Fabrication Of Composite Materials Research Articles

Estimation of Tensile and Flexure Strength of Hybrid Composites along with Epoxy as Matrix and Jute & E-Glass as Reinforcements

The natural fibers have the good properties such as mechanical and physical than artificial fibers in a many cases during the fabrication of composite materials that are used in many engineering applications. Also hybridization of fibers leads to impotent of mechanical properties these composites used in interior of aerospace vehicles, automobiles bumpers, decorative items, window panels, interior paneling, etc. where application pf load is very less. This research work is concentrated on the evolution of hybrid composite of Jute/E-glass reinforced with matrix epoxy using Hand layup method. Laminated composites specimens are prepared by calculating the required number of fiber layers and quantity of matrix based on the different volume fraction. The testing specimens are prepared for Tensile and Bending test as per standard of ASTM. The Universal Testing Machine is used to conducted Tensile and Bending test and results are plotted the graphs.

Progress in MOFs and MOFs-Integrated MXenes as Electrode Modifiers for Energy Storage and Electrochemical Sensing Applications

The global energy demand and environmental pollution are the two major challenges of the present scenario. Recently, researchers focused on the preparation and investigation of catalysts for their capacitive properties for energy storage devices. Thus, supercapacitors have received extensive interest from researchers due to their promising energy storage features and decent cyclic stability/performance. The performance of the supercapacitors are significantly influenced by the physicochemical properties of the electrocatalyst. In this review article, we have compiled the previous reports on the fabrication of MOFs-based composite materials with MXenes for energy storage and electrochemical sensing applications. The metallic and bimetallic MOFs and MOFs/MXenes materials for supercapacitor applications are reviewed. In addition, MOFs/MXenes-based hybrid composites are also compiled towards the determination of various toxic/hazardous materials, such as metal ions like copper ions, mercury ions, and picric acid. We believe that present review article may benefit the researchers working on the preparation of MOFs-based catalysts for supercapacitor and electrochemical sensing applications.

Covalently grafting silane coupling agents onto MXene‐reinforced carbon fibers for epoxy composites with improved mechanical properties

AbstractTwo‐dimensional (2D) MXene (MX) and silane coupling agents are increasingly used to modify carbon materials for the fabrication of composite functional materials, which exhibit enhanced electrical, optical, and mechanical properties due to the synergistic effects of both MX and silane. We demonstrate the modification of carbon fibers (CFs) with MX and three different kinds of silane coupling agents, including 3‐aminopropyltriethoxysilane, 3‐glycidyloxypropyldimethoxymethylsilane, and 3‐mercaptopropyltriethoxysilane, which are named as CF‐MX@N, CF‐MX@O, and CF‐MX@S, respectively, and further prepare the CF‐MX@silane/epoxy (EP) composites. The utilized silane coupling agents serve as bridges between MX and CFs, forming CF‐MX@silane composites. Through comparative analysis, it is found that the CF‐MX@S composites form a strong interface phase through covalent bonds, significantly enhancing the interface compatibility and revealing strong interface adhesion. The interfacial shear strength of the molded CF‐MX@S/EP composites increases to 119.7 MPa, with an 173.9% enhancement comparing to unmodified composites. This work can offer useful guidance and reference for selecting appropriate silane coupling agent to modify CFs with 2D materials to form high‐performance composite materials.Highlights Silane coupling agents are used as bridges to graft MXene‐modified CFs The surface modification of CFs is achieved by a simple one‐step approach Excellent interfacial phase is constructed through forming strong covalent bonds Microstructure and failure interface are responsible to interface strengthen.

