Natural Gas Hydrate Exploitation Research Articles

How shallow CO2 hydrate cap affects depressurization production in deeper natural gas hydrate reservoirs: An example at Site W17, South China Sea

The logging results from the Shenhu Sea show that the P-T conditions of NGH deposits are below the CO2 hydrate phase equilibrium curve. The burial depth difference between the CO2 hydrate stable zone and NGH deposits is usually above 100 m, which differs from the laboratory scale. Thus, whether CO2 hydrate caps can provide pore sealing and reinforcement of natural gas hydrate (NGH) overburden at the engineering scale is unknown. Based on this, we aimed to perfect research on the CO2 hydrate cap, including its formation process, effects on NGH exploitation, geomechanical response, and comprehensive benefit evaluation, by establishing a THMC model based on Site W17. Results indicate that (i) CO2 can form hydrates in the overburden layer with a conversion rate of about 28%, preventing the upward escape of residual liquid CO2 due to density difference. (ii) CO2 injection and CO2 hydrate cap formation can increase the decomposition driving force during depressurization to enhance production, but it fails to inhibit water invasion from the upper part of the NGH deposit due to the excessive depth difference. (iii) The CO2 hydrate cap causes strata uplift, thereby mitigating strata subsidence during depressurization production, especially for the cases of horizontal wells, where the subsidence is reduced by about 103.4%. (iv) Injecting too much CO2 may not benefit gas production, where part of the free gas will convert into NGH due to pressure rise. The optimal injection rate in this study is 40,000 m3/d. (v) Indicators like CO2 hydrate conversion rate, gas-water ratio, and maximum strata displacement show that horizontal well systems with CO2 hydrate caps are more beneficial than vertical well systems, and multi-branched well systems are more beneficial than single-direction well systems. These key findings may differ from the laboratory scale, which can provide a reference for applying CO2 hydrate caps in actual NGH exploitation.

Numerical Simulation of Secondary Hydrate Formation Characteristics and Effectiveness of Prevention Methods

The exploitation of natural gas hydrates by the pressure reduction method is affected by the decomposition heat absorption effect, and the range of the formation temperature reduction area is expanding. At the same time, the temperature reduction phenomenon is more significant around the production wells under the influence of gas throttling and expansion effects, and hydrate formation will occur under certain temperature and pressure conditions, leading to blockage of effective seepage channels in the reservoir in the region and elevation of seepage resistance, which may affect the output of hydrate decomposition gas. A numerical simulation model is constructed for the purpose of studying the secondary hydrate generation pattern around the well, analyzing the impact of secondary hydrates around wells on the production capacity, and assessing the effectiveness of prevention methods to inform the actual production of hydrates. The results demonstrate that secondary hydrate is typically formed in the near-well area of the upper part of the production well, and the secondary hydrate around the upper part of the production well is the first to be formed, exhibiting the highest saturation peak and the latest decomposition. The formation of the secondary hydrate can be predicted based on the observed change in temperature and pressure, and the rate of secondary hydrate formation is markedly rapid, whereas the decomposition rate, approximately 0.285 mole/d, is relatively slow. Additionally, the impact of secondary hydrates on cumulative gas production is insignificant, and the effect of secondary hydrates on capacity can be ignored. Hot water injection, wellbore heating, and reservoir reconstruction can effectively eliminate secondary hydrates around the well. Reservoir reconstruction represents a superior approach to the elimination of secondary hydrates, which can effectively enhance production capacity while preventing the generation of secondary hydrates.

Enhanced strategies for depressurization in offshore natural gas hydrate exploitation: An in-depth investigation into pathway optimization and production stability mechanisms

Natural gas hydrates have garnered widespread attention as a high-quality energy resource. Recent offshore extraction experiences suggest that depressurization is a technically mature and economically viable option. However, challenges such as reservoir temperature reduction, reservoir subsidence, secondary hydrate formation, and insufficient dynamics in later-stage hydrate decomposition still require improvements to the depressurization method. This study, based on field data from Japan's first offshore natural gas hydrate extraction, utilizes a self-developed numerical simulator to model and validate reservoirs at the field scale. Long-term production rate stability, total production, secondary hydrate formation, reservoir subsidence, evolution of permeability, and temperature-pressure paths were analyzed and optimized for the three mainstream depressurization modes: steady depressurization, stepwise depressurization, and cyclic depressurization. The results indicate that, under the condition of equal total work done throughout the entire depressurization process, steady depressurization with an effectively lower depressurization rate is the optimal choice. Cyclic depressurization, due to the formation of secondary hydrates reducing the permeability of certain reservoir zones, adversely affects gas production efficiency during the long-term stable production phase. This study enhances insights into the coupled evolution of multiple physical fields during the depressurization of offshore natural gas hydrates, providing valuable guidance for future on-site extraction plan designs.

