Excellent Mechanical Properties Research Articles

The Influence of Additively Manufactured Specimen Thickness on Laser-Induced Ultrasonic Signals

Selective laser melting (SLM) technology, employed in metal additive manufacturing, is widely utilised to fabricate components with precise dimensions and excellent mechanical properties by melting powder layer by layer. Laser ultrasonic testing is anticipated to be an efficient method for in-line monitoring in the additive manufacturing (AM) process. The conversion of specimens from thin to thick during the SLM manufacturing process has an impact on the ultrasonic signals. This paper focuses on the influence of AM specimen thickness changes on ultrasonic signals. In the finite element analysis, the incremental specimen thickness was maintained at 0.2 mm, which was the initial value. As the specimen thickness increased sequentially, ultrasonic signals were obtained from different specimens. The results demonstrate that Lamb waves are generated when the specimen is thin, and the dispersive characteristics weaken as the thickness increases. The dispersive phenomenon diminishes significantly once the specimen thickness exceeds 1 mm. By employing the f-k method, calculated dispersion curves for various specimen thicknesses were obtained. After fitting the derived dispersion curve, a mapping relationship is established with respect to the specimen thickness. Consequently, the fitting coefficient of the dispersion curve can therefore be utilized to characterize the thickness of the additive manufactured thin specimen.

Research on Hot Deformation Behavior of Cu-Ti Alloy Based on Machine Learning Algorithms and Microalloying

High strength and high elasticity copper alloys have good application prospects due to their excellent mechanical properties. The deformation and heat treatment in its preparation process are important steps to ensure the service performance. In this work, Cu-Ti based alloys were employed and hot compression experiments were conducted at 500-800℃ under four different strain rates. Their constitutive equations and thermal processing maps were constructed. The influence of microalloying elements on activation energy was also analyzed. The microstructure evolution and recrystallization behavior under hot deformation conditions were studied based on the results of TEM. At the same time, Arrhenius, back propagation neural network (BPNN) and support vector machine (SVM) algorithms were used to predict the flow stress of the alloy. The results indicate that the relationship between flow stress and the input factors (strain rate, temperature and deformation) can be well predicted using the support vector machine algorithm. Microalloying can increase the activation energy of copper alloys, and the sensitivity of activation energy to temperature changes is related to the interaction between precipitates and dislocations.

A machine-learning based framework for design and characterization of honeycombs with partial self-similar hierarchical architectures

Honeycomb structures with hierarchical topology are widely used in engineering fields for their excellent mechanical properties. Multiphase topology is proved to possess a larger design space than the traditional hierarchical topology. In this study, a partial self-similar hierarchical honeycomb (PSSHH), comprising of zero-order cell and first-order cell, was designed. Numerical simulations, validating against the experimental results, were carried out to investigate the in-plane crushing performance of PSSHHs with different configurations. An artificial neural network model was trained using the results of simulations. The ability and effectiveness of artificial neural networks in predicting and characterizing the crushing responses of PSSHH were evaluated through comparison with simulations. The model was primarily employed for optimizing the design of PSSHH to enhance the crushing performance. The results indicate that the optimized PSSHH outperforms traditional hexagonal honeycombs and fully self-similar hierarchical honeycombs in terms of initial peak force, mean crushing force, and energy absorption. Furthermore, the effect of number and organized patterns of the first-order cells along the loading direction on the mechanical properties of PSSHH is examined. The findings reveal that the formation and development of localized collapse bands are significantly affected by the number and distribution of hierarchical first-order cells. The deformation, which involves a sequential crushing process with the initial collapse of specific zero-order cells followed by the subsequent collapse of first-order cells, contributes to enhancing the crashworthiness performance of PSSHH.

Finite element modeling and analysis of the self-piercing riveting forming process with the ball-shaped die

Self-Piercing Riveting (SPR) technique faces challenges as it expands to low ductile materials. In this paper, the ball-shaped die is suggested to prevent the formation of cracks in sheets during the SPR process. The SPR model with the ball-shaped die was developed using the finite element method, and simulations of the joint forming process and tensile test were conducted. The influence of die depth and diameter on SPR forming process and quality was analysed. The simulation results showed that as the die diameter increases, the undercut decreases, and the remaining thickness of bottom increases. The undercut and the remaining thickness of bottom decreases with the increase of the depth of the die. When employing a ball-shaped die with a 1mm depth and 10mm diameter, the SPR joint with tight interlock and excellent mechanical properties can be obtained. The results of the simulation and experimental tests are consistent.

