A method for identifying fuel/tracer mixtures suitable for laser-induced fluorescence (LIF) measurements of in-cylinder equivalence ratios is presented. The concentrations of multiple LIF tracers are adjusted so that the total vapor-phase fluorescence is proportional to the instantaneous mass evaporation rate. In this way, LIF image intensities are proportional to local fuel mass, which in turn can be converted into local fuel equivalence ratios. Uncertainty generated by pressure and temperature dependencies of ketone tracers is assessed. A two-fuel-component mixture developed with the method is used to measure two-dimensional fuel equivalence ratios in an optically accessible direct-injection spark-ignition engine. Results are compared with the equivalence ratio distribution of a mixture with a single fuel component. It is found that the effect of fuel volatility on the equivalence ratio distribution at the time of spark becomes more distinct as the start-of-injection timing is retarded.
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