Permian-Triassic Research Articles

Hydrothermal karst cavities in a Devonian carbonate reservoir analogue (Rhenish Massif, Germany): Implications for geothermal energy potential

Deep geothermal reservoirs can provide renewable energy for electricity and heat generation [1]. In the Rhine-Ruhr area of western Germany, where Europe's largest district heating network is located, up to 1,300 m thick carbonates of Devonian age are available in ≥ 4,000 m depth [2, 3]. Near the surface, these rocks contain karst cavities, which host some of Germany´s longest caves [4, 5]. At reservoir depth, abundant karstification may significantly increase the geothermal reservoir potential [6] (Figure 1).
 In the Munich area (southern Germany) deep-seated karstified Upper Jurassic rocks are widely used for the city´s district heating network [7]. Most deep-seated geothermal systems are located at a depth of 1,000 m or more at temperatures over 60 °C [8]. Therefore, it is important to assess deep-seated karstified structures elsewhere to assess their geothermal reservoir potential. In the Rhine-Ruhr area, these could have the potential to be used as an alternative renewable energy resource.
 This study aims at the geological characterization of deep-seated (hydrothermal) karst cavities in Steltenberg Quarry (western Germany) where Middle/Upper Devonian carbonates (Massenkalk limestone) are present in the vicinity of two regional fault zones [9, 10]. We applied state of the art petrographical, geochemical, palaeothermometrical methods, and U-Pb dating. Here we present the first U-Pb age data of deep-seated hydrothermal karst precipitates in Germany, which formed at the Permian-Triassic boundary (252.4 ± 8.6 My, Table 1). The U-Pb age data of calcite cement veins (LMC 8), which were cutting the near-surface karst cavities before they got dissolved, points to an Oligocene maximum age (30.0 ± 2.81 My) of the karst cavities.

How Large Igneous Provinces Have Killed Most Life on Earth—Numerous Times

Evolution has not been a simple path. Since the first appearance of complex life, there have been several mass extinctions on Earth. This was exemplified by the most severe event during the Phanerozoic, the end-Permian mass extinction that occurred 252 million years ago and saw a loss of 90% and 70% of all marine and terrestrial species, respectively. Such mass extinctions have entirely reset ecosystems. Increasing evidence points to the massive eruption and crustal emplacement of magmas associated with large igneous provinces (LIPs) as key drivers of these events. Understanding how LIP events disrupted global biogeochemical cycles is of prime importance, especially as humans alter the atmosphere and biosphere today. We explore the cascading impacts of LIP events on global climate, oceans, and land—including runaway greenhouses, the release of toxic metals to the environment, the destruction of the ozone layer, and how global oceans are driven to anoxic and acidic states—all of which have parallels in the consequences of modern industrialisation.

Mass extinctions, their causes and consequences: an interview with Douglas H. Erwin and Shuzhong Shen.

'Mass extinctions' have been a hot topic for several decades. What triggers a mass extinction? How does a mass extinction impact the evolution of life? How does our ecosystem recover after a mass extinction? These questions attracted the interest of both scientists and the public alike. NSR spoke to two renowned researchers in the field of mass extinctions: Prof. Douglas H. Erwin from the National Museum of Natural History of the USA, and Prof. Shuzhong Shen from Nanjing University, China. Prof. Erwin has been interested in the end-Permian mass extinction since graduate school. He has worked on a variety of problems, from Permian gastropod systematics to the origin of animals. Currently his work focuses on the nature of evolutionary novelty and innovation. Prof. Shen's research career is centered upon the end-Permian mass extinction, Permian stratigraphy and global correlations, with taxonomic expertise on brachiopods and conodonts. The International Commission on Stratigraphy recognizes his outstanding singular contribution to stratigraphy and awarded him the ICS Stratigraphy Medal in 2019.

