Dependence Of Energy Density Research Articles

Exploration of potential-limited protocols to prevent inefficiencies in Li-O2 batteries during charge.

Metal-air batteries are promising energy storage systems with high specific energy density and low dependence on critical materials. However, their development is hindered by slow kinetics, low roundtrip efficiency, deficient capacity recovery, and limited lifetime. This work explores the effect of cycling protocols on the lifetime of Li-O2 cells, and the interplay between electrolyte composition and the upper cut-off voltage during charge. Our results suggest that constant-current-constant-voltage (CCCV) protocols accommodate the slower kinetics at the end of charge in Li-O2 cells better than the constant-current (CC) protocols majorly used in the field. These results suggest that CCCV protocols should be standardised to assess performance improvements in Li-O2 cells.

Assessment of Gravity Waves From Tropopause to Thermosphere and Ionosphere in High‐Resolution WACCM‐X Simulations

AbstractA new version of NCAR Whole Atmosphere Community Climate Model with thermosphere/ionosphere extension (WACCM‐X) has been developed. The main feature of this version is the species‐dependent spectral element (SE) dynamical core solved on a cubed sphere grid, eliminating the polar singularity and enabling simulations at high‐resolutions. Molecular viscosity and diffusion in the horizontal direction are also included. The Conservative Semi‐Lagrangian Multi‐Tracer Transport Scheme (CSLAM) is employed for the species transport. An efficient regridding scheme based on the Earth System Modeling Framework is used to map fields between the physics mesh and geomagnetic grid. Simulations have been performed at coarse (∼200 km and 0.25 scale height) and high (∼25 km and 0.1 scale height) resolutions. Spatial distribution of the resolved gravity waves from the high‐resolution simulations compares well with available observations in the middle and upper atmosphere. Analysis of the scale dependence of the gravity wave energy density and momentum flux shows that, while larger scale waves are dominant energetically at most latitudes, smaller scale waves contribute significantly to the total momentum flux, especially at mid‐high latitudes. The waves in the thermosphere are shown to be strongly modulated by the large‐scale wind through Doppler shift and molecular damping, and they cause large neutral atmosphere and plasma perturbations.

Programming Polarity Heterogeneity of Energy Storage Dielectrics by Bidirectional Intelligent Design.

Dielectric capacitors, characterized by ultra-high power densities, are considered as fundamental energy storage components in electronic and electrical systems. However, synergistically improving energy densities and efficiencies remains a daunting challenge. Understanding the role of polarityheterogeneity at the nanoscale in determining polarization response is crucial to the domain engineering of high-performance dielectrics. Here, a bidirectional design with phase-field simulation and machine learning is performed to forward reveal the structure-property relationship and reversely optimize polarity heterogeneity to improve energy storage performance. Taking BiFeO3-based dielectrics as typical systems, this work establishes the mapping diagrams of energy density and efficiency dependence on the volume fraction, size and configuration of polar regions. Assisted by CatBoost and Wolf Pack algorithms, this work analyzes the contributions of geometric factors and intrinsic features and find that nanopillar-like polar regions show great potential in achieving both high polarization intensity and fast dipole switching. Finally, a maximal energy density of 188 J cm-3 with efficiency above 95% at 8 MV cm-1 is obtained in BiFeO3-Al2O3 systems. This work provides a general method to study the influence of local polar heterogeneity on polarization behaviors and proposes effective strategies to enhance energy storage performance by tuning polarity heterogeneity.

EFFECT OF COAL PARTICLE SIZE DISTRIBUTION ON LASER IGNITION CHARACTERISTICS

The ignition of hard coal grades DG, G, Zh, and K under the action of laser pulses (1064 nm, 120 μs, 1.3 J) was studied for the fractions of microparticles with a narrow size distribution in the range of 0.25-44 μm. The kinetic characteristics of the glow of samples from the entire size range were measured for each coal rank. Three stages of ignition are distinguished for each fraction. The duration of the first stage coincides with the duration of the laser pulse. The duration of the second takes a time interval of 10-15 ms (DG, G and Zh coal ranks) and 3-5 ms (K coal rank). The duration of the third stage is 60-80 ms (DG, G, and G coals) and 20 ms (K coal rank). It has been established that the threshold ignition energy densities (ignition thresholds) at all three stages depend non-monotonically on coal particle sizes. The minimum values of ignition thresholds at all three stages are achieved at particle sizes equal to 2.2 (for DG rank coal), 4.0 (for G rank coal), 0.7 (for Zh rank coal) and 2.0 μm (for K rank coal). Using the results of the proximate analysis of coals, the observed dependences of critical energy densities on the size of coal particles are interpreted.

