Face-centered Cubic Research Articles

Dislocation-based finite element method for homogenized limit domain characterization of structured metamaterials

PurposeHeterogeneous and micro-structured materials have been the object of multiscale and homogenization techniques aimed at recognizing the elastic properties of the equivalent continuum. The proposed investigation deals with the mechanical characterization of the heterogeneous material structured metamaterials through analyzing the ultimate strength using the limit analysis of the Representative Volume Element (RVE). To get the desired material strength, a novel finite element formulation based on the derivation of self-equilibrated solutions through the finite elements devoted to calculating the lower bound theorem has been implemented together with the limit analysis in Melàn’s formulation.Design/methodology/approachThe finite element formulation is based on discrete mapping of Volterra dislocations in the structure using isoparametric representation. Using standard finite element techniques, the linear operator V, which relates the self-equilibrated internal solicitation to displacement-like nodal parameters, has been built through finite element discretization of displacement and strain.FindingsThe proposed work presented an elastic homogenization of the mechanical properties of an elementary cell with a geometry known in the literature, the isotropic truss. The matrix of elastic constants was calculated by subjecting the RVE to numerical load tests, simulated with a commercial FEM calculation code. This step showed the dependence of the isotropy properties, verified with Zener theory, on the density of the RVE. The isotropy condition of the material is only achieved for certain section ratios between body-centered cubic (BCC) and face-centered cubic (FCC), neglecting flexural effects at the nodes. The density that satisfies Zener’s conditions represents the isotropic geomatics of the isotropic truss.Originality/valueFor the isotropic case, the VFEM procedure was used to evaluate the isotropy of the limit domain and was compared with the Mises–Schleicher limit domain. The evaluation of residual ductility and dissipation energy allowed a measurement parameter for the limit anisotropy to be defined. The novelty of the proposal consisted in the formulation of both the linearized and the nonlinear limit locus of the material; hence, it furnished the starting point for further limit analysis of the structures whose elementary volume has been described through the proposed approach.

The effects of Nb on the microstructure and performance of laser-cladded Fe50-xMn30Co10Cr10Nbx high entropy alloy coatings

A laser cladding technique was employed to produce a Fe50-XMn30Co10Cr10NbX (X = 2.5, 5, 7.5, 10at%) high entropy alloy coating. This study delved into the influence of Nb concentration on the coating’s phase constitution, microstructural features, hardness, and wear resistance. The high entropy alloy coating exhibited a multifaceted structural composition, encompassing FCC (Face-Centered Cubic), HCP (Hexagonal Close-Packed), and BCC (Body-Centered Cubic) structures, along with the presence of Laves phase. Notably, the incorporation of Nb led to an augmentation in the Laves phase and modifications within the microstructure. The hardness of the cladding layer is higher than that of the substrate. With the increase of Nb content, the hardness of the cladding layer increases first and then decreases; the average hardness of the Fe42.5Mn30Co10Cr10Nb7.5 cladding layer is the highest, the maximum hardness is 429.8Hv, and the average hardness is 382.3Hv. The friction coefficient and weight loss of the cladding layer decreases first and then increases with the increase of Nb content. The friction coefficient and weight loss of the Fe42.5Mn30Co10Cr10Nb7.5 cladding layer are the smallest, which are 0.0132 g and 0.5974, showing the best wear resistance. The wear types of high entropy alloy cladding layer are both adhesive wear and abrasive wear. The addition of Nb into high entropy alloy will form the Laves phase, which can improve the mechanical properties of high entropy alloy.