Undrained triaxial tests of underconsolidated overlying sediments of hydrate deposits in the South China Sea

The South China Sea (SCS) is an important repository for natural gas hydrates (NGHs), where some NGH deposits and their overlying sediments (OSs) are in an underconsolidated state. During the exploitation of NGHs, the stability of the OSs of the NGH deposits is one of the key factors in ensuring mining safety. Especially under different consolidation degrees, the mechanical response and stability of the OSs will vary, which directly affects the safety and efficiency of the NGH mining. This research explores the influence of different consolidation degrees on the mechanical properties of the OSs of NGH deposits in the SCS. The strength and pore pressure characteristics were analyzed through undrained triaxial shear tests. The findings indicate that an increase in consolidation degree enhances the strain softening behavior, and an increase in initial effective stress enhance the strain hardening and shear contraction behaviors of the samples. The failure strength, modulus, and maximum excess pore pressure increase with the consolidation degree and initial effective stress, and there is an approximately linear correlation between failure strength and consolidation degree. Therefore, the exploitation of NGHs in the SCS must comprehensively consider the burial depth and consolidation degree of the OSs. The findings of this study will assist in optimizing mining plans and enhancing safety during the exploitation process.

Natural gas hydrate dissolution kinetics in sandy sediments: Implications for massive water production in field tests

The tremendous natural gas hydrate (NGH) reserve in globe makes it a promising future energy. The field test production indicates that massive water production may occur in the depressurization of sandy NGH reservoirs. The dissolution of NGH may play a significant role in this process. Therefore, quantifying the NGH dissolution kinetics and clarifying the relations between NGH dissolution and water production is crucial. In this work, a modified excess water method was developed to prepare quasi-homogenous water-saturated methane hydrate (MH) bearing sediments (HBS). The MH dissolution kinetics were investigated by flowing methane-free water through the HBS. The MH dissolution process could be divided into the rapid stage and the decayed stage. Preferential flow channels may form by the inhomogeneous MH dissolution. Water flux has a significant impact on the MH dissolution kinetics via affecting the mass transfer and the hydrate-water exposure in flow channels. When increasing the water fluxes from 2.0 mL·cm−2·min−1 to 6.1 mL·cm−2·min−1, the MH dissolution rate initially ramped up from 15.4 cm·d−1 to 36.0 cm·d−1 (mass transfer dominates), and then decreased to 28.7 cm·d−1 (flow channels dominate). MH saturation has an influence on dissolution kinetics. The MH dissolution rate increased from 27.1 cm·d−1 to 44.2 cm·d−1 when the MH saturations increased from 11.8 % to 60.1 %. Experimental results indicate that the preferential flow channels by inhomogeneous NGH dissolution could contribute to the massive water production in the depressurization of NGH reservoir. Large pressure gradient in NGH production may accelerate the NGH dissolution and the following massive water production. Homogeneous high-saturation HBS could more facilitate the hydrate-water exposure for dissolution, which could retard the onset of massive water production. This work may ignite some new thoughts on the water control and production optimization strategies in sandy NGH exploitation.

