Enriched MORB Research Articles

Slab break-off of the Kalamaili oceanic slab revealed by the latest Carboniferous mafic–ultramafic rocks in eastern North Tianshan (NW China)

Identifying the tectonic transition from oceanic subduction to collision is crucial for tracking the final stage evolution of ancient orogenic belts. In this study, we present new geochronological and geochemical data for the Mozbaysay mafic–ultramafic complex in the Balikun area, eastern North Tianshan of the southern Central Asian Orogenic Belt. This complex had intruded into the late Carboniferous volcano-sedimentary rocks and is comprised mainly of hornblende gabbro and lherzolite. Zircon U-Pb ages of the hornblende-gabbros reveal that this complex was emplaced at ca. 305 Ma. Geochemical analyses suggest these mafic–ultramafic rocks are characterized by slight enrichment of light rare earth elements (LREEs) and relatively depleted heavy rare earth elements (HREEs), resembling enriched mid-ocean ridge basalt (E-MORB). They also exhibit restricted (87Sr/86Sr)i ratios (0.702396–0.704295) and εNd(t) values (+7.0 to +9.1), indicative of a depleted mantle source with minimal crustal contamination. Incompatible element ratios (i.e., Nb/Ta, Zr/Hf, Rb/Nb, and Ba/Nb) suggest the involvement of subducted slab-derived aqueous fluids in their mantle source. These collectively indicate that the parental magmas of the Mozbaysay mafic–ultramafic rocks may have been generated by a mixed mantle source consisting of the E-MORB-like asthenospheric mantle, subcontinental lithospheric mantle (SCLM), and hydrous fluids from subducted slab. Furthermore, a slab break-off model is proposed to explain the generation of these latest Carboniferous mafic–ultramafic rocks. Integrating these findings with regional geological data, we propose that the tectonic transition from subduction (slab roll-back) to collision (slab break-off) along the Kalamaili suture zone occurred at ca. 305–300 Ma.

Petrogenesis of flood basalts and shield basanite from Mertolemariam- Abamineos area, northwestern Ethiopian plateau: Assessments for mantle source variations

Petrographic and geochemical data (major and trace elements) are presented for Oligocene flood basalts and Miocene shield lavas from the Mertolemariam-Abamineos area, northwestern Ethiopian Plateau to examine the petrogenesis of the erupted magmas and the nature of mantle source compositions. The Mertolemariam flood basalts have mainly aphyric and plagioclase phyric textures. The Abamineos shield lavas have sparsely clinopyroxene phyric to highly plagioclase-clinopyroxene phyric textures. Geochemical classification shows that the Mertolemariam Oligocene flood basalts are sub-alkaline in composition, whereas the Abamineos Miocene shield lavas are highly alkaline in composition. The Abamineos shield has a unique composition (i.e., basanites) compared with all other shield basalts (transitional to alkaline) in the northwestern Ethiopian Plateau. Major and trace element compositions display two distinct trends between Mertolemariam flood basalts and Abamineos shield basanites. Fractional crystallization, partial melting, and crustal contamination of a homogeneous mantle source cannot explain the compositional variations between the Mertolemariam flood basalts and the Abamineos shield basanites. The trace element composition suggests that the Mertolemariam Oligocene flood basalts were more likely generated from the mixing of OIB (mantle plume) and E-MORB (enriched asthenosphere) mantle components. The Abamineos Miocene shield basanites were derived from the mantle plume (OIB) component. LREE/MREE and LREE/HREE indicate that both groups possibly originated from a mantle source within the stability field of spinel and garnet. In comparison, the Mertolemariam flood basalts were formed by a higher degree of partial melting from relatively shallow depths than the Abamineos shield basanites. We propose a scenario that explains the magmatic genesis in the northwestern Ethiopian Plateau: volcanism initiated by the initial arrival of the mantle plume (OIB-like) beneath the lithosphere, which comes across a geochemically fertile and enriched MORB (E-MORB) mantle component in the upper asthenosphere. The hot mantle plume triggered melting of the fertile and enriched MORB, and then melting occurred in the plume (OIB-like) at depth in the stability field of spinel and garnet. Melts from the mantle plume (OIB-like) and E-MORB components mixed to produce sub-alkaline flood basalts during the Oligocene in the northwestern Ethiopian Plateau Subsequently, melts from the advanced upwelling mantle plume (OIB-like) produced Miocene shield lavas in the northwestern Ethiopian Plateau.

Geochemistry and magmatic petrology of meta-ophiolites from the Bajgan Complex (Makran Accretionary Prism, SE Iran): new insights on the nature of the Early Cretaceous Middle East Neotethys

