Energy Dispersive Method Research Articles

Unravelling of cellulolytic fungal consortium from humus soil for efficient lignocellulosic waste degradation

Cellulose is a complex polysaccharide composed of β 1, 4 glycosidic linkages and these linkages are broken down by a complex enzyme system called cellulase. Cellulase is an enzyme complex associated with β 1, 4 endoglucanase, β 1, 4 exoglucanase, and β glucosidase. The fungal strains were isolated from decomposed humus soil and screened for the best cellulolytic activity. Thirty-two isolates were screened among these; three were selected based on their morphological characters and hydrolytic capacity, viz, Cladosporium oxysporum N5, Aspergillus sigurros N6, and Cladosporium cladosporioides N12. Among these fungi, Cladosporium oxysporum N5 shows potential hydrolytic activity and was selected for optimization studies and evaluation of their cellulolytic capability. Cellulolytic strain Cladosporium oxysporum N5 produced maximum amount of cellulase enzyme at 5 days of incubation at 30 ℃ and pH 7, viz, β 1, 4 endoglucanase (167.83± U/ml), β 1, 4 exoglucanase (29.04± U/ml), and β glucosidase (34.07± U/ml). SEM coupled Energy dispersive X-ray and FTIR spectroscopy methods revealed the cellulose degradation efficiency of fungal cellulase by microscopic, elemental percentage, and functional group, respectively. An affordable and eco-friendly fungal-based cellulase that will boost industrially important commodity production such as food, beverages, pharmaceuticals, fertilisers, and biofuels.

Novel synthesis method of carbon nanofibers (CNFs) by using Proteus mirabilis bacteria

Carbon nanofiber (CNF) is a cylindrical carbon nanomaterial, with diameter around 100 nm and its length sometimes extends up to a few micrometers. Different types of CNFs are synthesized based on the production method, which differs dramatically in terms of structure, composition, and characteristics. Today, using green chemistry methods and microorganisms has resulted in biocompatible nanoparticles materials. In this work Proteus mirabilis bacteria were used as nanometer template for synthesis of carbon nanofibers. For this propose, two carbon electrodes were put into the solution containing Proteus mirabilis bacteria, sodium chloride, nickel chloride, molybdenum powder. To find optimized conditions for the synthesis of CNFs, the parameters of time, kind of electrodes and amount current were studied. The optimized conditions were found as follows: synthesis time 60 s, the carbon–carbon electrode and the electric current (90 A) with voltage of 24 V. The optimized synthesized carbon nanofibers were characterized with the techniques of FTIR spectroscopy, Raman spectroscopy, X-Ray diffraction, scanning electron microscopy coupled with energy dispersive (SEM-EDX) and BET method.

Research on the production of sorbent based on bentonite clay for wastewater treatment from chemical industries

In our country, the problem of water purification remains urgent, with the growth of external factors contributing to this, which can include an increase in the number of industrial enterprises, the development of agriculture, urban growth and others. To solve the problem of water purification it is economically advantageous to create new sorbents, with the available resources in our country.For the processing of of bentonite clay under experimental conditions, instrumental test methods were chosen using a scanning electron microscope (SEM) of the Jeol JSM-6490l V brand, a multi-parameter portable cyberscanner (PCD 650 Eutech) and a Q-1500 Derivatograph. In this article, we studied the bentonite of the Darbaza deposit. For physico-chemical analysis of clay from the Darbaza deposit, a specially selected sample was crushed, and sieved and its chemical composition was determined. Results. Based on the results of instrumental studies, the elemental and mineralogical composition of bentonite clay from the Darbazinsky deposit was determined using a scanning electron microscope JSM-6490l V (Jeol, Japan) using the energy-dispersive method. The resulting sorbent based on bentonite clay has a high sorption capacity and is recommended for use in the treatment of wastewater from chemical industries. The resulting sorbent based on bentonite clay from the Darbaza deposit makes it possible to purify wastewater from phosphate production from phosphate and other ions up to 60%. The developed sorbent based on bentonite clay has environmental and economic efficiency and connections with the use of local natural resources. Thus, it should be noted that for adsorption treatment of wastewater from chemical industries with a high degree, it is possible to use effective sorbents based on bentonine clays from the Darbaza deposit. It should also be noted that the use of bentonite clays for water purification by the sorption process is an effective and affordable alternative to adsorbents that show high adsorption capacity for various compounds.

