External Magnetic Field Research Articles

Magnetic Field Effect on Photocatalytic Dye Degradation: A Review

AbstractIn the present day, photocatalysis has become the primary and most promising technology to generate renewable energy and degrade environmental pollutants. Remarkable efforts have been made to improve photocatalytic efficiency. Among these, introducing an external magnetic field is considered a promising strategy to boost photocatalytic performance. This review explores the dynamic realm of improving photocatalytic efficiency, with a particular emphasis on the strategic integration of external magnetic fields. Examining recent breakthroughs, we reviewed the influence of magnetic fields on diverse catalyst materials, including both magnetic and nonmagnetic variants, 2D materials, and semiconductors. Comprehensive coverage is provided on the mechanisms governing photocatalytic dye degradation, materials utilized for catalysis, and the profound impact of magnetic fields on enhancing reaction kinetics. This review also focuses on recent advances in the application and effect of magnetic fields in the magnetic and nonmagnetic catalysts towards dye degradation. This review provides a forward‐looking view, highlighting the potential of magnetic field‐enhanced photocatalysis to play a central role in sustainable energy and environmental management.

Superconducting diode effect and interference patterns in kagome CsV3Sb5.

The interplay among frustrated lattice geometry, non-trivial band topology and correlation yields rich quantum states of matter in kagome systems1,2. A series of recent members in this family, AV3Sb5 (A = K, Rb or Cs), exhibit a cascade of symmetry-breaking transitions3, involving the 3Q chiral charge ordering4-8, electronic nematicity9,10, roton pair density wave11 and superconductivity12. The nature of the superconducting order is yet to be resolved. Here we report an indication of dynamic superconducting domains with boundary supercurrents in intrinsic CsV3Sb5 flakes. The magnetic field-free superconducting diode effect is observed with polarity modulated by thermal histories, suggesting that there are dynamic superconducting order domains in a spontaneous time-reversal symmetry-breaking background. Strikingly, the critical current exhibits double-slit superconductivity interference patterns when subjected to an external magnetic field. The characteristics of the patterns are modulated by thermal cycling. These phenomena are proposed as a consequence of periodically modulated supercurrents flowing along certain domain boundaries constrained by fluxoid quantization. Our results imply a time-reversal symmetry-breaking superconducting order, opening a potential for exploring exotic physics, for example, Majorana zero modes, in this intriguing topological kagome system.

Barkhausen Noise as A Magnetic Nondestructive Testing Technique

Magnetic Barkhausen Noise (MBN) is a magnetic-based non-destructive electromagnetic testing method. Due to the electromagnetic working principle of MBN, it can be used for ferromagnetic materials, which consist of small magnetic fields discredited by domain walls and oriented in various directions. In an external magnetic field application, the fields turn to the magnetic direction, and the domain walls move and cause magnetic flux jumps. The jumps are named Barkhausen Noise (BN). The domain wall movements are sometimes pushed down by microstructure, composition, and defects. As the magnetic domain walls break away from the pinning sites produce MBN signal. MBN can be used for different material properties such as microstructure, composition, residual stress, and hardness. The paper's purpose is to analyze MBN as an improved NDT, clarify the relationship between material properties and MBN profile, and introduce MBN's applications and test equipment of MBN.

Analysis of the performance and microbial community of continuous dark fermentation combined with steady static magnetic field

The effect of external static magnetic field on hydrogen production and its mechanism were studied by continuous dark fermentation with no pretreatment excess sludge as inoculum. The results showed that under conditions of 37 ± 1 ℃, HRT 8 h, OLR 15 g/(L· d) and no control of influent pH, 78 mT external static magnetic field by adding magnets on both sides of the reactor could accelerate the enrichment of Ethanoligenens and improve the activity of reduced coenzyme I (96 %), ferredoxin oxidoreductase (29 %) and pyruvate: ferredoxin oxidoreductase (7 %) so that the maximum hydrogen productivity could reach 1.657 L H2/L, which was 5 times higher than that of non-magnetic group. Moreover, the n-caproic acid production could also increase due to the enrichment of carbon chain elongation microorganisms. The decline of hydrogen production was mainly due to hydrogenotrophic methanogenesis and acetic acid accumulation. This study was benefit to understand the interaction mechanism between magnetic field and microorganisms during the process of biological hydrogen production.