Ultrahigh hardness with exceptional wear resistance of novel cost-effective nanostructured Fe40Ni25Cr25Mo5Al5 high-entropy alloy through cyclic closed-die forging process

Industry applications of current high-entropy alloys (HEAs) are limited by their prohibitive costs. Here, we present a cost-effective and facile approach to producing nanostructured HEAs with lower cost and exceptional mechanical properties. In the present work, the key was to design a novel cost-effective Fe40Ni25Cr25Mo5Al5 high-entropy alloy with an ultrafine-grained (UFG) microstructure through cyclic closed-die forging (CCDF) at room temperature for up to six passes. The as-homogenized alloy exhibited a dual-phase structure, with minor [CrMoFe]-rich dendrites dispersed in a nearly homogenous face-centered cubic (FCC) matrix. Increasing CCDF passes resulted in achieving a more homogeneous nanograin, accumulation of dislocations, fragmentation of [CrMoFe]-rich dendrites, and efficient distribution within the matrix, which provided ideal conditions for the development of a nanostructured Fe40Ni25Cr25Mo5Al5 alloy with superior mechanical properties (hardness and wear resistance). The highest microhardness (∼ 843 HV) and the lowest wear rate (∼ (0.9 ± 0.1) × 10–5 mm3.N−1.m−1) were obtained in the Fe40Ni25Cr25Mo5Al5 alloy after six CCDF passes. It was suggested that the Rotated Cube {001}<110> texture component of the CCDF-processed alloy contributed positively to the improvement of wear resistance properties. These findings suggest that CCDF processing has the potential to achieve cost-effective nanostructured high-entropy alloys and implement them in engineering and structural applications.

Tailoring elastic bandgaps and moduli of triply periodic minimal surface structures by a hybrid technique

This work aimed to investigate elastic dispersion behaviors of triply periodic minimal surface (TPMS) lattice structures. The dispersion curves were established using the finite element (FE) Bloch reduction method, in which the Bloch periodic boundary condition was implied via the Bloch transform matrix. Four different types of both surface- and solid-based TPMS lattices with varying relative densities were considered. It was found that only the solid-based Neovius and Schwarz structures provided complete elastic bandgaps. Then, elastic stiffnesses of the structures obtained by representative volume element (RVE) models were evaluated with regard to their achieved band gaps. Reducing the volume fraction of lattices obviously enhanced the bandgap behaviors, while decreasing the specific moduli. Moreover, new hybrid phononic lattices were introduced for tailoring the elastic bandgap and mechanical properties. The results showed that incorporating the strut-based face-centered cubic (FCC) lattice in the TPMS structures could obviously improve the bandgap characteristics and simultaneously maintain reasonable specific elastic properties. Finally, wave suppression structure by using the dispersion curves was demonstrated by examining a simple beam infilled with the periodic lattices under excited loads. It was shown that the TPMS structures could be well applied as an effective wave suppression feature in load-bearing structures.

A comparative study on nanoscale mechanical properties of CrMnFeCoNi high-entropy alloys fabricated by casting and additive manufacturing

Additive manufacturing (AM) has emerged as a pioneering method for fabricating high entropy alloys (HEAs), yet a comprehensive comparison of their nanoscale mechanical properties with those produced by the conventional casting method remains unexplored. In this study, the nanoindentation was utilized to investigate the nanoscale elastic and plastic characteristics in both additive-manufactured (AM-ed) and as-casted single-phase face-centered cubic (FCC) equiatomic CrMnFeCoNi HEAs. Herein, the hardness, reduced modulus, indentation size effect (ISE), yield strength, fracture toughness, and strain rate sensitivity were comprehensively investigated. The results indicated that the hardness of AM-ed HEA was higher than the as-casted HEA, and the reduced modulus values showed no notable distinction between the two samples. The AM-ed HEA demonstrated simultaneous enhancements in yield strength and fracture toughness compared to the as-casted HEA. The as-casted HEA possessed a more distinct indentation size effect (ISE) than the AM-ed HEA. It was observed that the AM-ed HEA exhibited relatively lower strain rate sensitivity and a larger activation volume. This direct comparison of the mechanical properties and deformation mechanisms from a nanoscale view offers unique insights for optimizing and advancing AM techniques in the fabrication of HEAs.

