Evolution Of Properties Research Articles

Dynamic STEM-EELS for single-atom and defect measurement during electron beam transformations.

This study introduces the integration of dynamic computer vision-enabled imaging with electron energy loss spectroscopy (EELS) in scanning transmission electron microscopy (STEM). This approach involves real-time discovery and analysis of atomic structures as they form, allowing us to observe the evolution of material properties at the atomic level, capturing transient states traditional techniques often miss. Rapid object detection and action system enhances the efficiency and accuracy of STEM-EELS by autonomously identifying and targeting only areas of interest. This machine learning (ML)-based approach differs from classical ML in that it must be executed on the fly, not using static data. We apply this technology to V-doped MoS2, uncovering insights into defect formation and evolution under electron beam exposure. This approach opens uncharted avenues for exploring and characterizing materials in dynamic states, offering a pathway to increase our understanding of dynamic phenomena in materials under thermal, chemical, and beam stimuli.

Effect of brazing process on microstructure evolution and mechanical properties of Ti6Al4V/ZrO2 joints after laser surface treatment

Effect of brazing process on microstructure evolution and mechanical properties of Ti6Al4V/ZrO2 joints after laser surface treatment

Effect of Recycled Fibers on the Mechanical Properties and Durability of Sand Concrete

Recycling waste in construction materials is part of a sustainable development approach aimed at creating new materials with characteristics that have been shown to be competitive with traditional materials. In this context, this study aims to recover steel, copper and aluminum wastes from blacksmiths’ workshops together with the reuse thereof in the form of reinforcing fibers in sand concrete. However, in order to assess the impact of this waste on the concrete properties, we introduced such wastes in the form of fibers at different proportions (0.4 %, 0.8 % and 1.2 %). Further, a series of tests was then carried out to determine the evolution of the concrete characteristics in the fresh state (workability and density) and in the hardened state (compressive strength, flexural strength, compressive strength obtained using a sclerometer and the speed of ultrasonic waves), as well as the concrete’s durability (absorption coefficient by immersion, by capillarity and the porosity accessible to water). In closing, the behavior of the concrete was assessed in the face of a chemical attack by H2SO4 and HCl by measuring mass loss. In virtue of thus, the results obtained demonstrated a positive evolution of certain properties of sand concrete as a function of the type and percentage of fibers incorporated into the composition of the concrete.

Geometric and electronic properties of anionic precious metal gold doped boron clusters AuBn - (n = 10-20)

Abstract Recently, the Au-B covalent bonds in gold doped boron clusters has attracted great attention. However, there are fewer theoretical reports on exploration their ground state structures and stabilities, especially for The medium sizes. Here, we study the structural evolution and electronic properties of the anionic Au doped boron clusters with medium sizes of n from 10 to 20 using the unbiased cluster structural searches combined with density functional theory (DFT) calculations. The results reveal that the quasi-planar AuB18 - (1A, C1) cluster shows excellent stability and a large vertical separation energy (VDE) of 4.25 eV. The good consistency between the computationally simulated photoelectron spectra and the experimental spectra strongly supports the correctness of our low-lying structures. Further bonding analyses show that the well-stabilized aromatic AuB18 - cluster is due to the active σ interactions between Au atom (6s orbitals) and B units (2p orbitals), as well as the large number of σ-bonds in the B18 - moiety with π-aromaticity. These findings enriched the family of Au-B alloy clusters and metal-doped boron-based aromatic clusters, which provide valuable information for the experimental characterization and preparation of boron-rich alloy nanoclusters in the future.