Layer effects on MXenes electrode and it applied to silicon composite structures

Despite the very high capacity of Si (4200mAh g−1), the widespread application of Si anodes has been hampered by drastic volume changes (up to 300 %) during cycling, leading to electrical contact losses and thus a sharp drop in capacity as the cycle life is shortened. Here we present a class of layered MXene/Si electrodes, which consist of nano-Si embedded in the interlayers of MXene to form a coupling effect, which can inhibit the huge volume change of Si during cycling. Therefore, layered MXene/Si has a highly reversible capacity, much improved cycling performance and excellent mechanical properties. First-principles calculations reveal the excellent electronic conductivity and good diffusion ability of layered MXene/Si, confirming the rapid storage of Li ions. This study provides useful information for the development and production of anode materials with high energy density and good mechanical properties.

Tensile yield behavior of isotactic polybutene-1

Relative to polyethylene or polypropylene, isotactic polybutene-1 (iPB-1) in form I is of high value for commercial applications due to its excellent mechanical properties; whereas, it tends to exhibit inconspicuous yield behavior closely related to poor energy consumption and thus weak toughness when subjected to uniaxial stretching. Regret, few studies had addressed how to control iPB-1 tensile yield behavior. As the tensile yield behavior of form I iPB-1 depended on the applied annealing temperature Ta and time ta as well as cyclic loading-unloading conditions, iPB-1 three-phase structure evolution was carefully characterized by wide-line solid-state 1H NMR. With Ta or ta increasing, the weakening tensile yield behavior of iPB-1 was accompanied by a decreasing rigid phase content which can be recognized by 1H NMR rather than DSC, revealing that a higher rigid phase content in iPB-1 favors a more significant typical tensile yield behavior. Therefore, the mutual contact possibility, dislocation and slip of iPB-1 rigid phase were proposed to be responsible for the tensile yield behavior. Furthermore, the weakening tensile yield behavior of iPB-1 due to annealing at a higher temperature can slowly recover back while further annealing at a lower temperature, implying the reversibility of destroyed rigid phase. Cyclic loading-unloading under a suitable fixed strain can promote formation of rigid phase in iPB-1, favoring appearance of the typical yield behavior. The results are of significance for understanding the structural origin of tensile yield behavior of iPB-1 and further tuning toughness of iPB-1 for its industrial applications.

Recent Advances in Biomaterial Design for Bone Regenerative Therapy: A Mini Review

Abstract: Longevity has been associated with morbidity and an increase in age-related illnesses, linked to tissue degeneration and gradual loss of biological functions. Bone is an important organ that gradually degenerates with increasing lifespan. The remodeling phase plays a huge role in maintaining the ability of bone to regenerate and maintain its stability and function throughout life. Hence, bone health represents one of the major challenges to elderly citizens due to the increase of injury associated with bone degeneration, such as fragility and risks of fractures. In the virtue of improving the regenerative function of bone tissues, a specialized field of bone tissue engineering (BTE) has been introduced to improve the current strategies in treating bone degenerative disorders. Most of the research performed in BTE focuses on the optimization of key components to generate new bone formation, including the scaffold. A scaffold plays a significant role in establishing the structural form that interconnects major elements of the tissue engineering triad. To date, many types of biomaterials have been explored in BTE, ranging from natural and synthetic materials to nanocomposites. However, ideal scaffolds that display excellent biocompatibility and mechanical properties, approved for clinical practices are yet available. This paper aims to describe the up-to-date advancements in scaffold for new bone generation, highlighting the essential elements and strategies in selecting suitable biomaterials for bone repair.

Effects of B2 ordered structure on the mechanical properties of TiZrHfCoNiCu high-entropy alloy

High-entropy alloys (HEAs) were once considered to be typical disordered solid solutions with various atoms randomly distributed in a lattice. Recent studies have found that owing to the chemical complexity of multiple primary elements, HEAs may also form ordered structures that directly influence their mechanical properties. In this study, B2-ordered and body-centered-cubic-disordered structures of TiZrHfCoNiCu HEAs were established using the special quasi-random structure method. The results of first principles calculations and ultrasonic wave velocity measurements indicated that the B2-ordered TiZrHfCoNiCu HEA exhibited superior phase stability, structural stability, and mechanical properties such as strength and hardness. Significantly, the results of this study revealed the physical mechanisms underlying the excellent mechanical properties of ordered HEAs and can guide their design and development accordingly.