The Bajgan Complex in the North Makran Domain (Makran Accretionary Prism) comprises disrupted meta-ophiolitic sequences originating from oceanic crust protoliths. They include ultramafic and mafic cumulates, isotropic gabbros, plagiogranites and basalts. Ultramafic–mafic cumulates and plagiogranites exhibit compositions akin to rocks formed in mid-ocean ridge settings. Isotropic gabbro and basalt protoliths can be subdivided into three distinct geochemical types. Type-1 rocks are sub-alkaline (Nb/Y < 0.1) with low Th, Nb and Ta contents and La N /Yb N ratios <1, resembling those of normal mid-ocean ridge basalts (N-MORB). Type-2 rocks display slight enrichment in Th, Ta, Nb (Nb/Y = 0.36–0.45) and La N /Yb N = 2.12–3.20, resembling the chemistry of enriched (E-) MORB. Type-3 basalts show an alkaline nature (Nb/Y = 0.88–1.82), significant Th, Ta and Nb enrichment, and high La N /Yb N ratios (7.01–20.08), resembling the chemistry of alkaline basalts (ocean island basalts, OIB). Petrogenetic modelling indicates that N-MORB protoliths originated from a depleted MORB mantle source, whereas E-MORB and OIB protoliths were generated from partial melting of sub-oceanic depleted sources that underwent varying degrees of OIB-type enrichment. The Bajgan meta-ophiolitic protoliths were formed within a Late Jurassic to Cretaceous oceanic basin influenced by mantle plume activity and plume–ridge interaction. Supplementary material : Field photographs, micrographs, rocks sampled, analytical methods and results, and supplementary tables are available at https://doi.org/10.6084/m9.figshare.c.7193937 Thematic collection: This article is part of the Ophiolites, melanges and blueschists collection available at: https://www.lyellcollection.org/topic/collections/ophiolites-melanges-and-blueschists

The Volcanism of the Meseta del Lago Buenos Aires, Patagonia: the Transition from Subduction to Slab Window

Abstract The Meseta del Lago Buenos Aires (MLBA) in southern Patagonia, a volcanic plateau formed from ~12 Ma to present, provides an opportunity to investigate the temporal evolution in volcanism as this region transitions from the subduction of the Nazca plate to the formation of the slab window produced by the collision of the Chile Ridge and the Andean subduction zone. Here, we report new major, minor, and trace element contents, as well as Sr, Nd, Pb, and Hf isotopes of the MLBA lavas. Three distinct geochemical endmembers can be distinguished in the MLBA basalts: a subduction-influenced endmember, a transitional component similar to the South Atlantic enriched mid-ocean ridge basalts, and an enriched component akin to the EM1 mantle composition. Lavas older than ~1.5 Ma define a compositional continuum between the subduction-influenced and transitional endmembers; this trend is also present in many other southern Patagonian plateaus regardless of their distance to the trench, eruption age, and the composition of the continental blocks where they are located. In contrast, MLBA basalts younger than ~1.5 Ma uniquely define a transition into the EM1 mantle component at the time when this region was affected by the slab window. The estimated pressures and temperatures of mantle-melt equilibration for the MLBA basalts indicates an increase in both parameters after the formation of the slab window that roughly correlate with the changes in lava composition. The basalts’ composition from all southern Patagonia plateaus points to the presence of the South Atlantic mid-ocean ridge basalt mantle influenced by the Discovery, Shona, and Bouvet hotspots rather than the sub-slab mantle, as represented by the Chile Ridge basalts. This observation challenges the hypothesis that the sub-slab mantle within the slab window has had an important role in the composition of the erupted lavas. Instead, it suggests the presence of a South Atlantic mantle beneath southern Patagonia either within the mantle wedge, consistent with a long-lasting South Atlantic convection cell beneath South America, or in the subcontinental lithospheric mantle metasomatized before or just after the opening of the South Atlantic basin, as demonstrated by the composition of southern Patagonia mantle xenoliths. Although it is difficult to precisely distinguish the contributions of the asthenosphere from that of the metasomatized subcontinental lithospheric mantle beneath this region, our work suggests significant contributions from the latter in the composition of the MLBA lavas.

Geologic fingerprints of the Rodinia breakup in the western North China Craton: Constraints from the Early Neoproterozoic (ca. 825–810 Ma) mafic volcanic and intrusive rocks in the Langshan tectonic belt

As an important component of the East Asian continental block, the North China Craton (NCC) is crucial for reconstructing Rodinia in the Neoproterozoic. However, whether the NCC is a component of the Rodinia supercontinent and records its breakup remains enigmatic. Here, we identified Langshan gabbro and mafic dikes with ages of ca. 829–826 Ma and mafic volcanic rocks with ages of 810 ± 3 Ma in the northeastern Alxa Block of the western NCC. The Langshan gabbro shows flat rare earth element (REE) patterns [(La/Yb)N = 1.3–1.5] and slight enrichment in most incompatible trace elements, similar to enriched mid-ocean ridge basalt. The mafic volcanic rocks show the geochemical features of oceanic island basalt, including high total alkaline content (7.86–8.47 wt%), enriched in light REEs (La/YbN = 8.0–9.1), and insignificant Eu anomalies. Together with contemporaneous felsic volcanic rocks identified in previous studies, the mafic volcanic rocks (ca. 810 Ma) define a bimodal association. The mafic intrusive and associated dike swarms from ca. 825–810 Ma along with the coeval Jinchuan ultramafic–mafic intrusions, followed by rifting sedimentary successions, were formed in an extensional rift setting, supporting the geologic fingerprints of the Rodinia breakup in the western NCC. The well-matched mafic magmatic barcodes, similar provenance, and sedimentary successions preserved in the Adelaide superbasin of southeastern Australia and the Langshan rift basin of the western NCC support a possible link between the NCC and Australia during the Early Neoproterozoic.

