Environmental Risk Research Articles

The effects of illicit drug use during pregnancy and parental hostility on problem behaviors in school-aged children over and above genetic influences.

Previous work has examined the impact of prenatal illicit drug use (PDU) on children's problem behaviors. However, many PDU-related risk factors, including genetic and rearing environmental risks, can also influence offspring's problem behaviors, thus confounding PDU, genetic, and rearing environmental influences. This study aimed to (a) identify effects of PDU on school-aged children's problem behaviors, including both externalizing and internalizing behaviors at Age 7, after controlling genetic and specific rearing environmental (e.g., maternal and paternal hostility at Ages 4.5 and 6) influences and (b) examine interaction effects between PDU and maternal and paternal hostility in predicting children's problem behaviors at Age 7. We used a parent-offspring adoption design to partition genetic and prenatal effects from postnatal rearing environmental influences. Participants were 561 children adopted at birth (42% female; 56% White, 19% multiracial, 13% Black/African American, 11% Latine, and 1% other), their adoptive parents, and their birth parents. Results indicate that PDU did not show a direct impact on Age 7 problem behaviors before or after controlling genetic risks and adoptive mother's and father's hostility. However, we found significant interactions between adoptive father's hostility and PDU when predicting children's problem behaviors, such that higher paternal hostility was associated with higher externalizing and internalizing behaviors for children whose birth mothers were non-use or rare use of illicit drugs during pregnancy. The results suggest that different from non- or rare drug-exposed children, higher levels of PDU may override the effects of paternal hostility, but not maternal hostility, on problem behaviors at Age 7. (PsycInfo Database Record (c) 2024 APA, all rights reserved).

Research Progress of Antibiotic Resistance Genes Removal in Food Waste During Anaerobic Digestion

Food waste is one of the important reservoirs of antibiotic resistance genes （ARGs）, and its resource utilization has potential environmental risks. Anaerobic digestion （AD） technology can concurrently achieve resource recovery and ARGs removal, which is one of the popular resource technologies for food waste management. However, the removal efficiency of ARGs during the AD process is limited, and thus the safety of digestate for agricultural use is still questioned. Therefore, how to improve the performance of ARGs removal during the AD process is critical for efficient and environmentally friendly bioconversion of food waste. This study summarized the transmission pathways and mechanisms of ARGs in food waste； discussed the effects of different operation parameters on the transmission of ARGs in food waste during the AD process； described the research progress of exogenous addition of conductive materials, feedstock pretreatment, etc., strategies to enhance the removal of ARGs； and analyzed the migration regularity and removal mechanism of ARGs in food waste during the AD process, which mainly included microbial community structure evolution, mobile genetic element changes, and environmental factor changes. Finally, this study prospected the future improvement of methane yield and ARGs removal in the AD process of food waste based on the existing research.

Ionic liquid based surfactant-free microemulsion as a new protocol for preparation of visible light active poly(methyl methacrylate)/TiO2 nanocomposite

The practical application of sensitized TiO2 nanocomposites is very satisfying due to their high photon utilization in visible light, simple recovery without affecting the photocatalytic performance, high energy efficiency, low potential environmental risk, and low operational costs. The objective of this study is developing the ionic liquid (IL)-based surfactant-free microemulsion, as a soft template, for preparation of a novel type of sensitized poly(methyl methacrylate)/TiO2 nanocomposite (PMMA/TiO2/IL). For this purpose, a series of visible light-responsive PMMA/TiO2/IL transparent nanocomposites were prepared in microemulsion composed of methyl methacrylate monomer, 1-buthyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), and 1-buthanol as amphi-solvent. Techniques such as diffuse reflectance spectroscopy (DRS)), attenuated total reflectance-fourier transform infrared (ATR-FTIR) spectroscopy, atomic force microscopy (AFM), field emission scanning electron microscopy (FE-SEM), and energy dispersive X-ray analysis (EDX) were used to characterize prepared nanocomposites. Photocatalytic degradation of methyl orange dye under visible light illumination, as an application in wastewater treatment, with the investigation of the influence of TiO2 content in the nanocomposite, pH, and nanocomposite reusability on photodegradation efficiency was studied and maximum value of 93.9% obtained at optimum conditions. The FESEM analysis indicated that the utilization of a relatively low amount of ionic liquid and also in absence of the surfactant ensures the monodispersity of the visible light sensitized TiO2 nanoparticles in the polymer matrix.