A coupled model of transport-reaction-mechanics with trapping, Part II: Large strain analysis

A coupled finite strain chemo-transport-mechanical formulation with trapping is here proposed to extend a previous work set in the realm of small strain theory in continuum mechanics. The theory is rooted in non-equilibrium rational thermodynamics. The kinematics is based on a multiplicative decomposition of the deformation gradient to account for swelling and shrinking, thermal, elastic and inelastic contributions. Mass balance laws and balance of linear and angular momentum, as well as the laws of thermodynamics for a convecting body, are directly formulated in their material description, after specifications of some standard transformation rules between current and reference configuration. Thermodynamic restrictions are identified based on the functional dependence of the referential Helmholtz free energy density, which is chosen as the thermodynamic potential, and further subjected to a constitutive additive decomposition. Constitutive prescriptions for the chemical potentials, referential heat and mass fluxes, chemical kinetics and the generalized heat equation lead to the establishment of the governing equations. The theoretical framework is complemented by numerical simulations, highlighting the potential of the proposed formulation in multi-physics applications.

Finite size effect on the thermodynamics of a hot and magnetized hadron resonance gas

The thermodynamic properties of a non-interacting ideal hadron resonance gas (HRG) of finite volume have been studied in the presence of an external magnetic field. The inclusion of background magnetic field in the calculation of thermodynamic potential is done by the modification of the dispersion relations of the charged hadrons in terms of Landau quantization. The generalized Matsubara prescription has been employed to take into account the finite size effects in which a periodic (anti-periodic) boundary conditions is considered for the mesons (baryons). We find significant effects of the magnetic field as well as system size on the temperature dependence of energy density, longitudinal and transverse pressure especially in low temperature regions. The HRG is found to exhibit diamagnetism (paramagnetism) in the low (high) temperature region whereas the finite size effect is seen to strengthen the diamagnetic behavior of the medium.

Measurements of dihadron correlations relative to the event plane in Au+Au collisions at GeV * *Supported in part by the Offices of NP and HEP within the U.S. DOE Office of Science, the U.S. NSF, the Sloan Foundation, the DFG cluster of excellence ‘Origin and Structure of the Universe’ of Germany, CNRS/IN2P3, STFC and EPSRC of the United Kingdom, FAPESP

Dihadron azimuthal correlations containing a high transverse momentum ( ) trigger particle are sensitive to the properties of the nuclear medium created at RHIC through the strong interactions occurring between the traversing parton and the medium, i.e. jet-quenching. Previous measurements revealed a strong modification to dihadron azimuthal correlations in Au+Au collisions with respect to p+p and d+Au collisions. The modification increases with the collision centrality, suggesting a path-length or energy density dependence to the jet-quenching effect. This paper reports STAR measurements of dihadron azimuthal correlations in mid-central (20%-60%) Au+Au collisions at GeV as a function of the trigger particle's azimuthal angle relative to the event plane, . The azimuthal correlation is studied as a function of both the trigger and associated particle . The subtractions of the combinatorial background and anisotropic flow, assuming Zero Yield At Minimum (ZYAM), are described. The correlation results are first discussed with subtraction of the even harmonic (elliptic and quadrangular) flow backgrounds. The away-side correlation is strongly modified, and the modification varies with , with a double-peak structure for out-of-plane trigger particles. The near-side ridge (long range pseudo-rapidity correlation) appears to drop with increasing while the jet-like component remains approximately constant. The correlation functions are further studied with the subtraction of odd harmonic triangular flow background arising from fluctuations. It is found that the triangular flow, while responsible for the majority of the amplitudes, is not sufficient to explain the -dependence of the ridge or the away-side double-peak structure. The dropping ridge with could be attributed to a -dependent elliptic anisotropy; however, the physics mechanism of the ridge remains an open question. Even with a -dependent elliptic flow, the away-side correlation structure is robust. These results, with extensive systematic studies of the dihadron correlations as a function of , trigger and associated particle , and the pseudo-rapidity range , should provide stringent inputs to help understand the underlying physics mechanisms of jet-medium interactions in high energy nuclear collisions.

