Enhanced Storage Capacity Research Articles

Enhancing solar flat plate collector efficiency with advanced phase change materials and expanded boron nitride

ABSTRACT Thermal energy storage, particularly through Phase Change Materials (PCMs), is gaining significant attention for its ability to enhance storage capacity and thermal conductivity. PCMs help alleviate the strain on renewable energy sources and stabilize load fluctuations. This study integrates a novel combination of LiNO3-NaSO4·10H2O-NaCl with boron nitride into Flat Plate Collectors (FPCs) to boost system performance. This Composite Phase Change Material (CPCM) increases latent heat value by up to 245.80 kJ, enhancing thermal decomposition and absorption rates while reducing heat losses. Boron nitride improves thermal conductivity by 25%, from 1.378 W/m·K to 5.543 W/m·K, increasing the CPCM's charging rate. The specific heat capacity rises from 4.2 J/g·°C to 5 J/g·°C at a maximum temperature of 90°C. As a result, the collector's efficiency improves by 15%, achieving an overall system efficiency of 88%. Water serves as the heat transfer fluid, and simulations are conducted using Python in Anaconda Jupyter Notebook.

Controlling of Crystal Facets by Dysprosium-Modified WO3/Carbon Nanofibers Enhance the Flexible Supercapacitor Performance.

Dysprosium-modified tungsten oxide/carbon nanofibers (Dy-WO3/PCNFs) are fabricated via electrospinning combined with high-temperature calcination to synthesize a flexible, self-supporting electrode material that does not require a conductive agent or binder. XRD and TEM analyses showed that introducing dysprosium promoted the preferential growth of WO3 crystals along the preponderance crystal planes involved in the electrochemical reaction, enhancing the exposure of the (002) and (200) crystal planes. Furthermore, DFT calculations demonstrated that the incorporation of Dy resulted in enhanced adsorption of Dy-WO3 by PCNFs, with an adsorption energy of -1.21eV. The Bader charge results indicate a transfer of 1.70 |e| from PCNFs to Dy-WO3. DFT calculations demonstrate that strong adsorption facilitates charge adsorption/desorption, which contributes to charge transfer and enhances storage capacity. The prepared Dy-WO3/PCNFs exhibited a high specific capacitance (557.28Fg-1 at 0.5Ag-1). Supercapacitors assembled with Dy-WO3/PCNFs as the positive electrode and CNFs as the negative electrode have high energy density (29.8Whkg-1 at a power density of 363.48Wkg-1). This study demonstrates the successful synthesis of Dy-WO3/PCNFs with exceptional electrochemical properties and offers significant insights into the design and application of flexible electrodes by incorporating dysprosium to modulate the crystal surface of WO3.

Influence of electrodes on the resistive switching characteristics of Al/Gd2Zr2O7/E (E=Al or ITO) RRAM devices

Sol-gel derived amorphous Gd2Zr2O7 (GZO) thin films with Al/GZO/E (E = ITO or Al) structures were prepared to demonstrate the effect of electrode material on the switching behavior of resistive random access memory (RRAM) devices. All devices exhibit bipolar resistive switching (BRS) mode. After the post-metal annealing (PMA) treatment, the AlOx interfacial layer contributes to enhancing oxygen ion storage capacity and limiting the electromigration of aluminum metal. The forming-free Al/GZO/ITO device exhibits a switching cycle of 3027, a Vset/Vreset ratio of −1.83 V/0.56 V, a Ron/Roff ratio of approximately 10, and a retention time of 104 s. And the Al/GZO/Al device features a dual-layer AlOx structure, significantly improving the integrity of filament rupture to reduce leakage current and increase the switching window. Its switching cycle is 1946, with a Vset/Vreset ratio of −3.47 V/0.29 V, a Ron/Roff ratio of approximately 102, and a retention time of 104 s. The oxygen storage capacity of the dual-layer AlOx interfacial layer in the Al/GZO/Al device surpasses that of the Al/GZO/ITO device, allowing for a reduction in the reset voltage and ensuring more complete filament rupture, thereby enhancing the RHRS. Accordingly, GZO thin films can be applied to achieve the desired RS characteristics on different electrodes, making them promising candidates for RRAM applications.