A novel approach for nanobubble generation toward biomedical applications

The stability of free-standing nanobubbles is a long-standing controversial problem due to the Laplace pressure catastrophe at the nanoscale. In most industrial circumstances, a large quantity of surfactants is required as stabilisers or emulsifiers to generate stable bubbles or foams. However, when surfactants exceed a certain level, they can adversely affect living organisms and pose environmental risks. Towards biomedical use, we investigated nanobubble generation through a mini-extruder in amino acid solutions. Herein, we considered glycine (having two acid dissociation constants, i.e. pKa values) and lysine (having three pKa values) as two model amino acids, conducting experiments with various concentrations (0.1 M, 0.5 M and 1 M), along with different pH values (above, equal to, and below the isoelectric points of each amino acids; 5.97 for glycine and 9.74 for lysine). Our results showcased the proof of concept that amino acids can stabilise nanobubbles in bulk for a few days. We achieved remarkable products of nanobubbles via nanopores by extrusion, with reproducible size distribution and stability. We also compared the extrusion protocol with the commonly used ultrasound method. It turned out that extrusion generated samples with smaller sizes and higher concentrations than sonication. This study provides a reliable protocol for generating small-scale nanobubbles for biomedical use, showing great potential in drug delivery for medical treatment.

Tailoring the physicochemical and dielectric properties of natural polymer using graphene nanoplatelet as filler

AbstractBio‐based flexible dielectric substrates have gained tremendous attention for their potential to reduce environmental risks from nonbiodegradable electronic waste. The present study demonstrates the fabrication of facile, nontoxic, and biodegradable chitosan‐based flexible dielectric substrate using graphene nanoplatelet (GNP) as a nanofiller. The detailed impact of different concentrations of GNP (1, 2, and 3 wt%) into the chitosan (CS) matrix was studied on physicochemical, morphological, mechanical, electrical, and thermal properties. The fabricated CS/GNP composites showed improved mechanical strength, thermal stability, and electrical properties compared with unmodified CS film. The composites exhibited excellent thermal stability (200°C) with a promising biodegradation rate (within 6 days). The mechanical strength of the unmodified CS film was increased unequivocally with 2 wt% GNP loading with tensile strength of 23.56 Mpa. Furthermore, the current–voltage (I–V) characteristic curves for CS/GNP (2%) and CS/GNP (3%) showed similar current conduction and ohmic behavior in flat, bending, and flat‐after‐bending modes. The dielectric measurements revealed that the CS/GNP composite with 2 wt% filler exhibited optimal performance having permittivity (έ) of 32.71 (at 102 Hz) with low dielectric loss of 0.04 (at 106 Hz). These results suggest that the dielectric films offer strong prospects as an eco‐friendly alternative for various applications.Highlights Biodegradable chitosan‐based flexible dielectric films were prepared. Films were made using a simple solvent casting method with 1–3 wt% GNP filler. Optimum physicochemical and electrical properties were seen at 2 wt% GNP. CS/GNP (2%) film exhibited ohmic behavior in both flat and bending modes. Excellent dielectric properties were achieved at 2 wt% GNP filler.

Adsorbent based on MOF-5/cellulose aerogel composite for adsorption of organic dyes from wastewater

Industries persistently contribute to environmental pollution by releasing a multitude of harmful substances, including organic dyes, which represent a significant hazard to human health. As a result, the demand for effective adsorbents in wastewater treatment technology is steadily increasing so as to mitigate or eradicate these environmental risks. In response to this challenge, we have developed an advanced composite known as MOF-5/Cellulose aerogel, utilizing the Pampas plant as a natural material in the production of cellulose aerogel. Our investigation focused on analyzing the adsorption and flexibility characteristics of this novel composite for organic dye removal. Additionally, we conducted tests to assess the aerogel’s reusability and determined that its absorption rate remained consistent, with the adsorption capacity of the MOF-5/cellulose aerogel composite only experiencing a marginal 5% reduction. Characterization of the material was conducted through XRD analysis, revealing the cubic structure of MOF aerogel particles under scanning electron microscopy. Our study unequivocally demonstrates the superior adsorption capabilities of the MOF-5/cellulose aerogel composite, particularly evident in its efficient removal of acid blue dye, as evaluated meticulously using UV–Vis spectrophotometric techniques. Notably, our findings revealed an impressive 96% absorption rate for the anionic dye under acidic pH conditions. Furthermore, the synthesized MOF-5/cellulose aerogel composite exhibited Langmuir isotherm behavior and followed pseudo-second-order kinetics during the absorption process. With its remarkable absorption efficiency, MOF-5/cellulose aerogel composites are poised to emerge as leading adsorbents for water purification and various other applications.

