The liquid CO2 phase change fracturing technique has been widely applied in rock engineering for a long time. However, the ground vibration characteristics in bench excavation have not been well demonstrated. In this study, the particle velocities, main frequencies, and displacements of rock induced by liquid CO2 blasting are investigated based on field tests and numerical simulations. Firstly, three field tests of bench excavation using DM83-1.4 type liquid CO2 storage tube were implemented in a specific highway slope project, in which the TC-4850 N vibration monitors were installed at horizontal distances of 4.2 m, 10.6 m, 20.3 m and 32.2 m from the detonation source to detect the rock vibration velocity and frequency. Subsequently, by employing the dynamic finite element program LS-DYNA, a three-dimensional numerical model was established, and then the particle velocities and displacements were analyzed and discussed. The research results indicate that the peak particle velocity (PPV) decays with distance in an exponential pattern, that is, the PPV decays rapidly in the near zone of the blasting source, and it decays more slowly in the far zone. At the position of 20.3 m in the horizontal distance and 15.8 m in elevation, an elevation amplification effect appears with an amplification factor of 1.12. Moreover, the vibration frequency generated by the liquid CO2 phase change fracturing technique is in the range of 0-80 Hz, which is much smaller than that induced by explosive blasting. The main frequency in the near-field of the blasting source is dominated by the radial frequency (Fr), while the vertical frequency (Fv) is dominant in the far-field. The attenuation law of displacement is generally consistent with the vibration velocity, and the difference between radial and tangential displacement increases gradually with distance.