Development of Ni-Mn-Ga Enabled Micropumps for Hybrid Microdevices in Microelectromechanical Systems

This study selects a single crystalline Ni-Mn-Ga alloy by its exceptional actuator attributes, high actuation speed, precise position control, rapid response to external magnetic fields, and extended operational lifespan. Researchers venture into uncharted territory, aiming to harness the potential of Ni-Mn-Ga alloy to revolutionize micropump performance and refine fluid manipulation within miniature devices. The methodology at the heart of this endeavor involves the seamless integration of this specialized alloy with microdevice technology, giving rise to a set of unique pump components that substantially boost pump efficiency. Crucially, Ni-Mn-Ga is the chosen material for the active part of the micropump. At the same time, MEMS fabrication handles the passive elements, all facilitated by the 0.18 µm semiconductor technology and Sivalco TCAD simulation software. Computational simulations validate the alloy's suitability, impressively achieving an accumulated flow volume of 0.15 x 10e-4 µL in 10 microseconds. Beyond its scientific significance, this research bridges MEMS technology and magnetic-enabled smart materials, showcasing the remarkable capabilities of Ni-Mn-Ga alloy in significantly enhancing micropump performance. These innovative solutions promise to open doors to groundbreaking applications in microfluidic systems across many scientific and industrial domains.

Enhancing magnetic drug targeting efficiency through computational analysis: Investigating Particle-RBC interaction and non-newtonian blood behavior

Cancer stands as a foremost global mortality determinant, characterized by a persistent deficit in therapeutic modalities capable of reliably and efficiently conveying anti-cancer pharmaceutical agents to profound tissue loci. Within this context, magnetic drug targeting (MDT) has emerged as an innovative approach to cancer management, offering the promise of minimal adverse effects. Accordingly, the current investigation endeavors to evaluate the capture efficacy (CE) of drug-loaded nanoparticles under the influence of an external magnetic field. To this end, a cylindrical neodymium magnet (NdFeB) is employed as the magnetic source. The finite element method (FEM) was utilized to solve the governing equations. The effect of several parameters, including particle diameter, drag force, blood properties, magnetic field intensity, blood’s non-Newtonian behavior, and particle-RBC interaction on the CE of nanoparticles has been investigated. Simultaneous effect of interaction forces and non-Newtonian behavior of blood on the capturing nanoparticles at the tumor site is considered as the novelty of the present work. Taking into account these two parameters will provide more realistic results. Finding showed that the magnetic field intensity and particles’ diameter positively affect the nanoparticles’ CE. For example, by increasing particle diameter from 250 nm to 1500 nm, the CE is increased from 22 % to 53 %, respectively. In addition, it was revealed that consideration of the particle-red blood cell (RBC) interaction, on average, causes a decrease in the CE of nanoparticles by up to 20 %. Regarding the non-Newtonian behavior of blood, it was found that considering blood as non-Newtonian fluid would decrease, on average, 25 % of CE of nanoparticles compared to Newtonian fluid. Results revealed that simultaneous considering the non-Newtonian behavior of blood and interaction forces significantly affect the CE of nanoparticles.