Tribological and corrosive properties examination of graphene oxide enriched electroless Ni[sbnd]P[sbnd]W composite coatings

This study focused on the mechanical, tribological, and corrosion behavior of graphene oxide (GO) reinforced NiPW composite coatings deposited by the electroless route. After deposition, all samples were analyzed using X-ray diffraction, field emission scanning electron microscope, scanning electron microscope, and energy dispersive spectroscopy methods. Hardness, tribological, and electrochemical tests of coatings were performed. The results demonstrated that the incorporation of GO effectively reduced friction, improved wear resistance, and enhanced corrosion resistance compared to NiPW coating. Among the tested concentrations, the NiPW/GO composite with 100 mg/L GO exhibited the lowest coefficient of friction as an average of 0.27 μ and the lowest corrosion potential value as Ecorr = −0.307 V.

Effect of silver chloride deposition technique on modified bentonite operating properties for radioactive iodide-ions localization in geological disposal facility for radioactive waste

This work discusses the influence of the technique of silver chloride deposition (via one-stage or two-stage method) onto performance attributes of modified bentonite for iodine ions localization in radioactive waste repositories. It has been established that bentonite modified via both techniques in wide range of AgCl content has high sorption properties (more than 95%) towards iodide anions, the AgCl deposition method has little-to-no effect on sorption properties. Investigation by scanning electron microscopy and energy dispersive X-ray spectroscopy methods and studying of silver leaching in various media showed that two-stage technique yield more uniform AgCl distribution and significantly higher resistance of AgCl to leaching than one-stage technique. Therefore, as a component of bentonite engineered safety barrier in geological disposal facility for radioactive waste use of bentonite modified with two-stage technique is preferable.

SYNTHESIS OF MULTICOMPONENT HEAT-SHIELDING RADIATION-RESISTANT CERAMICS WITH VARIATION OF STOICHIOMETRY OF CERAMIC COMPONENTS

The paper presents the results of obtaining multicomponent heat-protective radiation-resistant ceramic materials based on the WO3–Bi2O3–ZnO–TeO2–CeO2–ZrO2 compounds obtained by mechanochemical solid-phase synthesis with further annealing at a temperature of 1000 °C. The introduction of doping substances into the structure in the form of metal oxides makes it possible to prevent undesirable structural changes in ceramics and improve the durability and stability of the system. The choice of the synthesis of ceramics based on zirconium oxide is associated with the presence of several valuable physical and mechanical properties of the substance, and, as a consequence, the possibility of application in the field of functional materials for use in a variety of technical fields. The processes of phase formation in multicomponent ceramics based on oxide refractory compounds (WO3, Bi2O3, ZnO, TeO2, CeO2, ZrO2) were studied by scanning electron microscopy, energy dispersive and x-ray phase analysis methods. Using a combination of the presented methods, the following results were obtained, which make it possible to comprehensively characterize the samples under study, as well as establish the dependence of the influence of variations in the oxides used on the phase composition and morphological features of the ceramics. Analysis of morphological parameters showed that with increasing dopant concentration, a denser structure of agglomerates is formed, which is associated with sintering of particles at higher dopant concentrations. According to the obtained results of energy dispersive analysis, it was found that the addition of ZrO2 results a slight redistribution of elements in the structure, so the atomic content of Ce, W, Bi, and Te decreased by 2.58; 3.38; 2.12; 1.91 times, respectively, and the atomic content of Zn increased by 1.32 times. Analysis of diffraction patterns showed that the studied samples WO3-Bi2O3-ZnO-TeO2-CeO2-ZrO2 are characterized by the content of Zn3(TeO6), ZnTeO3, CeO2, Bi2O3, Bi2WO6, ZnWO4, Ce5Zr3O16, ZnO, (Zr0.98Ce0.02)O2 phases.