Early Triassic (Griesbachian) Deposits of High-Energy Events at the Northwestern Upper Yangtze Region, China

Following the latest Permian mass extinction (LPME), the ocean experienced turbulent conditions due to elevated temperatures during the Griesbachian (Early Triassic). These adverse conditions resulted in a prolonged delay in biotic recovery. However, the current understanding of the sedimentological responses of the ocean at that time to these adverse conditions remains incomplete. The Griesbachian harsh ocean conditions led to the formation of abnormal carbonate rocks (known as anachronistic facies) all around the world. These facies were influenced by a combination of environmental conditions, biotic factors, and actualistic sedimentological processes (e.g., waves and currents, sedimentation). However, the role of actualistic sedimentological processes in forming anachronistic facies during the Griesbachian has been underemphasized in the existing studies. In this research, we examine calcirudite beds, such as flat-pebble conglomerates, from Member 1 of the Feixianguan Formation across multiple sections, including Shangsi, Yudongzi, Dagouli, and Jianfeng in the Upper Yangtze Region. Our analysis is grounded in field investigations, thin-section observations, and the study of triggering mechanisms and formation processes. We identified and described five calcirudite beds (S1–S5) in the Shangsi section, two beds (D1–D2) in the Dagouli section, one at Jianfeng (J1), and one (Y1) in the Yudongzi section. Bed S1 features matrix-supported flat pebbles with a normal grading, interpreted as the result of a debris flow mass-transport process. Beds S2, S3, D1, and J1 contain large mud rip-up clasts, ooids, and bioclasts, suggesting a potential link with tsunami backwash. Beds S4, D2, and Y1 display hummocky cross-stratification and ‘chrysanthemum-shaped’ flat pebbles, indicating storm influence. The presence of vermicular limestones in Bed S5 suggests harsh marine environmental conditions. Collectively, this evidence suggests that high-energy oceanic conditions, including tsunamis and frequent storms, potentially influenced Early Triassic biotic recovery.

Late Permian to early Middle Triassic palaeoenvironmental reconstructions of the High Atlas, Morocco: Geodynamic and climate implications in the intertropical western Peri-Tethyan domain

This study characterizes the depositional environment and climate evolution from the late Permian to the early Middle Triassic, based on detailed sedimentological and palaeosol analysis. Sequence stratigraphy and palaeoenvironmental reconstructions were used to define the Permian-Triassic (P-T) evolution of the High Atlas basins as well as to make a comparison with European basins.The late Permian in Morocco is dominated by distal fluvial fan environment, under arid to semi-arid paleoclimate conditions. Above the P-T unconformity (BS1), the Lower Triassic deposits, record a similar climate evolution from arid to subhumid conditions. In the Argana Basin, the Early Triassic starts by an aeolian deflation lag, followed by stacked debris flow lobes and sheetflood ephemeral alluvial fan deposits, showing immature to locally mature calcretes. The Marrakech High Atlas basins are further characterized by well-developed aeolian dunes in alluvial fan environment. These arid environments evolve through time from proximal to distal deposits, as a retrogradational trend, until well-developed floodplain or lacustrine deposits under semi-arid to subhumid climate (maximum flooding surface, MFS). From MFS, the evolution from distal to proximal environments, testified the progradational trend which is capped by a newly defined angular unconformity (BS2). Above this tectonically induced BS2, the sedimentary section, dated as Anisian is characterized by palaeoenvironments that include meandering river fluvial packages deposited in a semi-arid floodplain.Basin configuration, border fault direction, palaeoenvironments and palaeocurrents recorded in the Argana Basin confirm an independent system, separate from the Marrakech High Atlas (MHA) area during the Triassic. Above BS1, remnant topographies resulted in discrete catchment and discrete drainage systems are evidenced by palaeocurrent and palaeowind measurements controlled by border faults. Palaeoenvironment reconstructions show that the MHA was made up of numerous independent basins during the Early Triassic and the remnant topographies are progressively infilled until BS2. After the BS2, the palaeo-drainage became axial and basins were probably connected in the MHA. Above the P-T unconformity, a common climate evolution is observed in Morocco during the Lower Triassic until BS2, which could correspond to the European Hardegsen unconformity. The sedimentation record shows a similar change in climate and geodynamics to that recorded from both Europe and Morocco.

Cadmium isotopic evidence for reduced deep-water marine primary productivity during the end-Permian mass extinction