Enhancing electrochemical energy storage in Zinc hybrid capacitors using 3D-printed GO/AC electrodes with Oxygen functional groups

Zinc-ion hybrid capacitors (ZIHCs), promising for energy storage, encounter challenges such as mismatched positive and negative electrode capacities. Addressing this, increasing the thickness of positive electrode proves effective. However, traditional thick electrodes show an extended ion diffusion paths, which slows reactions and decreasing charge-discharge efficiency. Innovations in electrode structures have been achieved through 3D printing technology with an "embedded" composite material of activated carbon and graphene oxide, creating grids with varying layers to explore the relationship between layer number and capacitor performance. Density Functional Theory (DFT) simulations confirm the crucial role of oxygen functional groups on graphene oxide in enhancing storage capacity, with these findings supported by excellent electrochemical performance in tests. Precise control of electrode structures through 3D printing optimizes ion transport pathways, achieving a high specific capacity of 0.92 mAh cm−2 at a current density of 10 mA cm−2, maintaining 86.4 % cycle stability after 8,000 cycles. These results underscore the potential of 3 D printing to advance electrode design and suggest new directions for research.

Maximizing Onboard Hydrogen Storage Capacity by Exploring High-Strength Novel Materials Using a Mathematical Approach.

Hydrogen fuel holds promise for clean energy solutions, particularly in onboard applications such as fuel cell vehicles. However, the development of efficient hydrogen storage systems remains a critical challenge. This study addresses this challenge by exploring the potential of high-strength novel materials, including glass, to maximize onboard hydrogen storage capacity. A mathematical approach was employed to evaluate the feasibility and efficacy of various high-strength materials for hydrogen storage. This study focused on capillary arrays as a promising storage medium and utilized mathematical modeling techniques to estimate the storage capacity enhancement achievable with different materials. The analysis revealed significant variations in storage capacity enhancements in different high-strength novel materials, with glass having promising results. Glass-based materials demonstrated the potential to meet or exceed US Department of Energy (DOE) targets for both gravimetric and volumetric hydrogen storage capacities in capillary arrays. By leveraging a mathematical approach, this study identified high-strength novel materials, including glass and polymers, capable of substantially improving onboard hydrogen storage capacity: 29 wt.% with 40 g/L for quartz glass and 25 wt.% with 38 g/L for Kevlar compared to 5.2 wt.% with 26.3 g/L from a conventional type IV tank. These findings underscore the importance of material selection in optimizing hydrogen storage systems and provide valuable insights for the design and development of next-generation hydrogen storage technologies for onboard applications.

High entropy alloys for hydrogen storage applications: A machine learning-based approach

Hydrogen is a clean energy carrier and has potential applications in energy storage, power generation, and transportation. This study explores the efficient and safe storage of hydrogen, particularly through solid-state methods using high entropy alloys (HEAs). HEAs have garnered attention for their versatility in tailoring properties for hydrogen storage. The integration of Machine Learning (ML) in designing HEAs offers an expedited approach, analyzing datasets and predicting material properties to enhance storage capacity, kinetics, and stability. Despite significant progress, the study acknowledges certain research limitations, particularly its relatively narrow focus on applying ML to HEAs for hydrogen storage. One of the biggest challenges with HEAs is their complexity, which.necessitates larger datasets to develop accurate predictive models. Collecting and analyzing existing HEA data for hydrogen storage using ML techniques is the main objective. Using algorithms like support vector regression (SVR), K-nearest (KNN), and random forest (RF), hydrogen-to-metal ratio (H/M) and valence electron configuration (VEC) are accurately predicted. The study proposes alloys with potential for HEA formation, identifying 741 with quaternary and 631 with quinary HEAs. These compositions are newly proposed and do not yet exist. Out of these, 774 HEAs are identified as potential candidates for hydrogen storage applications. Applying ML techniques, the selection process is more efficient, reducing the dependency on time-consuming experiments and making it easier to discover promising candidates.