Trivalent lanthanum and ytterbium doped meso-silica/ceria abrasive systems toward chemical mechanical polishing (CMP) and ultraviolet irradiation-assisted photochemical mechanical polishing (PCMP)

Ceria (CeO2)-based abrasives are widely utilized in ultra-precision grinding and chemical mechanical polishing (CMP) applications over silica materials due to their unique physicochemical properties. Both mechanical and chemical contributions to polishing processes are highly affected by the size, shape, structure, component, defect of CeO2 abrasives. Herein, the composites involved mesoporous silica (mSiO2) cores and La- or Yb-doped CeO2 shells were synthesized and characterized in terms of X-ray diffractometry, scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, scanning transmission electron microscopy–energy dispersive X-ray mapping methods. The polishing effectiveness of the proposed composites toward quartz glass was experimentally evaluated under both CMP and ultraviolet irradiation-assisted photochemical mechanical polishing (PCMP) conditions. The polishing results indicated that the low-modulus mSiO2 cores strongly exerted the cushion effects for the friction and abrasion to substrates. Consequently, the heterostructured mSiO2/La-CeO2 and mSiO2/Yb-CeO2 abrasive systems offered nearly non-damage and ultra-smooth surfaces with angstrom-level roughness compared to conventional rigid abrasives. The enriched Ce3+ and oxygen vacancy defects at La- and Yb- doped CeO2 surfaces were responsible for the improvements of tribochemical and photochemical activities, thus allowing evidently enhanced removal efficiency with the assistance of ultraviolet irradiation. A possible polishing mechanism on the multi-component abrasive systems was also proposed.

Synthesis of Lawsonia inermis-encased silver–copper bimetallic nanoparticles with antioxidant, antibacterial, and cytotoxic activity

Abstract The extract of the medicinal plant Lawsonia inermis, known as henna, was employed to synthesize silver–copper bimetallic nanoparticles (Ag–Cu NPs) in a unique, efficient, and cost-effective method. The shape, size, and structural features of synthesized Ag–Cu NPs were determined by ultra–visible spectroscopy, Fourier transform infrared spectroscopy, X-ray diffractometer, field emission scanning electron microscopy, transmission electron microscopy, and energy dispersive X-ray spectroscopy methods. The rod-shaped Ag–Cu nanoparticles, averaging 41.66 ± 17.18 nm in size, synthesized from L. inermis, exhibited potent antioxidant activity by inhibiting 2,2-diphenyl-1-picrylhydrazyl and 2,2′-azinobis (3-ethylbenzothiazoline-6-sulfonic acid) free radicals. They also displayed significant antibacterial effects against Pseudomonas aeruginosa (28 mm), Staphylococcus aureus (27 mm), Bacillus cereus (26 mm), and Escherichia coli (24 mm). Additionally, these nanoparticles induced notable morphological changes in cancer cells and demonstrated promising cytotoxicity against MDA-MB-231 tumor cells (IC50 = 37.40 µg·mL−1). However, they exhibited biotoxicity in Artemia nauplii, resulting in mortality rates ranging from 3.0% to 32.5%. The LC50 and LC90 values recorded for a 48-h exposure were 1.51 mg·L−1 and 2.59 mg·L−1, respectively. These findings highlight the potential application of L. inermis-derived Ag–Cu NPs in pharmacology and bio-nanomedicine.

Low concentration Sm3+ ions loaded zinc sodium borate glasses for solid state lighting devices

Herein, zinc sodium borate glasses containing samarium ions were fabricated using the traditional melt-quenching approach and explored using several spectroscopic and structural methods. The XRD data corroborated the host glass specimen's non-crystalline nature. Scanning electron microscopy and the energy dispersive X-ray spectroscopy method were utilized to study the morphological and homogenous attributes. The UV–Vis–NIR wavelengths of absorption showed a total of seventeen distinct Sm3+ ion peaks. The three transitions 4G5/2 → 6H9/2, 6H7/2, and 6H5/2 are evident in the PL data at wavelengths of 644, 597, and 561 nm, respectively, in the red, reddish-orange, and greenish-yellow zones. The luminescence intensity of the investigated glass specimens increases up to 0.4 mol% Sm3+ ion content thereafter reducing because of the non-radiative transfer of energy. The estimated JO intensity parameters exhibit a trend of Ω2>Ω4>Ω6. The trend of the assessed radiative parameters also demonstrated that they are sensitive to changes in the glass network. The Futchbauer-Ladenburgh theory was used to compute the emission cross-section of various transitions utilizing the radiative parameters. The 1931 CIE chromaticity coordinates assessments corroborate the reddish-orange luminescence from the fabricated glasses. The outcomes have proven that obtained BNZSmx glasses doped with low concentrations of trivalent samarium ions are well suited for reddish-orange solid-state lighting systems.