Enhancing neonicotinoid removal in recirculating constructed wetlands: The impact of Fe/Mn biochar and microbial interactions

Neonicotinoids pose significant environmental risks due to their widespread use, persistence, and challenges in elimination. This study explores the effectiveness of Fe/Mn biochar in enhancing the removal efficiency of neonicotinoids in recirculating constructed wetlands (RCWs). Results demonstrated that incorporating Fe/Mn biochar into RCWs significantly improved the removal of COD, NH4+-N, TN, TP, imidacloprid (IMI), and acetamiprid (ACE). However, the simultaneous presence of IMI and ACE in the RCWs hindered the elimination of NH4+-N, TN, and TP from wastewater. The enhanced removal of nutrients and pollutants by Fe/Mn biochar was attributed to its promotion of carbon, nitrogen, and phosphorus cycling in RCWs, along with its facilitation of the adsorption and biodegradation of IMI and ACE. Metagenomics analysis demonstrated that Fe/Mn biochar altered the structure and diversity of microbial communities in RCWs. A total of 17 biodegradation genes (BDGs) and two pesticide degradation genes (PDGs) were identified within RCWs, with Fe/Mn biochar significantly increasing the abundance of BDGs such as cytochrome P450. The potential host genera for these BDGs/PDGs were identified as Betaproteobacteria, Acidobacteria, Nitrospiraceae, Gemmatimonadetes, and Bacillus. This study offers valuable insights into how Fe/Mn biochar enhances pesticide removal and its potential application in constructed wetland systems for treating pesticide-contaminated wastewater.

Enhancing neonicotinoid removal in recirculating constructed wetlands: The impact of Fe/Mn biochar and microbial interactions

Neonicotinoids pose significant environmental risks due to their widespread use, persistence, and challenges in elimination. This study explores the effectiveness of Fe/Mn biochar in enhancing the removal efficiency of neonicotinoids in recirculating constructed wetlands (RCWs). Results demonstrated that incorporating Fe/Mn biochar into RCWs significantly improved the removal of COD, NH4+-N, TN, TP, imidacloprid (IMI), and acetamiprid (ACE). However, the simultaneous presence of IMI and ACE in the RCWs hindered the elimination of NH4+-N, TN, and TP from wastewater. The enhanced removal of nutrients and pollutants by Fe/Mn biochar was attributed to its promotion of carbon, nitrogen, and phosphorus cycling in RCWs, along with its facilitation of the adsorption and biodegradation of IMI and ACE. Metagenomics analysis demonstrated that Fe/Mn biochar altered the structure and diversity of microbial communities in RCWs. A total of 17 biodegradation genes (BDGs) and two pesticide degradation genes (PDGs) were identified within RCWs, with Fe/Mn biochar significantly increasing the abundance of BDGs such as cytochrome P450. The potential host genera for these BDGs/PDGs were identified as Betaproteobacteria, Acidobacteria, Nitrospiraceae, Gemmatimonadetes, and Bacillus. This study offers valuable insights into how Fe/Mn biochar enhances pesticide removal and its potential application in constructed wetland systems for treating pesticide-contaminated wastewater.