Microstructure evolution and mechanical properties of Cu–9Ni–6Sn alloy during continuous cold deformation process

A Cu–9Ni–6Sn alloy bar with pronounced axial columnar grains and a diameter of 10.5 mm was fabricated by using directional solidification technology, which was directly cold-drawn into a superfine alloy wire with a diameter of 40 μm without intermediate annealing. The strength and microstructure evolutions of the Cu–9Ni–6Sn alloy during the cold drawing were studied. The results indicate that twinning is more likely to occur in fiber structures ranging from 60 to 120 nm. A dual-fiber structure consisting of <111> and <100> orientations formed after cold-drawing. Unexpectedly, a large number of deformation twins were discovered within the <111> fibrous texture and later transformed into detwinning structures, disrupting the axial fibrous texture. The generation of deformation twinning primarily results from Ni and Sn elements disrupting crystal symmetry and reducing stacking fault energy of the alloy and the formation of <111> texture. The combined effects of detwinning structures and dislocation wall induced work-softening of the alloy, enabling high-strain processing and ultimately yielding nanocrystalline grains, i.e., the Cu–9Ni–6Sn alloy underwent cold drawing with a high train of 11.23 and obtained an average grain size of ∼38 nm, which exhibited a tensile strength of 1453 MPa.

Effects of recrystallization on interfacial microstructure evolution and shear strength of TiAl alloy joints

The effects of dynamic recrystallization (DRX) and post-bonding heat treatment (PBHT) on the interfacial microstructure evolution and mechanical properties enhancement of Ti-43Al-4Nb-1Mo-0.2B alloy joints, subjected to various bonding parameters, were thoroughly investigated through detailed microstructural characterization and shear performance tests. A strip-like DRX area was observed at the interface when bonding at 1100 °C, ≥30 MPa, for 60 min. Equiaxial- γ grains underwent discontinuous dynamic recrystallization during the bonding process, and tended to form flat grains parallel to the lamellae direction during recrystallization annealing (1000 °C/6 h) owing to the hindrance imposed by the lamellae on both sides. The orientations of lamellae on the both sides of bonding interface affects the lamellae's stress distribution and deformation behavior at the bonding interface, subsequently influencing the DRX behavior and the width of the DRX zone. Static recrystallization (SRX) during the recrystallization annealing treatment can eliminate bonding defects of joints bonding at lower pressures or temperatures. Optimal joints with fully lamellar interfacial microstructure and excellent shear properties can be obtained through single-α phase annealing treatment. Lamellae microstructure tailored through PBHT can significantly enhance the quality of joints, attributed to the homogeneity of the microstructure between the interface and matrix. The highest shear strength of 478 MPa, accounting for 82 % of the matrix strength, was obtained under the bonding parameters of 1100 °C/30 MPa/60 min-1290 °C/15 min. This work provides important DB process parameters for fabricating of complex structural parts of TiAl alloy.

Temperature Effect on Microstructure Evolution and Mechanical Properties of Fe–28Mn–8Al–1C Lightweight Steel via Supersonic Fine Particle Bombardment

Temperature Effect on Microstructure Evolution and Mechanical Properties of Fe–28Mn–8Al–1C Lightweight Steel via Supersonic Fine Particle Bombardment

Design of a first-of-A-kind instrumented advanced test reactor irradiation Capsule experiment for In situ thermal conductivity measurements of metallic fuel

Metallic fuel undergoes dramatic microstructural changes early in life due to fission gas swelling until ∼2–3 at% burnup which affects the conductivity of the material, however the evolution of metallic fuel thermal conductivity during this early phase burnup has never been successfully measured in situ. The Irradiated Material Properties Accelerated Characterization Test (IMPACT) experiment will be the first in a series of experiments to irradiate advanced nuclear metallic fuel specimens with novel embedded thermal conductivity probes in ATR. In the current work the IMPACT experiment final design and supporting analysis is reported in detail. Results are evaluated for various reactor operational conditions to meet the functional requirements of the experiment. The first iteration of this IMPACT experiment will provide data regarding thermal properties evolution in uranium-zirconium (U10Zr) fuel, but this experiment vehicle is envisioned for future advanced fuels and structural materials irradiations in ATR.