PH‐Tunable 3D Interconnected Network of Multiwalled Carbon Nanotubes /Polyacrylic Acid Hydrogel with Excellent Electromagnetic Radiation Shielding Capability

AbstractThe fabrication of durable and high anticorrosion hydrogel composite materials composed of multi‐walled carbon nanotubes (MCNTs) and crosslinked polyacrylic acid (PAA) for EMI shielding application is reported. The MCNTs contribute to the generation of 3D porous structures and enhance the mechanical properties of composite hydrogel. The 3D porous structure and high electrical conductivity inherited from ultrahigh electrically conductive MCNTs enable excellent EMI shielding properties with a total shielding efficiency EMI SE (SET) value of 32.8 dB (>99.9%) at only 3 wt% filler content of MCNTs. The MCNTs/PAA hydrogels also display superior EMI shielding performance under a strong acidic environment with SET > 99.99% while the 3D porous structure remained intact. The combination of electron–ion system in pH solution enriches the charge transfer and accumulation, enabling dipole orientation and polarization that are favorable for enhancing EMI attenuation. Moreover, the porous structure of MCNTs/PAA also contributes to partial trapping and dissipation of EM radiation energy via multiple scattering phenomena. This work thus paves the way toward applications of 3D hierarchical network materials for EMI shielding applications in both land and aqueous environments.

Microstructural characteristics and mechanical properties of 3D printed Kevlar fibre reinforced Onyx composite

Abstract The main objective of this study is to develop the Kevlar fibre reinforced Onyx composite (KFRO) material by employing the 3D printing technology and examine the effect of Kevlar fibre reinforcement percentage on microstructural characteristics and mechanical properties of developed composite material. The methodology of continuous fibre reinforced composites (CFRC) was followed and the Kevlar fibre reinforcement % was varied as 10 %, 20 % and 30 % in the composite material fabrication. Results disclosed that the KFRO composite 3D printed using 30 % Kevlar fibre reinforcement in Onyx matrix yielded greater tensile strength of 124 MPa, flexural strength of 105 MPa, impact toughness of 2.4 J and shore hardness of 76 D. The mechanical properties of KFRO composite were significantly improved at 20 % of Kevlar fibre reinforcement compared to 10 % of Kevlar fibre reinforcement. Further increase in Kevlar fibre reinforcement up to 30 % showed slight enhancement in mechanical properties of KFRO composite when compared to 20 % of Kevlar fibre reinforcement. The overall strength improvement is a result of the increased reinforcement, precise alignment of fibres in the loading direction, and the uniform distribution of fibres within the onyx.

Fabrication and Testing of Hybrid Polymer Composite Material by Using Carbon, Glass, Kevlar Fibers

Composites which made up of fiber reinforcements are universally endorsed option for the automobiles with a lightweight. Due to the unique properties of fiber-reinforced composites, it became a perfect alternative for traditionally used materials. Most of the automobile industries prefer polymer matrix fiber-reinforced composites for the reason that its light weight helps in carbon emission reduction and Additive manufacturing (AM) produces a complex shaped product from its data, layer by layer, with high precision and much less material wastage. As compared to the conventional manufacturing process, there are many positive environmental advantages of additive manufacturing technologies. Most importantly, there is less waste of raw material and the use of new and smart materials. In this work, we first focused on creating the composite material utilizing the Hand Lay-Up method with materials such as Carbon Fiber/Epoxy Composite with Copper Oxide (CuO) Nanoparticles and Banana Glass Fiber. Following that, we readied ASTMD638 specimens for both compressive and tensile testing. We created an ASTMD638 model for the investigation's tensile and compressive tests using Solid Works design program, and we then saved the design model in STL format. This STL format was uploaded into the CURA software for slicing. The slicing model was then saved into G-code format, and it was printed in a fused deposition modeling machine. Lastly, we tested both specimens using a compressive test setup in a Universal Testing Machine model (INSTRON-3369) UTM, and the results showed 3D printed files. Keywords: Glass Fiber, Banana Fiber, Carbon Fiber, Copper Oxide Nano filler, 3D printing Machine,Corbon Fiber Filament.

