Extensive Partial Melting Research Articles

From onset of Cadomian subduction to forearc-arc-continent collision: Insights from the Neoproterozoic Calzadilla Metaophiolite (SW Iberia)

ABSTRACT The Cadomian basement of SW Iberian Massif appears in the so-called Ossa-Morena Complex, which contains several allochthonous terranes that are key for deciphering the evolution of the Gondwana margin during the Neoproterozoic. In this context, the Calzadilla Ophiolite represents the remnants of an oceanic Ediacaran lithosphere formed by a boninitic mafic crust that overlies a serpentinized ultramafic section, the latter being the biggest outcrop of Cadomian serpentinites in Europe. In this work, the petrological and geochemical nature of the mantle section is analysed, as well as the tectonothermal evolution of both, the mafic crust and the ultramafic section. The algebraic analysis of whole rock geochemistry of the serpentinites indicates that the protolith corresponds to harzburgite. The geochemical fingerprint of the serpentinites, as well as the primary spinel crystals composition, shows that peridotites underwent high degrees of partial melting (up to 16%) in a forearc setting. Thermodynamic modelling and average PT methods were applied to serpentinites and mafic dykes from the ultramafic section as well as to amphibolites from the mafic section, both of which experienced progradation up to 4–5 kbar and 525–575°C. According to the data, the protoliths of the Calzadilla Ophiolite were formed in a peri-Gondwanan arc system developed during the subduction of oceanic crust below Gondwana. The roll-back of the subducting slab would induce the opening of the forearc basin at c. 602 Ma, protolith age of amphibolites from crustal section, with an extensive partial melting of the mantle wedge and the formation of boninitic-affinity magmas that constitute the mafic section of the Calzadilla Ophiolite. Metasomatism and serpentinization of the mantle wedge would occur via melt- and fluid–rock interactions. A compression-dominated stage at c. 540 led to the emplacement of the Calzadilla Ophiolite onto the Cadomian magmatic arc, with the development of the amphibolite-facies metamorphic imprint.

Records of the accretionary, collisional and post-collisional evolution of western Gondwana in the high-grade core of the Araçuaí-Ribeira orogenic system, SE Brazil

High-grade metamorphism, extensive partial melting, and polyphase deformation often obliterate records of pre-collisional stages in ancient orogens, making it hard to unravel Precambrian accretionary events. In western Gondwana, the high-grade core of the Araçuaí-Ribeira Orogenic System (AROS) comprises pre-collisional rock-assemblages largely disrupted, overprinted, and remelted by collisional and post-collisional tectono-metamorphic and igneous events, hampering reconstructions of its accretionary history. Detailed studies reveled remnants of an Early Tonian (860–840 Ma) island arc, forming km-size roof-pendants and mega-xenoliths within the composite Caxixe batholith, in the boundary zone between the Araçuaí and Ribeira orogens. We further characterize the Caxixe batholith and surrounding plutons, showing that the main stage of magmatism is composed of pre-collisional orthogneisses, partially migmatized and crystallized between ca. 607–580 Ma, thus, much later than the Tonian island arc records. Those Ediacaran granitic rocks represent intrusions of calc-alkaline magmas with elemental geochemistry and isotopic (εHf(t): −6 to −10, whole-rock εNd(t): −4.9 to −9.5, and 87Sr/86Sr(i): 0.706–0.711) data correlated with the continental-margin Rio Doce arc. This contrasts with signatures indicative of a mantle source εHf(t) = +10 to + 14, εNd(t) = +0.9 to + 6.4, and 87Sr/86Sr(i) = 0.698–0.704) of the Early Tonian arc remnants. Intruding the pre-collisional granitic plutons, garnet-bearing leucogranites dated at ca. 575 Ma and a mafic intrusion of ca. 560 Ma mark the transition from the syn-collisional to late-collisional stages. Post-collisional, non-deformed, A-type granites with the most evolved isotopic signatures (εHf(t): −22; εNd(t): −5.6 to −13.2) intruded at ca. 500 Ma, ending the long-lasting orogenic history documented in the region. Our results demonstrate that a basement composed of an early Tonian juvenile arc docked with a continental margin and hosted several intrusions of an early Ediacaran continental-margin magmatic arc that, in turn, were intruded by collisional and post-collisional magmas from the Late Ediacaran to Cambrian, finally forming the main plutonic masses of the Araçuaí-Ribeira Orogenic System (AROS) core, during the complex history of western Gondwana assembly.

