Entire Grain Research Articles

The evolution of granular surface structure and functional properties in rice starch during grain filling

The developmental changes in the granular surface structure and functional properties of starch during the entire grain filling period of rice (around 40 days) were investigated. The specific surface area of rice starch significantly decreased firstly then stabilized during growth due to increasing granular size. The pore volume decreased from 5.40 cm3/g at 6th day after anthesis (DAA-6) to 3.02 cm3/g (DAA-46). More starch granule-associated proteins (SGAPs) accumulated on the surface and in channels. Swelling power decreased by 46 %, whereas the flow behavior index (n) decreased by 32 % in upward curve during starch development from DAA-6 to DAA-30. Tan δ first dropped then remained steady at DAA 22–34 and lightly rebounded at the final stage, indicating that starch in the middle stage tended to have greater viscoelastic gel behavior at all sweeps. Mature starch showed lower in vitro hydrolysis rate and exhibited stronger enzymatic resistance. The results showed that granular surface features of rice starch may be an essential factor in determining rheological behavior and resistance to hydrolysis.

Unrevealing the mechanisms behind the cardioprotective effect of wheat polyphenolics.

Cardiovascular diseases pose a major threat to both life expectancy and quality of life worldwide, and a concerning level of disease burden has been attained, particularly in middle- and low-income nations. Several drugs presently in use lead to multiple adverse events. Thus, it is urgently needed to develop safe, affordable, and effective management of cardiovascular diseases. Emerging evidence reveals a positive association between polyphenol consumption and cardioprotection. Whole wheat grain and allied products are good sources of polyphenolic compounds bearing enormous cardioprotective potential. Polyphenolic extract of the entire wheat grain contains different phenolic compounds viz. ferulic acid, caffeic acid, chlorogenic acid, p-coumaric acid, sinapic acid, syringic acid, vanillic acid, apigenin, quercetin, luteolin, etc. which exert cardioprotection by reducing oxidative stress and interfering with different toxicological processes. The antioxidant capacity has been thought to exert the cardioprotective mechanism of wheat grain polyphenolics, which predominantly suppresses oxidative stress, inflammation and fibrosis by downregulating several pathogenic signaling events. However, the combined effect of polyphenolics appears to be more prominent than that of a single molecule, which might be attained due to the synergy resulting in multimodal cardioprotective benefits from multiple phenolics. The current article covers the bioaccessibility and possible effects of wheat-derived polyphenolics in protecting against several cardiovascular disorders. This review discusses the mechanistic pharmacology of individual wheat polyphenols on the cardiovascular system. It also highlights the comparative superiority of polyphenolic extracts over a single phenolic.

Twinning behavior and variant selection mechanism of b.c.c tantalum during dynamic plastic deformation

In this paper, the microstructure and twinning behavior of tantalum (Ta) during dynamic plastic deformation (DPD) were jointly analyzed in combination with impact experiments and molecular dynamics simulations, with a focus on the mechanism of variant selection for twinning. The results indicated that twins nucleate at grain boundaries and gradually grows with increasing deformation until it penetrates the entire grain. Due to the difference of grain boundary dislocation density, strain rate and deformation temperature have significant impacts on the quantity and distribution of twins. In addition, at room temperature, nearly half of the twin variants in DPD samples do not conform to Schmid law, and almost all the twin variants in liquid nitrogen samples do not follow to Schmid law. The activation of these non-Schmid variants is mainly affected by the strain coordination. Through this study, we have deepened our understanding of the dynamic microstructural response of Ta under high-speed deformation conditions.

Microstructural investigation of Au ion-irradiated Eu-doped LaPO4 ceramics and single crystals

