The magnetic ordering in ultrathin Co films on Cu(0 0 1) has been investigated via the polarization of light emitted after capture of spin-polarized electrons into excited atomic terms during grazing He scattering. A strong increase in the Curie temperature and the remanent spin polarization has been observed at a critical Co thickness t Co cr ≈ 1.7 ML . In agreement with a recent study on the same heteroepitaxial system, this behavior is attributed to the percolation of Co islands. For growth at an elevated temperature of 410 K, hysteresis loops reveal a strong increase in the irreversibility field at which the loop closes. This behavior is explained by an inhomogeneous distribution of growth-induced local magnetic anisotropies which make a complete reversal of the magnetization more difficult.