A new look at the geodynamic development of the Ediacaran–early Cambrian forearc basalts of the Tannuola-Khamsara Island Arc (Central Asia, Russia): Conclusions from geological, geochemical, and Nd-isotope data

Abstract Oceanic igneous rocks throughout the Altai-Sayan Fold Belt (ASFB) in central-southern Siberia are often considered to be late Precambrian–early Paleozoic accreted elements of oceanic crust – often of uncertain paleogeographic or geodynamic origin. We explore the role of suprasubduction zone settings in the formation of different ASFB terranes. Our study offers a non-accretionary perspective on the tectonomagmatic development of basalt-bearing units in the ASFB on the example of the forearc terrane of the Ediacaran–early Cambrian Tannuola-Khamsara island arc (herein termed Sayan-Tuvan forearc zone). We describe the geochemistry, structural geology, and stratigraphic relations of basalts of the Aldynbulak, Uttug-Khaia, and Chingin formations, which are integral parts of the Sayan-Tuvan forearc zone. The Aldynbulak basalt samples mainly fall in the compositional fields of ocean island basalts and enriched mid-ocean ridge basalts (E-MORB) and likely derived from a deep mantle source. The Uttug-Khaia and Chingin basalts are N- and E + T-MORB-like basalts, carrying forearc geochemical signatures. Specifically, the Chingin Formation contains boninite dikes and is associated with a boninite-bearing ophiolite. Boninites are commonly associated with forearc magmatism and thus a forearc formation setting is likely. Tectonic and stratigraphic considerations imply that the Aldynbulak basalts formed first, followed by the Uttug-Khaia and later the Chingin basalts and boninites. A schematic model, involving decompression melting of the mantle, is proposed for the development of the studied forearc basalt suites that are linked with the growth of the Tannuola-Khamsara island arc system 580–540 million years ago.

A carbon, nitrogen, and multi-isotope study of basalt glasses near 14°N on the Mid-Atlantic Ridge. Part B: Mantle source heterogeneities

Geochemical variations along mid-ocean ridges reveal the heterogeneous nature of the convecting upper mantle and geodynamic evolution of our planet (e.g., Hofmann, 2007; Parai et al., 2012). Although the occurrence of incompatible element and isotopically enriched mid-ocean ridge basalts (E-MORB) commonly arises from interaction with nearby mantle plumes, the source of E-MORBs far from known hotspots is debated. A well-known example of an enigmatic geochemical enrichment is found at 14°N on the Mid-Atlantic ridge (MAR). This is also one of the few locations worldwide where volatile-saturated E-MORBs, often referred to as “popping rocks” (PR), have been recovered. Although the mechanism(s) involved in popping rock generation remain elusive, compressional regimes associated with the exhumation and formation of oceanic core complexes (OCC) may be required to produce popping rocks via protracted volatile accumulation. However, the geochemical signature of OCC samples and their potential relationship to local geochemical enrichments associated with popping rock-affiliated MORBs remain unknown. Here, we present a comprehensive volatile characterization of popping rocks and associated MORBs (n = 19) sampled at 14°N on the MAR, including (n = 2) normal MORBs (N-MORB) from an oceanic core complex (OCC) and (n = 17) E-MORBs (Bekaert et al., Part A). We use isotopic and abundance data for volatile (carbon, nitrogen, noble gases) and radiogenic (Pb, Sr, Nd) elements, as well as the abundances of major and trace elements, to elucidate on the source(s) of E-MORBs at 14°N and discuss the potential origin(s) of geochemical heterogeneities within the upper mantle. We observe co-variations of helium and radiogenic element isotopes, suggesting potential contributions from a young HIMU-type (high μ = time-integrated 238U/204Pb) component in the OCC mantle source. The mantle source of the OCC samples is clearly distinct from that of PR-affiliated samples, suggesting no genetic relationship between OCC samples and E-MORBs. In addition, elevated Dy/Yb in OCC samples likely point to the incorporation of a subducted crustal component that is not observed in the mantle source of other MORB samples analyzed in this study. We report mantle source 40Ar/36Ar variations at 14°N, which, in line with previous studies, are interpreted as primarily reflecting variations in the amounts of recycled atmospheric Ar. Despite extensive evidence for drastic geochemical heterogeneities at 14°N on the MAR, we observe no significant δ15N variation (average δ15N = -4.49 ± 1.40 ‰) across N-MORB and E-MORB samples. This is a fundamental constraint, as the absence of significant N isotope variations across the upper mantle may imply that sedimentary N (with a typical δ15N ∼+6‰) is not extensively introduced within this reservoir during subduction. We investigate several scenarios that could explain this observation, including a significant contribution of altered oceanic crust to the overall budget of subducting slabs, quantitative return of subducting sedimentary N to the Earth's surface by arc volcanism, and/or preferential transport/preservation of sedimentary N in the lower mantle source of oceanic island basalts.

A carbon, nitrogen, and multi-isotope study of basalt glasses near 14°N on the Mid-Atlantic Ridge. Part A: Degassing processes