Environmental remediation potential of a pioneer plant (Miscanthus sp.) from abandoned mine into biochar: Heavy metal stabilization and environmental application

Pyrolysis stands out as an effective method for the disposal of phytoremediation residues in abandoned mines, yielding a valuable by-product, biochar. However, the environmental application of biochar derived from such residues is limited by the potential environmental risks of heavy metals. Herein, Miscanthus sp. residues from abandoned mines were pyrolyzed into biochars at varied pyrolysis temperatures (300–700 °C) to facilitate the safe reuse of phytoremediation residues. The results showed that pyrolysis significantly stabilizes heavy metals in biomass, with Cd exhibiting the most notable stabilization effect. Acid-soluble/exchangeable and reducible fractions of Cd decreased significantly from 69.91 % to 2.52 %, and oxidizable and residue fractions increased approximately 3.24 times at 700 °C. The environmental risk assessment indicated that biochar pyrolyzed over 500 °C pose lower environmental risk (RI < 30), making them optimal for the safe utilization of phytoremediation residues. Additionally, adsorption experiments suggested that biochars prepared at higher temperature (500–700 °C) exhibit superior adsorption capacity, attributed to alkalinity and precipitation effect. This study highlights that biochars produced by pyrolyzing Miscanthus sp. from abandoned mines above 500 °C hold promise for environmental remediation, offering novel insight into the reutilization of metal-rich biomass.

Innovative ceramic membrane plate filtration system for sustainable semiconductor industry wastewater treatment: A pilot scale study

Conventional methods of coagulation and flocculation are used to treat semiconductor industry wastewater, but they often fail to recover valuable silica particles and result in resource wastage and environmental risks. Despite the potential of membrane filtration for silica recovery, limited research is available on scaling up the process beyond laboratory scale. Therefore, this study aims to develop and evaluate the feasibility of pilot-scale ceramic membrane plate filtration system for treatment of diluted back grinding wastewater (DBGW) from the semiconductor industry. Specific objectives include assessing permeate quality in terms of rejection and benchmarking it to established standards, identifying fouling mechanisms, characterising sludge constituents and conducting life cycle assessment (LCA) to evaluate the environmental impacts of the ceramic membrane plate filtration system compared with conventional treatment. The pilot membrane plate filtration system demonstrated significant reductions of 85.71 % in chemical oxygen demand, 67.31 % in total suspended solid, 75 % in nitrate–nitrogen (NO3-N), 33.33 % in ammonia nitrogen (NH3-N), 74.07 % in colour and 98.37 % in turbidity. Effective mitigation of irreversible fouling during DBGW filtration was achieved using 0.1 M NaOCl, resulting in a flux recovery ratio of 95.35 %. The retained silica on the membrane exhibited a purity of 64 wt%, as confirmed by EDX analysis. The treated wastewater met various regulatory standards including Malaysia Industrial Effluent Discharge (Standard A and Standard B), restricted USEPA standard, NWQS Class IIA, IIB, III, IV and V, and Singapore’s greywater standards. The fouling mechanism of silica on the ceramic membrane was well represented by the standard blocking model with an R2 value of 0.92. Furthermore, LCA confirmed that the utilisation of the ceramic membrane plate filtration system exhibited fewer environmental impacts than conventional coagulation–flocculation methods. This study represents a significant breakthrough in wastewater treatment in the semiconductor industry in terms of concurrent recovery and reuse of silica to address environmental and resource sustainability concerns.

The critical role of organic matter for cadmium-lead interactions in soil: Mechanisms and risks

Understanding the interaction mechanisms between complex heavy metals and soil components is a prerequisite for effectively forecasting the mobility and availability of contaminants in soils. Soil organic matter (SOM), with its diverse functional groups, has long been a focal point of research interest. In this study, four soils with manipulated levels of SOM, cadmium (Cd) and lead (Pb) were subjected to a 90-day incubation experiment. The competitive interactions between Cd and Pb in soils were investigated using Fourier transform infrared spectrometer (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and X-ray adsorption near-edge structure (XANES) analysis. Our results indicate that Pb competed with Cd for adsorption sites on the surface of SOM, particularly on carboxyl and hydroxyl functional groups. Approximately 22.6 % of Cd adsorption sites on humus were occupied by Pb. The use of sequentially extracted exchangeable heavy metals as indicators for environment risk assessments, considering variations in soil physico-chemical properties and synergistic or antagonistic effects between contaminants, provides a better estimation of metal bioavailability and its potential impacts. Integrating comprehensive contamination characterization of heavy metal interactions with the soil organic phase is an important advancement to assess the environmental risks of heavy metal dynamics in soil compared to individual contamination assessments.