Morphological Characteristics of W/Cu Composite Nanoparticles with Complex Phase Structure Synthesized via Reactive Radio Frequency (RF) Thermal Plasma

The W/Cu binary system is characterized by its mutual insolubility and excellent wettability, making W/Cu composite materials ideal for managing thermal and electrical properties in electronic components. To optimize material properties, control over the microstructure is crucial, and nanocomposites with uniform dispersion offer significant advantages. In this study, W/Cu composite nanoparticles were synthesized by feeding a blended feedstock of tungsten trioxide (WO3) micro-powder and cupric oxide (CuO) micro-powder into a reactive radio frequency (RF) argon–hydrogen thermal plasma system. Cu-coated W nanocomposite particles were obtained through the vaporization, reduction, and condensation processes. The resulting nanocomposite particles were composed of body-centered cubic (BCC) α-W, A15 β-W, and face-centered cubic (FCC) Cu phases, with a chemical composition closely matching theoretical calculations. The phase evolution and morphological changes of the synthesized particles were analyzed as a function of heat treatment temperatures up to 1000 °C in a reducing atmosphere. Up to 600 °C, the phase composition and morphology remained stable. At 800 °C, localized diffusion and coalescence of Cu led to the formation of particulate Cu, and a significant phase transformation from metastable β-W to α-W was observed. Additionally, extensive Cu segregation due to long-range diffusion resulted in distinct Cu-rich and Cu-depleted regions. In these regions, notable sintering of W particles and the complete disappearance of β-W occurred. The results showed that the temperature-dependent redistribution of Cu plays a crucial role in the phase transformation of W and the morphology of W/Cu composite particles.

Auxeticity Tuning by Nanolayer Inclusion Ordering in Hard Sphere Crystals.

Designing a particular change in a system structure to achieve the desired elastic properties of materials for a given task is challenging. Recent studies of purely geometrical atomic models have shown that structural modifications on a molecular level can lead to interesting and desirable elastic properties. Still, the result of such changes is usually difficult to predict. The present work concerns the impact of nanolayer inclusion ordering in hard sphere crystals on their elastic properties, with special attention devoted to their auxetic properties. Two sets of representative models, based on cubic crystals consisting of 6×6×6 unit cells of hard spheres and containing either neighboring or separated layers of spheres of another diameter, oriented orthogonally to the [001] direction, have been studied by Monte Carlo simulations in the isothermal-isobaric (NpT) ensemble. Their elastic constants have been evaluated using the Parinello-Rahman approach. The Monte Carlo simulations showed that introducing the layer inclusions into a pure face-centered cubic (FCC) structure leads to the system's symmetry changes from cubic symmetry to tetragonal in both cases. Essential changes in the elastic properties of the systems due to layer ordering were found both for neighboring and separated inclusions. It has been found that the choice of a set of layer inclusions allows one to tune the auxetic properties in two crystallographic directions ([110][11¯0] and [101][1¯01]). In particular, this study revealed that the change in layer ordering (from six separated layers to six neighboring ones) allows for, respectively: (i) enhancing auxeticity of the system in the [101][1¯01] direction with almost loss of auxetic properties in the [110][11¯0] direction in the case of six separated layers, while (ii) in the case of six neighboring layers, keeping the auxetic properties in both auxetic directions independently of the size of spheres constituting inclusions.

Breaking strength-plasticity trade-off in heterostructure CrFeNiAl0.28Si0.09Ti0.02Cu0.01 high entropy alloy by heat-treatment-induced nano-precipitation

In this study, heat treatment was employed to enhance the mechanical properties of an as-cast CrFeNiAl0.28Si0.09Ti0.02Cu0.01 high entropy alloy (HEA) with the heterostructure consisting of face-centered cubic (FCC), body-centered cubic (BCC) and B2 phases. It was observed that, after heat treatment at 873 K for 1 h followed by water-quenching, well-dispersed L12 and L21 nano-precipitates could be formed in FCC phase and BCC phase of this as-cast HEA, respectively. Furthermore, it is worth noting that despite a noticeable reduction in dislocation density, this heat treatment process significantly enhances yield strength, ultimate tensile strength, plasticity and hardness simultaneously, which could be attributed to the formation of nano-scale precipitates mentioned above. These findings provide a novel approach for fabricating high-performance HEAs by introducing complex multi-level heterogeneity.