14°N on the Mid-Atlantic ridge (MAR) is one of only a few locations worldwide where volatile-saturated, geochemically enriched mid-ocean ridge basalts (E-MORBs) have been recovered. These basaltic glasses are so gas-rich that CO2-filled bubbles may “pop” when brought to the surface, due to the pressure and temperature change. Although these “popping rocks” have long been regarded as representative samples of un-degassed magmas sourced from the upper mantle, uncertainties regarding both their generation mechanism(s) and the potential effects of gas loss/accumulation processes have hampered unambiguous quantification of the upper mantle volatile element (water, carbon, nitrogen, noble gas) inventory. Fortunately, the extent and consequences of gas loss/accumulation processes can be tested by studying characteristic changes in volatile elements compositions, including 4He/40Ar* (where 40Ar* is 40Ar corrected for atmospheric contamination). To document the mechanism of popping rock generation and potential effects of degassing and gas accumulation processes on MORB volatile systematics, we present a comprehensive volatile characterization (carbon, nitrogen and noble gas systematics) of popping rocks and associated MORBs (n = 19) recently sampled at 14°N on the MAR, including 2 normal MORBs (N-MORB) from an oceanic core complex (OCC) and 17 E-MORBs. In line with previous studies, we find that PR exhibit the lowest 4He/40Ar* (1.08 ± 0.04) among all MORB samples, lower than the conventional mantle production ratio of 3 ± 1. Such low 4He/40Ar* could either (i) derive from accumulation of first-generated bubbles originating from open-system degassing of underlying magmas, or (ii) represent the actual upper mantle production ratio. We summarize the arguments in favor of each of these two scenarios (including the required accumulation times for radiogenic noble gases accumulation, the K/U and 232Th/238U of the upper mantle, popping rock vesicle size distributions, and physical considerations for vesicle growth and upwelling through a basaltic magma), and discuss their implications for the volatile composition of un-degassed magmas from the upper mantle. We find homogenous N isotope compositions (average δ15N of −4.49 ± 1.40 ‰ at 14°N) but variable δ13C (from −11 ‰ to −3.4 ‰), potentially compatible with the expectations for residual dissolved gas after Rayleigh fractionation. However, explaining the light δ13C signatures of PR via this process appears incompatible with any of the two scenarios proposed for explaining their low 4He/40Ar*, which would predict (i) 13C-enrichements and (ii) no fractionation relative to an initial composition at δ13C ∼ -5‰, respectively. After correction for solubility-controlled degassing fractionation and potential gas accumulation processes using 4He/40Ar* systematics, we find relatively homogeneous C/3He ((2.65 ± 0.51) × 109) but variable C/N (from 125 up to 4578), whose potential origins are discussed as part of a companion paper (Part B: Source effects).

Diverse Late Triassic arc magmatism and porphyry Cu deposits in the southeastern Tibetan Plateau: Related to slab tear along a subducting passive margin?

The subduction of the ocean–continent transition (OCT) zone on a passive margin has received limited attention, despite its significant impact on tectono-magmatic processes. This study focuses on the Late Triassic basalts and andesites in the southeastern Tibetan Plateau, where the Yushu-Yidun Arc belt intersects the Longmen Shan Fault system. The goal is to understand the interplay between these linear systems. The basalts exhibit trace element and isotopic signatures resembling those of within-plate enriched mid-ocean ridge basalts or ocean island basalts (EOBs), such as positive NbTa anomalies, high Nb/Th (7.72 to 10.3) and εNd(t) (+2.23 to +6.34) values, and low La/Sm values (2.69 to 4.05), suggesting an asthenospheric mantle source. The contemporaneous andesites display typical arc-like geochemical characteristics (e.g., enrichment in Ba, Th, and U but depletion in Nb, Ta, and Ti), with negative εNd(t) values (−2.41 to −1.08), indicating a mantle wedge source affected by subducted components. Geological evidence indicates that the Longmen Shan Fault zone, previously defined by its magmatic rocks, was an active OCT belt during the Late Triassic, separating the South China Continent from the Garze–Litang Ocean. Consequently, we propose a model suggesting the tearing of a subducted oceanic slab from the continental lithosphere within the OCT belt under the southernmost segment of the Yushu–Yidun Arc belt, driven by strong slab pull in the Garze–Litang Ocean subduction zone. This model effectively explains the intriguing geology of the Songpan–Garze–Hoh Xil Terrane, in which Late Triassic EOBs and normal arc-related igneous rocks coexist and are accompanied by abundant slab-derived mineralized porphyries. Our findings have global implications for investigating geochemically diverse magmatism and associated mineralization on passive continental margins.

Source variations in volatile contents of Bransfield Strait back-arc and Phoenix/West Scotia mid-ocean ridge lavas, northern Antarctic Peninsula

We present the first volatile contents (H2O, CO2, Cl, F, S) of young (< 6 Ma) submarine basaltic glasses from the Phoenix and West Scotia mid-ocean ridges and the Bransfield Strait back-arc of the South Shetland subduction zone in the Antarctic Peninsula.The volatile contents of the MORB glasses correspond well with those of published Pacific MORB and reflect covariations in source enrichment and extent of melting. Our results support the hypothesis that decreasing spreading rates at the Phoenix Ridge resulted in preferential melting of less abundant enriched MORB mantle, due to its greater fertility and higher volatile contents, relative to the more abundant depleted MORB mantle.The volatile contents of the Bransfield Strait back-arc glasses correlate with geochemical indicators of subduction processes and reveal an along-axis spatial distribution consistent with a toroidal inflow of sub-slab asthenosphere around the edges of the subducting plate into the mantle wedge. This inflow should be considered when assessing spatial and geochemical variability at subduction zones, particularly those with slab windows and tears.A small group of Bransfield Strait samples have volatile contents that do not correlate with geochemical signals of subduction influence. We speculate that these samples reflect flux melting of residual enriched mantle brought beneath the Bransfield Strait via corner flow following recent alkaline magmatism in the far eastern regions of the Antarctic Peninsula.Our new data on lavas from the W7 segment of the West Scotia Ridge reveal their source was significantly affected by subduction processes. Unexpectedly, these lavas have CO2-H2O pressures of vapor saturation that suggest they were collected in-situ and erupted relatively recently (∼6 Ma), at odds with previous interpretations of their origins. We suggest they originated from a subduction-modified mantle (lithosphere or asthenosphere) left behind by the eastward-migrating South Sandwich subduction zone sometime over the past ∼30 Myr. These lavas demonstrate the long-lasting effects of subduction processes on the upper mantle and their potential to influence melt compositions even in non-subduction environments today.We use the compositions of lavas from the Phoenix Ridge and Bransfield Strait to estimate mantle potential temperatures; our results agree well with global estimates for mid-ocean ridges and subduction zones, respectively.