Banana pseudo-stem and cattle manure for lactic acid production and the application of polylactic acid-cellulose silver nanoparticle-based nanocomposite films in food storage

Lactic acid is used in various industrial processes, including the production of emulsifiers, polymers, cosmetics, and pharmaceuticals. Fermentation of renewable biomass from natural sources has several advantages over costly chemical methods. Thermal and acidic pretreatments were used to improve the availability of sugars in the medium. Bacillus coagulans was isolated from the banana pseudostem; it was cultured with cattle manure-banana pseudostem for the improved production of lactic acid. Lactic acid production was high in the culture medium containing a 1:1 ratio of cow manure and banana pseudostem after 72 h of fermentation. After 24 h, lactic acid production was 19.4 ± 1.2 g/kg substrate, and it increased after 48 h (20.5 ± 0.1 g/kg substrate), and 72 h (26.3 ± 0.1 g/kg substrate). Lactic acid synthesized by B. coagulans was purified and used for the synthesis of polylactic acid. Polylactic acid was used for the fabrication of composite materials with cellulose and silver nanoparticles. The scanning electron microscopy image showed a smooth surface with uniform particle sizes. The fabricated nanoparticles showed antibacterial activity against food spoilage bacteria. The film was used to pack goat meat and chicken meat. The fabricated film reduced the bacterial load in the stored meat and improved food quality.

Fabrication of Titanium Alloy-Based Composite Materials from Bimodal Powder Mixtures Ti–6Al–4V–(Cu–Al) by Direct Selective Laser Melting

Fabrication of Titanium Alloy-Based Composite Materials from Bimodal Powder Mixtures Ti–6Al–4V–(Cu–Al) by Direct Selective Laser Melting

A facile and green synthesis of poly-hydroquinoline analogues in aqueous medium by CeO2-FAp@MWCNT as recyclable catalyst

The fabrication of composite materials with different loading of titanium dioxide on hydroxyapatite (CeO2-FAp@MWCNT) has been described in detail. The morphological and structural characteristics of the samples were assessed by several techniques such as FT-IR, SEM, TEM, BET, and p-XRD analysis. A four-component procedure was used to create novel poly-hydroquinoline analogues, and the catalytic efficiency of these composite materials was studied. Cyclohexanedione, ethyl acetoacetate/benzyl 3-oxobutanoate, NH4OAc, and a variety of substituted aldehydes were used in one-pot reaction that was carried out in an aqueous medium under heating condition. The approach produced high product yields (93–98 %) quickly (within 15 min) at room temperature. In addition, we assessed the effectiveness of the separated catalyst, which exhibited stable catalytic activity for a maximum of seven runs. This environmentally friendly approach provides simple workup, quick reaction times, high yields, reusable catalysts, a gentle reaction environment, and purification without the need for column chromatography.

Multi‐objective optimization of 3D printing process parameters using gray‐based Taguchi for composite PLA parts

AbstractThis study investigates the additive manufacturing (AM) process of 30% ceramic‐reinforced composite PLA material using the fused deposition modeling (FDM) technique. The effects of various printing parameters on tensile strength, build time, and material consumption are comprehensively analyzed through a combination of the Taguchi method, analysis of variance (ANOVA), and gray relational analysis (GRA). Experimental design parameters include nozzle diameter, infill density, infill pattern, wall line count, print speed, and layer height. Statistical analyses reveal significant contributions of these parameters to mechanical properties and production efficiency. Single and multi‐objective optimizations of the responses were performed. The single optimization resulted in a significant increase in tensile strength from 39.9 to 48.10 MPa. Production time was reduced from 16 to 9 min; material consumption decreased from 4.95 to 2.43 g for tensile test specimens. The use of GRA in multi‐objective optimization has led to a significant improvement of 8.31% in the gray relational grade (GRG) when compared to the initial parameter settings. These findings provide valuable insights for optimizing FDM processes in the fabrication of composite PLA materials. This contributes towards the advancement of additive manufacturing technology and its applications across various industries. and its applications across various industries.Highlights Tensile strength increased while reducing build time and material consumption. Optimal printing parameters were identified for a composite PLA material. Layer height and nozzle diameter were effective parameters.