Cathode performance of novel γ-LixV2O5/carbon composite in organic and aqueous electrolyte

Preparation of in-situ composites with carbon by pyrolysis of an organic precursor is an effective strategy to improve performances of insulating and semiconducting cathode materials. However, due to the property of organic precursor to act as a strong reductive agent during carbonization process, the in-situ synthesis of LiV2O5/C composite cathode material is delicate and presents a challenge for researchers, since vanadium in LiV2O5 coexists in two oxidation states, V4+ and V5+. In our research, we utilized an adopted conventional solid state method for the in-situ preparation of LixV2O5/C composite (x ≈ 0.86). By using methylcellulose polymer as a carbon source, LixV2O5/C was synthesized via two-step solid state reaction at elevated temperatures. LixV2O5 crystallized as gamma polymorph phase, and the amount of in-situ formed carbon does not exceed 3wt%. The electrochemical characteristics of the as-prepared LixV2O5/C were investigated in aqueous and non-aqueous electrolyte via cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) tests and electrochemical impedance spectroscopy (EIS). On lithium insertion/removal, the LixV2O5/C composite exhibits stable cycling performance and achieves significant storage capacity enhancement when compared to pristine LixV2O5 obtained under similar conditions. Under current densities of 0.1, 0.2, 0.3 and 1 A/g, the specific capacity enhancement is around 112, 91, 80 and 62 %, respectively. Replacing the organic electrolyte with the aqueous one has a negligible effect on the mechanism and efficiency of lithium intercalation within the LixV2O5/C, which opens up the possibility of using this material in aqueous as well as in organic-electrolyte batteries. The decay of cathode's activity evidenced during electrochemical exchange of lithium with sodium in aqueous environment comes as a result of the formation of electrochemically inactive β-NaxV2O5.

Amorphous to Crystalline Phase Transformation Enables Tunable Persistent Luminescence for Multi‐Mode Optical Information Storage

AbstractMulti‐mode luminescence tuning through in situ crystallization of topological glass holds significance for photonics applications. Here, NaAlSiO4:Eu2+‐based glass ceramics are presented as stable persistent luminescence (PersL) materials by controlling the phase transformation in Eu2+ doped Na2O‐Al2O3‐SiO2 from amorphous glass to crystalline nepheline phase. X‐ray and UV excited PersL colors from blue to yellow are realized by adjusting the crystallization duration time, and trap statuses reveal the dynamic PersL process with a trap redeployment from 0.83 to 1.09 eV during the transformation. Optical information storage model is constructed with a structure of stacked emitting layers to enhance storage capacity. X‐ray excited luminescence time‐lapse imaging is further demonstrated with optical memory longer than 5 days. These findings advance the development of superior stable PersL glass ceramics and offer optical manipulation tactics for multi‐mode optical information storage applications.

Future directions in geological research impacting renewable energy and carbon capture: A synthesis of sustainable management techniques

Geological research plays a pivotal role in shaping the future of renewable energy and carbon capture initiatives, offering insights into sustainable management techniques. This review synthesizes the future directions in geological research that impact renewable energy and carbon capture, focusing on sustainable management techniques. Future geological research will increasingly focus on enhancing the integration of renewable energy sources into existing energy systems. This includes the development of innovative geological mapping techniques to identify and characterize renewable energy resources with greater precision, aiding in the selection of optimal sites for energy production. Additionally, there will be a growing emphasis on utilizing geological data to assess the feasibility of carbon capture and storage (CCS) projects, particularly in volcanic regions, where the unique geological characteristics offer potential for efficient carbon sequestration. Another key aspect of future geological research is the advancement of monitoring and modeling techniques to evaluate the long-term performance and environmental impact of renewable energy and CCS projects. This includes the use of advanced geophysical and geochemical methods to monitor subsurface changes associated with energy extraction and carbon storage, ensuring the effectiveness and safety of these practices. Furthermore, future research will explore the potential of geological formations, such as deep saline aquifers and depleted oil and gas reservoirs, for large-scale carbon storage. This will involve developing strategies to enhance storage capacity and mitigate the risk of CO2 leakage, contributing to the sustainable management of carbon emissions. In conclusion, future geological research will play a critical role in advancing renewable energy and carbon capture technologies, offering sustainable management techniques that are essential for addressing climate change. By focusing on innovative mapping, monitoring, and modeling approaches, researchers can pave the way for a more sustainable energy future.