Ceramics and single crystals of LaPO4 monazite doped with Eu(III) were irradiated with 14 MeV Au5+ ions at three different fluences. Changes to crystallinity, local coordination environments, and topography were probed using grazing-incidence X-ray diffraction (GIXRD), vertical scanning interferometry (VSI), scanning electron microscopy (SEM), Raman, and luminescence spectroscopy. GIXRD data of the ceramics revealed fluence dependent amorphization. A similar level of amorphization was detected for samples irradiated with 5 × 1013 ions/cm2 and 1 × 1014 ions/cm2, whereas the sample irradiated with the highest fluence of 1 × 1015 ions/cm2 appeared slightly less amorphous. VSI showed clear swelling of entire grains at the highest ion fluence, while more localized damage to grain boundaries was detected for ceramic samples irradiated at the lowest fluence. Single crystal specimens showed no pronounced topography changes following irradiation. SEM images of the ceramic irradiated at the highest fluence showed topological features indicative of grain surface melting. Raman and luminescence data showed a different degree of disorder in polycrystalline vs. single crystal samples. While changes to PO4 vibrational modes were observed in the ceramics, changes were more subtle or not present in the single crystals. The opposite was observed when probing the local Ln-O environment using Eu(III) luminescence, where the larger changes in terms of an elongation of the Eu-O (or La-O) bond and an increasing relative disorder with increasing fluence were observed only for the single crystals. The dissimilar trends observed in irradiated single crystals and ceramics indicate that grain boundary chemistry likely plays a significant role in the radiation response.

Stress induced martensitic transformation in NiTi at elevated temperatures: Martensite variant microstructures, recoverable strains and plastic strains

To shed light on the origin of the loss of functional properties of NiTi with temperature increasing above 100 °C, we have investigated stress induced martensitic transformations in nanocrystalline NiTi shape memory wire by thermomechanical tensile testing supplemented with post-mortem reconstruction of martensite variant microstructures in grains by nanoscale orientation mapping in TEM. The stress induced martensitic transformation generating recoverable transformation strain as well as plastic strain is not completed at the end of the upper stress plateau. The higher is the test temperature, the larger is the volume fraction of retained austenite as well as the plastic strain. The martensite variant microstructures in NiTi wire deformed up to the end of the stress plateau at 120 °C contain partially detwinned single domains of (001) compound twin laminate filling entire grains. It is proposed that the stress induced martensitic transformation proceeds via habit plane interface between austenite and second order laminate of (001) compound twins and that the martensite promptly reorients and deforms plastically by dislocation glide in the [100](001) slip system. When the wire is loaded further beyond the end of the stress plateau, the stress induced martensitic transformation continues and the martensite deforms plastically. It is concluded that the observed gradual loss of superelastic functionality of NiTi with increasing temperature does not originate from the plastic deformation of austenite, as widely assumed in the literature, but that it derives from the loss of resistance of the stress induced martensite to the plastic deformation under increasing stress.

Arc-enhanced glow discharge ion etching of WC-Co cemented carbide for improved PVD thin film adhesion and asymmetric cutting edge preparation of micro milling tools

Wear-resistant thin films on cutting tools require effective ion etching to enhance adhesion and thus extended tool service life. Arc enhanced glow discharge (AEGD) ion etching, characterized by high ionization degrees and high etch rates, was applied to ultrafine-grained WC-Co cemented carbide, commonly used for micromilling cutters. The effect of AEGD ion etching on the surface integrity of WC-Co and the resulting adhesion behavior of a TiAlSiN thin film was investigated by varying the etching time in comparison with conventional glow discharge (GD) ion etching. In addition, the impact of intensive etching on the cutting edge geometry of micro end cutters and, in turn, on the cutting performance in micromilling of hardened and annealed high-speed steel was evaluated.AEGD achieves remarkable etch rates of 12 nm/min at extended etching times, which are 100 times greater than conventional glow discharge (GD) ion etching. Prolonged AEGD ion etching for ≥30 min removes entire near-surface WC grains and exposes carbides beneath, resulting in increased surface roughness. After the etching process, polished WC-Co substrates exhibit a slight reduction in residual compressive stresses, which steadily decrease with increasing AEGD ion etching time. Furthermore, a TiAlSiN thin film demonstrates high adhesion on AEGD-etched surfaces compared to GD ion etching. Even a brief 5 min AEGD ion etching ensures the highest adhesion class according to the Rockwell C indentation test. Moreover, the intensive material removal results in significant changes in cutting edge geometry of micro end cutters, yielding substantial cutting edge rounding and an asymmetrical shape with form-factors Κ ≥ 2. In cutting tests, the resulting cutting edge geometries effectively reduce the wear formation and the associated wear-related increase in process forces during micromilling hardened and tempered powder metallurgical high-speed steel. In summary, AEGD ion etching emerges as a highly effective method for both enhancing thin film adhesion and preparing adapted asymmetrical cutting edge geometries for micromilling tools.