Zeolites and their composites as novel remediation agent for antibiotics: A review

Antibiotic residues in aquatic environments pose significant challenges when exceeding permissible limits. Zeolites, particularly aluminosilicate zeolites, have emerged as effective adsorption materials and solid substrates for semiconductor photocatalysts, facilitating the removal of antibiotics from wastewater. This review highlights the versatility of zeolites and their composites in antibiotic remediation, showcasing recent advancements in adsorption and photocatalytic degradation. Noteworthy examples include Fe (III)-modified synthetic zeolite 13X, exhibiting a maximum tetracycline adsorption capacity of approximately 200 mg/g, and MoS2@Zeolite achieving a remarkable efficiency of 396.70 mg/g for tetracycline removal. Additionally, zeolite-based photocatalysts like Fe-TiO2/BEA zeolite and exceptional CdS/CaFe2O4-clinoptilolite demonstrate high removal percentages, reaching 100% for tetracycline and 86% for cefazolin, respectively. The discussion encompasses an introduction to zeolites, including synthetic and natural zeolites, as well as techniques for modifying natural zeolites. It further delves into the production of synthetic zeolites as well as the fabrication of zeolite-based composite materials. These findings underscore the potential of zeolites and their composites as novel remediation agents for tackling antibiotic contamination in aquatic ecosystems, paving the way for sustainable wastewater treatment strategies. It highlights key elements, distinct qualities, and areas needing further research, paving the way for future studies.

Enhancing Composite Material Fabrication through Optimization: Employing Fruit Peel or Shell Powder as Reinforcements using Taguchi-GRA-PCA Methodology

Enhancing Composite Material Fabrication through Optimization: Employing Fruit Peel or Shell Powder as Reinforcements using Taguchi-GRA-PCA Methodology

Graphene-loaded recycled PET: Exploring and enhancing electrical conductivity through processing and laser treatments near the electrical percolation threshold

The blend of polyethylene terephthalate (PET), among the most employed polymer, with graphene, among the most adopted conductive carbon materials, may represent a favorable and sustainable approach for the fabrication of value-added conductive composite materials. This work targeted on the fabrication of melt-compounded composites via injection molding process starting from homemade recycled PET (r-PET) and different loadings of graphene nanoplatelets (GnPs) with different lateral sizes (5 and 25 μm, respectively), used as conductive fillers. Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) investigations of the different r-PET/GnP-based compounds provided information about composition, textural and structural properties of the melt-compounded specimens, which were correlated with their DC electrical properties. Graphene loadings higher than ca. 9.5–10 wt% were found enough to achieve the electrical percolation within the two material types. With higher graphene loadings, electrical conductivity increased, due to the formation of a progressively developed percolation network. Notably, the effects of the different GnP loadings, GnP lateral sizes and crystallinity degree of the polymer on the conductivity of the of the melt-compounded specimens were investigated. Furthermore, the effect on the electrical properties of CO2 laser irradiation at different scribing speeds on r-PET/GnP composites with graphene loading below the percolation threshold, was verified. By altering locally the morphology and structure, the irradiation process impacted the electrical properties. Notably, the resulting low sheet resistance suggests potential applications in low-power electronics. In brief, the approach and methodology adopted in the present work, along with the results, can contribute to the development of future upcycling into more valuable and sustainable conductive materials and devices based on recycled PET with a reduced environmental footprint.

Investigation of Fiber-Matrix Interface Strength via Single-Fiber Pull-Out Test in 3D-Printed Thermoset Composites: A Simplified Methodology.

The emergence of additive manufacturing technologies for fiber-reinforced thermoset composites has greatly bolstered their utilization, particularly within the aerospace industry. However, the ability to precisely measure the interface strength between the fiber and thermoset matrix in additively manufactured composites has been constrained by the cumbersome nature of single-fiber pull-out experiments and the need for costly instrumentation. This study aims to introduce a novel methodology for conducting single-fiber pull-out tests aimed at quantifying interface shear strength in additively manufactured thermoset composites. Our findings substantiate the viability of this approach, showcasing successful fiber embedding within composite test specimens and precise characterization of fiber pull-out strength using a conventional mechanical testing system. The test outcome revealed an average interfacial strength value of 2.4 MPa between carbon fiber and the thermoset epoxy matrix, aligning with similar studies in the existing literature. The outcome of this study offers an affordable and versatile test methodology to revolutionize composite material fabrication for superior mechanical performance.