Optimising miniaturised hydrocyclones for enhanced separation of microplastics

Microplastics, particularly those in the 5–20µm range, pose substantial risks in aquatic environments, yet effective removal techniques are limited. This study assesses two critical geometric parameters of a 10 mm mini-hydrocyclone: inlet radius and insertion angle. Along with the inlet velocity, they are optimised collectively to enhance the MPs’ removal. Computational Fluid Dynamics (CFD) simulations using the Mixture model and Reynolds stress model were employed to track the particle–water–air interactions, revealing the flow dynamics and absence of an air core. The Response Surface Methodology (RSM) using a Box-Behnken design of experiments was adopted to assess the impact of the geometric and operational parameters and determine the optimal design. Recovery efficiency, concentration efficiency, and split rate were recorded during experiments and compared with CFD results, showing a good agreement between experiments and CFD simulations. The resulting novel design achieved an 88.53% MPs recovery and a concentration efficiency of 1.83, which represents an obvious improvement over the commercial design’s MPs recovery efficiency of 79.97% and concentration efficiency of 1.68. Simulations reveal that the novel design shortens the path for MPs through the forced turbulence region and modifies the velocity and turbulence fields, enhancing the concentration gradient of MPs within the mini-hydrocyclone’s chamber. Moreover, the novel design exhibits a more robust response to inlet velocity variations, a crucial advantage for its application in arrays. Experiments further confirm that a matrix composed of 10 novel mini-hydrocyclones achieves 10 percentage points higher recovery efficiency than the matrix with 10 commercial mini-hydrocyclones. These findings mark a significant step towards effective MP removal, addressing a critical environmental issue.

Sustainable supply chain management and CEO compensation: does CSR committee matter?

ABSTRACT This study extends the existing literature on sustainable supply chain management (SSCM) and executive compensation by focusing on an important part of the company’s value chain, namely its supply chain (SC) and the associated risks. Through a quantitative study of companies listed on the SBF 120 over the period 2007–2021, our results emphasise the role of CSR committee to improve the relationship between the implementation of sustainable SC initiatives and CEO compensation. The CSR committee can be a way to improve the identification and consideration of environmental and social risks linked to the SC. We demonstrate the advantage of the presence of a CSR committee for the CEO themselves by increasing their compensation when they are more engaged in CSR activities. This result adds original insights to the existing literature which has already demonstrated the benefit of this committee for the other stakeholders. Thus, our results encourage the boards to implement this non-binding CSR committee as a supplementary governance mechanism.

Temporal metabolic dynamics and heterogeneity of viable but nonculturable Pseudomonas aeruginosa induced by chlorine disinfection at single-cell resolution

Characterizing the metabolic network and dynamics of Viable But Nonculturable (VBNC) bacteria is crucial for their identification and control. In this study, single-cell Raman spectroscopy was used to explore the metabolic intricacies of VBNC P. aeruginosa induced by chlorine disinfection over 24 h. VBNC P. aeruginosa exhibited significant reductions of 75.98 %, 84.26 % and 81.07 % in carbohydrate, protein and nucleic acid Raman peaks, signaling decreased metabolic activity in these crucial components. Intriguingly, lipid metabolism in VBNC P. aeruginosa remained robust, indicating a potential adaptation to environmental stress. Furthermore, this study analyzed Raman characteristic peaks to examine metabolic conversion in these bacteria. VBNC P. aeruginosa displayed distinct phase-specific metabolic conversion patterns compared to culturable ones. These findings shed light on the temporal dynamics of metabolic processes, such as lipid-carbohydrate conversion, which appeared to be ongoing throughout the incubation period in VBNC P. aeruginosa. Compared to the culturable state, VBNC P. aeruginosa exhibited reduced isotopic assimilation rates for carbon, nitrogen and hydrogen by 40.57 %, 44.62 % and 39.45 %, indicating decreased substrate uptake for biomolecular synthesis. Additionally, the metabolic heterogeneity index of the VBNC bacterial population increased by 37.28 %, with this heterogeneity displaying a progressive increase with the duration of the culture. This observation suggests VBNC P. aeruginosa differentiation into distinct subpopulations, believed crucial for survival in challenging environments. These findings reveal the metabolic dynamics of VBNC state bacteria, providing insights into their adaptive strategies and implications for environmental health risk assessment and precise control technologies.

Sustainable supply chain management and CEO compensation: does CSR committee matter?