Coexisting High-Al and High-Cr Chromitites in the Dingqing Ophiolite (SE Tibet): Inferences to Compositional Heterogeneity in the Tethyan Upper Mantle

The Dingqing ophiolite represents a significant allochthonous ophiolite nappe in the eastern segment of the Bangong–Nujiang suture zone in southeastern Tibet. The microanalytical data of associated podiform chromitites classify them into two distinct varieties: high-Al and high-Cr. The coexistence of both high-Cr and high-Al chromitites in the Dingqing ophiolite suggests a complex or multistage evolutionary history of the host rocks. New petrological and geochemical analyses are used herein to unravel the interrelationships between the chromitite ores and host rocks and assess the mechanism of formation. The Dingqing ophiolitic nappe is made up mainly of harzburgite, dunite, and less abundant pyroxenite and gabbro. Several small lens-shaped bodies of chromitite ore are mostly confined to the harzburgite rocks, with ore textures varying from massive to sparsely disseminated chromite. In addition to magnesiochromite, the orebodies contain minor amounts of olivine, amphibole, and serpentine. The textural relationships provide compelling evidence of plastic deformation and partial melting of the associated peridotites. Detailed examination of the Cr-spinel grains reveals a wide range of composition, spanning from high-Al (Cr# = 3.18–59.5) to high-Cr (Cr# 60.3–87.32). The abundances of the platinum-group element (PGE) in chromitites are significantly variable (93 to 274 ppb). Formation of the Dingqing peridotites most likely took place in a mid-ocean ridge (MOR) setting, and subsequent modifications by supra-subduction zone (SSZ) melts resulted in heterogenous or mixed geochemical characteristics of these rocks. Chemistry of the spinel–olivine–clinopyroxene assemblage demonstrates multiple stages of partial melting of the source mantle rocks, including an early phase of restricted partial melting (~20%–30%) and a later phase of extensive partial melting (>40%). The formation of the high-Al chromitite type was associated with the early phase (constrained melting), whereas extensive partial melting in the late stages likely led to the accumulation of high-Cr podiform chromitite bodies.

Variation in technical properties of granitic rocks with metamorphic conditions

Granitic rocks constitute a global raw material key asset for aggregate production. Their technical performance is, however, highly variable and knowledge on the aggregate functionality of granites in different geological settings is incomplete. This study investigates systematic variations in resistance to fragmentation (Los Angeles value) and wear (Micro-Deval value) for granitic rocks along a 150 km long east–west trending metamorphic gradient across the Eastern Segment of the Sveconorwegian Province in Scandinavia. In essence, the metamorphic gradient represents a transition from pristine granite to stromatic migmatitic orthogneiss and granulite. Along this profile, the aggregate functionality is governed by the behaviour of quartz and feldspar during metamorphic recrystallisation. Two critical metamorphic variables were identified: temperature and hydrous fluids. Recrystallisation at comparably low metamorphic temperatures, ≤ 600 °C, result in irregular grain shapes and fine-grained quartz aggregates that in turn result in low Los Angeles and Micro-Deval values, i.e., high-quality materials for road construction. At higher metamorphic temperatures, > 600 °C, grain coarsening and smoothening of grain boundaries result in significantly higher Los Angeles and Micro-Deval values. At high temperatures, high availability of hydrous fluids promoted extensive partial melting and post-deformational crystallisation which resulted in remarkably poor aggregate performance, with Los Angeles and Micro-Deval values consistently above 40% and 12%, respectively. In contrast, deformation at high temperature but low availability of hydrous fluids resulted in inequigranular textures with high proportions of very fine-sized crystals, interlocking textures, and aggregates with Los Angeles and Micro-Deval values down to 19% and 5%. The consistent variation in metamorphic microtextures correlate with macro-fabrics at the outcrop scale, allowing assessment of aggregate functionality already in the field. For migmatitic gneisses, the proportion and strain state of leucosome are the most critical parameters.

The largest plagiogranite on Earth formed by re-melting of juvenile proto-continental crust

The growth of continental crust through melt extraction from the mantle is a critical component of the chemical evolution of the Earth and the development of plate tectonics. However, the mechanisms involved remain debated. Here, we conduct petrological and geochemical analyses on a large (up to 5000 km2) granitoid body in the Arabian-Nubian shield near El-Shadli, Egypt. We identify these rocks as the largest known plagiogranitic complex on Earth, which shares characteristics such as low potassium, high sodium and flat rare earth element chondrite-normalized patterns with spatially associated gabbroic rocks. The hafnium isotopic compositions of zircon indicate a juvenile source for the magma. However, low zircon δ18O values suggest interaction with hydrothermal fluids. We propose that the El-Shadli plagiogranites were produced by extensive partial melting of juvenile, previously accreted oceanic crust and that this previously overlooked mechanism for the formation of plagiogranite is also responsible for the transformation of juvenile crust into a chemically stratified continental crust.