Metasomatized mantle source of nascent oceanic crust in the Guaymas Basin, Gulf of California

The geochemical characteristics of nascent oceanic crust play a crucial role in unraveling the mantle dynamics of the initial opening of an ocean. The Gulf of California, located at the East Pacific margin, is one of the best examples of an active and obliquely rifted continental margin. However, the mantle source composition of the nascent oceanic crust in the central part of the Gulf has not yet been comprehensively investigated. Here, we report in situ major and trace element contents as well as BSr isotope compositions for basaltic glass samples from off-axis sills drilled by the International Ocean Discovery Program (IODP) Expedition 385 at Sites U1547 and U1548 in the Guaymas Basin in the central part of the Gulf of California. These glassy samples represent tholeiites and predominantly show trace element patterns akin to those of enriched mid-ocean ridge basalts (E-MORBs) but with distinctive enrichments in Ba and K and depletions in Nb, Ta, and Ti. In addition, these samples have high B contents (3.07–3.67 ppm) with enriched Sr isotopes (87Sr/86Sr = 0.7032–0.7037) and heavy B isotopes (δ11B = −5.52‰ to 1.20‰). The mixing model based on B/Nb values and SrB isotopes shows that the nascent oceanic crust in the Guaymas Basin might be generated through partial melting of a depleted MORB mantle (DMM) source metasomatized by melts from subducted slab materials referring to partially dehydrated sediment and altered oceanic crust components. The magmas in the Gulf of California show a systematic decline in their enrichment in fluid-mobile elements (Ba) and depletion in fluid-immobile elements (Nb, Ta, and Ti) from the northern (e.g., Isla San Luis volcanic center) to the central part (Guaymas Basin) and southward to the mouth (e.g., Alarcón Basin) of the Gulf. This suggests that the enriched (recycled) components in their mantle source were gradually extracted and exhausted during Gulf opening and oceanic crustal accretion that advanced in a northward direction. Our results indicate that the Guaymas Basin magmas were derived from a mantle that was fertilized by subduction components. The subduction signature corroborates the Gulf opening as a process that started in response to long-term oblique convergence at the eastern Pacific plate margin without any influence from a mantle plume. This evolution is different from nascent ocean basins that evolved from intraplate rifting, such as the Red Sea, leading to vastly different mantle source characteristics.

Causes of Cretaceous subduction termination below South China and Borneo: Was the Proto-South China Sea underlain by an oceanic plateau?

The South China, Indochina, and Borneo margins surrounding the South China Sea contain long-lived arcs that became inactive at approximately 85 Ma, even though an embayment of oceanic crust (the ‘Proto-South China Sea’) remained in the intervening region. This oceanic crust eventually subducted in the Cenozoic below Borneo and the Cagayan arc, while the modern South China Sea opened in its wake. To investigate the enigmatic cessation of Mesozoic subduction below South China and Borneo, we studied a fragment of oceanic crust and overlying trench-fill sediments that accreted to NW Borneo during the final stages of Paleo-Pacific subduction. Based on radiolarian biostratigraphy of cherts overlying the pillow basalts and detrital zircon geochronology of the trench-fill, we constrained the minimum age of the oceanic crust during accretion to 40 Ma. This shows that subduction cessation was not related to ridge subduction. Geochemical analysis of pillow basalts revealed an enriched mid-ocean ridge basalt signature comparable to oceanic plateaus. Using paleomagnetism, we show that this fragment of oceanic crust was not part of the Izanagi Plate but was part of a plate (the ‘Pontus’ Plate) separated from the Izanagi Plate by a subduction zone. Based on the minimum 40 Ma age of the oceanic crust and its geochemistry, we suggest that Mesozoic subduction below South China and Borneo stopped when an oceanic plateau entered the trench, while the eastern plate margin with the Izanagi Plate remained active. We show how our findings offer opportunities to restore plate configurations of the Panthalassa-Tethys junction region.

The journey of the Band-e-Zeyarat ophiolite (Makran Accretionary Wedge, SE Iran) from the mid-ocean ridge to the accretionary complex: new insights from its sedimentary cover and associated basaltic dykes and sills