Marine primary productivity is a key control on the stability of marine ecosystems. Decreasing marine primary productivity might have led to the end-Permian mass extinction, although this is debated. However, the changes in primary productivity at different seawater depths during the end-Permian mass extinction remain poorly constrained. We investigated the Cd isotopic systematics of shallow-water (Dajiang) and deep-water (Shangsi) sedimentary sections in South China. Combined with previously published data from an intermediate–deep-water section (Meishan), we were able to reconstruct the depth changes in marine primary productivity. In the Dajiang section, prior to the mass extinction, the Cd isotopic compositions of seawater (δ114/110CdSW) varied from +0.73‰ to +0.92‰, with an average of +0.83‰±0.13‰ (2SD; n=11). During and after the mass extinction, δ114/110CdSW varied from +0.73‰ to +0.91‰, with an average of +0.81‰±0.12‰ (2SD; n=12). In the Shangsi and Meishan sections, prior to the mass extinction, δ114/110CdSW varied from +0.47‰ to +0.85‰, with an average of +0.66‰±0.16‰ (2SD; n=35). During and after the mass extinction, δ114/110CdSW varied from −0.19‰ to +0.36‰, with an average of −0.02‰±0.27‰ (2SD; n=27). During the end-Permian mass extinction, the marine primary productivity recorded by Cd isotopes in the relatively deep-water sections was considerably reduced, which may have caused the destruction of relatively deep-water marine ecosystems. We suggest that upward expansion of sulfidic and anoxic deep water, possibly due to the volcanic eruption of the Siberian Traps large igneous province, was one of the causes of the decrease in marine primary productivity. However, the marine primary productivity did not change in the shallow-water section during the end-Permian mass extinction, although changes in the types of marine primary producers are evident from the fossil record. This change in the types of primary producers may have contributed to the mass extinction in shallow-water platform environments. Vertical variations in the changes in primary productivity indicate that the environmental factors leading to the extinction event mainly began in deep waters during the end-Permian mass extinction.

The first record of Permo-Triassic palynomorphs and palynological change across the Triassic-Jurassic transition in the onshore Ruvu Basin, Tanzania

The Ruvu Basin in northeastern coastal Tanzania is one of the least studied basins in the country. It likely contains a record of the pre-and post-breakup sequences of the Gondwana supercontinent. In this study, the first comprehensive palynological investigation on drill-cuttings samples from the Makarawe-1 well in the Ruvu Basin was conducted. In the lower section of this well, four distinct palynologic intervals are recorded: Aratrisporites spp.-Klausipollenites schaubergeri interval (Upper Permian); Reduviasporonites spp. interval (Permo-Triassic transition); Extinction Interval (Permo-Triassic extinction) and Alisporites-Falcisporites Interval (Upper Triassic). This implies that the Ruvu Basin heralds a succession across the Permian-Triassic boundary and its associated extinction. We also record substantial palynological change across the transition to the upper portion of the Makarawe-1 well, where marine dinoflagellate cysts and abundant Classopollis pollen dominate the assemblage. Based on the ranges of dinoflagellate cysts supplemented by pollen-spore ranges, two main palynological intervals (the Classopollis-Nannoceratopsis interval and the Wanaea clathrata interval) are here established. These intervals are of late Middle Jurassic and Late Jurassic (Bajocian - Kimmeridgian) age. This suggests possible correlations with the Lugoba, Msata, Msolwa, Magindu and Malivundo formations of the Ruvu Basin. The findings presented herein suggest a downhole extension of the Wanaea clathrata interval (Oxfordian-Kimmeridgian) sensu [Msaky 2007] to 1215–1235 m. In addition, the Nannoceratopsis-dominated assemblage is indicative of an Early Jurassic association that developed during immediate post-break-up phase, with low-salinities and basinal restriction. With similarity to the Ngerengere dinocyst assemblage reported in previous studies, these results further suggest that the Ngerengere beds are not a so-called Karoo equivalent, but rather a syn- or post-breakup sequence. The recorded intervals are highly similar to other palynostratigraphic units of Africa, Australia, Europe and South America. The data collected in this study add important insights for the general stratigraphic framework within this poorly constrained coastal basin, while also providing a perspective on more distant correlations using palynology.

Pre-Mesozoic sediments of the Tunguska sedimentary basin complicated by the products of intrusive trap magmatism: Hydrocarbon potential, development issues and their solutions