Mineralogical and isotopic peculiarities of high-Cr chromitites: Implications for a mantle convection genesis of the Bulqiza ophiolite

Submicroscopic to micro-diamonds, silicates, wüstite, platinum group minerals (PGM), sulfides and ultra-high pressure (UHP) mineral inclusions have been recovered from podiform and banded chromitites of the Bulqiza ophiolite in Albania. The alignment of acicular silicate inclusions with crystallographic planes of magnesiochromite suggests an exsolution origin. Positive and negative-crystal faces of cubic silicate inclusions are consistent withs a high-temperature paragenesis.Micro-inclusions and nanoparticles (<500 nm) of RuOs bisulfides (laurite; RuS2), OsIr, and Os-Ir-Ru alloys, tolovike, irarsite, IrNi sulfides, and millerite (NiS) are also common in the Bulqiza chromitites. Dispersed spherical, nano-inclusions of IrPt and OsIr may reflect formation of the IrPt and OsIr particles by sulfide liquid immiscibility. The high Cr# of the chromitites, their evolved whole-rock PGE abundances, and IPGE/PPGE ratios (≥ 10) suggest extensive partial melting, likely in a supra-subduction zone (SSZ) environment. This interpretation is supported by the variable 187Re/188Os (0.0103–0.0271) and 187Os/188Os (0.12600–0.13014) ratios and the low γOs isotope values (mean + 0.01) of the chromitites, reflecting derivation from heterogeneously depleted mantle materials. The presence of remarkably zoned zircons with UPb ages (164–3354 Ma) represents the addition of crustal materials.Discrete micro-diamonds, PGM, and sulfide inclusions point to a super-reducing (SuR), ultra-high pressure (UHP) origin. We propose a genetic model that involves incorporation of crustal and UHP phases into the mantle by convection or subduction. The UHP and crustal silicates are consistent with a subduction-related origin, but the presence of super-reduced (SuR) inclusions suggests equilibration under subduction-disparate mantle conditions.

Geochemical and metamorphic record of the amphibolites from the Tuting–Tidding Suture Zone ophiolites, Eastern Himalaya, India: implications for the presence of a dismembered metamorphic sole

AbstractThe Tuting–Tidding Suture Zone (TTSZ), exposed along Dibang and Lohit river valleys in Arunachal Himalaya, NE India, is the easternmost continuation of the Indus–Tsangpo Suture Zone (ITSZ) and consists of ophiolites associated with metabasics and carbonates. Amphibolites, existing at the base of the ophiolite complex, were studied using whole-rock, mineral chemical analyses and pressure–temperature (P-T) pseudosection modelling to understand their metamorphic and petrogenetic history, and interpret the tectonic environment of their formation. They exhibit two-stage deformation, where D1 is depicted by polymineralic inclusion trails in former melt pools and the main foliation represents D2. Sub-alkaline tholeiitic character, high-field-strength element (HFSE) ratios and mid-oceanic ridge basalt (MORB) -like rare earth element (REE) patterns with negative Eu anomaly indicate that the protolith of these amphibolites originated in a spreading regime by extensive partial melting of a depleted mantle source at shallow depth. Petrography, mineral chemistry and P-T modelling indicate a three-stage metamorphic history for them. M1 is the prograde (c. 2.1 GPa, c. 450°C) defined by garnet centre compositions corresponding to the D1 event. The existence of former melts in the samples demarcates the M2 stage (1.4–1.8 GPa, c. 600°C). The rocks later underwent retrogression (M3: 0.8–1.0 GPa, 480–520°C), which corresponds to the D2 event. These observations suggest that the protolith of the TTSZ amphibolites originated in a mid-oceanic ridge setting, which accreted below a subduction zone where it underwent M1 metamorphism followed by M2 metamorphism, corresponding to partial melting of the rocks. Finally, the M3 event occurred during the obduction phase of the ophiolite complex, where the amphibolites were obducted as the metamorphic sole of the TTSZ ophiolites.

Tectonic implications of juxtaposed high- and low-pressure metamorphic field gradient rocks in the Turvo-Cajati Formation, Curitiba Terrane, Ribeira Belt, Brazil