A Comparative Study on Electrochemical Performance of Single versus Dual Networks in Lithium Metal/Polysulfide-Polyoxide Co-Network/Lithium Titanium Oxide Cathode

The present article introduces a strategy for controlling oxidation and reduction reactions within polymer electrolyte membrane (PEM) networks as a means of enhancing storage capacity through the complexation of dissociated lithium cations with multifunctional groups of the polymer network. Specifically, co-polymer networks based on polysulfide (PS) and polyoxide (PO) precursors, photo-cured in the presence of succinonitrile (SCN) and lithium bis(trifluoro methane sulfonyl imide) (LiTFSI) salt, exhibited ionic conductivity on the order of mid 10−4 S/cm at ambient temperature in the 30/35/35 (weight %) composition. Lithium titanate (LTO, Li4Ti5O12) electrode was chosen as an anode (i.e., a potential source of Li ions) against lithium iron phosphate (LFP, LiFePO4) cathode in conjunction with polysulfide-co-polyoxide dual polyelectrolyte networks to control viscosity for 3D printability on conformal surfaces of drone and aeronautic vehicles. It was found that the PS-co-PO dual network-based polymer electrolyte containing SCN plasticizer and LiTFSI salt exhibited extra storage capacity (i.e., specific capacity of 44 mAh/g) with the overall specific capacity of 170 mAh/g (i.e., for the combined LTO electrode and PEM) initially that stabilized at 153 mAh/g after 50th cycles with a reasonable capacity retention of over 90% and Coulombic efficiency of over 99%. Of particular interest is the observation of the improved electrochemical performance of the polysulfide-co-polyoxide electrolyte dual-network relative to that of the polyoxide electrolyte single-network.

Sorption properties of nanostructured ball-milled porous silicon for solid-state hydrogen storage up to 80 bar

Solid-state storage is a feasible solution to store hydrogen compared to commercially available techniques. The disadvantage of using metal and complex hydrides for storage is the elevated temperature operation (>400 °C) and slow reaction kinetics. Porous materials like carbon nanostructures, metal-organic frameworks, zeolites, and porous polymers possess high surface energy and hydrogen affinity. However, cryogenic temperature operation and low storage at ambient conditions are major limitations for practical storage applications. Modifying the material morphology and storage parameters to enhance hydrogen storage is under intense investigation. This study focuses on nanostructuring porous silicon (PS), evaluating its structural characteristics, and investigating its ability to store hydrogen at up to 80 bar. The challenges of large particle size and low-pressure hydrogen storage in the novel porous material is addressed with possible mechanisms. The discussion explored the potential of utilizing interconnected pores via nanoscale engineering and increased charging pressure to optimize hydrogen exposure. Nanostructuring the hand-grinded porous Si (HGPS) reduces crystallite size, boosts surface energy and enhances thermodynamics. At 80 bar and 120 °C, the ball-milled PS (BMPS) exhibits a hydrogen storage capacity of 10.7 wt%. The isosteric heat of adsorption is utilized to optimize storage conditions to achieve useable capacity. The hydrogen adsorption pressure is optimized between 40 and 60 bar, where the storage capacity ranges from 2 wt% and 6 wt% (meeting the hydrogen storage target set by the US Department of Energy). X-ray Photoelectron Spectroscopy investigates surface states and bonding involving silicon hydrides. The effect of nanostructuring on decomposition energy is observed by differential scanning calorimetry. The decreased crystallite size, examined through X-ray diffraction and Raman spectroscopy, exposes nanopores accessible to hydrogen. The accessibility enhances storage capacity in free and surface-affixed states, rendering BMPS for reversible storage applications. The lower temperature requirement for hydrogen adsorption and release from storage material aligns with Sustainable Development Goal 7 (SDG 7) on affordable and clean energy.