Effects of Gd on the microstructure and mechanical properties of GdxCoCrFeNiV0.4 high-entropy alloys

This study investigated the microstructure and mechanical properties of GdxCoCrFeNiV0.4 alloys. Various techniques such as XRD, SEM, EBSD, and TEM were utilized, alongside hardness and compression tests at room temperature. The findings revealed that the high-entropy alloy without Gd element exhibited a single face-centered cubic (FCC) phase. Upon the introduction of Gd element, the phase composition shifted to FCC + hexagonal structure (HS) phases, and further addition of Gd resulted in the presence of FCC + HS + body-centered cubic (BCC) phases. Additionally, the inclusion of Gd element led to the precipitation of Gd-rich particles within the alloy. The Vickers hardness test results revealed a significant increase in alloy hardness as the Gd content rose, from 177.5 HV for Gd0 to 848.4 HV for Gd0.4. This suggests that the presence of the HS phase and BCC phase notably influences alloy hardness. Furthermore, compressive test outcomes demonstrated that the alloy's yield strength rose from 173.74 MPa for Gd0 to 1356.17 MPa for Gd0.3 with increasing Gd content. However, the excessive addition of Gd elements results in significant precipitation of V and Cr elements, leading to grain coarsening, adversely affecting its mechanical properties. The high strength of Gd-containing high-entropy alloys can be attributed to various strengthening mechanisms, such as solid solution strengthening, the presence of the HS phase, the precipitation of a small number of Gd-rich particles, and the grain refinement caused by the addition of Gd.

Microstructure characterization and properties of CuFeCo heterostructure alloys

The microstructure and properties of Cu66.6(FeCo)33.4 and Cu60(FeCo)40 alloys were investigated. Microstructural observations show that CuFeCo alloys have formed dual-phase heterostructures comprising face-centered cubic (FCC) and body-centered cubic (BCC) phases. The average grain size of the CuFeCo alloys after cold rolling and aging is less than 10 μm. Cu66.6(FeCo)33.4 has better elongation and electrical conductivity, while Cu60(FeCo)40 has better tensile strength, hardness, saturation magnetization, and electromagnetic interference shielding effectiveness. An increased FeCo content in a finer second phase with a larger volume fraction, leading to more phase boundaries. This enhances the strength of the CuFeCo alloys while simultaneously reducing their elongation. The obtained results can be used for further development of alloys with FCC/BCC dual-phase heterostructures.

Intrinsic tensile brittleness of tilted grain boundaries and its shear toughening

In the endeavors of working with microstructures in polycrystalline metals for better strength and ductility, grain boundaries (GBs) are placed at the front burner for their pivotal roles in plastic deformation. Often the mechanical properties of polycrystalline metals are governed by mutual interactions among GBs and dislocations. A thorough comprehension of GB deformation is therefore critical for the design of metals of superb performance. In this research, we investigated the mechanical behavior of symmetric tilt grain boundaries in face-centered cubic (F.C.C.) nickel, which may be subject to tension, shearing, and mixing-mode load using molecular dynamics simulations. We observed that (1) there exist four types of micro deformation mechanisms in GBs, and illustrate at the atomistic scale their distinctions and their dependence on the activation of lattice slip in the crystal; (2) GBs are intrinsically brittle under tension but exhibit ductile behavior during shearing. Shifting from pure tension with increasing shear component during mixing-mode load leads to GB toughening; and (3) there lacks conceivable dependence of GB tensile strength on tilted GBs, in contrast to a relatively rough trend of greater shear strength in GBs of large misorientation. GB energy shows no direct connection with GB strength, as broadly reported in existing literature. This research enhances our mechanistic understanding of GB plasticity in crystalline metals, and points to a potential way of making strong-yet-tough polycrystalline metals through GB engineering: in addition to GB structure manipulation, tuning the loading mode of GBs may open another avenue for their better performance.