Preparation method and industrialization of Ta-based ultra high temperature ceramic Tujia jar tea baking jar materials

The production materials of traditional Tujia jar tea often face problems such as poor high-temperature performance and poor durability. To improve the temperature resistance and durability of tea baking utensils, this study proposes a new type of TaC ultra-high temperature ceramic. TaC ceramics with excellent performance were prepared through powder metallurgy technology, including high-energy ball milling to ensure uniform mixing, followed by compression molding and high-temperature sintering. The test results demonstrated excellent mechanical properties, with a maximum depth of 948.67 nm and a contact depth of 954.45 nm, proving outstanding compressive and wear resistance. The hardness reached 21.4±0.5 Gpa, and the elastic modulus was 397.2±8.7 Gpa, both of which indicate its stability under high loads. In addition, the fracture toughness was 2.8±0.2 Mpa*m1/2. At a high temperature environment of 1000 °C, the oxidation rate constant of TaC ceramics was only 0.183 mg2 *cm−4 *h, which demonstrates its excellent high-temperature stability. The development of this TaC ceramic not only strengthened the traditional production process of Tujia teapots and tea roasting teapots, thereby improving the product’s service life, but also holds potential for other industrial applications that demand ultra-high temperature stability. These contributions provide new directions for the high-temperature application of ceramic materials and bring tangible economic and technological value to related industries.

Achieving enhanced thermal conductivity and mechanical properties in Mg-Zn-Gd-Zr alloys via regulation microstructure characteristics

It is well known that the microstructure of metallic materials determines the mechanical properties. However, the effect of microstructure on thermal conductivity lacks an accurate quantitative description of this relationship. In this work, the mechanism of variation in mechanical and thermal conductivities with microstructure was revealed by the characterization of cast, heat-treated, and extruded Mg-xZn-yGd-0.6Zr (wt%) alloys: ZV66, ZV62, and ZV26. The contributions of solution atoms, second phases, grain size, and dislocations to the yield strength and thermal conductivity were quantitatively calculated, and their effects on the plasticity and work-hardening behavior were qualitatively analyzed. The results show that hot extrusion promotes the precipitation of nanoprecipitates, such as MgZn2, Mg4Zn7, and Mg5Gd, resulting in the reduction of Zn and Gd solute atoms and the introduction of high-density dislocations and grain boundaries. The extruded ZV66 alloy exhibits excellent mechanical properties and thermal conductivity (a tensile yield strength of 232 MPa, an elongation of 22 %, and a thermal conductivity of 127.6 W/(m·k)); these values are better than those reported for similar products. The achievement of high strength and thermal conductivity is attributed to the precipitation of solute atoms to improve thermal conductivity in addition to grain boundary strengthening and work-hardening strengthening to improve strength. These findings provide new insights into achieving excellent strength–thermal conductivity property amalgamations in magnesium alloys by tailoring their microstructure.

A novel Cu-containing TiZrNb-based medium entropy alloy with excellent mechanical properties, antibacterial activity and biocompatibility

Bacterial infection and stress shielding remain significant challenges in the field of orthopedic implant applications. Therefore, it is imperative to develop novel medical implant materials that possess exceptional mechanical properties, antibacterial efficacy, and biocompatibility. The current study reports a novel Ti1.2Zr1.2Nb0.6Cu0.15 medium entropy alloy (MEA) with an optimal combination of mechanical properties, antibacterial activity and biocompatibility. In the Ti1.2Zr1.2Nb0.6Cu0.15 MEA, bits of copper-enriched phases were uniformly dispersed within the body-centered cubic matrix phase. The MEA exhibited good strength-ductility combination with the yield strength of 906 MPa and the fracture elongation of 17.4%. It is noteworthy that the MEA had a significantly lower elastic modulus (∼67GPa) compared to pure titanium and Ti6Al4V (∼110GPa) thus mitigating stress shielding. Meanwhile, the Cu ions released by the alloy resulted in remarkable antibacterial efficacy with an antibacterial rate of 99% against Escherichia coli. Furthermore, this alloy displayed corrosion resistance and biocompatibility comparable to those of the Ti6Al4V alloy. These findings provide novel insights for designing antibacterial implant materials with excellent comprehensive performance.

Synthesis of All-Peptide-Based Rotaxane from a Proline-Containing Cyclic Peptide.