Numerical simulation of the hydrogen charging process in an adsorption storage tank

Adsorption storage utilizing activated carbon is acknowledged as a promising approach for hydrogen storage duo to its high efficiency. This study compares the activated carbon adsorption storage method with the conventional empty tank storage approach. Finite element simulation is conducted to analyze the hydrogen charging process. Results reveal that under conditions with an initial temperature of 281 K and a storage pressure of 50 MPa, the adsorption tank exhibits a higher system volumetric capacity compared to the empty tank, with an increase of 12.6%. Furthermore, the influence of activated carbon's macroporosity and adsorption performance on storage capacity is investigated. It is indicated that increasing macroporosity effectively enhances storage capacity. Additionally, a comparison between the hydrogen storage performance of AX-21 activated carbon and carbon nanotubes (CNTs) highlights the significant impact of adsorption performance of the adsorbent materials on the storage capacity and temperature distribution.

Reinforced PEO/Cs polymers blend with Al2O3/TiO2 hybrid nanofillers: Nanocomposites for optoelectronics and energy storage

This work focuses on the meticulous preparation and characterization of polyethylene oxide (PEO)/chitosan (Cs) polymer blends infused with aluminum oxide nanoparticles (Al2O3 NPs) and sol-gel synthesized titanium oxide nanoparticles (TiO2 NPs). Employing the casting method, the study delves into a comprehensive analysis of the structural, optical, electrical, and dielectric properties exhibited by the resulting PEO/Cs-Al2O3/TiO2 nanocomposites. Structural evaluations utilized transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FT-IR). UV–Vis spectra showed enhanced optical properties, with the indirect optical energy gap decreasing from 5.23 eV to 5.01 eV for blends with 2.4 wt% Al2O3/TiO2 NPs. The AC conductivity of the polymeric nanocomposites showed enhanced values compared with the pure blend. Additionally, dielectric permittivity and modulus exhibit tunability, presenting advantageous prospects with varying Al2O3/TiO2 NPs concentrations in the PEO/Cs blend. The Nyquist plots reveal distinctive features, including semicircular arcs at the low-frequency part and an inclined spike at the high-frequency part, with decreasing arc radius corresponding to increasing nanofiller contents. These observations are best fitted to two models of equivalent circuits. The engineered PEO/Cs-Al2O3/TiO2 nanocomposite capacitor showed enhanced storage capacity and controlled conductance characteristics. The findings of this study revealed that these nanocomposites hold promise as bandgap tuners, optical sensors, permittivity-tunable nanodielectrics, and novel host matrices for the development of solid polymer flexible electrolytes, thereby contributing to the next generation of energy storage and conversion devices with superior performance.

Electrospun synthesis of polyaniline and titanium dioxide nanofibers as potential electrode materials in electrochemical hydrogen storage

To meet the imperative of advancing sustainable energy, prioritizing storage systems for clean energy, such as hydrogen, is crucial. However, challenges exist in hydrogen storage, and focusing on nanofibers that incorporate appropriate nanoparticles emerges as a promising approach to enhance storage capacity. In this study, polyaniline/polyvinyl alcohol (PANI/PVA) nanofibers and polyaniline/polyvinyl alcohol/titanium dioxide (PANI/PVA/TiO2) nanofibers were synthesized using the electrospinning method under constant conditions. After characterization of the nanofibers by various techniques, the nanocomposites were used as novel electrode materials for a first time for electrochemical hydrogen energy. Electrochemical tests were conducted on the synthesized nanofibers, and an optimal current of 1.5 mA was determined. The electrochemical analyses obtained revealed a significant improvement in the maximum hydrogen storage capacity with the presence of TiO2 nanoparticles. It increased from 654.8 mAh/g for PANI/PVA nanofibers to 1250 mAh/g for PANI/PVA/TiO2 nanofibers. The difference in storage capacity is attributed to the addition of TiO2 nanoparticles.

