The development and application of the Envelope Peak-over-Threshold (EPOT) method is summarized for the roll motion of a ship in irregular waves. The method is based on the conventional Peak-over-Threshold (POT) method, but uses an envelope of the peaks for declustering the data. As suggested by a reduced-order model, a power-law tail should be applicable for the peaks of roll motions, which allows the introduction of physical considerations into the statistical model. A data-driven Generalized Pareto distribution (GPD) is applied to study the behavior of the shape parameter on large-volume samples in order to confirm the theoretical prediction of the tail structure. The physics-informed statistical model approximates data above a suitable threshold with a Pareto distribution, while the threshold is determined with a prediction error criterion. An example is included, where extrapolations with GPD are compared to the physics-informed model.