Reconstruction of martensite variant microstructures in grains of deformed NiTi shape memory alloy by TEM

Two transmission electron microscopy (TEM) based methods were applied to reconstruct martensite variant microstructures in entire grains of plastically deformed nanocrystalline NiTi wires. First method consists in manual TEM analysis of composite electron diffraction patterns and dark field images of microstructures taken using carefully selected Bragg spots. Second method involves automated orientation/phase mapping of martensite variant microstructures in TEM (ASTAR). Application of these two methods helped us to discover new mechanism of the plastic deformation of monoclinic B19’ martensite in NiTi shape memory alloys called kwinking as it combines dislocation slip based kinking and deformation twinning in martensite.In this work, we describe how the martensite variant microstructures in nanograins of plastically deformed NiTi shape memory wire are reconstructed using the TEM based methods and discuss their advantages and disadvantages. The application of the first manual method requires tilting the TEM lamella so that all martensite variants in the analysed grain are oriented in a common low index zone. Such common crystal lattice direction exists in each grain of plastically deformed martensitic NiTi wire because the microstructures were created by the kwinking deformation mechanism. The requirement to orient the selected grain into a common unique direction in monoclinic lattice, on the other hand, is not unique to kwinking and represents a severe limitation of the SAED-DF method due to the constraints on tilting the TEM lamella. Application of the automated crystal orientation mapping ASTAR method enables detailed orientation analysis of nanoscale martensite variant microstructures in generally oriented grains of deformed NiTi wires as well as pointwise ex-situ analysis of interfaces with excellent resolution in real and orientation space.

Dynamic development of changes in multi-scale structure during grain filling affect gelatinization properties of rice starch

Rice was collected over the entire grain filling period (about 40 days) to explore the multi-structure evolution and gelatinization behavior changes of starch. During the early stage (DAA 6–14), the significant reduction in lamellar repeat distance (10.04 to 9.68 nm) and relative crystallinity (26.6 % to 22.7 %) was due to initial rapid accumulation of amylose (from 9.38 % to 14.05 %) and short amylopectin chains. Meanwhile, the decreased proportion of aggregation structure resulted in a decrease in the gelatinization temperature and a narrowed range of gelatinization temperature also indicated an increase in homogeneity as starch matured. Gelatinization enthalpy was mainly controlled by aggregation structure, which was negatively and positively related to the amylose content and the degree of order respectively. Peak viscosity of starch pasting increased and reached a maximum (924 cP) at DAA-21 due to larger granule size. Amylose and short amylopectin chains with degree of polymerization 6–12 showed positive and negative correlation with short-term retrogradation ability (setback value) respectively. The dynamics of different scale structure during grain filling had varying degrees of impact on gelatinization properties.

Microstructure and texture evolution in AZX311 Mg alloy during in-plane shear deformation

The current study examined the deformation mechanisms, microstructure, and texture evolution in AZX311 Mg alloy sheets subjected to in-plane shear (IPS) deformation. Different levels of shear strains, with values 0.05, 0.10, and 0.15, were applied along the rolling direction (RD) using a specialized in-plane shear testing jig. The strain measurement for the applied shear deformation was conducted utilizing the digital image correlation (DIC) technique. The strain distribution was found to be nearly homogeneous over sufficiently large areas, thereby allowing the microstructural measurements to yield relevant statistical data. A thorough microstructural examination across the thickness using electron back-scattered diffraction (EBSD) revealed that the application of IPS strain led to the formation of a significant number of tensile twins (TTWs) in the sheet. This was evidenced by the emergence of two satellite peaks at the periphery of the pole figures. As the shear strain increased, the proportion of TTWs in the material also increased, encompassing the entire parent grain and leading to the formation of what has been termed as “all-twinned microstructure”. The microstructural and texture investigation after IPS deformation revealed that TTWs were the dominant deformation mechanism that defined the microstructure and texture under IPS deformation, while dislocation slip activity was dominated by prismatic slip, as evidenced by the resolved shear stress analysis in this study. Consequently, this research highlights the effect of IPS deformation on the microstructure and texture evolution throughout the thickness of an Mg alloy sheet and elucidates the underlying mechanisms.