Dichotomous dynamics of magnetic monopole fluids

A recent advance in the study of emergent magnetic monopoles was the discovery that monopole motion is restricted to dynamical fractal trajectories [J. N. Hallén et al., Science 378, 1218 (2022)], thus explaining the characteristics of magnetic monopole noise spectra [R. Dusad et al., Nature 571, 234 (2019); A. M. Samarakoon et al., Proc. Natl. Acad. Sci. U.S.A. 119, e2117453119 (2022)]. Here, we apply this novel theory to explore the dynamics of field-driven monopole currents, finding them composed of two quite distinct transport processes: initially swift fractal rearrangements of local monopole configurations followed by conventional monopole diffusion. This theory also predicts a characteristic frequency dependence of the dissipative loss angle for AC field-driven currents. To explore these novel perspectives on monopole transport, we introduce simultaneous monopole current control and measurement techniques using SQUID-based monopole current sensors. For the canonical material Dy2Ti2O7, we measure [Formula: see text], the time dependence of magnetic flux threading the sample when a net monopole current [Formula: see text] is generated by applying an external magnetic field [Formula: see text] These experiments find a sharp dichotomy of monopole currents, separated by their distinct relaxation time constants before and after t ~[Formula: see text] from monopole current initiation. Application of sinusoidal magnetic fields [Formula: see text] generates oscillating monopole currents whose loss angle [Formula: see text] exhibits a characteristic transition at frequency [Formula: see text] over the same temperature range. Finally, the magnetic noise power is also dichotomic, diminishing sharply after t ~[Formula: see text]. This complex phenomenology represents an unprecedented form of dynamical heterogeneity generated by the interplay of fractionalization and local spin configurational symmetry.

Synthesis, modifications, and applications of iron-based nanoparticles.

Magnetic nanoparticles (MNPs) are appealing materials as assistant to resolve environmental pollution issues and as recyclable catalysts for the oxidative degradation of resistant contaminants. Moreover, they can significantly influence the advancement of medical applications for imaging, diagnostics, medication administration, and biosensing. On the other hand, due to unique features, excellent biocompatibility, high curie temperatures and low cytotoxicity of the Iron-based nanoparticles, they have received increasing attention in recent years. Using an external magnetic field, in which the ferrite magnetic nanoparticles (FMNPs) in the reaction mixtures can be easily removed, make them more efficient approach than the conventional method for separating the catalyst particles by centrifugation or filtration. Ferrite magnetic nanoparticles (FMNPs) provide various advantages in food processing, environmental issues, pharmaceutical industry, sample preparation, wastewater management, water purification, illness therapy, identification of disease, tissue engineering, and biosensor creation for healthcare monitoring. Modification of FMNPs with the proper functional groups and surface modification techniques play a significant role in boosting their capability. Due to flexibility of FMNPs in functionalization and synthesis, it is possible to make customized FMNPs that can be utilized in variety of applications. This review focuses on synthesis, modifications, and applications of Iron-based nanoparticles.

Development and characterization of lipid nanocapsules loaded with iron oxide nanoparticles for magnetic targeting to the blood-brain barrier.

Brain drug delivery is severely hindered by the presence of the blood-brain barrier (BBB). Its functionality relies on the interactions of the brain endothelial cells with additional cellular constituents, including pericytes, astrocytes, neurons, or microglia. To boost brain drug delivery, nanomedicines have been designed to exploit distinct delivery strategies, including magnetically driven nanocarriers as a form of external physical targeting to the BBB. Herein, a lipid-based magnetic nanocarrier prepared by a low-energy method is first described. Magnetic nanocapsules with a hydrodynamic diameter of 256.7 ± 8.5nm (polydispersity index: 0.089 ± 0.034) and a ξ-potential of -30.4 ± 0.3mV were obtained. Transmission electron microscopy-energy dispersive X-ray spectroscopy analysis revealed efficient encapsulation of iron oxide nanoparticles within the oily core of the nanocapsules. Both thermogravimetric analysis and phenanthroline-based colorimetric assay showed that the iron oxide percentage in the final formulation was 12 wt.%, in agreement with vibrating sample magnetometry analysis, as the specific saturation magnetization of the magnetic nanocapsules was 12% that of the bare iron oxide nanoparticles. Magnetic nanocapsules were non-toxic in the range of 50-300μg/mL over 72h against both the human cerebral endothelial hCMEC/D3 and Human Brain Vascular Pericytes cell lines. Interestingly, higher uptake of magnetic nanocapsules in both cell types was evidenced in the presence of an external magnetic field than in the absence of it after 24h. This increase in nanocapsules uptake was also evidenced in pericytes after only 3h. Altogether, these results highlight the potential for magnetic targeting to the BBB of our formulation.