Evolution of thermoelectric transport properties of Sb2Te3–Sb2Se3 solid-solution alloys depending on phase formation behavior

Sb2Te3-based alloys exhibit decent thermoelectric transport properties in the mid-temperature range above 550 K. However, the study on Sb2Te3 alloys has been limited in simple doping approach. Herein, evolution in the thermoelectric transport properties associated with the phase formation of solid solution alloys of Sb2(Te1−xSex)3 (x = 0, 0.25, 0.33, 0.5, 0.75, and 1.0) compositions is investigated to widen the strategy to solid solution alloying. A single phase of the Sb2Te3 rhombohedral structure formed from x = 0 to 0.5, whereas mixed phases with an orthorhombic structure of Sb2Se3 was observed at x = 0.75. The electrical conductivity weighted mobility were gradually decreased as Se content increases to x = 0.75. Consequently, the power factor was decreased gradually and significantly to 0.076 mW/mK2 for x = 0.75 (Sb2(Te0·25Se0.75)3) compared with 2.6 mW/mK2 of the pristine sample. The total thermal conductivity of 2.0 W/mK for the Sb2Te3 was significantly reduced gradually to 0.64 W/mK for x = 0.75 owing to simultaneous decrease in electrical and lattice thermal conductivities. The reduction in lattice thermal conductivity is mainly owing to the addition point defect scattering caused by the Se addition. Nevertheless, thermoelectric figure of merit zT of Sb2Te3 is gradually decreased from 0.64 to 0.11 for x = 0.75 at 650 K due to the degradation in electrical transport properties. Furthermore, the theoretical zT was estimated for all samples with varying carrier concentration based on single parabolic band model.

Propagation properties of a partially coherent Laguerre–Gaussian beam with multiple off-axis vortex phases

In this paper, a new theoretical model of a partially coherent Laguerre–Gaussian (LG) beam carrying multiple off-axis vortex phases was established. The evolution properties of the focused intensity of the beam after passing through a thin lens were theoretically studied, and then the modulation effect of multiple off-axis vortex phases on the beam with multiring structured intensity was explored. The results indicate that the multiple off-axis vortex phases can reconstruct the multiring structured intensity within the LG beam, thus generating a structured intensity with multilobe and multiring patterns. What is more, the intensity distribution of the lobes between two adjacent rings is complementary, and its number is related to the number and topological charge of off-axis vortex phases. However, with a decrease in the coherence, such a multilobe and multiring structured intensity distribution disappears, gradually evolves into a polygonal flat-topped distribution, and finally degenerates into a quasi-Gaussian distribution. This work demonstrates the effective regulation of multiple off-axis vortex phases on a beam with a multiring structured intensity and indicates that regulating the multiple off-axis vortices provides an additional degree of freedom for optical field modulation, which will have potential applications in the fields of optical micromanipulation and optical information storage.

The evolution of microstructure and mechanical properties of Inconel 625 alloy fabricated by laser powder bed fusion via novel hybrid scanning strategy

Four innovative hybrid scanning strategies (0° + 67°, 45° + 67°, 67° + 67° and 90° + 67°) of laser powder bed fusion (LPBF) have been proposed to tailor the microstructure and mechanical properties of Inconel 625 alloy for the first time. The experiment results revealed in sample I (0° + 67°) and sample IV (90° + 67°) a gradient structure is formed, progressing from randomly textured slender columnar crystals (001) to randomly textured equiaxial fine crystals, and finally to equiaxial and fine columnar crystals. In samples II (45° + 67°) and III (67° + 67°), isometric and columnar crystals are uniformly distributed throughout the sample. The tensile strengths of samples treated via hybrid scanning strategy in LPBF (sample I: 1270 ± 8 MPa, sample II: 1400 ± 6 MPa, sample III: 1390 ± 5 MPa and sample IV: 1360 ± 5 MPa) surpassed those of conventionally manufactured samples, including Inconel 625 alloy fabricated by LPBF using a single scanning strategy. This superiority can be attributed to the presence of fine grains, elevated residual stress levels, and the formation of stacking faults. The results of the nanoscratch test reveal that the bottom surface of samples I and IV demonstrates superior abrasion resistance in comparison to the top surface, which can be attributed to the higher relative density, finer grain size, lower elastic modulus and lower Schmidt factors in the bottom surface. These findings hold significant implications for tailoring the microstructure and properties of Inconel 625 alloy, especially in the realm of additively manufactured materials featuring heterogeneous structures.