The Band-e-Zeyarat ophiolite (BEZO) sedimentary cover in the Makran Accretionary Prism (SE Iran) records a complex tectono-sedimentary evolution, extending from its formation at a mid-ocean ridge (MOR) setting to deformation in an accretionary prism. Stratigraphic and biostratigraphic data indicate the occurrence of a Valanginian transition zone sequence separating the volcanic sequence and pelagic sedimentary cover. The latter consists of lower Hauterivian cherty limestone passing upwards to upper Hauterivian–Barremian marl and limestone. The pelagic sedimentary cover continues with post-Barremian–Cenomanian (?) marls. Arenites are interlayered in the sedimentary cover; they are composed of rock fragments derived from volcanic-arc and continental margin settings. The BEZO sedimentary cover is intruded by dykes and sills showing enriched MOR basalt chemical affinity. Structural analysis indicates a polyphase deformation history that involved faulting and folding. Our multidisciplinary results indicate that the BEZO formed in a MOR setting and that it was subsequently overprinted by off-axis and within-plate magmatism as it spread away from this MOR. The Band-e-Zeyarat oceanic crust was incorporated into the Makran prism in the latest Late Cretaceous–Paleocene and was further deformed via strike-slip faulting along the dextral Minab-Sabzevaran fault during the Miocene–Pliocene. Supplementary material: A geological sketch map of the Band-e-Zeyarat ophiolite, photomicrographs of arenites, microphotographs of selected calcareous nannofossil taxa, a geochemical discrimination diagram, a table with semiquantitative estimation of calcareous nannofossil abundance, and a text with detailed descriptions of analytical methods, accurancy, and detection limits for whole-rock geochemical analysis are available at https://doi.org/10.6084/m9.figshare.c.6843835 Thematic collection: This article is part of the Ophiolites, melanges and blueschists collection available at: https://www.lyellcollection.org/topic/collections/ophiolites-melanges-and-blueschists

The Late Carboniferous Mafic–Ultramafic Complex Induced by Slab Breakoff in Eastern North Tianshan, Central Asian Orogenic Belt

The Late Carboniferous to Early Permian is a critical period of the Chinese Tianshan, witnessing the tectonic transition from subduction to post-collisional extension during the final amalgamation of the Central Asian Orogenic Belt (CAOB). The late Carboniferous Mozbaysay mafic–ultramafic complex in the Qijiaojing–Balikun area, eastern North Tianshan, provides important clues for revealing the nature and timing of this tectonic transition. The Mozbaysay complex comprises mainly hornblende gabbros and lherzolites. LA-ICP-MS U-Pb zircon ages of hornblende gabbro yielded a weighted mean age of 306 ± 1.9 Ma for this complex. These mafic–ultramafic rocks have high contents of MgO (up to 30 wt.%), Cr (up to 2493 ppm), and Ni (up to 1041 ppm), but low contents of SiO2 (40.34–47.70 wt.%). They are enriched in LREE and show characteristics of enriched mid-ocean ridge basalts (E-MORB). The relatively high Th/Yb and Ba/Nb ratios imply the mantle sources could have been metasomatized by slab–mantle interaction with aqueous fluids from dehydration of the subducted slab. Thus, these mafic–ultramafic rocks were most likely produced by partial melting of the asthenospheric and lithospheric mantle with a slight influence of slab-derived fluids. Therefore, we suggest that the formation of these Late Carboniferous mafic–ultramafic rocks was triggered by the decompression-induced influx of asthenospheric heat and melting through a slab window during post-collisional slab breakoff. Combined with geological data, the petrogenetic links of the Late Carboniferous mafic–ultramafic rocks in eastern North Tianshan to slab breakoff suggest that the tectonic transition from convergence to post-collision most likely initiated in situ at ca. 306 Ma and lasted to ca. 300 Ma.

Clinopyroxene Compositions of E-MORB-Type Gabbro from Bingdaban Ophiolites in Central Tianshan, NW China: Insights into the Evolution of the Magmatic System and Geodynamic Setting

Clinopyroxene, one of the primary rock-forming minerals in mafic rocks, is the major host of lithophile elements in the mantle lithosphere and plays a crucial role in understanding mantle evolution and rock petrogenesis. Taking the Bingdaban ophiolite as an example, this study employed electron probe microanalysis and in situ trace element analysis to investigate the geochemistry of clinopyroxene in gabbros to determine the magma series and evolution, constrain the physicochemical conditions of the magmatic processes and explore the petrogenesis and tectonic setting. Representative gabbro samples were subjected to zircon U–Pb isotopic analysis, yielding an age of 424.3 ± 5.9 Ma. Geochemical investigations revealed that the Bingdaban gabbros exhibit tholeiitic composition, suggesting a genesis associated with enriched mid-ocean ridge basalt (E-MORB). Mineralogical analyses indicated that the clinopyroxene in the gabbros was Mg-rich, Fe-poor, and alkali-poor, representing a subalkaline series. The compositional end members of clinopyroxene were calculated as Wo38.9–48.0En30.9–48.1Fs10.4–24.4, indicating a predominance of diopside with a minor amount of augite. Temperature–pressure conditions imply that these rocks formed in a high-temperature, low-pressure, and shallow-source environment. Compositional estimates of the melt in equilibrium with clinopyroxene are consistent with the overall characteristics of the host rock, reflecting an E-MORB setting. The Bingdaban gabbro likely originated from an initially depleted mantle source that later received an input of enriched mantle material, indicating formation in either an initial oceanic or immature back-arc basin tectonic setting.