External static magnetic field mitigates nitrogen loss during agro-waste composting

Nitrogen is a crucial component in the composting process of agricultural waste and serves as a key nutrient source for organic fertilizer production. However, nitrogen loss during composting is inevitable, and how to retain it needs further investigation. The effects of static magnetic field on nitrogen conversion during agro-waste composting were explored. Results showed that low magnetic field intensity treatment reduced NH3 by 29.68 % but raised N2O by 1.57 %, while high intensity treatment reduced both NH3 and N2O by 3.51 % and 4.35 %, respectively. Pearson correlation analysis revealed that external static magnetic field regulated NH3 emission by affecting temperature, pH, electrical conductivity and NH4+-N, while modulated N2O emission by influencing moisture content, volatile solids, nxrA, nirK, norB, nosZ and NO2--N. The findings stated that external static magnetic field effectively reduced nitrogen loss, enhanced its retention and exhibited the potential to become an effective technical measure to promote nitrogen utilization during composting.

Biocompatible polyethersulfone membrane modified by hydrophilic polymer decorated magnetic nanoparticles gilded by facile external magnetic field

AbstractPolymer‐based membranes such as polyethersulfone are widely used for hemodialysis and bio‐related applications; however, this type of membrane still fails to satisfy optimum performance in terms of clearance, safety, and bio‐adaptability. Herein, a polymer brush of polyvinylpyrrolidone is decorated on the surface of magnetic nanoparticles by using reversible addition‐fragmentation chain transfer polymerization (RAFT), and under the guidance of an external magnetic field, the prepared magnetic nanoparticles with the polymer brush system are blended with a polyethersulfone membrane during a liquid‐liquid phase inversion process. The prepared membranes with different loads of the pure magnetic nanoparticle and polyvinylpyrrolidone@magnetic nanoparticle polymer brushes are prepared, compared with the pristine membrane, the modified membrane shows a high flux value at 349 L m−2 h−1 and 99.9% bovine serum albumin protein rejection. This membrane also demonstrated improved hydrophilicity and pore structure compared with the pristine membrane. Concerning the blood biocompatibility analysis, the modified membranes acquire prolonged time for clotting factors such as prothrombin time, activated partial thromboplastin time, and thrombin time while exhibiting less fibrinogen concertation at 0.4 g L−1. Furthermore, for the first time, an innovative method for fouling detection based on magnetic field attenuation due to protein accumulation on the membrane surface is reported; the method in this work could be a positive booster for the safe use of polymeric membranes in hemodialysis and bio‐based applications.

Constructing anisotropic bulk Ni/Pt nanocomposites to enhance transverse thermoelectric efficiency

Anisotropic bulk Ni/Pt nanocomposites were constructed by aligning Ni/Pt nanowires, combining the advantages of nanotechnology, spin Seebeck effect (SSE), and anomalous Nernst effect (ANE) to enhance thermoelectric performance. The thermoelectric power can be improved by increasing the ANE and SSE coefficient, enhancing the thermal resistance in the direction of heat flow, and improving the utilization efficiency of the Ni/Pt interface. The results demonstrated that the ANE and SSE volage (VANE+SSE) of Ni/Pt nanocomposites are larger than the ANE volage (VANE) in bulk Ni nanocomposite. When the external magnetic field is along the nanowire, the VANE+SSE is increased by a factor of 1.52 compared to its perpendicular orientation. This work provides a new idea to enhance SSE and ANE voltage by constructing anisotropic bulk nanocomposites, providing an opportunity for their application in thermoelectric devices.

Vibration behavior prediction of submerged nanobeams with axially traveling supports: numerical, analytical, and machine learning approaches