The Turvo-Cajati Formation (TCF) is an important unit forming the Curitiba Terrane, a major segment of the southern Ribeira Belt, SE Brazil. It is composed of rocks of greenschist (LTCF), amphibolite (MTCF) and granulite (HTCF) facies conditions. Previous studies in the HTCF indicate that the unit underwent extensive partial melting under high-pressure conditions (670–810 °C and 9.5–12 kbar), within the kyanite stability field. In this paper, a study of the metamorphic zoning within the LTCF and MTCF is undertaken using pseudosection modeling in the NCKFMASHTO and MnNCKFMASHTO model systems coupled with detrital zircon U–Pb geochronology. Four metamorphic zones are recognized for the LTCF and MTCF: biotite, garnet, staurolite and sillimanite zones, with predominance of sillimanite zone and pressures lower than 8 kbar, as staurolite breaks down straight to sillimanite, without formation of a kyanite zone. Pseudosections yielded metamorphic peak conditions of ~530–560 °C and ~6–7.5 kbar (garnet zone) and ~660–690 °C and ~6–7.5 kbar (sillimanite zone). The metamorphic field gradient is flat and of low to medium pressure, below the typical Barrovian-type baric regime, and different from the HTCF. Available petrological and geochronological data suggest that the TCF comprises a paired low-P and high-P metamorphic belt, associated with a major Ediacaran suture zone in the southern Ribeira Belt. Probability density plots from detrital zircon U–Pb ages indicate late-Cryogenian-Ediacaran arc-related and Rhyacian sources for all TCF sub-units. This scenario suggests that the TCF is made up of a collisional juxtaposition of an accretionary wedge (HTCF) and a back-arc basin (LTCF and MTCF) on the border of a microplate, which includes a Rhyacian basement microcontinent, the Atuba Complex. It is inferred the high metamorphic gradient recorded in the LTCF and MTCF was related with asthenospheric upwelling in the back-arc region, which also produced extensive partial melting in the Atuba Complex basement.

Genesis and geodynamic evolution of serpentinized ultramafics and associated magnesite deposits in the Al-Wask ophiolite, Arabian Shield, Saudi Arabia

Situated along the Yanbu Suture Zone, the Al-Wask ophiolite is one of the largest and best-preserved ophiolite sequences in the Proterozoic Arabian shield. A mantle section of serpentinized ultramafics is structurally overlain by a crustal section of gabbros and pillow lavas. The whole ophiolite sequence is capped by pelagic sedimentary cover, and tectonically emplaced over a metamorphosed island-arc volcano-sedimentary succession. The Al-Wask ultramafic rocks are strongly deformed, metamorphosed, and altered by carbonatization and silicification. Samples dominated by antigorite indicate upper greenschist to lower amphibolite facies peak metamorphic grade, whereas samples dominated by lizardite and magnesite preserve lower grade conditions that we interpret as a cooling path buffered to low CO₂ activity by the increasing stability of magnesite with decreasing temperature. Nearly all the primary silicate minerals have been replaced by serpentine minerals, leaving only relics of primary olivine and chromian spinel. Petrographic observation of relict olivine and spinel and of mesh and bastite textures in the serpentines suggest that the peridotite protoliths were mainly harzburgite with minor dunite. Whole-rock compositions of serpentinites show low CaO (&lt;0.1 wt.%), Al₂O₃ (&lt;1.5 wt.%), and Y (&lt;0.4 ppm) combined with high Mg# (0.90–0.92), Ni, Co, and Cr contents; all these indicate a highly refractory mantle protolith. The mineral chemistry of relict primary spinel and olivine provides additional petrogenetic and geodynamic indicators. The high Cr# (&gt; 60) and low TiO₂ (≤0.2 wt. %) of spinel and high forsterite contents (90–92) of associated olivine indicate residual mantle that underwent extensive partial melt extraction. The whole-rock and mineral chemistry of the serpentinized ultramafic rocks are both consistent with extracted melt fractions from ∼32 to 38 percent. This extent of melting is typical of fore-arc supra-subduction zone settings, which is the most likely tectonic environment for formation and preservation of the Al-Wask ophiolite. Two types of magnesite deposits can be distinguished in the Al-Wask mantle section: an early generation of massive magnesite and a later generation of magnesite veins. Hence the Al-Wask ophiolite underwent multiple stages of carbonatization, likely involving different sources of CO₂-bearing fluids. The massive magnesite likely formed at relatively high temperature during cooling from peak metamorphic condition from CO₂-bearing fluid probably derived from decomposition of subducted carbonates. Using thermodynamic calculations in the simple MgO-SiO₂-H₂O-CO₂ system, we constrain the path of the reaction boundary where lizardite and magnesite can coexist at equilibrium. On the other hand, the cryptocrystalline magnesite veins fill tectonic fractures and likely formed at low temperature and shallow levels, after serpentinization and ophiolite obduction.