Enhancing high-speed digital systems: MVL circuit design with CNTFET and RRAM

Multiple Value Logic (MVL) circuits in high-speed digital systems can represent significantly more information than traditional binary logic circuits. The increasing demand for enhanced data storage capacity has driven the adoption of MVL circuits. However, designing MVL circuits presents challenges, particularly in achieving improved performance aligned with the desired threshold voltage. To address this challenge, harnessing carbon nanotube field-effect transistors (CNTFETs) has been instrumental in designing MVL circuits. CNTFETs offer distinct advantages due to their large resistors. Furthermore, substituting these resistors with Resistive Random Access Memory (RRAM) to implement Ternary logic circuits enhances storage capacity by enabling multiple resistance states within a single cell. This paper presents a novel MVL circuit design that leverages the unique characteristics of CNTFETs and RRAM. Additionally, gate implementation is explored using a Recurrent Neural Network − Long-Short Term Memory (RNN-LSTM) based Tasmanian Devil Optimization algorithm. The practical implementation uses Synopsis HSPICE software with CNTFET technology at 32 nm. A comprehensive performance analysis compares this approach with state-of-the-art solutions regarding delay, area, and power consumption. Significant reductions in area, power consumption, and transistor count are revealed with the proposed approach.

Enhanced Storage Capacity via Anion Substitution for Advanced Delayed X-ray Detection.

X-ray radiation information storage, characterized by its ability to detect radiation with delayed readings, shows great promise in enabling reliable and readily accessible X-ray imaging and dosimetry in situations where conventional detectors may not be feasible. However, the lack of specific strategies to enhance the memory capability dramatically hampers its further development. Here, we present an effective anion substitution strategy to enhance the storage capability of NaLuF4:Tb3+ nanocrystals attributed to the increased concentration of trapping centers under X-ray irradiation. The stored radiation information can be read out as optical brightness via thermal, 980 nm laser, or mechanical stimulation, avoiding real-time measurement under ionizing radiation. Moreover, the radiation information can be maintained for more than 13 days, and the imaging resolution reaches 14.3 lp mm-1. These results demonstrate that anion substitution methods can effectively achieve high storage capability and broaden the application scope of X-ray information storage.

Porous and graphitic carbon nanosheets with controllable structure for zinc-ion hybrid capacitor

The imbalances of storage capacity and reaction kinetics between carbonaceous cathodes and zinc (Zn) anodes restrict the widespread application of Zn-ion hybrid capacitor (ZIHC). Structure optimization is a promising strategy for carbon materials to achieve sufficient Zn2+ storage sites and satisfied ion–electron kinetics. Herein, porous graphitic carbon nanosheets (PGCN) were simply synthesized using a K3[Fe(C2O4)3]- and urea-assisted foaming strategy with polyvinylpyrrolidone as carbon precursor, followed by activation and graphitization. Sufficient pores with well-matched pore sizes (0.80–1.94 nm) distributed across the carbon nanosheets can effectively shorten mass-transfer distance, promoting accessibility to active sites. A partially graphitic carbon structure with high graphitization degree can accelerate electron transfer. Furthermore, high nitrogen doping (7.2 at.%) provides additional Zn2+ storage sites to increase storage capacity. Consequently, a PGCN-based ZIHC has an exceptional specific capacity of 181 mAh g−1 at 0.5 A g−1, superb energy density of 145 Wh kg−1, and excellent cycling ability without capacity decay over 10,000 cycles. In addition, the flexible solid-state device assembled with PGCN exhibits excellent electrochemical performances even when bent at various angles. This study proposes a straightforward and economical strategy to construct porous graphitic carbon nanosheets with enhanced storage capacity and fast reaction kinetics for the high performance of ZIHC.

Mo-doped porous Co3O4 nanoflakes as an electrode with the enhanced capacitive contribution for asymmetric supercapacitor application

Cobalt oxide (Co3O4) electrode materials have tremendous properties for supercapacitors, such as being environmentally friendly, having a high surface area, being low cost, and having high theoretical specific capacitance (3560 Fg−1). However, its poor electronic conductivity restricts the performance of the practical application. Doping transition metal ions into the host materials is an effective method to improve conductivity and enhance storage capacity. In this research work, we studied Mo-doped Co3O4 nanostructure electrodes synthesized using the electrodeposition technique. The integrated material samples were characterized by XRD, SEM with EDAX, XPS, FTIR, Raman spectra, UV–visible, and BET for their structure, morphology, composition, optical, and surface area properties. The 2 mM Mo-doped Co3O4 electrode exhibits excellent electrochemical pseudocapacitive properties. The optimized Mo2-doped Co3O4 shows a maximum specific capacitance of 1674 Fg−1 at 10 mA cm−2 current density in 1 M KOH electrolyte solution. Finally, the asymmetrical hybrid supercapacitor device (AsHScD) Mo2-Co3O4//rGO) demonstrates the highest power density of 159.0 KWKg−1 and maximum energy density of 13.80 WhKg−1 with a long-term stability of 95 % up to 2000 cycles. The Mo2-Co3O4 electrode is a promising candidate material for a charge-storage hybrid supercapacitor in an aqueous 1 M KOH electrolyte.