This work surveyed the vibration behavior and stability analysis of an underwater moving flexible nanosize beam, implementing numerical and analytical methods as well as tree-based machine learning (ML) algorithms. Dynamic modeling is performed based on the nonlocal stress-strain gradient theory (NSSGT), incorporating variable environmental conditions, surface energy, and rotational inertia effects. The natural frequencies and instability threshold are computed numerically. The exact closed-form mathematical expression for the critical towing velocity of the nanosize beam is determined analytically. Also, decision tree regression and least-squares boosting tree (LSBT) regression algorithms are exploited to predict stability boundaries and the fundamental vibration frequency, and their efficiency is surveyed accordingly. Comparative studies and parametric investigations are conducted. The impressions of geometry, added mass coefficient, scale ratio parameter, surface layer characteristics, fluid mass ratio, humidity, temperature rise, and external magnetic field intensity on the nanosystem dynamics are examined and illuminated. It is detected that the results of the analytical method and ML-based approaches are consistent with those reported by the numerical technique and literature. The results asserted that the proposed ML algorithms have acceptable performance and excellent effectiveness in computational time and cost. It is comprehended that the dynamic features of submerged traveling nanobeams drastically depend on the rotational inertia effects and thickness-dependent scale effects. The stability of the immersed movable nanoscale beams is perceived to improve by increasing the scale ratio parameter and the added mass coefficient. From the perspective of the optimal design of engineering instrumentation tools, the outcomes of the current article can be applied as an inclusive benchmark.

Magnetic phase diagrams and magnetocaloric effect of alternate layers of nanoborophene like: A Monte Carlo study

Here, we have investigated the magnetic properties and magnetocaloric effect of the alternate layers of nanoborophene like of a ferrimagnetic mixed spin 2 and 3/2 in a Blume–Capel model, employing the Monte Carlo method. The ground states at different parameters planes are found. Besides, we also determined the reduced compensation temperature and critical temperature to vary the number of layers (L). The impact of L, reduced exchange couplings Rσσ, RSσ, and reduced crystal field on the total magnetizations. In addition, the various parameters L, Rσσ, RSσ, and t also have distinct influences on the hysteresis loop are also analyzed. The Cp, -ΔSm, and ΔTa as a function of reduced temperature under the effect of several reduced external magnetic fields were discussed. Lastly, the impacts of the reduced external magnetic field on the relative cooling power were also studied. We hope that these results can be used as a basis for the application of materials, spintronics, energy storage, and magnetic refrigeration devices.

Comparison of Various Theoretical Measures of Aromaticity within Monosubstituted Benzene.

The effects of monosubstitution on the aromaticity of benzene are assessed using a number of different quantitative schemes. The ability of the mobile π-electrons to respond to an external magnetic field is evaluated using several variants of the NICS scheme which calculate the shielding of points along the axis perpendicular to the molecule. Another class of measures is related to the drive toward the uniformity of C-C bond lengths and strengths. Several energetic quantities are devised to approximate an aromatic stabilization energy and the tendency of the molecule to maintain planarity. There is a lack of consistency in that the various measures of aromaticity lead to differing conclusions as to the effects of substituents on the aromaticity of the ring.

Dual-mode rectangular microwave cavity for precision spectroscopy of hyperfine structure in muonium

Precision microwave spectroscopy of the ground-state hyperfine structure in muonium provides a stringent test of the Standard Model in particle physics. The MuSEUM collaboration is preparing for such a measurement, aiming for precision down to ≈1ppb, utilizing the world’s most intense pulsed muon beam at J-PARC. The measurement of the Zeeman-split structure with an external magnetic field of 1.7T also precisely determines the muon’s magnetic moment (≈10ppb). In the future, improved precision of the magnetic moment can be potentially obtained by measurements with different magnetic field strengths, however, it entails upgrading current cylindrical microwave cavities to rectangular ones. As the first step for the upgrade, we have developed a dual-mode rectangular cavity for the measurement with 2.9T field. The electromagnetic design and production have been established, and frequency sweeping with two desired modes has been successfully demonstrated. Moreover, the overall performance of the measurement at 2.9T field was evaluated with Monte Carlo simulations. These studies pave the way for a further extension of the MuSEUM experiment at various strengths of the magnetic fields.

Spin-polarization effects in the one-photon pair production in a supercritical magnetic field

A theoretical study is performed for the single-photon creation of an electron–positron pair in an external magnetic field. We present general expressions for process rates that are valid for arbitrarily high field strengths. Simple analytical expressions are obtained in the limiting cases of weak and strong fields. The emphasis is placed on the investigation of the spin alignment of the created particles as a function of the incident photon polarization and magnetic field strength. The obtained results show that the maximum value of the polarization degree of electrons (positrons) decreases in supercritical magnetic field.

Efficiency of magnetic zeolitic imidazolate framework-8 (ZIF-8) modified graphene oxide for lead adsorption.