Влияние поверхностной модификации на морфологические характеристики и микротвердость стали ХВГ

During the experiment, carried out in two stages, a thin-film coating of molybdenum is obtained on substrates made of steel grade HVG. The first stage included preliminary ion implantation of molybdenum. The second stage is the production of a thin-film molybdenum coating by balanced magnetron sputtering. During the study using scanning electron microscopy, microphotographs are obtained that visually confirmed the uniformity and homogeneity of the thin-film coating. The values of average surface roughness Sa is obtained by probe microscopy suggest that it decreases after applying a thin-film coating. Using the energy dispersive analysis method, the mass concentration of molybdenum on the surface of the modified tool steel was determined, which is 92,4 %. Experimental modes of modification of KhVG steel with a thin-film coating have been obtained, which have a significant effect on the average roughness and microhardness of its surface. It has been shown that the experimental modes used in the work make it possible to obtain a strengthening of the surface of HVG steel after applying a thin-film coating of molybdenum, with preliminary ion implantation several times. The adhesion force between the thin-film coating and the HVG steel substrate is determined. High adhesion values obtained using the method proposed by Gerald Frankel from Ohio State University indicate good quality of the applied coating. All of the above indicates the prospects of using the above-mentioned methodology in the mechanical engineering industry.

Study of the Structural, Morphological, Strength and Shielding Properties of CuBi2O4 Films Obtained by Electrochemical Synthesis.

In this research, the formation processes of CuBi2O4 films were examined using atomic force microscopy, energy dispersive analysis and X-ray diffraction analysis methods. The films were synthesized through electrochemical deposition from sulfuric acid solutions at a potential difference of 3.5 V. The duration of film growth was set to between 10 and 90 min to assess the possibility of controlled film growth and preserve the stability of their structural properties during growth over an extended period. An analysis of the data obtained by X-ray diffraction revealed that the resulting film samples are highly ordered structures with a tetragonal CuBi2O4 phase. The results of the connection between the thickness of CuBi2O4 films and strength properties depending on the time of film deposition were obtained. The results of the shielding efficiency of low-energy γ-quanta using CuBi2O4 films were obtained.

Comparative Analysis of the Silver Nanoparticle's Yield for Pico-Femto-Nanosecond Laser Generation.

Comparative analysis of different laser regimes of silver nanoparticle generation in water was performed for laser pulsewidth in the range of 300 fs-100 ns. Optical spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy and method of dynamic light scattering were used for nanoparticle characterization. Different laser regimes of generation were used with varying pulse duration, pulse energy and scanning velocity. The proposed universal quantitative criteria as productivity and ergonomicity of the obtained colloidal solutions of nanoparticles were investigated to compare different laser regimes of production. The efficiency per unit energy for picosecond generation of nanoparticles, free from the influence of nonlinear effects, turns out to be higher by 1-2 orders of magnitude than for nanosecond generation.

X-ray phase analysis of carbon nanotubes obtained by the arc discharge method

In the presented article, the purity, quality, and surface morphology of graphite, carbon nanotube, and functionalized carbon nanotube were comparatively studied by scanning electron microscopy (SEM), energy dispersive (EXD) methods, X-ray phase analysis. It was determined that the diffraction peaks of the X-ray phase analyses of the carbon nanotube obtained by the arc discharge method depend on the morphological properties of the substance and allow obtaining initial information about the dimensions of the carbon nanotube and the distance between the walls.

Temperature-dependent dielectric measurements and structural properties of barium stannate (BaSnO3)

Cubic perovskite BaSnO3, synthesized by solid-state reaction method, was structurally characterized using temperature-dependent X-ray and Raman spectroscopy studies along with room temperature neutron diffraction analysis. Here, we report the effect of temperature on the structural parameters of BaSnO3 in correlation with dielectric properties. Sample homogeneity and elemental composition were studied by scanning electron microscopy and energy dispersive X-ray spectroscopy methods. The compound maintains cubic symmetry even at high temperatures and exhibits gradual increase in unit cell volume owing to thermal expansion. To understand high temperature phase transition, if any, and capacitance behavior, high temperature dielectric measurements were carried out. High value of dielectric constant was obtained at low frequencies as the temperature was increased, which may be due to the presence of oxygen vacancies or the lone-pair effect.