(Invited) Dye-Sensitized Photo Rechargeable Battery for Indoor Applications

Dye-Sensitized Solar Cells (DSSCs) have great potentials owing to their aesthetic colors, transparency and low cost. Furthermore, they are favorable for indoor system, because DSSCs have great power conversion efficiency (PCE) at low light. However, there are still several problems in the practical applications. Therefore, our group suggested the new concepts of organic materials and devices for approaching to real application. For this aim, we developed dye-sensitized photo rechargeable solar battery for indoor light saving.Until now, most of single-structured photo-rechargeable devices considered photo-charging process at high light intensity (mainly standard AM 1.5G sunlight). Furthermore, it is very difficult to combine dye-sensitized solar cells with lithium ion battery in a monolithic device because of their intrinsic mismatch energy levels of photo (-0.5 V vs NHE) and storage electrode (-3.0 V vs NHE). We came up with this intrinsic issues by using the overlithiation reaction of LiMn2O4 (ca. 0.0 V vs NHE) for energy storage and finally, achieved self-powered dye-sensitized photo rechargeable battery (DSPB, FTO/TiO2/Dye/Redox mediator/Pt-Li+ conducting separator/Li+ solution/ LixMn2O4) in monolithic devices, and suggested new concepts for energy recycle of indoor lightening. Next, we investigated the light intensity dependence of photo-charged energy density with different redox mediator (or charge regenerator for oxidized dye), such as I−/I3 −, Co2+/3+(bpy)3, Cu+/2+(dmp)2. Finally, the DSSBs were successfully working at low light intensity (11.5% of ηoverall at 0.15 mW cm−2 (500 lux)), operating the commercial IoT wireless sensor node using only indoor light sources.

The Investigation for Thickness-Dependent Electrical Performance on BaTiO3/BiFeO3 Bilayer Ferromagnetic Capacitors

Bilayer barium titanate (BaTiO3, BTO)/bismuth ferrite (BiFeO3, BFO) capacitive devices were fabricated and systematically analyzed from the aspects of thin-film material crystallography and electrical characterization. The tetragonal phase (T) of BTO with the reducing thickness (150 nm) was demonstrated through carefully adjusting the conditions of sputtering process and post-thermal treatments. The thickness dependence of polarization, energy density, permittivity, and leakage current was investigated in the BTO/BFO bilayer system. It showed that 150-nm BFO film is an optimal thickness, which led to the substantial increase in energy density up to 920 mJ/cm3 with the charge/discharge efficiency of 79.7% at 10 V. The permittivity of 150-nm BFO bilayer device was found to be 258, which is much higher than the single -layer BFO and other BTO/BFO devices with different BFO thicknesses. Leakage current could be reduced by three orders with the increasing thickness of BFO layer from 30 to 225 nm. In addition, the leakage current of BTO/BFO bilayer capacitors was 102 times lower than BFO single layer with the same total thickness. The result showed that the leakage current of BFO material could be significantly reduced in the bilayer system. The performance of BTO/BFO bilayer capacitors indicates that it is a promising technique for the implementation of nanoscale, lead-free, and nonelectrochemical thin-film energy storage-related applications.