Design of novel high entropy alloys based on the end-of-life recycling rate and element lifetime for cryogenic applications

The equiatomic face-centred cubic (FCC) CoNiCrFeMn alloy, known as the Cantor alloy, is renowned for its high ductility under extreme conditions, such as cryogenic temperatures. Despite this, it suffers from low hardness and yield strength (YS) and includes elements with significant supply concerns. This study introduces novel non-equiatomic CoNiCrFeMn alloys, designed using machine learning (ML)-assisted-high-throughput atomistic simulations to enhance sustainability and mechanical properties such as hardness and YS while maintaining the alloy's single-phase FCC structure. We incorporated two critical sustainability indicators, end-of-life recycling rate (EOL−RR) and lifetime (τ), to guide the alloy design process. Mean-flow stress (MFS), measured from the yield point to 15% strain during tensile tests, was used to assess and predict the mechanical properties. Two alloys, with cobalt contents of 12.5% and 21.5%, were developed and analysed. The Co12.5 alloy showed better sustainability (44% improvement in τ with almost the same mechanical properties), while the Co21.5 alloy exhibited better mechanical properties (20% improvement in MFS with almost the same sustainability) as the equiatomic system. Their stable FCC microstructures were confirmed through CALPHAD modelling and X-ray diffraction (XRD) analysis of vacuum arc melted, as-cast samples. The results highlight the potential of integrating sustainability metrics into high-performance alloy design.

Concurrent dramatic enhancement of high-temperature strength and ductility in a high-entropy alloy via chain-like dual-carbides at grain boundaries

Grain boundaries (GBs) are often known as intergranular cracking sources in alloys at high temperatures, resulting in limited high-temperature strength and ductility. Here, we propose a GB-dual-carbide (denoted as GB-DC) strengthening strategy and have developed a high-performance (NiCoFeCr)99Nb0.5C0.5 high-entropy alloy (HEA) with exceptional strength-ductility synergy at 1073 K. Chain-like coherent M23C6 carbides have been successfully introduced at GBs and remain a cube parallel crystallographic orientation with the face-centered cubic (FCC) matrix during deformation. Nano-scale NbC particles are distributed alternatively between M23C6 carbides and inhibit their coarsening. Both strength and ductility of the GB-DC HEA increase dramatically at strain rates ranging from 10−4 to 10−2 s−1 at 1073 K, compared with those of the single-phase NiCoFeCr HEA. Specifically, yield strength of 142 MPa, ultimate tensile strength of 283 MPa, and elongation of 34 % were obtained, which are twice that of the reference NiCoFeCr HEA (82 MPa, 172 MPa, and 18 %, respectively). EBSD investigations demonstrated that chain-like carbides enhance the GB cohesion at high temperature, and TEM analysis revealed that dislocations can go through the coherent phase boundaries (CPBs) and activate dipoles inner M23C6 carbides, which weakened the stress concentration in GBs. This substantially reduces the critical stress for dislocation generation and transmission to a stress level lower than that required for intergranular fracture. Theoretical estimation suggests that carbides result in a much higher activation energy (∼510 kJ/mol) for GB sliding and a rather low interface energy (∼101 mJ/m2) compared with the GB energy (1000 mJ/m2), which rationalizes the enhanced GB cohesion by carbides.

Influence of grain sizes and secondary phases on the mechanical behavior and corrosion resistance in a non-equiatomic NiCrCoFeMoAlTi high-entropy alloy

Single-phase face-center cubic (FCC) structured Ni27.7Cr24Co23.5Fe15.7Mo1.6Al3Ti4.5 high-entropy alloy (HEA) samples with different grain sizes were first achieved, suggesting smaller grain size improved corrosion resistance and strength. Subsequently, aging was performed on the sample with the smallest grain size (∼9.5 μm), leading to the formation of lots of nano-sized spherical coherent L12 precipitates at FCC grain interior, along with some σ phase and non-spherical L12 precipitates at grain boundaries. Therefore, a superior combination of mechanical and corrosion properties was achieved. Secondary phases caused chemical and structural changes in the passive film due to galvanized corrosion, leading to slightly lower corrosion resistance.