Effect of Using Fractals as Grain Configuration on the Performance of Solid Rocket Motors

Grain design is a very crucial consideration for determining the performance of solid propellant rocket motors. A rocket’s performance and combustion characteristics (thrust profile, chamber pressure variation, propellant mass flow rate, and sliver among other important performance parameters) depend very strongly on the grain configuration. We propose fractal shapes (Koch star, Koch snowflake, Gosper, and Cesaro) as new port geometries and theoretically predict their performance using simulations based on the fast-marching method implemented in the open-source software Open-Motor. The initial thrust for fractal geometry grains was found to be significantly higher than the commonly used industry standard BATES and Finosyl ports. The fractal grains also showed a significant decrease in sliver as compared to the Finocyl port that is generally used to increase performance as compared to the circular BATES ports. Especially, The Koch snowflake port had a drastically lower sliver. These new grain geometries proposed in this work can be used for applications in which low initiation and ignition times along with high initial thrust are crucial. Moreover, these geometries can improve the performance of the solid rocket motor (SRM) owing to their better regression characteristics which promise complete utilization of the entire grain web.

Cereals and cereal products - a scoping review for Nordic Nutrition Recommendations 2023.

Cereals and cereal products have traditionally been staple foods in many countries including in the Nordics and Baltics. Cereals can be consumed with their entire grain kernel and are then referred to as whole grains or can be consumed after removal of the bran or germ and are then referred to as refined grains. The terms cereals and grains are often used interchangeably. In this scoping review, we examine the associations between intake of cereals and cereal products and major health outcomes to contribute to up-to-date food-based dietary guidelines for the Nordic and Baltic countries in the Nordic Nutrition Recommendations 2023 project. Five qualified systematic reviews that covered non-communicable diseases, mortality, and risk factors were identified, and a supplementary literature search was performed in the MEDLINE and Cochrane databases for more recent studies and other endpoints. Compared to other high-income countries, the Nordic populations have a high consumption of whole grain foods. In some of the countries, rye constitutes a substantial fraction of the cereal consumption. However, few studies are available for specific cereals, and most of the research has been performed in predominantly wheat-consuming populations. The evidence suggests clear dose-response associations between a high intake of whole grains and lower risks of cardiovascular disease, colorectal cancer, type 2 diabetes, and premature mortality. The lowest risks of morbidity and mortality were observed for 3-7 servings of whole grains per day, equivalent of 90-210 g/day (fresh weight or ready-to-eat whole grain products, such as oatmeal or whole grain rye bread). Evidence from randomized trials indicates that a high intake of whole grains is beneficial for reducing weight gain. There is less evidence for refined grains, but the available evidence does not seem to indicate similar beneficial associations as for whole grains. It is suggested that replacing refined grains with whole grains would improve several important health outcomes. Cereals are plant foods that can be grown in most of the Nordic and Baltic regions.

Absorption, accumulation, and distribution of atmospheric metals in rice (Oryza sativa L.)

Crop metal contamination caused by atmospheric metal pollution has been increasingly reported. To investigate the absorption, accumulation, and distribution of atmospheric metals in rice (Oryza sativa L.), a field experiment was conducted with rice grown at an atmospheric metal pollution site and a background site. The concentrations of Pb, Cd, Cu, Mn, and Zn in the atmospheric deposition at the pollution site were significantly higher than those at the background site. Consequently, the rice tillering number decreased by 56–64% and the yield decreased by 53–69% at the pollution site compared to the background site. Particularly, Pb isotope analysis found that 76% of the Pb in the rice grain at the pollution site was attributed to atmospheric Pb. Furthermore, observations by transmission electron microscopy found penetration through the leaf cuticle seems to be the primary pathway for the absorption of atmospheric metals. Using laser ablation inductively coupled plasma-mass spectrometry, it was found that the distribution of metals in rice grains at the two sites was similar, with Pb, Cr, Fe, Mn, Cu, and Ca mainly in the bran layer while Cd and Zn uniformly distributed throughout the entire grains. Possible solutions to address atmospheric metal pollution in crops are discussed.