Rotaxane cross-linkers enhance the toughness of the resulting rotaxane cross-linked polymers through a stress dispersion effect, which is attributed to the mobility of the interlocked structure. To date, the compositional diversity of rotaxane cross-linkers has been limited, and the poor compatibility of these cross-linkers with peptides and proteins has made their use in such materials challenging. The synthesis of a rotaxane composed of peptides may result in a biodegradable cross-linker that is compatible with peptides and proteins, allowing the fortification of polypeptides and proteins and ultimately leading to the development of innovative materials that possess excellent mechanical properties and biodegradability. However, the chemical synthesis of all-peptide-based rotaxanes has remained elusive because of the absence of strong binding motifs in peptides, which prevents an axial peptide from penetrating a cyclic peptide. Here, we synthesized all-peptide-based rotaxanes using an active template method for proline-containing cyclic peptides. The results of molecular dynamics simulations suggested that cyclic peptides with an expansive inner cavity and carbonyl oxygens oriented toward the center are favorable for rotaxane synthesis. This rotaxane synthesis method is expected to accelerate the synthesis of peptides and proteins with mechanically interlocked structures, potentially leading to the development of peptide- and protein-based materials with unprecedented functionalities.

Development in the Study of Mechanical Prop-erties and Damage Constitutive Models of Rub-ber-Reclaimed Concrete

Advances in rubber-reinforced concrete technology and its applications in engineering are cru-cial for the thorough recycling and safe disposal of waste tire rubber and construction debris. Rubber-reinforced concrete (RAC) is a concrete material produced by substituting some fine and coarse aggregates with waste rubber particles and recycled aggregates. The incorporation of waste rubber particles endows RAC with distinctive mechanical properties and a distinct damage constitutive model. The mechanical properties of rubber recycled concrete mainly in-clude compressive strength, tensile strength, flexural strength, and elastic modulus. Compared to traditional concrete, RAC exhibits slightly lower compressive and flexural strengths but sig-nificantly enhanced tensile strength. This is due to the changes in mechanical properties caused by the softness and elastic properties of rubber particles. In addition, the addition of rubber particles can also improve the energy absorption capacity and impact resistance of concrete. On the other hand, in order to describe the damage behavior of rubber recycled con-crete, some constitutive models were studied. Common models include linear elastic model, plastic model, and damage model. The linear elastic model is suitable for describing the be-havior of rubber recycled concrete during the elastic stage; The plastic model is suitable for describing its deformation behavior during the plastic stage; The damage model can better describe the fracture and failure behavior of rubber recycled concrete, including shear damage, tensile damage, and compression damage. Tailored to the unique characteristics of RAC, these models consider the stiffness of rubber particles and the deformation characteristics of the binding materials, enabling accurate predictions of the stress-strain behavior of RAC. In conclusion, rubber-reinforced concrete possesses excellent mechanical and durability proper-ties, which can be accurately described and predicted using appropriate constitutive models. These findings are crucial for advancing the application and development of rubber-reinforced concrete.

3D printing of interferon γ-preconditioned NSC-derived exosomes/collagen/chitosan biological scaffolds for neurological recovery after TBI

The reconstruction of neural function and recovery of chronic damage following traumatic brain injury (TBI) remain significant clinical challenges. Exosomes derived from neural stem cells (NSCs) offer various benefits in TBI treatment. Numerous studies confirmed that appropriate preconditioning methods enhanced the targeted efficacy of exosome therapy. Interferon-gamma (IFN-γ) possesses immunomodulatory capabilities and is widely involved in neurological disorders. In this study, IFN-γ was employed for preconditioning NSCs to enhance the efficacy of exosome (IFN-Exo, IE) for TBI. miRNA sequencing revealed the potential of IFN-Exo in promoting neural differentiation and modulating inflammatory responses. Through low-temperature 3D printing, IFN-Exo was combined with collagen/chitosan (3D-CC-IE) to preserve the biological activity of the exosome. The delivery of exosomes via biomaterial scaffolds benefited the retention and therapeutic potential of exosomes, ensuring that they could exert long-term effects at the injury site. The 3D-CC-IE scaffold exhibited excellent biocompatibility and mechanical properties. Subsequently, 3D-CC-IE scaffold significantly improved impaired motor and cognitive functions after TBI in rat. Histological results showed that 3D-CC-IE scaffold markedly facilitated the reconstruction of damaged neural tissue and promoted endogenous neurogenesis. Further mechanistic validation suggested that IFN-Exo alleviated neuroinflammation by modulating the MAPK/mTOR signaling pathway. In summary, the results of this study indicated that 3D-CC-IE scaffold engaged in long-term pathophysiological processes, fostering neural function recovery after TBI, offering a promising regenerative therapy avenue.