Microstructure and mechanical properties of laminated ferrous medium-entropy alloys fabricated by direct energy deposition and post-rolling annealing treatment

Laminated ferrous medium entropy alloy (Fe-MEAs), Fe75(CoCrNi)25/Fe60(CoCrNi)40, was successfully fabricated by direct energy deposition (DED). Due to the component mixing during DED process, a transition layer with face-centered cubic (FCC) and body-centered cubic (BCC) dual-phase was obtained in the Fe60(CoCrNi)40 layer after rolling and annealing. This dual-phase exhibits higher strength compared to a single FCC phase, thereby enhancing the overall strength of the material. During the deformation process of the laminated material, interface constraint will lead to high yield strength, resulting in performance superior to that predicted by the rule of mixtures. Moreover, the transition layer plays an important role in strain transferring and shows greater strain-hardening ability than the other two layers, enhancing the overall ductility of the laminated alloy.

Evolution process of T1 precipitate in Al–Cu–Li–TiC/TiB2 alloy during aging treatment

In this study, particle-reinforced aluminium matrix composites (PRAMCs) of an Al–Cu–Li alloy were prepared using nano-sized TiB₂+TiC particles. The relationship between TiB₂+TiC nanoparticles and T1 precipitates during the ageing process, as well as the influence of TiC + TiB₂ particles on the growth process of T1 precipitates during the ageing process, were investigated. The grain sizes of the A0 and A1 samples were found to be 249.89 μm and 86.42 μm, respectively. The dislocation density is greater in the deformed A1 sample. The coefficient of thermal expansion (CTE) effect generated by TiC and TiB₂ particles stimulates the precipitation process of T1 precipitates. The A1 alloy reached the peak ageing state in a shorter time and yielded a greater number of T1 precipitates. The precipitation process of T1 precipitate is: SSSS→T1P→T1. The transition from T1P (face-centered cubic, FCC) to T1 (hexagonal close packing, HCP) entails a modification in the order of packing. The recently formed T1P precipitate is attached to the established T1 precipitate and extends along the c-axis through the shared copper-rich layer that has formed on both sides of the mature T1 precipitate. The mechanical properties of sample A1 are optimal at T = 22h, with a yield strength, tensile strength, and elongation of 520 MPa, 553 MPa, and 8.2%, respectively. In comparison to the A0 sample, the yield strength and tensile strength exhibited an increase of 5.05% and 5.13%, respectively.

Effect of grain size on the deformation mechanism and fracture behavior of a non-equiatomic CoCrNi alloy with low stacking fault energy

Manipulation of stacking fault energy (SFE) plays a significant role in microstructure control and in turn mechanical properties of advanced alloys. In this work, we present the influence of grain size on the mechanical properties and fracture behavior of a non-equiatomic CoCrNi alloy with low SFE. Specimens with controlled grain sizes ranging from 0.61 to 6.4 µm were fabricated through rolling and annealing. A novel SFs-dominated plastic deformation mechanism was discovered. Tensile strength decreases monotonically with increasing grain size, while ductility achieves a peak value at the medium grain size, contradicting with the typical behavior observed in most single-phase face-centered cubic (FCC) metallic materials deformed primarily by dislocation slips and/or twinning. The fracture behavior changes from void coalescence to quasi cleavage with grain coarsening, and the fracture mechanisms were analyzed. Additionally, the evolution of SFs and phase transformation is explored at various deformation strains.

Laser clad CoCrFeNiTixNby hypoeutectic high-entropy alloy coating: Effects of Ti and Nb content on mechanical, wear and corrosion properties

High-entropy alloys (HEAs) exhibit significant potential for advanced wear and corrosion-resistant applications. This study investigates the influence of Ti and Nb doping on the microstructure, phase composition, and properties of CoCrFeNiTixNby HEAs synthesized using high-speed laser cladding (HLC). The results demonstrate that increasing Ti and Nb content transforms the coating structure from a face-centered cubic (FCC) phase to a hybrid structure comprising FCC, body-centered cubic (BCC), and Laves phases, leading to a linear enhancement in surface hardness. The incorporation of Ti and Nb not only promotes the preferred orientation of the FCC phase (111) crystal plane but also significantly enhances tensile strength, though this comes at the expense of reduced plasticity. Specifically, the CoCrFeNiTi0.6Nb0.15 coating attains an ideal balance between strength and ductility, with a tensile strength of 1641.8 MPa and a tensile strain of 15.9 %, achieved through the formation of a eutectic structure. This coating also exhibits superior wear resistance and outstanding corrosion resistance, which are attributed to the stability of the passivation film, reinforced by the (111) crystal plane and high-density dislocations. These findings provide both theoretical and empirical foundations for the design of high-performance HEAs, underscoring their potential in industrial applications requiring robust wear and corrosion resistance.