Factors Influencing Worker Safety in Grain Handling: An Advisory Panel Perspective

HighlightsFindings confirmed that out-of-condition grain is a primary causal factor in grain entrapment and engulfment.The advisory panel confirmed that grain quality has implications for grain dust explosions.Findings highlighted a lack of in-depth knowledge expected from an expert panel, specifically on aspects of protective grain quality traits.Abstract. Out-of-condition grain has been identified as a primary causal factor in grain entrapments and engulfments. The quality of grain also has implications for grain dust explosions. Limited research has examined exactly which elements of grain condition influence worker safety in grain handling. This research project aimed to establish an advisory panel to examine and provide input on how elements of grain condition relate to worker safety risks in grain handling. A purposeful sampling technique was used to obtain a sample of grain handling and storage experts to function in an advisory role for the project. A primary aim of this research was to understand the problem further, provide input on tested variables, and guide educational and dissemination efforts. As is true for qualitative methodologies, those selected as part of the targeted sample cannot be generalized to other experts in the field of grain handling. The final sample contained six industry representatives, five academic professionals, and two insurance/regulatory professionals. Participants interviewed had varied expertise with grain-based safety events. Of those interviewed, 23% of participants had personal experience, 54% had bystander or investigator experience, and 23% had training experience. Semi-structured interviews were conducted to further understand the problem, provide input on important elements in safe grain handling, and guide educational and dissemination efforts. Interviews were analyzed with a primary objective to identify elements of grain condition that play a role in the incidence of grain entrapment, grain engulfments, or grain dust explosions. NVivo 14 was used to conduct a thematic analysis, and four overall themes were identified, which included challenges to worker safety in the grain handling industry, areas where improved communication is needed, grain quality indicators that may play a role in safety incidents, and available mitigation strategies. The themes are the opinions of the advisory panel and may not reflect those of the entire grain handling industry. Keywords: Expert panel, Grain bin safety, Grain handling hazards, Grain quality.

Grain chain management and development: evidence form Agri-SMEs in Kosovo

Purpose This study aims to explore the grain chain in Kosovo. This study also aims to analyse the role of actors involved in the supply, production, processing, marketing and distribution of the grain value chain. Design/methodology/approach The study uses qualitative methods. A total of 60 semi-structured interviews are conducted with actors involved in the entire grain value chain. Findings Findings reveal that the country depends on grain imports and lacks an organised grain market, which is often distorted by the present political situation. Stakeholders are partly integrated in the grain value chain, and they are not very efficient in production. The existence of an informal market influences the decision-making of actors involved in the grain chain. The grain value chain displays mixed governance types, and the relationships among actors are based on the trust mechanism. Originality/value The research draws the importance of agriculture’s public policies to sustain domestic grain production. Public–private partnerships should be created to restore the grain market. Trading policies should be revised because they play a crucial role in enhancing fair competition between domestic and foreign traders.

Compound Feed Industry: benchmarks, potential opportunities

Relevance the main component for production of feed products in livestock industry is feed grain. The provision of the republic with grain crops, as well as exports, are associated with their use for fodder purposes, consumption traditionally accounts for more than half of the domestic consumption of their processed products. The goal is to study the problems and prospects of the feed industry, which determines the effective functioning of the entire grain market, supplying agricultural enterprises and farms with necessary and high-quality feed. This was largely facilitated by the intensive development of food industry and grain farming, which became the main suppliers of raw materials for feed mills. Methods – comparative, systemic, statistical analysis, logical generalization. Results – the authors note that in the structure of feed raw materials, main share falls on barley, oats, wheat, while the share of corn and legumes has decreased. Based on the available livestock, the standard needs of animal husbandry are not provided. The export orientation of domestic grain production is primarily aimed at the needs of the world market, at the same time, domestic needs are satisfied on a residual basis. Rational use of cereals will improve the quality and competitiveness of animal products. The opportunities created by «National Company «Food Contract Corporation» JSC for the sale of grain fodder to poultry farms enhance holding back the prices for finished food products by concluding agreements with manufacturers and retail chains. Conclusions – it is obvious that the basis for the transfer of the livestock complex to industrial resource-saving technologies is the creation of a solid forage base. Without a balanced feeding of animals in terms of protein and vitamin-amino acid composition, other measures will not have the expected result. Emphasis is placed on the need to increase the capacity of large enterprises to provide feed products on industrial scale and manufacture dry nutritious feed mixtures in feed mills and factories based on their own raw materials, mineral and vitamin supplements for grain processing and livestock farms.