Microstructure Evolution and Mechanical Properties of 7A52 Aluminum Alloy Thin Sheet Repaired with Friction Stir Surfacing

A solid-state repair technique based on surface friction welding is investigated in depth to achieve excellent mechanical properties of damaged 7A52 aluminum alloy. The results show that the yield strength and tensile strength along the repair direction are 436 MPa and 502 MPa, respectively, at a rotational speed of 1400 rpm and a travel speed of 300 mm/min, which are about 157.9% and 129.7% of those before the defects were repaired, respectively, while the elongation is 17.2% compared to the base material. Perpendicular to the repair direction, the yield strength and tensile strength are 254 MPa and 432 MPa, which are 111.4% and 129.7% of those before the defects were repaired, respectively, while the elongation is 11.8% compared to the base material. The mechanical properties of the repaired areas are still improved compared to those of the defect-free sheets. On the one hand, this is attributed to the dynamic recrystallization of the nugget zone due to the thermo-mechanical coupling, resulting in the formation of a fine, equiaxed grain structure; on the other hand, the precipitated Mg2Si phase, which is incoherent within the base material, transforms into the Al12(Fe, Mn)3Si phase, as well as the precipitation of the Al6Mn phase and η′ phase, resulting in the enhancement of the properties. The material fracture at the junction of the nugget zone and the heat-affected zone occurs after repair, which is attributed to the significant difference in the texture of the nugget zone and the heat-affected zone, as well as to the stress concentration at the junction.

Reprogrammable, Sustainable, and 3D-Printable Cellulose Hydroplastic.

Modern human societies are highly dependent on plastic materials, however, the bulk of them are non-renewable commodity plastics that cause pollution problems and consume large amounts of energy for their thermal processing activities. In this article, a sustainable cellulose hydroplastic material and its composites, that can be shaped repeatedly into various 2D/3D geometries using just water are introduced. In the wet state, their high flexibility and ductility make it conducive for the shaping to take place. In the ambient environment, the wet hydroplastic transits spontaneously into rigid materials with its intended shape in a short time of <30 min despite a thickness of hundreds of microns. They also possess humidity resistance and are structurally stable in highly humid environments. Given their excellent mechanical properties, geometry reprogrammability, bio-based, and biodegradable nature, cellulose hydroplastic poses as a sustainable alternative to traditional plastic materials and even "green" thermoplastics. This article also demonstrates the possibility of 3D-printing these hydroplastics and the potential of employing them in electronics applications. The demonstrated hydroshapable structural electronic components show capability in performing electronic functions, load-bearing ability and geometry versatility, which are attractive features for lightweight, customizable and geometry-unique electronic devices.

Properties and Mechanism of Friction‐Reducing Silicone Rubber Modified with Hyperbranched Polysiloxane

AbstractDuring the utilization of silicone rubber, excessive friction can cause damage to the contact surface and the material itself. Therefore, friction‐reducing modification of silicone rubber has attracted much attention. In this paper, hyperbranched polysiloxanes with different structures is synthesized for friction‐reducing modification of silicone rubber. Infrared spectroscopy, nuclear magnetic resonance spectroscopy and amine titration tests reveal that hyperbranched polysiloxanes are successfully synthesized by the hydrolytic condensation of 3‐aminopropyltriethoxysilane and their Michael addition with four acrylates with different alkyl chains. The friction coefficients and mechanical properties of silicone rubber are evaluated. Hyperbranched polysiloxanes significantly reduces friction and maintained excellent mechanical properties of silicone rubber. Silicone rubber with butyl‐ester‐secondary‐amino hyperbranched polysiloxane displays the best overall performance, with static and dynamic friction coefficients decreasing by 33.99% and 43.16% compared with that of pure silicone rubber, respectively, and a tensile strength of 10.80 MPa. The friction‐reducing mechanism of hyperbranched polysiloxanes on silicone rubber is investigated by contact angle test and dynamic mechanical analysis. Hyperbranched polysiloxanes migrates to the surface due to the incompatibility of alkyl chains with silicone rubber matrix. Consequently, the shielding effect produced by hyperbranched polysiloxanes on the surface depresses the adsorption activity of silicone rubber surface thereby reducing friction.This article is protected by copyright. All rights reserved