Microstructure refinement and wear resistance enhancement of cost-effective Fe50−2xMn30Co10Cr10NixCux (x = 0, 5 at%) high-entropy alloys through cyclic closed-die forging process

Novel low-cost Fe50−2xMn30Co10Cr10NixCux (x = 0, 5 at%) high-entropy alloys (HEAs) were produced by vacuum melting and then processed by the cyclic closed-die forging (CCDF) process. It was found that both the as-homogenized and CCDF-processed specimens primarily consisted of a single face-centered cubic (FCC) structure, and the severe plastic strain through CCDF did not result in phase transformations. The microstructure of the CCDF-processed Fe50Mn30Co10Cr10 alloy after the sixth pass demonstrated a uniform structure with ultrafine grains measuring 285 nm in size, whereas for the CCDF-processed Fe40Mn30Co10Cr10Ni5Cu5 alloy, the grain size was 135 nm, with a relatively uniform distribution. The CCDF-processed Fe50Mn30Co10Cr10 and especially the Fe40Mn30Co10Cr10Ni5Cu5 alloy exhibited significantly higher microhardness compared to the as-homogenized state, with microhardness values being 2.42 and 2.72 times higher, respectively. Furthermore, the wear test results indicated that the CCDF processing effectively increased the wear resistance of the alloys, which was attributed to the changes in morphology and distribution of as-cast dendrites, along with the grain refinement of the matrix phase during CCDF. The CCDF-processed Fe40Mn30Co10Cr10Ni5Cu5 alloy exhibited the lowest wear rate, i.e., (1.2 ± 0.2) × 10–5 mm3.N−1.m−1, whereas that for the Fe50Mn30Co10Cr10 alloy was (2.4 ± 0.1) × 10–5 mm3.N−1.m−1. Analysis of wear surfaces indicated that the wear mechanisms of the as-homogenized HEAs were adhesive wear and abrasive wear with some delamination, while plastic deformation and adhesive wear were significantly reduced in the CCDF-processed specimens, especially in the Fe40Mn30Co10Cr10Ni5Cu5 alloy. These findings suggest that CCDF has the potential to achieve cost-effective nanostructured HEAs and to implement them in engineering applications.

In Situ Investigation of Tensile Response for Inconel 718 Micro-Architected Materials Fabricated by Selective Laser Melting.

Topology optimization enables the design of advanced architected materials with tailored mechanical properties and optimal material distribution. This method can result in the production of parts with uniform mechanical properties, reducing anisotropy effects and addressing a critical challenge in metal additive manufacturing (AM). The current study aims to examine the micro-tensile response of Inconel 718 architected materials utilizing the Selective Laser Melting Technique. In this context, three novel architected materials, i.e., Octet, Schwarz Diamond (SD), and hybrid Schwarz Diamond and Face Centered Cubic (FCC), were tested in three different relative densities. The specimens were then subjected to uniaxial quasi-static tensile tests to determine their key mechanical properties, including elastic modulus, yield strength, and ultimate tensile strength (UTS), as well as the scaling laws describing the tensile response of each architected material. In situ Scanning Electron Microscopy (SEM) has been performed to observe the structure and grain morphology of the 3D printed specimens along with the phase transitions (elastic, plastic), the crack propagation, and the overall failure mechanisms. The results highlight the effect of the lattice type and the relative density on the mechanical properties of architected materials. Topologically optimized structures presented a 70-80% reduction in overall strength, while the SD and SD&FCC structures presented higher stretching dominated behavior, which was also verified by the n-value range (1-2) extracted from the identification of the scaling laws.