The research presented herein is part of a larger project delving into the mechanisms and pathways for reactive condensation of Chromium (Cr) vapors in high-temperature (>500o C) environments. The overall goal of this research project is to improve fundamental understanding of reactive condensation pathways for chromium (Cr) vapors generated in high-temperature systems such as exhaust manifolds, steam turbines, boilers, or solid oxide fuel cells (SOFCs). Reactive evaporation of Cr from stainless steels commonly used in these systems is well-documented; however, the interactions between volatilized Cr species and surrounding interfaces during complex and dynamic system exposures is poorly understood. Understanding the interactions between volatilized Cr species and downstream components during operation is critical for improving system performance, environmental health, and safety as some condensed Cr forms toxic hexavalent Cr(VI) species. The focus of this study is on the effects of alkaline oxides present within the substrate material on reactive condensation mechanisms of Cr vapors. Studying the reaction mechanisms between Cr vapors and ceramic surfaces has direct application to SOFCs as these materials are widely used in the field. For example, alumina-silica glass-ceramics are used as sealants in SOFCs. These materials belong to the SiO2–Al2O3 system and contain different compositions of oxides including CaO, Na2O, MgO, K2O, B2O3, Y2O3, and BaO. Another sealing material used in SOFCs is mica, a class of silicate minerals that forms into distinct layers. Two types of mica commonly used in SOFC applications are muscovite (potassium aluminum silicate hydroxide fluoride, KAl2(AlSi3O10)(F,OH)2), and phlogopite (potassium magnesium aluminum silicate hydroxide, KMg3(AlSi3O10)(OH)2). The specific research objective is to explore the effects of alkaline oxide additives in aluminosilicates on Cr collection and speciation. To accomplish this objective, an experimental platform was designed to assess interactions between samples of high-temperature steel alloys or Cr oxide (Cr2O3) powder with ceramic insulating materials. The chemical composition of the insulating materials used in this study range from pure silica (SiO2) and alumina (Al2O3) to combinations thereof with and without inclusions of alkaline earth metals (e.g., Ca, Mg). Preliminary results show three- to four-fold increases in Cr(VI) formation on silica fibers with weight percentages of ~30 and ~40 percent alkaline oxides (CaO and MgO), respectively, after exposure to volatile Cr species, relative to low-alkaline silica. Figure 1 presents an overview of the experimental concept, Cr(VI) test kit, and preliminary results for dependency on alkaline oxide content. Figure 1
Read full abstract