Application of X-rays to interpret alloying effects on the 3d and 4s4p electron populations of nickel-boron-nitrogen metal matrix composites

For this experiment, nickel-boron and nickel-boron-nitrogen alloys are created using the electrochemical deposition method. Utilizing energy-dispersive X-ray methods, the nickel-boron and nickel-boron-nitrogen alloys are characterized. X-ray diffraction was used to examine the crystal structure of nickel-boron and nickel-boron-nitrogen alloys. An energy dispersed X-ray fluorescence spectrometer is used to gather X-ray photons from the present samples. The number of radiated X-ray photons from the present specimens is used to compute the Kβ/Kα intensity ratios. The theoretical Coulomb and Babushkin gauges are used to calculate the populations of the 3d and 4s4p electrons. The observed data imply that shielding effects from 4s3d orbitals, hybridization, changes in energy levels, and charge transfer mechanism may be the causes of the variance in 3d and 4s4p electron populations. In an effort to clarify the conclusions drawn as a result of all these computations, this study contrasts the results with those of pure nickel.

白色X線応力測定法の基礎と応用

The X-ray diffraction method has been already established as one of the most effective nondestructive evaluation method of a stress in crystalline materials. Since white X-ray beam has a wide wavelength range, a diffraction angle has to fix during a measurement to obtain a lattice spacing using the Bragg’s low. Therefore, the white X-ray method has some different features from the characteristic X-ray method. For example, the information of lattice spacing of many lattice planes in a material can be obtained simultaneously on the same diffraction angle. Because all equipment are held fixed position during a measurement, it is advantageous to in-situ measurement under the special environment such as high temperature or high pressure. In the present review article, a brief history of development of the white X-ray method is covered and some factors related to the measurement accuracy is explained. Fundamentals of the measurement system using white X-ray and the energy dispersive method are presented. Applications of the method using white X-ray obtained from a rotating target type X-ray generator to the measurement of residual stress of a surface ground material and a coating material are described. Furthermore, applications of the method using high energy white X-ray generated in the synchrotron radiation facility SPring-8 to the measurement of internal strain of a material loaded by four-point bending and strain distribution in the vicinity of crack tip in a material introduced a fatigue crack are also described.

X-RAY FLUORESCENCE DETERMINATION OF SILVER IN COLLOIDAL SOLUTIONS

Objective. To develop the basics of technology for X-ray fluorescence determination of silver in colloidal solutions. Relevance. Silver preparations are interesting as an alternative to antibiotics. Сurrently on the pharmaceutical market there is a large number of silver-containing colloidal dietary supplements, 70% of which contain silver in ionic form. The energy dispersive method of X-ray fluorescence analysis is an express method without long-term sample preparation. Materials and methods. Silver proteinate (8% Ag), Sigma-Aldrich; ProtargolLor (P.J.S.C. “Pharmstandard”, Kursk); Sialor (J.S.C. RENEWAL®); Argitos colloidal silver (“Nanosphere”, Russia), Argent Colloidal (Nutri expert, France). Dual Laser Light Scattering 2D-DLS (Zetasizer Malvern). Energy dispersive spectrometer Shimadzu EDX-7000 (Japan); OriginLab Corporation, USA. Results. The technology of the X-ray fluorescence determination of silver in colloidal solutions from various companies was described in this paper. The present study has exploited the energy dispersive spectrometer Shimadzu EDX-7000 (Japan). The fluorescence intensity at AgKα = 22.105 keV depends linearly on the silver concentration in the range of 0.01% - 1% according to the equation I = (5.1 ± 0.1) · СAg for silver nitrate and I = (1.64 ± 0.03) · CAg for silver proteinate, which is due to the effect of the organic matrix. Conclusion. The new XRF method was applied for quality control of protargol and other Ag-containing drugs and parapharmaceuticals.

Hydrogen Absorption Reactions of Hydrogen Storage Alloy LaNi5 under High Pressure.