ABSTRACT This study extends the existing literature on sustainable supply chain management (SSCM) and executive compensation by focusing on an important part of the company’s value chain, namely its supply chain (SC) and the associated risks. Through a quantitative study of companies listed on the SBF 120 over the period 2007–2021, our results emphasise the role of CSR committee to improve the relationship between the implementation of sustainable SC initiatives and CEO compensation. The CSR committee can be a way to improve the identification and consideration of environmental and social risks linked to the SC. We demonstrate the advantage of the presence of a CSR committee for the CEO themselves by increasing their compensation when they are more engaged in CSR activities. This result adds original insights to the existing literature which has already demonstrated the benefit of this committee for the other stakeholders. Thus, our results encourage the boards to implement this non-binding CSR committee as a supplementary governance mechanism.

Aqueous VOCs in complex water environment of oil exploitation sites: Spatial distribution, migration flux, and risk assessment

Pollution of the aqueous environment by volatile organic compounds (VOCs) has caused increasing concerns. However, the occurrence and risks of aqueous VOCs in oil exploitation areas remain unclear. Herein, spatial distribution, migration flux, and environmental risks of VOCs in complex surface waters (including River, Estuary, Offshore and Aquaculture areas) were investigated at a typical coastal oil exploitation site. Among these surface waters, River was the most polluted area, and 1,2-Dichloropropane—which emerges from oil extraction activities—was the most prevalent VOC. Positive matrix factorization showed that VOCs pollution sources changed from oil exploitation to offshore disinfection activities along River, Estuary, Offshore and Aquaculture areas. Annual volatilization of VOCs to the atmosphere was predicted to be ∼34.42 tons, and rivers discharge ∼23.70 tons VOCs into the Bohai Sea annually. Ecological risk assessment indicated that Ethylbenzene and Bromochloromethane posed potential ecological risks to the aquatic environment, while olfactory assessment indicated that VOCs in surface waters did not pose an odor exposure risk. This study provides the first assessment of the pollution characteristics of aqueous VOCs in complex aqueous environments of oil exploitation sites, highlighting that oil exploitation activities can have nonnegligible impacts on VOCs pollution profiles.

Building resilience: Insights into ecosystem-based integrated environmental risk reduction approaches for urban environments in coastal Bangladesh

The intricate relationship between environmental quality, ecosystem services, and human well-being underscores the importance of understanding and addressing environmental complexities. Considering these issues, this research aims to propose ecosystem-based approaches for mitigating environmental risks within the Khulna City Corporation (KCC) area, while also elucidating the connection between ecosystem services and these risks. By doing so, it indirectly addresses disaster risk reduction approaches, acknowledging the relationship between environmental degradation and increased disaster occurrences. Leveraging multi-spectral Landsat images from 2001 (Landsat-5), 2011 (Landsat-5), and 2021 (Landsat-8), the study evaluates LULC dynamics and quantifies ecosystem service values (ESVs) using the Benefit Transfer Method. Additionally, seven key indicators, including land use-based carbon emissions, elevation, LST, NDVI, NDWI, NDSI, and NDBI, were analyzed to monitor spatiotemporal changes. The weighted overlay method was employed to integrate raster data and delineate environmental risk zones driven by deteriorating ESVs in KCC. Notably, the study reveals a significant increase in highly environmental risk areas from 7 % to 34 % and a decrease in medium-risk areas from 92 % to 60 % of the total area between 2001 and 2021 due to the decline in ecosystem services resulting from unplanned rapid urbanization. Furthermore, a moderate negative correlation (R2 values of 0.56, 0.67, and 0.69) between ESVs and the environmental risk index underscores the linkage between deteriorating ecosystem services and the expansion of high-risk zones. Furthermore, this study advocates policies such as drought-resistant tree plantations, community involvement, post-disaster resource provision, funding allocation, and stakeholder knowledge dissemination to enhance the resilience of KCC.