Hafnium isotopic record of mantle-crust interaction in an evolving continental magmatic system

Tracing the origin and evolution of magmas on their pathway through the lithosphere is key to understanding the magmatic processes that eventually produce eruptions. For ancient magmatic provinces, isotope-geochemical tracers are powerful tools to probe the source regions and magma-crust interaction during ascent and storage. Here we present hafnium isotopic compositions of ID-TIMS dated zircons to trace the evolution of the Middle Triassic magmatic province in the Southern Alps (northern Italy) at high temporal resolution. Systematic changes in hafnium isotopic composition with time record progressively stronger crustal assimilation over 3.5 million years, followed by a rapid increase in εHf towards more juvenile compositions for the major pulse of mafic intrusions and post-intrusive volcanic ash beds within one million years. We interpret these trends to reflect variations in mantle-crust interaction through time. Initial intrusions of basaltic dykes into the relatively cold lower crust cause only limited crustal melting and assimilation but an ensuing magma injection into progressively hotter crust results in more extensive partial melting and assimilation of crustal material. Subsequent intrusions into the magmatic lower-crustal roots cannibalize previous intrusions with progressively less isotopic contrast due to dilution with mantle-derived magmas. This is potentially accompanied by an increase in magma flux due to delamination of dense lower crustal cumulates into the subcontinental lithospheric mantle. The observed trends in hafnium isotopic composition therefore do not necessarily require tectonic re-organizations or changes in mantle sources. Instead these trends may trace variations in mantle-crust interaction during thermally induced chemical maturation of the lower crustal magmatic roots progressively replacing ancient pelitic to mafic lower crustal lithologies by juvenile cumulates.

Genesis of high-potassium calc-alkaline peraluminous I-type granite: New insights from the Gaoligong belt granites in southeastern Tibet Plateau

Silicic magmas, primarily felsic I- and S-type granite (sensu lato), play a key role in understanding the compositional evolution and differentiation of the continental crust. However, the genetic models of felsic I-type granites remain controversial. Herein we investigate the Gaoligong granite (sensu lato) belt in southern Tibet and compare its features with an extensive dataset that we compiled on high‑potassium calc-alkaline peraluminous I-type granite from typical granitic belts around the word with a view to gain insights on the genesis of felsic I-type granites. The Early-Cretaceous granites from Gaoligong belt mostly belong to high-K calc-alkaline peraluminous I-type series. Zircon LuHf (εHf(t) = −16.3 – +0.9) and whole-rock SrNd isotopic data (εNd(t) = −14.6 – +3.0) on these rocks show highly variable and evolved nature, suggesting that the granites were generated by partial melting of lower crustal materials with possible involvement of upper crustal materials, followed by mixing, leading to marked variation in source compositions.Compilation of the dataset and comparison with felsic I- and S-type granites show the following salient features: (1) possibly distinct trends of Al2O3, P2O5, K2O, Rb, Sr, Pb, Th, U and Ga vs. MgO + FeOT between the felsic I-type granites and those S-types; and (2) there are notably higher and variable zircon Hf (εHf(t) > 10ε units) and whole-rock SrNd (εNd(t) > 5ε units) isotopic compositions of I-type granites than those of the S-types. Comparison with experimental liquids and other typical cases around the world, indicate that the felsic I-type granites from Gaoligong are similar to those secondary I-type granites, where mixing processes and extensive partial melting of the heterogeneous lower crust by a mantle-like magma control the variable components. The range of compositional diversity is significantly higher for the studied felsic I-type granites than those typical S-type granites from north Queensland. Our study provides further insights into the application of geochemical and isotopic proxies to differentiate felsic I- and S-type granites.

Early Paleozoic Granite in the Talate Mining District, Chinese Altay, and its Geological Significance for the Altay Orogenic Belt

Zircon dating, geochemical and Nd‐Sr isotopic analyses have been determined for samples from two granitic intrusions in the Talate mining district, Chinese Altay. Our data suggest that these intrusions were emplaced from 462.5 Ma to 457.8 Ma. These rocks have strong affinity to peralumious S‐type granite and are characterized by prominent negative Eu anomalies (δEu=0.20–0.35), strong depletion in Ba, Sr, P, Ti, Nb, Ta and positive anomalies in Rb, Th, U, K, La, Nd, Zr, Hf. Nd‐Sr isotopic compositions of the whole rock show negative ∊Nd(t) values (−1.21 to −0.08) and Mesoproterozoic Nd model ages (T2DM=1.20–1.30 Ga). Their precursor magmas were likely derived from the partial dehydration melting of Mesoproterozoic mica‐rich pelitic sources and mixed with minor mantle‐derived components, under relatively low P (≤1 kbar) and high T (746–796°C) conditions. A ridge subduction model may account for the early Paleozoic geodynamic process with mantle‐derived magmas caused by Ordovician ridge subduction and the opening of a slab window underplated and/or intraplated in the middle–upper crust, which triggered extensive partial melting of the shallow crust to generate diverse igneous rocks, and provided the heat for the crustal melting and juvenile materials for crustal growth.

