In this paper, we study the existence of transversal homoclinic orbits in a planar circular restricted four-body problem, based on the perturbation theory of integrable Hamiltonian systems. We start from a planar circular restricted four-body model and regard it as a perturbation of the two-body model. Then, in order to conveniently study unbounded orbits, we transform the infinite points to finite points by a non-canonical transformation, arriving at a non-Hamiltonian system with degenerate fixed points. According to the extended Melnikov method, we finally prove that there exist transversal homoclinic orbits in this four-body model.