WUE in humid and humid/semi-humid regions; (3) Utilizing the SEM analysis method, it was evident that NDVI exerted the most substantial direct positive influence on potential vegetation WUE in China, whereas VPD and PRE had notable negative impacts. In arid/semi-arid regions, PRE emerged as the primary determinant of WUE. Conversely, in regions where water resources were not limiting, TEM and VPD exerted a more pronounced influence on potential vegetation WUE. This indicated that while vegetation restoration generally enhanced potential vegetation WUE, other factors such as PRE, TEM, and VPD played critical roles in different climatic zones, shaping the regional variations in WUE.

A study on the measurement and influencing factors of the urban wastewater treatment efficiency in China based on the superefficiency SBM-Tobit model

A study on the measurement and influencing factors of the urban wastewater treatment efficiency in China based on the superefficiency SBM-Tobit model

Thermal performance investigation of rhombus shape roughened solar air collector- A novel approach

Current study investigates parametric study on thermal performance of a rhombus-shaped artificially roughened absorber plate (RAP) used in solar air collector. Experimental investigations were performed in month of April–May 2024 in mechanical department of MANIT, Bhopal. Relative roughness pitch (P/e), relative roughness height (e/Dh), number of elements (W/Vr) and relative diagonal length (dr/e) in the range of 8–12, 0.0225–0.03375, 9–11, and 8–12 respectively are used as geometrical parameters for current study. Reynolds number (Re) is varied from 2000 to 14000. Thermal efficiency (ղth) is reported in terms of collector heat removal factor (FR), and collector efficiency factor (F′). A significant enhancement in ղth has been observed, ranging from 1.42 to 1.63 times higher when compared to the performance data of smooth plates. Maximum ղth of 79.48% was found at P/e = 10, e/Dh = 0.03375, W/Vr = 10, dr/e = 9.6 at mass flow rate (m˙) = 0.031 kg/s. Collector's performance parameter are reported as (FRτα) and (F0UL). value of (FRτα) and (F0UL) is reported 0.8612 and 15.82 for rhombus shape at optimal geometrical parameters.

Navigating Financial Success: Comprehensive Strategies for Optimal Funding and Strategic Financial Planning

In the world today, globalization has made the business environment very dynamic, and as such, organizations must come up with good financial strategies that will help them remain viable in the long run. This paper aims to discuss general approaches to effective funding and financial planning which is vital in enhancing financial performance and reducing risks that may occur in the dynamic economic environment. The use of emerging financial technologies like blockchain, AI, and big data has changed how financial management is done and has made it more accurate and efficient. However, these technologies also present new problems such as cyber risk and legal concerns. Also, the increasing concerns of Environmental, Social, and Governance (ESG) factors in investment decisions show that financial planning should consider sustainability. The paper also focuses on the specific financial problems of SMEs and the necessity of targeted measures to help them improve their financial management. This paper, based on a literature review done between the years 2019 to 2024, aims at providing a framework for financial success in the form of strategic financial planning, efficient financing strategies, FinTech innovations, and ESG factors to help firms succeed in an ever-evolving economy. Keywords: Strategic Financial Planning. Optimal Funding, FinTech, Environmental, Social, and Governance (ESG), Small and Medium-Sized Enterprises (SMEs).

Navigating Alkaline Hydrogen Evolution Reaction Descriptors for Electrocatalyst Design

The quest for efficient green hydrogen production through Alkaline Water Electrolysis (AWE) is a critical aspect of the clean energy transition. The hydrogen evolution reaction (HER) in alkaline media is central to this process, with the performance of electrocatalysts being a determining factor for overall efficiency. Theoretical studies using energy-based descriptors are essential for designing high-performance alkaline HER electrocatalysts. This review summarizes various descriptors, including water adsorption energy, water dissociation barrier, and Gibbs free energy changes of hydrogen and hydroxyl adsorption. Examples of how to apply these descriptors to identify the active site of materials and better design high-performance alkaline HER electrocatalysts are provided, highlighting the previously underappreciated role of hydroxyl adsorption-free energy changes. As research progresses, integrating these descriptors with experimental data will be paramount in advancing AWE technology for sustainable hydrogen production.

NaCl aerosol filtration over filter media with intrafiber porosity: can filtrate capacity be increased by wicking into this pore volume?

This paper investigates a novel fiber-based filter media wherein a NaCl filtrate is collected and reservoired not only onto the surfaces of the fibers and within their inter-fiber voidage but also within the internal porosity of high pore volume nanoporous fibers or vapor grown carbon nanofibers (VGCF) floc used to fabricate the media. This transport process is shown to occur through a NaCl dissolution into the water-filled nanopores of the fiber and a subsequent intra-fiber wicking phenomenon. The study further elucidates two distinct NaCl accommodation mechanisms which are uniquely available to filter media containing nanoporous intrafiber porosity: (1) wicking and capillary condensation of liquid NaCl aerosols directly into the intrafiber pores at high RH, and (2) dissolution of otherwise solid NaCl aerosols deposited onto fiber surfaces (at low RH) into the interior nanopores of the fiber because these pores (when hydrophilic) are saturated with water (even at low RH). To investigate these two mechanistic regimes, various media were fabricated possessing multiscale porosity in the form of: (i) embedded flocs of VGCFs (4.108 cm3gm-1pore volume), (ii) hydrophilic and high pore volume activated carbon fibers (ACFs, 0.950 cm3gm-1) and (iii) solid graphite fibers. These media were then comparatively evaluated toward NaCl aerosol filtration at different relative humidities. Pressure drop measurements versus filtrate accumulation and SEM-EDAX VGCF demonstrated the location and transport of NaCl into the intrafiber voidage. Media containing both VGCF floc and ACF accumulated 1200% more NaCl at low RH (and a specified pressure drop) than similar media prepared from non-porous graphite fibers, with an additional 315% increase from low to high RH. A Gibbs free energy driving force model is provided to illustrate the driving forces favoring water condensation into the nanopores and solid NaCl aerosol dissolution into the water phase. Filtration efficiency and quality factor assessments for the various media are also systematically evaluated to demonstrate the observed mechanistics.