High Strain Rate Deformation Behavior of Gradient Rolling AZ31 Alloys

A dynamic impact test was performed on as-rolled AZ31 alloys with gradient microstructure under various strains. The microstructural evolution and mechanical properties were systematically investigated. As the strain rate gradually increased, an increasing number of twins were formed, facilitating dynamic recrystallization (DRX), and the mechanical properties were also gradually improved. The microstructure became heterogeneous at higher strain rates, but the peak stress decreased. The impact process resulted in a significantly higher performance due to microstructural refinement, work hardening by dislocations, and precipitates. In addition, both the adiabatic shear band and the adjacent crack experienced a temperature rise that exceeded the recrystallization temperature of the alloys. This observation also explains the presence of ultrafine recrystallized grains within the adiabatic shear band and the appearance of molten metal around the crack.

High Strain Rate Deformation Behavior of Gradient Rolling AZ31 Alloys

A dynamic impact test was performed on as-rolled AZ31 alloys with gradient microstructure under various strains. The microstructural evolution and mechanical properties were systematically investigated. As the strain rate gradually increased, an increasing number of twins were formed, facilitating dynamic recrystallization (DRX), and the mechanical properties were also gradually improved. The microstructure became heterogeneous at higher strain rates, but the peak stress decreased. The impact process resulted in a significantly higher performance due to microstructural refinement, work hardening by dislocations, and precipitates. In addition, both the adiabatic shear band and the adjacent crack experienced a temperature rise that exceeded the recrystallization temperature of the alloys. This observation also explains the presence of ultrafine recrystallized grains within the adiabatic shear band and the appearance of molten metal around the crack.

Extension of a phase-field KKS model to predict the microstructure evolution in LPBF AlSi10Mg alloy submitted to non isothermal processes

The out-of-equilibrium heterogeneous microstructure typical of AlSi10Mg processed by Laser Powder Bed Fusion (LPBF) is often modified by further heat treatment to improve its ductility. According to literature, extensive experimental investigations are generally required in order to optimize these heat treatments. In the present work, a phase-field approach is developed based on an extended Kim–Kim–Suzuki (KKS) model to guide and accelerate the post-treatment optimization. Combined with CALculation of PHAse Diagrams (CALPHAD) data, this extended KKS model predicts microstructural changes under anisothermal conditions. To ensure a more physical approach, it takes into account the enhanced diffusion by quenched-in excess vacancies as well as the elastic energy due to matrix/precipitate lattice mismatch. As the developed model includes the computation of the evolution of the thermo-physical properties, its results are validated through comparison with experimental DSC curves measured during the non-isothermal loading of as-built LPBF AlSi10Mg. The computed microstructure evolution reproduces the microstructural observation and successfully explains the peaks in the DSC heat flow curve. It thus elucidates the detailed microstructural evolution inside the eutectic silicon phase by considering the growth and coalescence of silicon precipitates and the matrix desaturation.