Generation of Solenoidal Modes and Magnetic Fields in Turbulence Driven by Compressive Driving

Abstract We perform numerical simulations of hydrodynamic (HD) and magnetohydrodynamic (MHD) turbulence driven by compressive driving, to study the generation of solenoidal velocity components and the small-scale magnetic field. We mainly focus on the effects of mean magnetic field (B 0) and the sonic Mach number (M s ). The dependence of solenoidal ratio (i.e., ratio of solenoidal to kinetic energies) and magnetic energy density on M s in compressively driven turbulence is already established, but that on B 0 is not yet. We also consider two different driving schemes in terms of the correlation timescale of forcing vectors: a finite-correlated driving and a delta-correlated driving. Our findings are as follows. First, when we fix the value of B 0, the solenoidal ratio after saturation increases as increases. A similar trend is observed for generation of magnetic field when B 0 is small. Second, when we fix the value of , HD and MHD simulations result in similar solenoidal ratios when B 0 is not strong (say, M A ≳ 5, where M A is Alfvén Mach number). However, the ratio increases when M A ≲ 5. Roughly speaking, the magnetic energy density after saturation is a linearly increasing function of B 0 irrespective of M s . Third, generation of the solenoidal velocity component is not sensitive to numerical resolution, but that of magnetic energy density is mildly sensitive. Finally, when initial conditions are same, the finite-correlated driving always produces more solenoidal velocity and small-scale magnetic field components than the delta-correlated driving. We additionally analyze the vorticity equation to understand why higher and B 0 yield a larger quantity of the solenoidal velocity component.

The effect of energy density on texture and mechanical anisotropy in selective laser melted Inconel 718

Laser additive manufacturing offers a unique way of tuning microstructure to improve alloy properties with a high degree of freedom by modifying the process parameters such as energy density. This work focuses on the energy density dependence of texture anisotropy and mechanical properties processed by selective laser melting (SLM) of IN 718 superalloy at different laser scanning speeds. It was found that strong columnar grains and 〈001〉 fiber texture become insignificant due to insufficient epitaxial growth as energy density decreases. The discrepancies in Taylor factor distributions induced by texture anisotropy are mainly responsible for the difference in tensile mechanical properties for samples built at different orientations. High Taylor factors lead to the increased strength of diagonally built testing samples. In addition, grain refinement enhances the strengthening effect as energy density decreases.

Magnetic properties of Co film in Pt/Co/Cr2O3/Pt structure

Magnetic properties of Co film in Pt/Co/α-Cr2O3/Pt/α-Al2O3 structure were investigated. Co layer thickness tCo dependence of perpendicular magnetic anisotropy energy density K reveals that the bulk magnetic anisotropy plays an important role in the system in addition to the interfacial anisotropy. Damping constant α monotonically increases with the decrease of tCo but not proportionally to 1/tCo. Both K and α increase with the increase of Pt layer thickness tPt from 3 nm to 5 nm and keeps almost constant in the tPt range between 5 nm to 20 nm. These results are of importance to understand the magnetization switching behavior driven by the magneto-electric (ME) effect as well as to design the spintronics device using the ME effect.

Hypothesis of a Weak Nonlocality for Determining the Binodal of a Binary Alloy

This work proposes an approach for the calculation of equilibrium solubility limits in binary alloys, which is an alternative to approaches based on gradient expansions. The proposed approach rests on the description of alloys in terms of a weak nonlocality, which generalizes the classical local equilibrium hypothesis. This results in a theory that can be used to derive the explicit concentration dependence of all used parameters solely from knowledge of the concentration dependence of free energy density, which is impossible within the framework of existing approaches.

Studies on Possible Ion-Confinement in Nanopore for Enhanced Supercapacitor Performance in 4V EMIBF4 Ionic Liquids.