CH4 hydrate dissociation and CH4 leakage characteristics: Insights from laboratory investigation based on stratified environment reconstruction of natural gas hydrate reservoir

Submarine natural gas hydrates (NGHs) are one of the largest methane reservoirs on Earth, offering huge potential as an alternative energy source and serving as a crucial global carbon sink. However, the substantial risk of methane leakage during NGH development seriously threatens marine and global ecological and environmental safety, presenting a major challenge for commercial NGH exploitation. Focusing on the unknown leakage mechanisms, this study employed a new simulation device to construct a stratified environment and to investigate the characteristics of hydrate dissociation and methane leakage during depressurization production, under conditions of varied fracturing in overlying sediment. A movable module was used to dynamically isolate and connect the hydrate reservoir with the overlying layer. The results showed that the intrusion of overlying water decelerated the reservoir depressurization rate, leading to a mass of hydrate reformation. The invasion locations and flow paths of the overlying water were influenced by the fracture scale of the overlying sediment. Benefiting from the additional sensible heat and reservoir space occupation of the overlying water in the later production stages, the methane recovery ratio in the fracture-containing systems were not significantly affected. However, the leakage methane increased as fracture channels enlarged, reaching up to 9.90 % of the total methane content in the hydrate reservoir. The leakage mechanism primarily involved local overpressure, buoyancy effects, and diffusion. The research, for the first time, experimentally revealed the response relationship between methane leakage and hydrate dissociation, providing foundational data and theoretical support for the safe and efficient NGH development.

Exploring Porous Flow Behavior of the Decomposed Gas from CH4 Hydrate in Clayey Sediments by Molecular Dynamics Simulation.

A fundamental understanding of the fluid flow mechanism during CH4 hydrate dissociation in nanoscale clayey sediments from the molecular perspective can provide invaluable information for macroscale natural gas hydrate (NGH) exploration. In this work, the fluid flow behaviors of the decomposed gas from CH4 hydrate within clayey nanopores under different temperature conditions are revealed by molecular dynamics (MD) simulation. The simulation results indicate that the key influencing factors of gas-water flow in nanoscale clayey sediments include the diffusion and the random migration of gas molecules. The influencing mechanisms of fluid flow in nanopores are closely related with the temperature conditions. Under a low temperature condition, the gas diffusion process is impeded by the secondary hydrate formation, leading to the decline in gas transport velocity within nanopores. However, it is still noteworthy that the gas-water fluid flow channels are not completely blocked by the occurrence of secondary hydrate. Under a high temperature condition, the significant phenomenon of water migration during gas flow is observed, which can be ascribed to the gas-liquid entrainment effect in nanopores of the clayey sediment. These results may provide valuable implications and fundamental evidence for improving gas production efficiency in future field tests of NGH exploitation in marine sediments.

Submarine slope stability during the exploitation of natural gas hydrate from horizontal wells

Horizontal wells have the advantages of high production, considerable access to reserves, and effective sand production control; thus, they are potential well types for hydrate exploitation. In the process of hydrate mining, the decomposition of hydrate will cause the deterioration of the mechanical properties of the reservoir, which may induce submarine landslides, especially in the case of multiple horizontal wells, and the risk of submarine landslides is further increased. Therefore, it is necessary to study the influence of the horizontal well pattern adopted for hydrate mining on the stability of submarine slopes. First, a triaxial mechanical experiment of gas hydrate-containing sediments was carried out, and the mechanical parameters of the hydrate-containing sediments were obtained. Second, a thermal-fluid-solid multifield coupling model considering the hydrate phase transition during the production process was established. Finally, on the basis of the finite element strength reduction method, a slope stability evaluation model for hydrate extraction from a horizontal well pattern was established, and the influence of hydrate extraction from horizontal wells on the stability of submarine slope was analyzed. The results show that the peak strength, elastic modulus and cohesion of gas hydrate-containing sediments increase with increasing hydrate saturation. In the process of hydrate exploitation via horizontal wells, with the reduction in well spacing and the increase in the number of production wells, the risk of slope instability increases. Wells positioned along the slope strike are more conducive to slope stability than those positioned perpendicular to the slope strike. The slope stability increases gradually as the slope dip decreases. When the number of wells is the same, the slope stability increases gradually with increasing well spacing and production pressure.