Assessing the key concerns in snow storage: a case study for China

Abstract. Snow security plays a crucial role in ensuring the success of winter sports events and supporting the ski industry. One effective approach to enhancing snow reliability is through snow storage. Despite its potential benefits, investigations of snow storage in China have been limited. To address this gap, we implemented snow storage covered with geotextiles at two venues, namely the Big Air Shougang (BAS) in Beijing for the Beijing 2022 Winter Olympic Games and the National Biathlon Center (NBC) in Chongli for the Beijing 2022 Winter Paralympic Games, in response to possible extreme meteorological conditions. To assess the key concerns associated with snow storage, ablation (the process of snow loss) and snow properties, we introduced a fine-snow-pile monitoring system and the SNOWPACK model. Our observations revealed that, by 18 February, the snow pile at BAS had lost 158.6 m3 of snow (equivalent to 6.7 % of the initial volume). Subsequently, the accelerated ablation was influenced by meteorological conditions and a thin geotextile layer. Between 16 January and 15 April, the snow pile at BAS experienced a total loss of 1242.9 m3 of snow (corresponding to 52.7 % of the original volume). Regarding snow properties, no significant variations were modeled at the study sites, except for the upper part of the snow piles. Notably, the evaporation of the geotextiles contributed to slowing the ablation process. Consequently, we discourage the use of impermeable coverage schemes for snow storage. Instead, the thickness of the cover played a vital role in preserving the snow pile. At Beijing and Chongli, the 0.7 and 0.4 m thick cover layers, respectively, were found to protect approximately half of the snow pile height over the summer season. Importantly, the evolution of snow properties was consistent across the different cover thicknesses. The findings of our study have implications for the ski industry in China, as they provide valuable insights into snow storage techniques and their impact on snow reliability.

Automated Scanning Dielectric Microscopy Toolbox for Operando Nanoscale Electrical Characterization of Electrolyte‐Gated Organic Transistors

AbstractElectrolyte‐gated organic transistors (EGOTs) leveraging organic semiconductors' electronic and ionic transport characteristics are the key enablers for many biosensing and bioelectronic applications that can selectively sense, record, and monitor different biological and biochemical processes at the nanoscale and translate them into macroscopic electrical signals. Understanding such transduction mechanisms requires multiscale characterization tools to comprehensively probe local electrical properties and link them with device behavior across various bias points. Here, an automated scanning dielectric microscopy toolbox is demonstrated that performs operando in‐liquid scanning dielectric microscopy measurements on functional EGOTs and carries out extensive data analysis to unravel the evolution of local electrical properties in minute detail. This paper emphasizes critical experimental considerations permitting standardized, accurate, and reproducible data acquisition. The developed approach is validated with EGOTs based on blends of organic small molecule semiconductor and insulating polymer that work as accumulation‐mode field‐effect transistors. Furthermore, the degradation of local electrical characteristics at high gate voltages is probed, which is apparently driven by the destruction of local crystalline order due to undesirable electrochemical swelling of the organic semiconducting material near the source electrode edge. The developed approach paves the way for systematic probing of EGOT‐based technologies for targeted optimization and fundamental understanding.

Microstructural Evolution and Mechanical Property of Cu–Cr–Zr–ZrB2 Composites Subjected to Cryorolling and Aging Treatment

A new strategy has been developed to combine the nanotwins and dual‐scale particles into copper matrix composites and the comprehensive properties of Cu–1Cr–0.3Zr–1ZrB2 exhibit excellently with the addition of intermediate aging and cryorolling. The effects of different deformation processes on the evolution of microstructure, room temperature, and elevated‐temperature mechanical properties are investigated. The result demonstrates that the number of nanoscale Cr precipitates increases obviously after intermediate aging. The nanosized Cr precipitates impede the movement of grain boundaries and dislocations, resulting in the refinement of deformation bands and the dislocation tangle. The combined effect of intermediate aging and cryorolling also improves the formation of nanotwins, which plays an important role in enhancing the tensile strength of composites. The tensile strength, elongation, and conductivities of the composites subjected to two‐step cryorolling reach 653 MPa, 8.02%, and 79.51% IACS, respectively, showing an optimum comprehensive property. In addition, the stable nanotwins and the uniform distribution of dual‐scale particles inhibit the recrystallization process at elevated temperatures, contributing to improving the mechanical behavior at elevated temperatures and heat‐resistant performance of composites.