Refining the timing and mechanism of the Triassic partial melting in the Sulu UHP orogen, China: Zircon and garnet evidence from a felsic vein and its host granitic gneiss

Partial melting of high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic rocks in subduction zones has great influence on both the chemical and physical properties of deeply subducted continental crust. Felsic veins in HP-UHP metamorphic rocks are products of partial melting and thus would be a key target to trace partial melting in HP-UHP terranes. This contribution is an integrated study of petrology, zircon and titanite U-Pb ages, as well as zircon Hf-O and major minerals O isotope compositions for a felsic vein and its host granitic gneiss in the Sulu UHP terrane to decipher the timing and mechanism of partial melting. Zircon U-Pb dating for the inherited magmatic zircon cores of the granitic gneiss constrains the protolith age at ca. 750 Ma. The inherited zircons had an average δ18O value of 0.03 ± 0.15‰ and yielded a weighted mean εHf(t) value of −1.16 ± 0.54 and two-stage Hf model ages of 1707 ± 65 Ma. These results suggest that the protolith was derived from reworking of Paleoproterozoic crust in a Neoproterozoic rift. In the two samples, broad garnet core/mantle domains are of metamorphic origin and narrow garnet rims of peritectic origin. There are large differences in δ18O values between the protolith magmatic zircon (δ18O = 0.03 ± 0.15‰) and metamorphic garnet (−4.14 ± 0.21‰ for the felsic vein and −4.13 ± 0.11‰ for the host granitic gneiss), suggesting that the negative δ18O fingerprints might result from hydrothermal alteration or multi-episodes of rift magmatism after the formation of the protolith. Zircon from the felsic vein yielded a U-Pb age of 212 ± 3 Ma. Titanites from the two studied samples show undistinguishable U-Pb ages of 227 ± 14 Ma and 212 ± 6 Ma within the analytical uncertainties. These ages register the timings of the partial melting. The approximately consistent δ18O values of the metamorphic zircon (−4.78 ± 0.15‰) and metamorphic garnet indicate that the melt was sourced from the surrounded gneiss in a closed system, which might be triggered by breakdown of phengite. According to a compilation of partial melting in the Sulu UHP terrane, there exists a clear spatio-temporal variation. The ca. 237-224 Ma partial melting in the northern UHP zone might be due to its relatively high temperature metamorphism; the most extensive partial melting occurred at ca. 220-215 Ma in both the southern and northern UHP zones, which might be triggered by the detachment of the preceding subducted slab; and partial melting of the northern UHP zone continued to ca. 210 Ma due to heat supply from the underneath mantle. Such a variation might be dictated by the tectonic evolution of the different UHP slices. Accordingly, the whole partial melting process of UHP rocks in the Sulu UHP terrane might have lasted for about 27 Myr with two major episodes at ca. 230–224 and 220-215 Ma.

Petrology and geochemistry of serpentinized peridotites from Hahajima Seamount in Izu-Bonin forearc region

Serpentinites, which contain up to 13 wt% of water, are important reservoirs for chemical recycling in subduction zones. In the past two decades, forearc mantle serpentinites were identified in different locations around the world. Here, we present petrology and whole rock chemistry of ultramafic and mafic rocks dredged from the Hahajima Seamount, which is located 24-40 km west to the junction of the Izu-Bonin Trench and the Mariana Trench. Nearly all the collected samples are extensively hydrated, and olivine grains in ultramafic rocks are replaced by serpentine minerals, with only one sample preserving remaining trace of orthopyroxene. Our new results show that the Hahajima serpentinized peridotite samples are all MgO-rich (similar to 42 wt%), but have low contents in Al2O3, CaO, rare earth and high field strength elements, which is consistent with the overall depleted character of their mantle protoliths. Model calculations indicate that these Hahajima peridotite samples were derived from 10%-25% partial melting of the presumed fertile mantle source, which is generally lower than those of peridotites from Torishima Forearc Seamount, Conical Seamount and South Chamorro Seamount (mostly >25%). All the serpentinites from these four forearc seamounts show strong enrichment in fluid-mobile and lithophile elements (Li, Sr, Pb and U). In details, Hahajima Seamount serpentinites do not have obvious enrichment in Cs and Rb, and display remarkably high abundances of U. These observations indicate that the serpentinization of Hahajima peridotites occurred by addition of seawater or low temperature seawater-derived hydrothermal fluid, without or with little contribution from slab-derived fluids. The geochemical signature of serpentinites from Hahajima Seamount could be interpreted as the result of the combination of extensive partial melting and subsequent percolation of seawater through the mantle wedge.