Supercapacitors have the rapid charge/discharge kinetics and long stability in comparison with various batteries yet undergo low energy density. Theoretically, square dependence of energy density upon voltage reveals a fruitful but challenging engineering tenet to address this long-standing problem by keeping a large voltage window in the compositionally/structurally fine-tuned electrode/electrolyte systems. Inspired by this, a facile salt-templating enables hierarchically porous biochars for supercapacitors filled by the high-voltage ionic liquids (ILs). Resultant nanostructures possess a coherent/interpenetrated framework of curved atom-thick sidewalls of 0.8-/1.5-nanometer pores to reconcile the pore-size-dependent adlayer structures of ILs in nanopores. Surprisingly, this narrow dual-model pore matches ionic radii of selected ILs to accommodate ions by unique coupled nano-/bi-layer nanoconfinements, augmenting the degree of confinement (DoC). The high DoC efficiently undermines the coulombic ordering networks and induces the local conformational oscillations, thus triggering an anomalous but robust charge separation. This novel bi-/mono-layer nanoconfinement combination mediates harmful overscreening/overcrowding effects to reinforce ion-partitioning, mitigating long-lasting conflicts of power/energy densities. This interesting result differs from a long-held viewpoint regarding the sieving effect that ion-in-pore capacitance peaks only if pore size critically approaches the ion dimension. Optimal biocarbon finally presents a very high/stable operational voltage up to 4 V and specific energy/power rating (88.3 Wh kg−1 at 1 kW kg−1, 47.7 Wh kg−1 albeit at a high battery-accessible specific power density of 20 kW kg−1), overwhelmingly outperforming most hitherto-reported supercapacitors and some batteries. Such attractive charge storage level can preliminarily elucidate an alternative form of a super-ionic-state high-energy storage linked with both the coordination number and coulombic periodism of the few ion-sized mesopores inside carbon electrodes, escalating supercapacitors into a novel criterion of charge delivery.

Laser energy density dependence of performance in additive/subtractive hybrid manufacturing of 316L stainless steel

An enormous amount of research effort goes into the manufacturing process for additive manufacturing (AM) or subtractive manufacturing (SM) process for property microstructure. Moreover, additive/subtractive hybrid manufacturing (ASHM), which combines additive and subtractive processes in a single machine, has provided an important opportunity to increase the high percentage of stock utilization and produce complex functional components. However, the system comprehensive investigation and the study of ASHM-manufactured parts by various process parameters have rarely been reported. The present paper depicted the effect of laser energy density (ψ) on the phase change, density, microstructure, Vickers hardness, and tensile testing within the ASHM specimens. It was observed that the highest Vickers microhardness, the largest tensile strength, and the attendant ductility were gained at ψ =222 J/mm3, the most excellent value, which was put down to the high density and relatively fine grains. The results of this study have a better knowledge of the ASHM method to produce a high surface state and mechanical behavior 316L SS component by governing laser energy density (ψ).

Time Evolution of Density Parameters for Matter and Dark Energy and their Interaction Term in Brans-Dicke Gravity

In the framework of Brans-Dicke (BD) theory, the first part of the present study determines the time dependence of BD parameter, energy density and equation of state (EoS) parameter of the cosmic fluid in a universe expanding with acceleration, preceded by a phase of deceleration. For this purpose, a scale factor has been chosen such that the deceleration parameter, obtained from it, shows a signature flip with time. Considering the dark energy to be responsible for the entire pressure, the time evolution of energy parameters for matter and dark energy and the EoS parameter for dark energy have been determined. An effective interaction term, between matter and dark energy, has been proposed and calculated. Its negative value at the present time indicates conversion of matter into dark energy. Using this term, the time dependence of the rates of change of matter and dark energy has been determined. It is found that the nature of dependence of the scalar field upon the scale factor plays a very important role in governing the time evolution of the cosmological quantities studied here. The present study provides us with a simple way to determine the time evolution of dark energy for a homogeneous and isotropic universe of zero spatial curvature, without involving any self-interaction potential or cosmological constant in the formulation.

Probing ultralight bosons with binary black holes

We study the gravitational-wave (GW) signatures of clouds of ultralight bosons around black holes (BHs) in binary inspirals. These clouds, which are formed via superradiance instabilities for rapidly rotating BHs, produce distinct effects in the population of BH masses and spins, and a continuous monochromatic GW signal. We show that the presence of a binary companion greatly enriches the dynamical evolution of the system, most remarkably through the existence of resonant transitions between the growing and decaying modes of the cloud (analogous to Rabi oscillations in atomic physics). These resonances have rich phenomenological implications for current and future GW detectors. Notably, the amplitude of the GW signal from the clouds may be reduced, and in many cases terminated, much before the binary merger. The presence of a boson cloud can also be revealed in the GW signal from the binary through the imprint of finite-size effects, such as spin-induced multipole moments and tidal Love numbers. The time dependence of the cloud's energy density during the resonance leads to a sharp feature, or at least attenuation, in the contribution from the finite-size terms to the waveforms. The observation of these effects would constrain the properties of putative ultralight bosons through precision GW data, offering new probes of physics beyond the Standard Model.