Coexisting Nb-enriched basalts and arc volcanic rocks in the northern Qiangtang Terrane, China: Implications for the effects of ambient mantle on subduction zone magmatism

The petrogenesis of Nb-enriched basalts (NEBs) is controversial. NEBs are generally considered to form by melting of either a mixed enriched and depleted mantle source or a mantle wedge metasomatized by adakitic melts. Here we present geochronological, petrological, geochemical, and Sr-Nd-Os isotope data for Early Permian volcanic rocks from the Tuotuohe area in the northern Qiangtang Terrane, China. The studied volcanic rocks can be divided into two groups: arc basalts and basaltic andesites in the lower sequence and NEBs in the upper sequence. Zircon grains from one basaltic andesite sample in the lower sequence yielded a concordia age of 302.0 ± 1.1 Ma. The geochemical and isotopic characteristics suggest that the NEBs were derived from a mixed source consisting of enriched mid-oceanic ridge basalts (MORB)- to oceanic-island basalt-like ambient mantle and slab-derived fluids, whereas the arc basalts and basaltic andesites originated from a source made of the MORB-type ambient mantle modified by slab-derived melts. We propose for the first time that the Nb enrichment of the NEBs was most likely inherited from high-Nb ambient mantle and is independent of the addition of slab-derived components. In addition to slab-derived components, the nature of the ambient mantle is also an important factor controlling the diversity of arc magmatism. Our new findings show that the Late Carboniferous−Early Permian magmatism in the northern Qiangtang Terrane was related to northward subduction of the Paleo-Tethys Ocean, suggesting that subduction might have occurred in at least the Early Permian rather than in the previously thought Middle Permian.

The early Late Triassic Yumen mafic rocks in the eastern Tethyan Himalaya: A record of the progressive opening of the Yarlung Zangbo Neo-Tethyan Ocean

The timing of the opening of the Yarlung Zangbo Neo–Tethyan Ocean (YZNTO) is debated. In this contribution, geochemical and geochronological analyses of diabase, pillow basalt and layered basalt from the Upper Triassic Yumen tectonic mélange (T3Y) of the eastern Tethyan Himalaya in South Tibet are used to elucidate the timing and the magmatic evolution preceding the development of the YZNTO. Zircon U-Pb geochronology indicates that the Yumen mafic rocks crystallized in the Late Triassic (diabase, c. 225 Ma). These rocks display alkaline basalt affinities and have variable enrichment in Ba, U, Pb, Sr and Ti and depletion in Rb, Th and Nb. The diabase and pillow basalt samples have compositions transitional between enriched mid–ocean ridge basalt and ocean island basalt (OIB); layered basalt is more compatible with an OIB affinity. Whole–rock εNd (t) ratios of the mafic rocks range from +5.5 to +11.5 and zircons from a diabase have εHf(t) values varying from – 1.1 to +10.0. Whole–rock trace element concentrations indicate that the parental magmas of the Yumen mafic rocks were derived from the mantle at variable depths extending from the garnet to spinel stability fields. The Yumen mafic rocks originated from partial melting of a heterogeneous magma source composed of dominant depleted asthenospheric magmas and the addition of some components of an ancient and enriched lithospheric mantle; negligible crustal contamination occurred. Combined with previous studies, we conclude that the Yumen mafic rocks were probably produced in an intercontinental rift setting with extremely thin continental lithosphere in the early Late Triassic prior to the opening of the eastern YZNTO. The YZNTO progressively opened along the northern edge of the Indian plate from west to east in the Phanerozoic.

A polygenetic origin for the Sikhoran ultramafic-mafic complex in South Iran

The nature and geodynamic setting of the Sikhoran ultramafic–mafic complex, southwest Iran, is debated, with multiple competing theories having been proposed in recent years. The Sikhoran ultramafic–mafic complex is located in the southern part of the Sanandaj-Sirjan metamorphic-magmatic zone (SSMMZ) and is comprised of porphyroclastic, transitional and layered ultramafic-mafic sequences of Carboniferous age. These units are cut by isotropic gabbros, diabasic and pegmatoid gabbroic dikes with ages ranging from Permian to the Cretaceous. These bodies also intrude into Upper Paleozoic metamorphic rocks, where they induced high-temperature contact metamorphism during the Late Carboniferous. Here we present new textural descriptions, mineral and whole-rock geochemical analyses, and the results of zircon UPb dating of magmatic mafic rocks and metamorphic host rocks from this region in order to reconstruct the petrogenesis of the Sikhoran ultramafic–mafic complex. Zircon UPb ages from layered gabbros indicate Late Carboniferous (320.8 ± 6.4 Ma) crystallization, which is similar to the age of the Upper Paleozoic host gneisses (334.6 ± 4.9 Ma). By contrast, isotropic gabbros that cross-cut the complex have a crystallization age of 178.3 ± 2.3 Ma, and anatectic quartz diorite/plagiogranite produced from partial melting of hosting amphibolite in contact with the gabbros yielded Late Triassic-Early Jurassic ages (187.2 ± 2.6 Ma). These data suggest a polygenetic origin and a range of tectonic settings for various parts of the ultramafic-mafic complex. Geochemical modeling shows that mantle plume-related melting (∼5–40%) of metasomatized mantle could have formed the ultramafic-mafic layered cumulate complex during the Late Carboniferous. A geochemical transition from island arc tholeiite (IAT) isotropic gabbros to cross-cutting enriched mid-ocean ridge basalts (E-MORB)–diabasic dikes occurred between the Late Triassic-Early Jurassic to the Late Cretaceous. The mantle-derived ultramafic parts of the Sikhoran ultramafic-mafic complex have similarities with other known ultramafic-mafic mantle plumes (e.g., Tinaqulllo, Lherz, and Ronda), and its layered ultramafic-mafic segment has similarity with layered intrusions (e.g., Pulur complex in Turkey). The highest observed crystallization temperature in porphyroclastic, transitional and layered ultramafic mantle sections of ∼1140 °C is considered as the mantle potential temperature, since the highest crystallization temperatures are observed in the most forsteritic olivine crystals. Based on amphibole chemistry, the crystallization conditions of transitional to layered ultramafic rocks at 900–1005 °C occurred at high H2O contents in a melt between nickel–nickel oxide (NNO) −8.5 and NNO −9.0, which lies along the NNO−2 buffer. These results are consistent with a model in which the opening of the Zagros Neotethys Oceanic basin in the Esfandagheh region initiated in the Late Carboniferous, alongside the formation of an extensional environment that allowed ascent of a subcontinental mantle plume. Subduction initiation of oceanic lithosphere began during the Late Triassic-Early Jurassic and ended in the Late Cretaceous.