What’s in an age? Calculation and interpretation of ages and durations from U-Pb zircon geochronology of igneous rocks

Accurate assessment of the duration of zircon crystallization within igneous rocks is critical for constraining the time scales of magmatic evolution and storage, which have important implications for our understanding of magmatic fluxes and volcanic hazards. However, estimation of crystallization durations from finite geochronologic data sets is difficult and typically relies on numerous implicit assumptions. In this contribution, we evaluate these assumptions and provide recommendations for better interpretation of crystallization durations from individual samples by developing a simplified theoretical framework to relate zircon growth, nucleation, and armoring rates to zircon ages. We first investigate single zircon analyses and show that ages produced with methods that integrate the entire grain or grain fragments (e.g., chemical abrasion−isotope dilution−thermal ionization mass spectrometry [CA-ID-TIMS]) are inevitably biased toward the second half of the zircon growth interval, while subsampling of grains via microbeam approaches will only capture the majority of the zircon crystallization duration when the microbeam spot size is less than ∼25% of the zircon minor axis, and the analytical uncertainty of the measurement is less than ∼20% of the duration over which the individual zircon grew. We subsequently investigate the distribution of zircon mean ages produced through various combinations of zircon growth rate, nucleation rate, and the probability of zircon being armored by major phases. We show that zircon age distributions cannot be directly predicted from the rate of zircon mass crystallized, as many combinations of growth, nucleation, and armoring rates result in distinct age distributions, yet they produce nearly identical mass crystallization rates. Finally, we develop two equations that can be used to constrain the duration of crystallization observed within individual samples. In scenarios where the observed age dispersion is consistent with the reported analytical uncertainties, the first equation can be used to estimate the maximum duration. Otherwise, when the measured zircon population is overdispersed, a second equation constrains the minimum duration of zircon crystallization.

Kyanite petrogenesis in migmatites: resolving melting and metamorphic signatures

Aluminosilicates (kyanite, sillimanite and andalusite) are useful pressure–temperature (P–T) indicators that can form in a range of rock types through different mineral reactions, including those that involve partial melting. However, the presence of xenocrystic or inherited grains may lead to spurious P–T interpretations. The morphologies, microtextural positions, cathodoluminescence responses and trace element compositions of migmatite-hosted kyanite from Eastern Bhutan were investigated to determine whether sub-solidus kyanite could be distinguished from kyanite that crystallised directly from partial melt, or from kyanite that grew peritectically during muscovite dehydration reactions. Morphology and cathodoluminescence response were found to be the most reliable petrogenetic indicators. Trace element abundances generally support petrographic evidence, but protolith bulk composition exerts a strong control over absolute element abundance in kyanite. Sample-normalised concentrations show distinctive differences between petrogenetic types, particularly for Mg, Ti, V, Cr, Mn, Fe and Ge. LA-ICP-MS element maps, particularly combined to show Cr/V, provide additional information about changing geochemical environments during kyanite growth. Most kyanite in the studied migmatitic leucosomes is of sub-solidus origin, with less widespread evidence for peritectic crystallisation. Where present, grain rims commonly crystallised directly from the melt; however, entire grains crystallised exclusively from melt are rare. The presence of kyanite in leucosomes does not, therefore, necessarily constrain the P–T conditions of melting, and the mechanism of growth should be determined before using kyanite as a P–T indicator. This finding has significant implications for the interpretation of kyanite-bearing migmatites as representing early stages of melting during Himalayan evolution.

Investigation on Nutritional, Phytochemical, and Antioxidant Abilities of Various Traditional Rice Varieties.