Fundamental insights into multistep depressurization of CH4/CO2 hydrates in the presence of N2 or air

Exploitation of natural gas hydrates provides an alternative way to address energy crisis. Dilute CO2 gas (13–30mol%CO2 with remaining N2/Air) injection into CH4 hydrates for hydrate swapping (SW) allows cheaper and more practical CH4 recovery and in-situ CO2 sequestration. However, the roles of N2/Air in dilute CO2 gas during exploitation remain unknown. It is unclear whether depressurization should be coupled after SW and continued below CH4 hydrate stability pressure. This work employed multistep depressurization (MD) to dissociate the mixed hydrates formed after SW from 86.5 to 97.9 bar at 0.7–1.2 °C in bulk-water and sandpack with CH4 hydrate saturation of 4.1–25.3 %. Effects of N2/Air on exploitation were investigated by examining hydrate morphologies and gas compositions. Morphological results in bulk-water indicated higher N2 fraction in 20mol%CO2/N2 triggered more CO2-rich hydrate reformation and CH4-rich hydrate dissociation. Exploitation results in sandpack indicated 13mol%CO2/N2 produced the highest CH4 swapping percent (46.6 %) and CO2 hydrate sequestration percent (29.1 %). Air exerted weaker promoting effects on exploitation compared with equivalent N2. The promotion of N2/Air on exploitation was dominated by dilute CO2 gas injection altering mixed hydrate equilibrium which varied with time-dependent gaseous compositions during MD. l-methionine of 3000 ppm had stronger promoting effects on CO2 sequestration in sandpack than bulk-water depending on mass transfer and water availability. Ceasing points (13.9–31.4 bar) suggested MD could be continued below CH4/above CO2 hydrate stability pressures and before water production. For the first time, this study provided insights into the roles of N2/Air to determine injection gas types and depressurization schemes for efficient and safe hydrate exploitation in gas-rich hydrate-bearing sediment.

Monitoring the developmental trend and competitive landscape of natural gas hydrate through patent analysis.

Natural gas hydrate (NGH) is a significant alternative energy resource in achieving carbon neutrality. The developmental trend and competitive landscape of NGH exploitation and production are crucial for policymakers in government, managers of enterprises, and researchers. This study introduces a novel framework for conducting an in-depth analysis of NGH, integrating patentometrics, technology evolution, and correlation relationships to monitor developmental trends and competitive landscape through patent analysis. The results indicate that China, the USA, and Japan have distinct technology advantages. Current technological developments in the NGH field focus primarily on extraction technologies, equipment, and processing systems. The co-opetition analysis among countries reveals that the most extensive international cooperation network is primarily in Europe and the USA, with national partnerships in Asia concentrated in China and Japan. Institutional cooperation remains limited, primarily within universities in China, while both the USA and Japan foster collaboration between enterprises. The competitive landscapes of key NGH-related technologies among countries and institutions are also examined. This study contributes not only to monitoring the developmental trend and competitive landscape in NGH but also to providing policy recommendations for government and enterprises regarding strategic management and collaborative innovation.

An improved analytical model of effective thermal conductivity for hydrate-bearing sediments during elastic-plastic deformation and local thermal stimulation

As one of the crucial thermal properties controlling the dissociation of natural gas hydrate (NGH), effective thermal conductivity (ETC) should be precisely determined to improve the efficiency of NGH exploitation. But so far, most existing analytical ETC models of hydrate-bearing sediments could not accurately characterize the evolution of ETC. In this paper, an improved analytical model is derived for quantitatively revealing physical relations between ETC and various influencing factors during elastic-plastic deformation and local thermal stimulation processes, including hydrate saturation change, complex pore structures evolution, and hydrate occurrence patterns transition. The effectiveness of the proposed model is validated against available experimental data and compared with other existing models, then effects of various critical parameters on ETC are investigated. Results show that the porosity of hydrate-bearing sediments is accurately predicted during both loading and unloading processes, and the calculated ETC values under various conditions (effective stress, hydrate saturation, and temperature) are satisfactory with the test data. Contributions of elastic deformation and plastic deformation to ETC increments are quantitatively obtained. It is noteworthy that this proposed model is significant to reveal the evolution mechanisms of ETC, helping to accurately predict gas production and offer better plans for efficient NGH exploitations.