Simple and efficient removal of Pb(II) ion from aqueous solution through adsorption has accelerated the development of many new composites to improve this popular method. In this study, the composites of graphene oxide (GO), zeolitic imidazolate framework-8 (ZIF-8), and magnetic materials were synthesized via coprecipitation method utilizing a different molar ratio between FeCl2 and FeCl3 of 1:0.5, 2:1, 3:1.5, and 4:2. The ZIF-8/GO was prepared via room temperature synthesis method prior to its further modification with magnetic materials for ease of separation. It was observed that the MZIF-8/GO2 of molar ratio 2:1 showed the best performance in adsorbing Pb(II) ion. As confirmed by FESEM image, it appeared to be ZIF-8 particles that have grown all over the GO platform and overlayed with Fe3O4 granular-shaped particles. The MZIF-8/GO2 successfully achieved 99% removal of Pb(II) within 10min. The optimum values obtained for the initial concentration of Pb (II) were 100mg/L, pH of 4 to 6, and adsorbent dosage used was 10mg. The Langmuir isotherm and the pseudo-second-order kinetic model were deemed suitable to evaluate the adsorption of Pb(II) using MZIF-8/GO2. Results showed that MZIF-8GO2 achieved a maximum adsorption capacity of 625mg/g of Pb(II) adsorption. All parent materials demonstrated a good synergistic effects, while exhibiting a significant contribution in providing active sites for Pb(II) adsorption. Therefore, this ternary composite of MZIF-8/GO2 is expected to be a promising adsorbent for Pb(II) adsorption from aqueous solution with an added value of ease of post phase separation using external magnetic field.

Field-Induced Slow Magnetization Relaxation of a Tetrahedral S=2 FeIIS4-Containing Complex.

In the work described herein, the spin relaxation properties of the mononuclear tetrahedral S = 2 [Fe{(SPiPr2)2N}2] complex (1) were studied by employing static and dynamic magnetic measurements al liquid helium temperatures. In the absence of an external direct current (DC) magnetic field, 1 exhibits fast magnetization relaxation. However, in the presence of external magnetic fields of a few kOe, slow relaxation is induced as monitored by alternating current (AC) magnetic susceptibility measurements up to 10 kHz, in the temperature range 2-5 K. Analysis of the temperature dependence of the corresponding relaxation time reveals contributions by Quantum Tunnelling of Magnetization, and the Direct and Orbach processes in the magnetization relaxation mechanism of 1. The energy barrier, Ueff, of the Orbach process, as determined by this analysis, is compared with that related to the zero field splitting parameters of 1 which were previously determined by high- frequency and -field electron paramagnetic resonance and Mössbauer spectroscopies.

Impact of heat and mass transfer on the magnetohydrodynamic two-phase flow of couple stress fluids through a porous walled curved channel using Homotopy Analysis Method

The analysis of heat and mass transfer in the movement of immiscible couple stress fluids through a curved channel whose walls are at two different temperatures is the focus of the current work. Immiscible fluids are subjected to an external magnetic field that is taken normal to the fluid’s flow. For suction or injection in the flow, the channel walls are presumed to be porous. The buoyancy force, which is modelled using the Boussinesq approximation, and a constant pressure gradient cause the flow of the couple stress fluids in the curved channel. The highly non-linear coupled differential equations associated with the proposed work are solved with the use of the semi-analytic Homotopy Analysis Method. The semi-analytical expression of the various flow variables such as flow velocity, temperature, concentration, etc. is obtained by solving these non-linear differential equations after they have been non-dimensionalized by taking into account non-dimensional parameters. From the obtained results authors have noted how the two immiscible couple stress fluids’ flow velocity, temperature, and concentration behaviour depend on the flow-effecting parameters, including the couple stress parameter, curvature parameter, Schmidt number, and so on. Further, the authors of the proposed work have analysed the effect of various flow parameters on heat and mass transfer. Since the authors have studied the two-phase flow of couple stress fluids in a porous walled curved channel together with the effect of magnetic field, the current model has various applications in the fields of crude oil extraction, filtration, nuclear reactor, and bio-mechanics.