Hydrogen production, storage, and transportation: recent advances.

One such technology is hydrogen-based which utilizes hydrogen to generate energy without emission of greenhouse gases. The advantage of such technology is the fact that the only by-product is water. Efficient storage is crucial for the practical application of hydrogen. There are several techniques to store hydrogen, each with certain advantages and disadvantages. In gaseous hydrogen storage, hydrogen gas is compressed and stored at high pressures, requiring robust and expensive pressure vessels. In liquid hydrogen storage, hydrogen is cooled to extremely low temperatures and stored as a liquid, which is energy-intensive. Researchers are exploring advanced materials for hydrogen storage, including metal hydrides, carbon-based materials, metal-organic frameworks (MOFs), and nanomaterials. These materials aim to enhance storage capacity, kinetics, and safety. The hydrogen economy envisions hydrogen as a clean energy carrier, utilized in various sectors like transportation, industry, and power generation. It can contribute to decarbonizing sectors that are challenging to electrify directly. Hydrogen can play a role in a circular economy by facilitating energy storage, supporting intermittent renewable sources, and enabling the production of synthetic fuels and chemicals. The circular economy concept promotes the recycling and reuse of materials, aligning with sustainable development goals. Hydrogen availability depends on the method of production. While it is abundant in nature, obtaining it in a clean and sustainable manner is crucial. The efficiency of hydrogen production and utilization varies among methods, with electrolysis being a cleaner but less efficient process compared to other conventional methods. Chemisorption and physisorption methods aim to enhance storage capacity and control the release of hydrogen. There are various viable options that are being explored to solve these challenges, with one option being the use of a multilayer film of advanced metals. This work provides an overview of hydrogen economy as a green and sustainable energy system for the foreseeable future, hydrogen production methods, hydrogen storage systems and mechanisms including their advantages and disadvantages, and the promising storage system for the future. In summary, hydrogen holds great promise as a clean energy carrier, and ongoing research and technological advancements are addressing challenges related to production, storage, and utilization, bringing us closer to a sustainable hydrogen economy.

Sucralose, an eco-friendly novel promoter of carbon dioxide hydrate formation: Kinetic investigation

Gas hydrates represent a cutting-edge technology for the separation and storage of greenhouse gases, capturing the interest of numerous researchers. Nevertheless, the challenges of low storage capacity and slow hydrate formation can be surmounted through the application of kinetic promoters. This study investigates the kinetic parameters of CO2 hydrate formation with the influence of sucralose, an eco-friendly additive, at various concentrations. Lab-scale experiments were conducted in a reactor, with initial conditions of 3 MPa pressure and 274.15 K temperature. Among the tested concentrations, the addition of 0.75 wt% sucralose exhibited the highest gas consumption and storage capacity. Compared to pure water at t = 300 min, the inclusion of 0.75 wt% sucralose resulted in a 37 % increase in gas consumption and a corresponding enhancement in storage capacity. Likewise, at t = 20 min, the water-to-hydrate conversion and storage capacity (SC) increased by approximately 35 % compared to pure water. However, as the sucralose concentration in the aqueous solution surpassed 0.75 wt%, the promoting effect on gas consumption declined, showing a diminishing return. Notably, a slight inhibitory behavior was observed during the experiment with a 10 wt% sucralose concentration. Furthermore, the experiments were replicated for certain sucralose concentrations in the aqueous solution under the same initial pressure but at an elevated temperature of 276.15 K. The results demonstrated a reduction in the promoting effect of sucralose, suggesting that raising the cell temperature during the hydrate formation process negatively impacted the kinetic parameters.