Tribological evaluation of thermoplastic polyurethane-based bearing materials under water lubrication: Effect of load, sliding speed, and temperature

AbstractPolymers are widely used in bearing applications. In the case of water-lubricated stern tube bearings, thermoplastic polyurethane (TPU)-based composites are used due to their excellent wear resistance, corrosion resistance, and tunable mechanical properties. Their tribological performance, however, depends on operating conditions. In this work, TPU was blended with carbon fiber, graphene platelet, and ultra-high molecular weight polyethylene (UHMWPE). Friction tests of TPU based-composites against copper countersurface were carried out in water to mimic the actual operating conditions of the bearing. Most of the resulting contacts were in the boundary lubrication regime, in which friction was attributed to both contact mechanics of asperities as well as water lubrication. Our results show that the viscoelasticity of TPU has a considerable impact on its tribological performance. Water lubrication at 50 °C promotes the softening of polymer surface material during sliding, resulting in higher fluctuation in the coefficient of friction and wear loss. This is attributed to the reduced thermomechanical properties. In addition, Schallamach waviness is observed on worn surface. The tribological properties of TPU are significantly improved by the inclusion of carbon fiber, graphene platelet, and UHMWPE. The formation of graphene transfer-layers and UHMWPE transfer film reduces friction and wear loss, while the inclusion of carbon fiber enhances wear resistance due to improved mechanical properties and load bearing capacity.

Synthesis of star‐shaped epoxy resin with excellent mechanical properties using triazine as a skeleton

AbstractThe high‐performance development of advanced resin matrix composites has resulted in higher requirements for the mechanical strength and toughness of epoxy resin matrices. However, enhancing the toughness of the epoxy resin while maintaining its mechanical strength remains a considerable challenge. In this study, we utilized triazine rings as the skeleton, and introduced flexible chain segments and other forces into the polymer cross‐linked network to fabricate a star‐shaped epoxy resin (CNE) with exceptional mechanical properties. Benefiting from its meticulously designed rigid‐flexible integrated structure, after curing by 4,4′‐diaminodiphenylmethane (DDM), it demonstrated outstanding mechanical properties. The storage modulus of CNE/DDM was measured at up to 5.48 GPa; moreover, its tensile modulus and strength went as high as 5.04 GPa and 134.72 MPa respectively, and it also exhibited an elongation at break of up to 3.35%. The mechanical properties of CNE/DDM are far superior to those of AFG‐90 (N,N‐diglycidyl‐4‐glycidyloxyaniline)/DDM. Over all, the findings of this study thus provide an effective synthesis pathway toward achieving epoxy resins with high modulus, strength, and toughness.

Bottom-up Assembling Hierarchical Enamel-like Bulk Materials with Excellent Optical and Mechanical Properties for Tooth Restoration.

Enamel has good optical and mechanical properties because of its multiscale hierarchical structure. Biomimetic construction of enamel-like 3D bulk materials at nano-, micro-, mesh- and macro-levels is a challenge. We reported a novel facile, cost-effective, and easy large-scale bottom-up assembly strategy to align 1D hydroxyapatite (HA) nanowires bundles to 3D hierarchical enamel structure with the nanowires bundles layer-by-layer interweaving orientation. In the strategy, the surface of oleate templated ultralong HA nanowires with a large aspect ratio was functionalized with amphiphilic 10-methacryloyloxydecyl dihydrogen phosphate (MDP). Furtherly, the MDP functionalized HA nanowire bundles were assembled layer-by-layer with oriented fibers in a single layer and cross-locked between layers at a certain angle at mesoscale and macroscale in the viscous bisphenol A-glycidyl methacrylate (Bis-GMA) ethanol solution by shear force induced by simple agitation and high-speed centrifugation. Finally, the excessive Bis-GMA and ethanol were removed, and (Bis-GMA)-(MDP-HA nanowire bundle) matrix was densely packed under hot pressing and polymerized to form bulk enamel-like materials. The composite has superior optical properties and comparable comprehensive mechanic performances through a combination of strength, hardness, toughness, and friction. This method may open new avenues for precisely controlling the nanowires assembly to develop hierarchical nanomaterials with superior properties for many different applications. This article is protected by copyright. All rights reserved.