Polybutylene adipate terephthalate (PBAT) composites for thermally conductive, fire retardant, high dielectric applications using BaTiO3 and MWCNTs as fillers

This study provides a comprehensive investigation of the fabrication of novel composite materials by blending polybutylene adipate terephthalate (PBAT) with barium titanate (BaTiO3) and multiwalled carbon nanotube (MWCNT) fillers. Prior to fabricating the composites, the filler surface treatments were tailored to enhance their compatibility with the PBAT matrix. Adipic acid (AA), a monomer for PBAT, was employed on the surface of the BaTiO3 particles, while butanediol (BD) also a monomer of PBAT was used to modify the surface of the MWCNTs to ensure effective interaction with the PBAT chains during the composite fabrication process. The composite samples were produced by melt-blending at 140 °C, followed by injection molding at the same operating temperature for subsequent analysis. The results revealed remarkable improvements in the dielectric constant, thermal conductivity, fire retardancy, and tensile strength of the 40 wt% BaTiO3 and MWCNT-PBAT blends compared to pure PBAT. The incorporation of BaTiO3 additionally contributed to enhanced fire retardancy, mechanical properties, and dielectric properties, making the composite material more resistant to ignition and flame spread, thus rendering it suitable for applications requiring elevated fire safety. In addition, the inclusion of MWCNT improved thermal conductivity, enabling promising and efficient heat dissipation in various applications.

Experimental Investigation and Analysis of Mechanical Properties of Chopped Strand Mat-E Glass Fiber Polyster Resin & Silica Powder Composites

Composite materials play a vital role in many industrial applications. Researchers are working on fabrication of new composite materials worldwide to enhance the applicability of these materials. In view of this the mechanical performance of the composite material is essential. The objective of the present work is to analyze the effect of Silica powders content on the mechanical behavior of woolen E-glass 350gm-Glass fiber reinforced. Five different types of composites are fabricated using 0%,2%,4%,6%,8%wt of Silica powders with woolen-E glass fiber and polyester resin. The polyester resin, catalyst and accelerator are mixed in 50:1:1weight ratio in polyester matrix Silica. The aim of the project is to investigate the effect of Silica powders with woolen e-glass 350gm for making the composite material stronger and tougher. The investigation is carried out by mixing different weight percentages of the Silica powders with the polyester resin and preparing individual samples. After woolen- eglass preparation, the materials were properly mixed using the hand-lay techniques and different specimens were prepared with different compositions of the Silica powders. After all the samples were prepared, mechanical tests were carried out on the samples to ascertain the changesobserved due to the composition of Silica powders. The obtained results of various samples specimens were compared and graphically charted to characterize the new composites material. Keywords: Chopped Strand Mat (CSM) 450 G M-Glass Fiber; Silica Powder; Polyester Resin;Hand-Lay;Catalyst;Accelerator.

A Mini-Review: Fabrication of Polysaccharide Composite Materials Based on Self-Assembled Chitin Nanofibers.

This mini-review presents the fabrication methods for polysaccharide composite materials that employ self-assembled chitin nanofibers (ChNFs) as functional components. Chitin is one of the most abundant polysaccharides in nature. However, it is mostly not utilized because of its poor feasibility and processability. Self-assembled ChNFs are efficiently obtained by a regenerative bottom-up process from chitin ion gels using an ionic liquid, 1-allyl-3-methylimodazolium bromide. This is accomplished by immersing the gels in methanol. The resulting dispersion is subjected to filtration to isolate the regenerated materials, producing ChNF films with a morphology defined by highly entangled nanofibers. The bundles are disintegrated by electrostatic repulsion among the amino groups on the ChNFs in aqueous acetic acid to produce thinner fibers known as scaled-down ChNFs. The self-assembled and scaled-down ChNFs are combined with other chitin components to fabricate chitin-based composite materials. ChNF-based composite materials are fabricated through combination with other polysaccharides.