A high-fidelity dual-channel fluorescence probe for benzoyl peroxide detection and toxicity early warning in food, zebrafish, and mice

Benzoyl peroxide (BPO), as a widely used organic peroxide, has attracted widespread attention from all sectors of society for its environmental hazards and potential risks to human health. Herein, we employed a Förster resonance energy transfer (FRET) strategy to construct a novel ratiometric fluorescent probe CY-DCI for BPO detection in food, zebrafish, and mice. Specifically, a hemicyanine fluorophore and a dicyanoisophorone fluorophore were connected with a piperazine group as donor and acceptor, respectively, and an olefinic unsaturated bond as the reaction site. CY-DCI has favorable selectivity and an excellent detection limit as low as 58.1nM, and the recovery rates for real-sample detection ranged from 95.8% to 104%, with relative standard deviations (RSD) less than 2.58%. To further improve its practicality, silica gel plates and test strips containing CY-DCI (0-50μM) were developed for naked-eye detection of BPO with satisfactory results. Additionally, this novel probe was then applied for ratiometric imaging of living zebrafish and mice and showed high ratiometric imaging resolution in the green and red channels, thus demonstrating its practical application for BPO detection and toxicity early warning in food and biosystems. Environmental ImplicationFirstly, Benzoyl peroxide (BPO) affects soil microbial activity, thereby disrupting soil structure and function. Secondly, BPO leads to the death of aquatic organisms and destroys the balance of the aquatic ecosystem. Thirdly, BPO may cause damage to human tissues and induce related diseases. In addition, BPO is highly flammable and may cause explosive decomposition. In short, BPO is harmful to the environment and should be used with care and better managed. Therefore, it is important to develop a new and efficient method and technology for the rapid detection of BPO.

Comparing Energetics and Physiological Trait Patterns of North American Birds to Support Ecological Risk Assessment

The environmental risk assessment (ERA) of plant protection products (PPPs) is commonly conducted for a number of standard laboratory species, though its scope includes all species, especially those that are vulnerable or endangered. This begs the question of how the eco-physiological and life history traits of those data-rich species compare to those of less documented species. This paper investigates the utility of a database of such traits, the Add-my-Pet collection of Dynamic Energy Budget theory, for the ERA of North American birds. We identified 72 bird species in the collection that have a federal listing status or are otherwise of interest for the ERA of PPPs and compared their eco-physiological and life history traits in relation to body size, feeding guild, and taxonomic identity to those of 446 terrestrial Holarctic birds, as well as those of standard lab species, notably the northern bobwhite, mallard, and zebra finch. The properties of standard lab species generally align with those of a similar taxonomy and size, with the notable exception of the relatively high reproductive capacity of the northern bobwhite and mallard due to the unique properties of laboratory study data. In addition, taxonomy appears to be a better predictor of eco-physiological traits than feeding guild. We conclude that, to identify representative species for the ERA of PPPs, more traits need to be included, such as those directly linked to the likelihood of exposure and those related to reproductive behavior.

A systems-based analysis to rethink the European environmental risk assessment of regulated chemicals using pesticides as a pilot case

A growing body of scientific literature stresses the need to advance current environmental risk assessment (ERA) methodologies and associated regulatory frameworks to better address the landscape-scale and long-term impact of pesticide use on biodiversity and the ecosystem. Moreover, more collaborative and integrative approaches are needed to meet sustainability goals. The One Health approach is increasingly applied by the European Food Safety Authority (EFSA) to support the transition towards safer, healthier and more sustainable food. To this end, EFSA commissioned the development of a roadmap for action to establish a European Partnership for next-generation, systems-based Environmental Risk Assessment (PERA). Here, we summarise the main conclusions and recommendations reported in the 2022 PERA Roadmap. This roadmap highlights that fragmentation of data, knowledge and expertise across regulatory sectors results in suboptimal processes and hinders the implementation of integrative ERA approaches needed to better protect the environment. To advance ERA, we revisited the underlying assumptions of the current ERA paradigm; that chemical risks are generally assessed and managed in isolation with a substance-by-substance, realistic worst-case and tiered approach. We suggest optimising the use of the vast amount of information and expertise available with pesticides as a pilot area. It is recommended to as soon as possible adopt a systems-based approach, i.e. within the current regulatory framework, to spark a step-wise transition towards an ERA framed at a system level of ecological and societal relevance. Tangible systems-based and integrative steps are available. For instance, the rich sources of existing data for prospective and retrospective ERA of pesticides could be used to reality-benchmark existing and new ERA methods. To achieve these goals, collaboration among stakeholders across scientific disciplines and regulatory sectors must be strengthened.