Investigation on fatigue crack propagation failure mechanism of hydraulic lifting pipe in deep‐ocean natural gas hydrate exploitation

AbstractIn deep‐ocean natural gas hydrate exploitation operation, the fatigue failure mechanism has attracted more and more attention from scholars, but it has not been effectively disclosed. Therefore, in this work, a multifield coupling and multiple‐nonlinear vibration model of lifting pipe is established, which can accurately determine the alternating stress of deep‐ocean lifting pipe. Second, according to Forman theory, the calculation method of crack propagation length and depth on the surface of a deep‐water riser is established, which is verified by the comparison between the experimental and theoretical model calculation results. The results demonstrate that, first, the effect of residual stress in the welded joint of deep‐ocean lifting pipe should be considered in the later parameter influence analysis. Second, the fatigue growth life of deep‐water pipe with small outflow velocity is mainly determined by tensile stress, and that is determined by both tensile stress and bending stress with large outflow velocity. Third, more attention should be paid to the vibration of the lower pipe on‐site to reduce its vibration frequency and vibration stress amplitude, which can effectively reduce the surface crack propagation state of the deep‐ocean pipe and improve the service life of the pipe. Fourth, properly adjusting the tension coefficient of the tensioner during field operation can effectively improve the safety of the pipe, and the optimal tension coefficient is related to the configuration of the deep‐ocean pipe system, which can be analyzed and determined by the model.

Microscopic experimental study on the effects of NaCl concentration on the self-preservation effect of methane hydrates under 268.15 K

It is known that salt ions are abundant in the natural environment where natural gas hydrates are located; thus, it is essential to investigate the self-preservation effect of salt ions on methane hydrates. The dissociation behaviors of gas hydrates formed from various NaCl concentration solutions in a quartz sand system at 268.15 K were investigated to reveal the microscopic mechanism of the self-preservation effect under different salt concentrations. Results showed that as the salt concentration rises, the initial rate of hydrate decomposition quickens. Methane hydrate hardly shows self-preservation ability in the 3.35% (mass) NaCl and seawater systems at 268.15 K. Combined the morphology of hydrate observed by the confocal microscope with results obtained from in situ Raman spectroscopy, it was found that during the initial decomposition stage of gas hydrate below the ice point, gas hydrate firstly converts into liquid water and gas molecules, then turns from water to solid ice rather than directly transforming into solid ice and gas molecules. The presence of salt ions interferes with the ability of liquid water to condense into solid ice. The results of this study provide an important guide for the mechanism and application of the self-preservation effect on the storage and transport of gas and the exploitation of natural gas hydrates.

Time-dependent deformation of marine gas hydrate-bearing strata conditioned to a wellbore: Experiments and implications

Natural gas hydrate (NGH) is a promising alternative energy resource, whereas marine NGH exploitation suffers from various potential geo-environmental concerns. The existence of a production wellbore not only provides channel for gas extraction, but also causes specific boundary conditions for the occurrence of geo-environmental risks. Almost all kinds of geo-environmental risks during NGH production initiate from time-dependent deformation of the near-wellbore strata. In this paper, the pressuremeter test (PMT) method was firstly introduced to investigate the lateral creep behaviors of the NGH-bearing sediment. The PMT probe was used to apply outwards lateral stress onto the hydrate-bearing sediment to simulate the horizontal stress state of the near-wellbore reservoir during drilling, completion, and/or hydraulic fracturing, during which the pressure inside the wellbore is higher than the reservoirs static pressure. The results indicated that the decelerated creep accounts for more than 70% of the lateral strain before the effective stress reaches the long-term strength. The hardening modulus of the sediment was proven to be increased from the magnitude of ∼102 MPa–∼103 MPa, when the hydrate saturation increases from 2.2% to 50.0%. The PMT creep test results can be used for interpretation of the in-situ horizontal stress and geomechanical parameters such as pro-plastic pressure and ultimate pressure. Based on the fact that PMT test results complies with the previous results from other techniques, a field-applicable PMT technique for NGH reservoir test is suggested to be developed in future study, and a systematic hypothesis and workflow for NGH reservoir modelling is also proposed in this study.