Multistage Remobilization of the Southwestern Margin of the South China Plate: Insights From Zircon U‐Pb Geochronology and Hf Isotope of Granitic Rocks From the Yao Shan Complex, Southeastern Tibet Plateau

AbstractThe Yao Shan complex, located at the southwestern margin of the South China plate, to the east of the Sanjiang‐Southeast Asia Tethyan domain, and at the northern extension of the Day Nui Con Voi massif of the Ailao Shan‐Red River shear zone, provides a reasonable example to study the multistage tectonic remobilization of continental plates. In this paper, we present new zircon LA‐ICP‐MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) U‐Pb dating results and Hf isotopic data of the granitic plutons and dikes from the Yao Shan complex. Zircon U‐Pb ages of the granitic intrusions mainly concentrate on three periods: 825–780, 82–69, and 31–29 Ma. The zircons are characterized by mainly negative εHf(t) values with TDMC ages of 2637–1645, 1964–1610, and 2077–1400 Ma, respectively. The results show that the Yao Shan complex record evidences for three episodes of extensive partial melting of middle and lower crustal Precambrian crystalline basement rocks. They contributed to the granitic magmatism in relation to tectonic processes and structural deformation from Neoproterozoic, Late Cretaceous to Oligo‐Miocene. Therefore, we argue that the southwestern margin of the South China plate is the weakness for multistage remobilization throughout the tectonic evolution of the plate after its primary cratonization. Remobilization of the plate margin is related to oceanic plate subduction, triggered by rifting in a passive continental margin setting, induced by extension at back‐arc setting, or resulted from continental extrusion.

How long can the middle crust remain partially molten during orogeny?

Extensive partial melting of the middle to lower crustal parts of orogens, such as of the current Himalaya-Tibet orogen, significantly alters their rheology and imposes first-order control on their tectonic and topographic evolution. We interpret the late Proterozoic Aracuai orogen, formed by the collision between the Sao Francisco (Brazil) and Congo (Africa) cratons, as a deep section through such a hot orogen based on U-Pb sensitive high-resolution ion microprobe (SHRIMP) zircon ages and Ti-in-zircon and Zr-in-rutile temperatures from the Carlos Chagas anatectic domain. This domain is composed of peraluminous anatexites and leucogranites that typically exhibit interconnected networks of garnet-rich leucosomes or a magmatic foliation. Zirconium-in-rutile temperatures range from 745 to 820 °C, and the average Ti-in-zircon temperature ranges from 712 to 737 °C. The geochronologic and thermometry data suggest that from 597 to 572 Ma this domain was partially molten and remained so for at least 25 m.y., slowly crystallizing between temperatures of ∼815 and >700 °C. Significant crustal thickening must have occurred prior to 600 Ma, with initial continental collision likely before 620 Ma, a time period long enough to heat the crust to temperatures required for widespread partial melting at middle crustal levels and to favor a “channel flow” tectonic behavior.

Petrogenesis and Geodynamic Implications of Late Jurassic Diorite Porphyry in the Neoproterozoic Ophiolitic Mélange of NE Jiangxi (South China)

Mesozoic magmatism is widespread in the eastern South China Block and has a close genetic relationship with intensive polymetallic mineralization. However, proper tectonic driver remains elusive to reconcile the broad intracontinental magmatic province. This study presents integrated zircon U–Pb dating, Hf isotopes and whole‐rock geochemistry of the Xiwan dioritic porphyry in the NE Jiangxi ophiolitic mélange. Zircon U–Pb dating by SIMS and LA‐ICP‐MS methods yielded an emplacement age of ∼160 Ma for the Xiwan diorite, confirming its inclusion into the Mesozoic magmatic province in SE China, instead of a component of the Neoproterozoic ophiolitic mélange genetically. The dioritic rocks have low SiO2 (58.08wt%–59.15wt%), and high Na2O (5.00wt%–5.21wt%) and MgO (4.60wt%–5.24wt%) contents with low TFeO/MgO ratios (1.02–1.09). They show an adakitic geochemical affinity but exhibit relatively low Sr/Y ratios (24.8–31.1) and high Y contents (14.6–18.3 ppm) compared to the Dexing adakitic porphyries. In addition, the Xiwan diorites have moderately evolved zircon Hf isotopic compositions (εHf(t)=−6.1‐ −0.1; TDM2=1597–1219 Ma). These elemental and isotopic signatures suggest that the Xiwan diorite formed through partial melting of a remnant arc lower crust (i.e., early Neoproterozoic mafic arc‐related rocks) in response to the underplating of coeval mafic magmas. In conjunction with the temporal‐spatial distribution and complex geochemical characteristics of the Mesozoic magmatism, our case study attests to the feasibility of a flat‐slab subduction model in developing the broad intracontinental magmatic province in SE China. The flat‐slab delamination tends to trigger an asthenospheric upwelling and thus results in extensive partial melting of the overlying lithospheric mantle and lower crustal materials in an extensional setting during the Mesozoic.