Rice (Oryza sativa L.) is a popular grain that is consumed by almost half of the world's population. Rice has several distinct breeds classified as traditional and ancient grains. The consumption of rice by 60% of the world's population is a staple food. Entire grain rice, often known as brown rice, is the unpolished counterpart of white rice, containing bran, germ, and endosperm. Eating whole-grain rice is linked to many health benefits; thus, scientists have focused on identifying and quantifying bioactive chemicals in this meal. The present study assessed the physio-chemical, cooking attributes, mineral contents, phytochemicals, and free radical scavenging capabilities of conventional rice cultivars using known approaches according to particle size analysis. Rice grain lengths varied between 4.10 ± 16 and 6.20 ± 007. The length and thickness ratios of rice were not substantially different (p > 0.05). Kattuyanam has the maximum protein content (9.99 ± 06%) of all the rice varieties that were physio-chemical investigated. It also has highest phenolic content and antioxidant properties compared to gallic acid equivalent (334.900 ± 61g) (GAE)/100g, followed by anthocyanins and flavonoids. Total phenolic content and phenolic fractions of the HPLC profile in tested landraces indicate the presence of bioactive substances derived from traditional rice cultivars and a range of phytonutrients, including phenol, revealing their healthy potentials in the present study.

Rpp-Gene pyramiding confers higher resistance level to Asian soybean rust

Asian soybean rust (ASR) causes large reductions in soybean yield, affecting the entire grain market. With low fungicide efficiency, the use of resistant cultivars can be an economical, safe, efficient, and sustainable control alternative. However, the great variability and aggressiveness of ASR and the use of Rpp genes are limited. Thus, gene pyramiding is a promising strategy for the development of cultivars with high resistance to a greater number of isolates. Thus, the objective of this study was to evaluate sister lines, previously evaluated by Meira et al. (2022). https://doi.org/10.1007/s10681-020-02667-x), presenting different Rpp-pyramided genes for resistance to Phakopsora pachyrhizi to clarify the pyramiding effect of two originally developed Rpp-pyramided lines compared to two existing lines or lines possessing only a single Rpp of resistance under field conditions. Rpp-pyramided lines 52117-1 (Rpp2 + Rpp1-b), 52117-57 (Rpp2 + Rpp1-b), 52117-59 (Rpp2 + Rpp1-b) + 52117-60 (Rpp2 + Rpp4) showed high resistance levels compared to resistant sources and resistance control, carrying a single Rpp gene PI 200487 (Rpp5), PI 200492 (Rpp1), PI 230970 (Rpp2), PI 459025A (R pp4), and PI 506764 (Rpp3 + Rpp5) with significant reductions in sporulation levels (SL), number of uredinia per lesion (NoU), and frequency of lesions with uredinia (%LU). Only, the line 52117-54 (Rpp2 + Rpp1-b), and 52117-63 (Rpp2 + Rpp4) showed resistance level smaller than PI 594723 (Rpp1-b) and similar resistance levels than PI 230970 (Rpp2), respectively. Rpp-pyramided lines carrying Rpp2 + Rpp1-b (52116-54, 52116-74, 52117-21, 52117-59 and 52117-60), and Rpp2 + Rpp4 (52117-60), and single gene Rpp1-b were classified as “highly resistant” and “resistant”. Furthermore, one sister line, 52117-57 (Rpp2 + Rpp1-b), showed immunity under field conditions. The Rpp-pyramided genes are an alternative for achieving high resistance levels against ASR.

Dislocation Mechanism and Grain Refinement of Surface Modification of NV E690 Cladding Layer Induced by Laser Shock Peening.

To investigate the relationship between the dislocation configuration and the grain refinement in the NV E690 cladding layer caused by laser shock peening, NV E690 high-strength steel powder was used to repair prefabricated pits in samples of 690 high-strength steel by laser cladding, where the laser shock peening of the cladding layer was performed by laser shock at different power densities. X-ray diffraction, scanning electron microscopy, and transmission electron microscopy were used to observe the microstructures of these samples before and after the laser shock process. The results showed that the metallurgical bonding between the cladding layer and the substrate after laser cladding repair was good. When the laser power density was 4.77 GW/cm2, multiple edge dislocations, dislocation dipoles, and extended dislocations were distributed over the cladding layer. When the laser power density was 7.96 GW/cm2, a geometrically necessary dislocation divided the large original grain into two subgrains with different orientations. When the laser power density was 11.15 GW/cm2, geometric dislocations divided the entire large grain into fine grains. The grain refinement model of the NV E690 cladding layer, when treated by laser shock peening, can describe the grain refinement process induced by the dislocation movement of this cladding layer.