Experimental Investigation and Analysis of Mechanical Properties of Chopped Strand Mat-E Glass Fiber Polyster Resin & Graphite Powder Composites

Composite materials play a vital role in many industrial applications. Researchers are working on fabrication of new composite materials worldwide to enhance the applicability of these materials. In view of this the mechanical performance of the composite material is essential. The objective of the present work is to analyze the effect of graphite powders content on the mechanical behavior of woolen E-glass 350gm-Glass fiber reinforced. Five different types of composites are fabricated using 0%,2%,4%,6%,8%wt of graphite powders with woolen-E glass fiber and polyester resin. The polyester resin, catalyst and accelerator are mixed in 50:1:1weight ratio in polyester matrix graphite. The aim of the project is to investigate the effect of graphite powders with woolen e-glass 350gm for making the composite material stronger and tougher. The investigation is carried out by mixing different weight percentages of the graphite powders with the polyester resin and preparing individual samples. After woolen- eglass preparation, the materials were properly mixed using the hand-lay techniques and different specimens were prepared with different compositions of the graphite powders. After all the samples were prepared, mechanical tests were carried out on the samples to ascertain the changesobserved due to the composition of graphite powders. The obtained results of various samples specimens were compared and graphically charted to characterize the new composites material. Keywords: MattE-Glass 350gm; Polyester resin; Graphite powders; Hand- Lay technique ; Catalyst & Accelerator.

Preparation and Characterization of Bismaleimide-Resin-Based Composite Materials.

This study utilized bismaleimide (BMI) resin, reinforced with introduced ether bonds, as a binding matrix, in combination with silicon carbide (SiC), for the fabrication of composite materials. A thorough investigation was conducted to assess the influence of diverse processing parameters on the mechanical properties and high-temperature thermo-oxidative stability of these composites. Experimental results indicate a notable improvement in the mechanical properties of the composites upon the incorporation of ether bonds, in contrast to their unmodified counterparts. The variation in performance among composites with different ratios and molding densities is apparent. Within a certain range, an increase in resin content and molding density is correlated with improved bending strength in the composites. With a resin content of 27.5 vol% and a molding density of 2.31 g/cm3, the composite achieved a maximum flexural strength of 109.52 MPa, representing a 24% increase compared to its pre-modification state. Even after exposure to high-temperature heat treatment, the composites displayed commendable mechanical properties compared to their pre-ether bond modification counterparts, maintaining 74.5% of the strength of the untreated composites at 300 °C. The scanning electron microscopy (SEM) microstructures of composite materials correlate remarkably well with their mechanical properties.

Manufacturing of bioinspired Bouligand structures using ultrasound assisted 3D printing

Materials with bioinspired Bouligand structures provide a new approach to explore isotropic fiber-reinforced composites. However, it is challenging to manufacture composites with various fibers along with a three-dimensional helical structure. In this work, to accomplish the alignment of a three-dimensional (3D) helical structure of fibers in a composite material, an acoustically aligned fiber technology was incorporated with a rotating mechanism in a stereolithography 3D printer. Firstly, the formation process of acoustic standing wave was simulated and the relationship between standing wave parameters and planar line arrays was then established. Secondly, Bouligand composites with various parameters were fabricated using an acoustic-assisted 3D printing technology and the effect of the angle between the interlayer fiber arrays on the mechanical properties was experimentally measured. Finally, heat sink and meniscus structures with Bouligand structure were fabricated using carbon nanofiber and glass nanofiber, respectively. The 3D printing processing method integrating acoustic alignment technology and rotating mechanism provides a new method for fabrication of composite materials with complex fiber structures.