Molecular dynamics study on roles of surface mixed hydrate in the CH4/CO2 replacement mechanisms

The CH4/CO2 replacement method is a promising approach for the exploitation of natural gas hydrates, offering dual benefits of extracting CH4 and sequestering CO2. This technique not only facilitates the extraction process but also mitigates the greenhouse effect and maintains geological stability, thereby contributing to sustainable energy utilization and environmental preservation. Currently, there are multiple viewpoints about the replacement mechanism. Furthermore, mixed hydrates can form on the surface during the replacement process. The unclear mechanism of CH4/CO2 replacement and the obstruction of mass transfer caused by the mixed hydrate impede its practical applicability. Clarifying the effects of surface mixed hydrate in replacement mechanisms can offer valuable insights for identifying optimal operating conditions in practical exploitation applications. Therefore, the present study aims to reveal the significant roles of surface mixed hydrates in the replacement mechanism by employing the molecular dynamics simulation methodology. The results showed that under the mechanism of cage complete rupture, the surface mixed hydrate decomposes rapidly to form a thickening water zone. Additionally, each layer of the hydrate cage structure undergoes a process from deformation or partial rupture to sudden complete disintegration, which is concomitant with an abrupt change of potential energy. Under the mechanism of cage incomplete rupture, the surface mixed hydrates hinder mass transfer and decelerate the reaction rate. A similar situation arises when the number of the surface mixed hydrate layers is increased. Therefore, the key to distinguishing the replacement mechanism lies in whether the environmental conditions are sufficient to break the potential energy barrier of the surface mixed hydrate and disrupt its cage structure.

DEM-CFD coupling verification and analysis of a sand control medium structure with weakened particle blockage performance

This study addresses the prominent contradiction between solid phase control and production capacity release during the exploitation of natural gas hydrate in fine silty sand reservoirs. A novel mechanical sand control medium structure incorporating the filter slots/nets (referred to as the sand control component, SCC) and the cylindrical/spherical structures placed outside the SCC (referred to as the blockage control component, BCC) has been designed. Concurrently, a DEM-CFD sand-retaining numerical model is developed, and the traditional/new structural screens have been separately simulated for sand retention. Through the spatiotemporal evolution of DEM and CFD characteristic model parameters during simulation, the blockage mechanism and characteristics of fine particles are obtained. Compared to the traditional screen structure without a BCC, the existence of a BCC effectively evacuates particles within the accumulated sand body towards the wellbore, reducing the compactness and stress level within the sand body; while the pressure loss generated by fluid flow through the sand body decreases, significantly improving the porous and permeable conditions within the sand body. The degree of influence of a BCC on different DEM and CFD characteristic model parameters is further determined and ranked. A comprehensive blockage optimization index is introduced to quantify the performance of weakening sand blockage by the BCC and optimize the spatial position of the BCC. The BCC enables the design of sand control schemes to reduce the filter aperture of the SCC to a sufficiently small size to effectively control the fine silty sand production, while avoiding gradually severe blockage as production progresses.

Investigation on multi-parameter of hydrate-bearing synthetic sediment during hydrate replacement process: A in-situ X-ray computed tomography study

Carbon sequestration can be achieved by carbon dioxide replacement in natural gas hydrate exploitation, which reducing greenhouse gas emissions and providing an effective solution to address climate change, while simultaneously protecting the environment and promoting sustainable energy development. Gas replacement can achieve gas exploitation, gas storage, and stability enhancement simultaneously. However, time-varying microstructure evolution of the hydrate-bearing sediment (HBS) during this process remain a large amount of uncertainty. In this study, with microfocus computer tomography, hydrate replacement process is realized using xenon gas to replace krypton hydrate. During this period, the initial hydrate saturation and effective confining pressure were 63 % and 1 MPa respectively, the results were obtained as follows: 1. Hydrate occurrence dynamically adjusted during replacement process due to the “barrier effect” and “diffusion effect”. 2. Dissociated water migration occurred in the sediment, and this induced local hydrate enrichment temporarily and blockages, but the blockages were eventually dredged with the dissociation of the Kr hydrate. 3. The sphericity and surface roughness of the hydrate particles were slightly improved, the pore space connectivity was well enhanced, and both tortuosity and absolute permeability was better strengthened after replacement process, where the absolute permeability was increased by 225.23 %, though the blockage occurrence temporarily weakened this strengthener.