Energy Density Dependence of Bonding Characteristics of Selective Laser-Melted Nb–Si-Based Alloy on Titanium Substrate

Spherical Nb–20Si–24Ti–2Cr–2Al pre-alloyed powders were processed by selective laser melting (SLM) on Ti6Al4V substrates with different energy densities. A series of single tracks and single layers were produced using different processing parameters, including powder size, laser power, scanning speed and hatch distance. Results showed that the pre-alloyed powders ranging from 45 to 75 μm were more applicable to SLM with less balling tendency, in comparison with those between 75 and 180 μm. The increase in linear energy density (LED) resulted in the decrease in contact angle and the increase in the width of single track as well as its penetration depth into the substrate. Smaller hatch distance leaded to a larger remelted part of the former track and a higher volumetric laser energy density. With a thickness of 75.6 μm, an interfacial intermediate layer, enriched in Ti and depleted in Nb, Si, Cr and Al, was formed between the SLM part and the Ti6Al4V substrate. The mechanisms of the elimination of balling phenomenon by employing a higher LED and the interfacial bonding characteristics between Nb–Si-based alloys via SLM and the Ti6Al4V substrate were discussed.

Photon electrodynamics and photon structure as a bunch of one of many possible states of electromagnetic field

Fundamental laws of conservation are used to show that electromagnetic field is generally represented (even in vacuum at ρ = 0 and j = 0) using four vectors D, E, B, and H with different equations of state (material equations) that are linear for electromagnetic waves and nonlinear for photons and particles. An equation that describes different states of electromagnetic field (i.e., different but not arbitrary relationships of field vectors E, H, D, and B) is derived. It is shown that electromagnetic wave and photon are different states of electromagnetic field that exhibit different dependences of energy density on field vectors. Partial analytical solutions are obtained for a photon (spatially localized bunch of electromagnetic field energy) that propagates at a velocity of light along a single (as distinct from electromagnetic wave) direction.

Surface ablation and threshold determination of AlCu4SiMg aluminum alloy in picosecond pulsed laser micromachining

Interaction of an ultrafast pulsed laser with material surface has become a research hotspot in recent years. Picosecond pulsed laser micromachining of AlCu4SiMg aluminum alloy and determination of the ablation threshold are the main research directions, which have vitally important theoretical significance and application value. The ablation characteristics of aluminum alloy under different focusing characteristics and energies were experimentally investigated with picosecond ultrafast laser pulses. The different ablation areas of laser Gaussian beam were divided based on ablation threshold, morphological characteristics, and interaction mechanism. The surface morphologies and feature sizes, including ablation width (i.e. diameter), ablation depth, ablation depth-to-width ratio, ablation area, ablation volume, and single pulse ablation rate, of the ablation craters were studied; and the variation of their ablation distributions with laser energy density were analyzed. The results showed that the irradiated surface morphologies of aluminum alloy under the focal lengths of 100 and 150mm were better, and the ablation width increased with the increase of focal length; however, the ablation depth decreased clearly. More distinct morphological characteristics at high energy and better ablation quality at low energy were exhibited by ablation crater surface. Ablation area could be divided into ablation, melt, redeposition, phase-transformation, and modification regions, and the entire regions were dominated by multiphoton ionization and avalanche ionization. The ablation feature sizes, increasing monotonically in laser energy density, exhibited approximately linear dependence on the energy density at low energy-density. When the energy density reached a certain critical value, the increasing extent decelerated gradually, and tended increasingly towards saturation. According to the linear dependence of laser energy density on the ablation crater area, the average ablation threshold of AlCu4SiMg aluminum alloy with a picosecond pulsed laser was determined to be about 0.122Jcm−2 at a repetition rate of 1kHz under the number of pulses of 1000 and 2000. More number of pulses resulted in smaller ablation threshold, and the ablation threshold decreased at different degrees with the increase of low repetition rate.