Formation of Archean greenstone belts: Insights from an assemblage-scale study in the western Superior craton

Archean greenstone belts contain the oldest volcanic rocks on Earth and can provide critical insights into Earth’s early evolution. This study chooses the Sturgeon Lake greenstone belt in the easternmost Western Wabigoon terrane (WWT) of the Superior craton to illustrate an option for better understanding the formation of Archean greenstone belts. Our dataset includes outcrop observations, bulk compositions of 77 mafic to felsic volcanic samples, and in-situ U-Pb, Lu-Hf, and trace elements of zircon from 14 intermediate to felsic volcanic samples. The results revealed that this greenstone belt had broadly continuous volcanism from ca. 2780 to 2725 Ma, followed by a tectonic quiescence prior to a ca. 2707–2703 Ma volcanism at the terrane boundary. The intermediate volcanic rocks are characterized by variable Th/Nb and highly depleted Hf (zircon ƐHf(i) = +3 to + 6), interpreted to be derived from mantle sources ranging from those of normal mid-ocean ridge basalts (N-MORB) to those of enriched MORB (E-MORB), which commonly assimilated various felsic crustal components. The mafic volcanic rocks are dominated by low La/Sm basalts with negligible Nb, Ta anomalies and limited range of Th/Nb, forming a mantle array on the Th/Yb-Nb/Yb plot and consistent with oceanic crust of N-MORB to enriched N-MORB affinities. Some basalts from the ca. 2738–2725 Ma assemblages, however, gave high La/Sm, negative Nb and Ta anomalies, and limited range of Th/Nb plotting above and parallel to the mantle array. These basalts might be associated with passive subcretion and rollback of oceanic crust of the stagnant-lids tectonics or subduction of oceanic lithosphere as in modern-style plate tectonics, both of which are supported by trace element compositions of zircon that indicate hydrous, oxidized, large-ion lithophile element-enriched, and medium- to high-pressure magmas. Identification of three magma-series would not be possible if the data were lumped together, which is commonly seen in terrane- or craton-scale studies that sometimes propose contrasting interpretations of rock origins and Archean geodynamic processes. This detailed approach of distinguishing rock types and zooming into the subunits of a greenstone belt offers a practical solution to more accurately characterize Archean volcanic rocks and to better understand the early Earth.

From arc accretion to within-plate extension: Geochronology and geochemistry of the Neoproterozoic magmatism on the northern margin of the Yangtze Block

Early Neoproterozoic arc magmatism and arc accretion processes are fundamental issues in reconstructing the Rodinia supercontinent. In this study we present new data of zircon U-Pb geochronology, Hf-O isotopes and whole-rock geochemistry for the magmatic rocks (including 12 felsic volcanic rocks, 3 granodioritic intrusions, 8 basaltic extrusive rocks and 12 gabbroic intrusions), which are spatially independent, in the Dahongshan area on the northern margin of the Yangtze Block. The investigated intermediate-felsic rocks are dated at ca. 970 Ma, ca. 885–865 Ma, ca. 840–830 Ma and ca. 810–790 Ma by in situ ion probe and laser zircon U-Pb dating methods. The mafic rocks are dated at ca. 870 Ma by in situ ion probe. Combined with previous age data, our new geochronology results suggest continuous magmatic activities from ca. 970 Ma to ca. 790 Ma in the Dahongshan area with a magmatic flare-up at ca. 840 Ma. The ca. 970–840 Ma mafic rocks, as well as the contemporaneous intermediate-felsic rocks, show enrichments in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depletions in high-field strength elements (HFSEs), representing arc-related tectonic settings. Zircon grains from these rocks generally have positive εHf(t) values from +7.3 to +14.7 and slightly elevated δ18O values from +5.59 to +6.89, indicating a dominant juvenile source with minor supracrustal incorporation. In contrast, the ca. 830–790 Ma mafic rocks are characterized by E-MORB- (enriched mid-ocean ridge basalt) and OIB- (oceanic island basalt) like and the contemporaneous felsic rocks show characteristics of A2-type granites, implying a within-plate extension environment. Zircon grains from the ca. 830–790 Ma felsic rocks display broad εHf(t) values from −5.7 to +15.3 and low mantle δ18O values from +3.81 to +6.11, implying multiple magma sources for their generation and the imprinting of high-temperature hydrothermal alteration. The relative contributions of the mature crustal component in the Dahongshan magmas decreases from 10–20 % in the ca. 970–840 Ma felsic rocks to 0–10 % in the ca. 830–790 Ma felsic rocks. The Neoproterozoic magmatic activity on the northern margin of the Yangtze Block recorded an integrated evolution from accretion of previous oceanic arc (ca. 970–870 Ma) at ca. 870–840 Ma to within-plate extension (ca. 830–790 Ma) in response to the convergence and divergence of the supercontinent Rodinia.