Hydrogen can be stored in the interstitial sites of the lattices of intermetallic compounds. To date, intermetallic compound LaNi5 or related LaNi5-based alloys are known to be practical hydrogen storage materials owing to their higher volumetric hydrogen densities, making them a compact hydrogen storage method and allowing stable reversible hydrogen absorption and desorption reactions to take place at room temperature below 1.0 MPa. By contrast, gravimetric hydrogen density is required for key improvements (e.g., gravimetric hydrogen density of LaNi5: 1.38 mass%). Although hydrogen storage materials have typically been evaluated for their hydrogen storage properties below 10 MPa, reactions between hydrogen and materials can be facilitated above 1 GPa because the chemical potential of hydrogen dramatically increases at a higher pressure. This indicates that high-pressure experiments above 1 GPa could clarify the latent hydrogen absorption reactions below 10 MPa and potentially explore new hydride phases. In this study, we investigated the hydrogen absorption reaction of LaNi5 above 1 GPa at room temperature to understand their potential hydrogen storage capacities. The high-pressure experiments on LaNi5 with and without an internal hydrogen source (BH3NH3) were performed using a multi-anvil-type high-pressure apparatus, and the reactions were observed using in situ synchrotron radiation X-ray diffraction with an energy dispersive method. The results showed that 2.07 mass% hydrogen was absorbed by LaNi5 at 6 GPa. Considering the unit cell volume expansion, the estimated hydrogen storage capacity could be 1.5 times higher than that obtained from hydrogen absorption reaction below 1.0 MPa at 303 K. Thus, 33% of the available interstitial sites in LaNi5 remained unoccupied by hydrogen atoms under conventional conditions. Although the hydrogen-absorbed LaNi5Hx (x < 9) was maintained below 573 K at 10 GPa, LaNi5Hx began decomposing into NiH, and the formation of a new phase was observed at 873 K and 10 GPa. The new phase was indexed to a hexagonal or trigonal unit cell with a ≈ 4.44 Å and c ≈ 8.44 Å. Further, the newly-formed phase was speculated to be a new hydride phase because the Bragg peak positions and unit cell parameters were inconsistent with those reported for the La-Ni intermetallic compounds and La-Ni hydride phases.

Histological, elemental, and ultrastructural analysis of melanin in mantle of Pacific oyster (Crassostrea gigas).

Colorful shell of bivalve is mainly because of the biological pigments, of which melanin plays an important role in shell color formation. More and more studies focus on the genes function involved in melanin synthesis, but relatively few studies address the biochemical character and ultrastructure of melanin in bivalve from microscopic perspective. Here, we investigated the histological structure of mantle of Crassostrea gigas with orange shell color. Distribution of melanin in mantle was verified with histochemical staining. In addition, immunofluorescence technique showed that strongly positive signal of CgTYR was specific to the mantle margin, which is consistence with the location of brown granules in H&E staining. The further result of elementary composition of melanin displayed that metal Ca, Fe, and Zn were detected using scanning transmission electron microscope and energy dispersive spectroscopy mapping methods. Next, based on TEM observations, it was speculated that the series of cellular events leading to the formation and release of melanin. Melanocyte in the primary stage showed many mitochondria and rough endoplasmic reticulum as well as an extensive Golgi complex with numerous vesicles intermingled with melanosome. Subsequently, melanosome was expended and their hue gradually intensified, and Golgi complex and mitochondria were still observed in the cytoplasm. Finally, after melanosome was discharged into intercellular spaces, the disintegration of membranes in some cells, and severe cellular vacuolization. These data enrich the understanding of ultrastructural characteristic and formation of melanin in mantle of bivalve and pave the way for further investigating shell coloration at the cellular level.

The Influence of Shock Wave Surface Treatment on Vibration Behavior of Semi-Solid State Cast Aluminum—Al2SiO5 Composite

The semi-solid state casting procedure was used to manufacture as-cast AA5083, 1 and 2 wt.% of aluminosilicate reinforced composite material. After solidification, developed as-cast materials were subjected to shock wave treatment in the subsonic wind tunnel. Various techniques were used to evaluate the change in shock wave exposure, including mechanical and structural analysis, which is a field dedicated to the study of vibrations and other material properties. The research methods involved developed material grain structure and surface morphology, such as field emission scanning electron microscope, X-ray diffraction, and the energy dispersive method. This study shows that the microhardness value of the matrix material is increased before and after exposure to shock wave treatment compared to the developed composite material. The natural frequency of the developed composite increases as a result of the addition of aluminosilicate reinforcement before and after the shock wave. In addition, the shifting of frequency mechanism is studied to know the influence of shock wave surface treatment. The results obtained show the potential of the application of this material in the area of robotic parts.