Long‐Life Pillar[5]quinone Cathode for Aqueous Zinc‐Ion Batteries

AbstractAqueous zinc ion batteries (ZIBs) are currently gaining a significant amount of attention as a low‐cost and high safety energy storage option. While mostly inorganic structures are used as cathode materials in aqueous zinc batteries, these materials undergo structural degradation, therefore, alternative organic cathodes are expected to be developed to replace inorganic materials in aqueous zinc ion batteries (AZIBs). In this work, pillar[5]quinone (P5Q) is used as a cathode in AZIBs for the first time. Besides investigating the charge storage mechanism and interfacial property evolution of P5Q by various ex situ analyses, electrochemical quartz crystal microbalance (EQCM) and density functional theory (DFT) demonstrates both Zn2+ and H+ incorporation. The P5Q exhibits &gt;99 % Coulombic efficiency through 10000 cycles at ultra‐fast (500 °C) current density, yielding a capacity value of approximately 120 mAh g−1 at the end of the cycle. When the current density is changed from 500 °C to 120 °C, an initial discharge capacity of approximately 182 mAh g−1 is achieved, demonstrating outstanding performance with over 80 % capacity retention for the subsequent 7000 cycles.

Research on reasonable coal pillar staggered distance in shallow multi-seam mining

In shallow buried closely spaced multi-seam mining in Jurassic Coalfield in western China, due to specific reasons, it is inevitable that the lower and upper coal seam working faces and coal pillars are overlapped, resulting in stress concentration, uneven subsidence of the ground surface, the deformation and damage of the roadway intensified. In order to decrease surface damage and stress concentration, combined with physical simulation, engineering practices and theoretical analyses, reasonable coal pillar staggered distance in shallow multi-seam mining is investigated. The evolution properties of three-field (stress field, displacement field and fracture field) based on coal pillar staggered distance (CPSD) were analyzed, the determination method of rational CPSD was put up. Research findings reveal that concentrated stress results from upper and lower pillar stress superposition, and the lower pillar should be arranged in the low-stress zone. Through rational pillar arrangement, the uneven subsidence of surface is reduced, and the concentrated fractures of overlying strata and surface are decreased. For No. 1–2 and No. 2–2 coal seam mining, as CPSD is increased, subsidence above the upper coal pillar increases and the uneven subsidence of surface decreases, the concentrated stress reduced by 25%, the width of surface fractures reduced 81.1%. Consequently, rational CPSD on the basis of coupling control of three-field can be determined, the reasonable CPSD is 40–55 m. It can provide a method to realize underground safe mining and ground surface green mining in shallow multi-seam mining.

Microstructures evolution, texture characteristics and mechanical properties of extruded Mg-9Gd-3Nd-1Zn-1Sn-0.5Zr alloy

In this study, a comprehensive investigation was conducted to explore the microstructural evolution, texture characteristics, and mechanical properties of extruded Mg-9Gd-3Nd-1Zn-1Sn-0.5Zr alloys with varying extrusion ratios (ERs). Moreover, the high-temperature mechanical properties of the alloy and analyzed the corresponding fracture mechanisms were investigated. The findings unveiled a refinement in grain size and an improvement in homogeneity with increasing ER. Such refinement coincided with the disruption of coarse Mg5(Gd, Nd, Zn) eutectic phases, facilitating dynamic recrystallization. As a result, the extruded alloy manifested small grains, significant orientation difference in grain boundaries, and a weakened texture. In particular, the average grain size in the extrusion direction (ED) diminished to 13.29 μm (ER4), 9.62 μm (ER16), and 4.05 μm (ER25). And the ED texture of the ER4 alloy featured a strong (0001) basal bimodal pattern, whereas the ER16 and ER25 alloys showcased a random texture. Furthermore, the ER25 alloy displayed notable work hardening at temperatures of 200 °C or below, exerting a significant influence on its stress–strain curve. The ultimate tensile strength (UTS) of the alloy remained consistently above 275.09 MPa, demonstrating ductile fracture characteristics characterized by numerous dimples at temperatures of 200 °C or higher. The study identified the second phase as the primary contributor to enhancing the high-temperature tensile characteristics of the alloy. In summary, this research developed a unique high-strength Mg-9Gd-3Nd-1Zn-1Sn-0.5Zr alloy characterized by fine grain and texture strengthening. The alloy exhibited remarkable stability at temperatures of 250 °C or lower, making it a promising candidate for applications in high-temperature applications.