Optimized dual-gas co-production from hydrate reservoirs with underlying gas through depressurization & well closure cycling: An experimental evaluation

The regular depressurization method for the exploitation of natural gas hydrate, while effective in gas production, carries a high risk of hydrate regeneration and significant reservoir shrinkage. In this study, the hydrate reservoirs containing underlying gas were synthesized by controlling the initial water distribution, and confining pressure was applied to replicate sub-seafloor conditions. An innovative cyclic depressurization (DP) + well closure (WC) cycling scheme was implemented to facilitate the joint production of hydrate and underlying gas. The heat transfer, gas production, and sediment deformation characteristics during dual-gas co-production were compared and examined considering different DP and WC duration. The findings clearly indicate that the DP + WC cycling method yielded significantly superior results compared to the regular DP approach. Specifically, it achieved effective CH4 recovery rates 1.83–2.33 times higher, temperature recovery rates 1.2–1.3 times greater, and a reduced the duration of reservoir contraction. More importantly, the extent of influence on these factors could be controlled by adjusting DP or WC duration. A discovery like this offers diverse gas production approaches tailored to various hydrate reservoir requirements. Overall, this study provides preliminary evidence that the DP + WC cycling method allows for the simultaneous attainment of efficient production and reservoir security, highlighting its potential significance for gas production from hydrate reservoirs containing underlying gas.

Influence of gravity on methane hydrate dissociation characteristics by depressurization in marine hydrate reservoirs

Since the thickness of hydrate-bearing sediments is usually tens to hundreds of meters, the influence of gravity on hydrate dissociation characteristics can no longer be ignored. In this study, experimental simulations were designed to investigate the influences of gravity on hydrate dissociation characteristics by depressurization. The experimental results showed that for sealed water-rich marine hydrate reservoir, gravity could cause more water to migrate downward. The free pore space in sediments was thus rapidly vacated, resulting in faster hydrate dissociation and gas production. The average gas production rate increased from 0.018 mol/min to 0.038 mol/min. In addition, the free pore space at the top of the sediments was vacated first. Hydrate dissociation there was thus faster. For unsealed water-rich marine hydrate reservoir, gravity could not only cause more and faster migration of water, but also more easily cause the formation of dominant channels for water migration, leading to an effective reduction in reservoir pressure. The cumulative water yield increased from 1380g to 8950g. Hydrate thus dissociated. Hydrate dissociated faster at positions close to the mining well where the pressure was lower. These findings can provide deep insights into the spatial evolution of multiphase flows during the exploitation of natural gas hydrates.

Cementation breaking and grit separation characteristics of weakly cemented natural gas hydrate by a new structure hydrocyclone

Solid fluidization exploitation technology is one of the most promising methods for the safe exploitation of shallow natural gas hydrates (NGH) in the deep sea. However, after primary jet breaking in the solid fluidization exploitation, the hydrate and argillaceous silt particles are in a state of weak cementation and agglomeration. When the argillaceous silt particles enter the offshore drilling platform with the drilling fluid, it causes substantial sand production, high energy consumption, and pipeline blockage, considerably affecting the development process of the NGH test. Therefore, in-situ desanding has become one of the key technologies of solid fluidization exploitation. In this study, a coupling method of hydrocyclone cementation breaking and hydrocyclone desanding was proposed, and a new structure of cementation breaking and grit separation hydrocyclone was designed. In a lab-designed cementation breaking and grit separation hydrocyclone system, the cementation breaking and grit separation characteristics of weakly cemented NGH similar materials in the swirl flow field were studied. The experimental results under the operating conditions studied show that the swirl flow field exhibits good cementation breaking and grit separation performance for weakly cemented NGH similar materials. For weakly cemented NGH similar materials with a compressive strength of 0.06–0.42 MPa, the cementation breaking efficiency of the cementation breaking and grit separation hydrocyclone is in the range of 27.17–99.61%. After the cementation breaking, the mixture of hydrate similar materials (hydrophilic polyethylene powder) and quartz sand was separated in the hydrocyclone. The separation efficiency of hydrate similar materials is 27.59–99.64%, and the desanding efficiency is 87.66–99.98%. The cementation breaking and grit separation of weakly cemented NGH similar materials were successfully realized. Based on the experimental data, a multiple regression model for the cementation strength of similar materials and the swirl flow field strength was established using the least squares method. This method is expected to provide new technical support for in-situ desanding and safe exploitation of the deep-sea shallow NGH production process.