Age of crustal melting in Higher Himalayan Crystalline Sequence (Darjeeling, Eastern Himalaya): Constraints from SHRIMP U–Pb geochronology

The paper presents the petrological and geochronological studies of migmatite from an important section of Higher Himalayan Crystalline Sequence of Eastern Himalaya. Migmatites collected from the area characteristically contain biotite‐garnet‐sillimanite‐plagioclase‐K‐feldspar‐quartz as an important mineral assemblage, which has experienced extensive partial melting through dehydration melting reaction involving biotite. In this study, P–T evolution of these migmatites has been constrained through the use of multiequilibrium thermobarometry program winTWQ, conventional thermobarmetry, and pseudosection modelling in the MnNCKFMASHTO model system using Perple_X software. The unification of these three calculations demonstrates that the migmatite experienced peak pressure and temperature at 7.2 ± 0.5 kbar and 775 ± 20 °C, respectively. SHRIMP U–Pb chronological results yield the timing of crustal melting (21 Ma) in the migmatite.

Geochemistry of Mesoproterozoic Deonar Pyroclastics from Vindhyan Supergroup of Central India: Evidences of Felsic Magmatism in the Son Valley

ABSTRACT Deonar Pyroclastics of Semri Group in the Vindhyan Supergroup originated as a result of violent and explosive intra-basinal submarine volcanism during the Mesoproterozoic period. These pyroclastics are rhyolitic to rhyodacitic in composition, comprised of banded, massive, pumiceous flow, breccia, vitric tuff, lapilli and volcanic bomb. The pyroclastic deposits represent welded and non-welded ignimbrites, exhibit typical eutaxitic texture. Mantle normalized multi-element patterns show enrichment in LILs and depletion in HFSFs. Ti, Nb and REE contents show close correlation with Zr, indicating their immobile character. HFSEs and Th/Nb, La/Nb and Zr/Nb values indicate contamination and these signatures represent mixing between mantle-derived rocks and the average continental crust. Deonar Pyroclastics reflect continental rift environment. Felsic magma plausibly generated by underplating of the mature Proterozoic crust of the Indian craton (which acted like a ‘heating lens’) resulted in extensive melting of metabasalt in the lower crustal levels. The high heat flow beneath the Indian shield accentuated heat generation which led to extensive partial melting of metabasalts. Thus, generation of rhyolitic magma occurred along the reactivated deep seated fractures and rifting of the craton, resulting in the explosive intra-basinal felsic vulcanicity in the Vindhyan basin.

Textural development in sulfide-matrix ore breccias in the Voisey's Bay Ni-Cu-Co deposit, Labrador, Canada

Magmatic Ni-Cu sulfide ores at Voisey’s Bay contain complex assemblages of extremely heterogeneous rocks. These range from polymict breccias, with rock fragments in sulfide-rich and/or sulfide-poor matrices, to heterogeneous “vari-textured” gabbros with rapid short range variations in grain size and content of hydrous phases. Rock fragment populations in the breccias include endogenous olivine gabbros (cumulate and non-cumulate) and cumulate peridotites along with extensively depleted plagioclase-hercynite gneisses interpreted as restites from extensive partial melting of country rock quartzo-feldspathic paragneisses. Using a combination of desk-top microbeam XRF mapping at cm scale and 3D X-ray tomography, we show that both sulfide-poor and sulfide-rich breccias comprise heterolithic assemblages of clasts within a matrix of olivine gabbro. This matrix is characterised by an interconnected 3D framework of plagioclase crystals, highly variable in grain size at mm to cm scale, with interstitial olivine and poikilitic clinopyroxene, and is texturally indistinguishable from clast-free olivine gabbro. Sulfide forms interconnected networks at cm to dm scale and possibly larger. Much of the plagioclase developed by outgrowth from the margins of paragneiss xenoliths when the porosity was occupied by silicate melt. The observed range of textures is explained by a model of percolation of molten sulfide through variably crystalline inter-clast matrix, displacing the silicate melt to leave the refractory plagioclase-olivine or in some cases plagioclase-only component, now entirely within a sulfide matrix. The process is analogous to that believed to have formed interspinifex ore in komatiite-hosted deposits. Biotite rims on plagioclase enclosed in sulfide are interpreted as the result of reaction between plagioclase, olivine and a hydrous component derived from the sulfide melt itself, with a possible component of migrating residual silicate melt wicking along sulfide-silicate contacts. This sulfide infiltration model offers an alternative to the current model for upward emplacement of a slurry of silicate melt, sulfide melt and breccia fragments as a late stage injection into the dyke-sill complex. The preserved range of textures is interpreted as being due to gravity-driven percolation of sulfide liquid through a pre-existing partially molten intrusion breccia. In this model, the breccia serves as a physical trap site, accumulating downward migrating sulfide liquid. However, the invariable close mutual association of sulfide and rock fragments at Voisey’s Bay implies a common derivation.