The sedimentary basin examined in this paper is the largest of the three main basins of the Siberian Platform: the Tunguska (S > 1.2 million km2), the Irkutsk (S = 825 thousand km2) and the Pre-Verkhoyansk-Vilyui (according to various estimates, from 280 to 350 thousand km2). Meanwhile, in the Tunguska sedimentary basin area (as of 01.01.2023), only seven hydrocarbon fields have been discovered (quite insignificant in terms of reserves), which is a fairly modest result in comparison to the other two above-mentioned sedimentary basins (much smaller in area) and cannot be explained by the fact that the Tunguska sedimentary basin is poorly studied in terms of oil and gas geology prospecting criteria. Despite the considerable amount of information on the geological structure of the Tunguska sedimentary basin obtained during geological surveying, prospecting and thematic works; special studies devoted to detailed structural and facies analysis and the history of formation of the Permian–Triassic intrusive stratum, all of the above is clearly insufficient. The correlation of the northern and southern types of sections of this stratum is also insufficiently developed, considering the role of facies substitution of the tuffs from the southern part of the Tunguska sedimentary basin by the lavas of its northern territories. Regional studies concerning the identification of magmatic activity centers and determination of the main types of natural mechanisms that initiated the global process of trap magmatism are insufficiently presented. The appearance in recent years of the new data on the little- studied areas of the Putorana Plateau in the north of the sedimentary basin made it possible to create a more comprehensive picture and begin to study the history of the formation of the volcanic strata of the entire sedimentary basin. Thus, despite the relatively poor geological study of the Tunguska sedimentary basin and the presence of traps (reservoir and transgressive intrusions) in the section, the oil and gas prospects of this sedimentary basin can be assessed rather optimistically. Most of the predicted and potential hydrocarbon resources are associated with the Vendian–Lower Cambrian and Riphean complexes.

The Nature of the Puchezh-Katunki Impact Structure (the Central Part of the East European Platform): Results of the U‒Th‒Pb Isotope System Study of Detrital Zircons from Explosive Breccias

The Puchezh-Katunki crater is located in the central part of the East European Platform in the area of the Gorky Reservoir, has a diameter of ~80 km and is morphologically expressed by the central uplift of the basement (Vorotilov knoll) and the ring depression surrounding it, on the periphery of which there is a ring terrace. The crater is filled with various coptogenic (explosive (?)) formations – breccias of various types, bodies of suvites and tagamites. The results of studying the U‒Th‒Pb isotopic system of detrital zircon grains from variegated explosive Puchezh breccias in the northwestern part of the ring terrace (three samples) are presented. The weighted average of the three youngest U‒Pb datings of detrital zircon from all studied samples is 258 ± 7 Ma, which corresponds to the Late Permian. We took this dating as the lower age limit of the Puchezh breccias. A comparison of the age sets of detrital zircon grains from the samples studied by us and from (i) crystalline rocks of the Vorotilov knoll and ring depression suvites and (ii) Upper Permian–Lower Triassic sandstones of the Zhukov ravine reference section (Moscow syneclise) was carried out. The absence among the detrital zircon from the Puchezh breccia grains, whose U‒Th‒Pb isotopic system is comparable with the parameters of zircon from the rocks of the Vorotilov knoll and suvites, indicates the local nature of the Puchezh-Katunki explosion, in which the impact-thermal impact did not affect the detrital zircons in rocks of the marginal part of the annular terrace of the crater. The high similarity of the sets of ages of detrital zircon grains from the lens of redeposited sandstones of the Puchezh breccias and Upper Permian rocks of the Zhukov ravine section indicates that the Puchezh breccias were formed mainly due to the recycling of the Upper Permian–Lower Triassic sequences underlying the explosive formations. We consider the Uralides paleoorogen as the main source for the deposits of the central regions of the East European Platform in the stratigraphic interval close to the Permian–Triassic boundary. The deposits were formed as a result of a high degree of mixing and averaging of clastic material of sedimentary flows containing the Uralian and Asha provenance signals.

Comment on "Dying in the Sun: Direct evidence for elevated UV-B radiation at the end-Permian mass extinction".

Liu etal. present evidence of increased abundance of UV-B-absorbing compounds in fossilized sporomorphs at the end-Permian mass extinction based on Fourier transform infrared (FTIR) spectroscopy. Their approach assumes that UV-B-absorbing compounds are present in the fossilized sporomorphs spanning the extinction interval and that they can be quantified using FTIR. However, further analysis reveals that the signal that they aim to focus on is weak and poorly resolved against nonrandom background interference most likely associated with water vapor. We also show that the peak detection methods that they use are inappropriate for use on these fossil sporomorphs because their methods select only 3.9% of the spectra at the target waveband of interest. The reconstruction that they present is based on baseline variations in the spectra and cannot be confidently attributed to variations in UV-B-absorbing compounds. "Direct" evidence for UV-B radiation at the end-Permian mass extinction cannot be claimed to have been observed in this record.

Response to Comment on "Dying in the Sun: Direct evidence for elevated UV-B radiation at the end-Permian mass extinction".

Seddon and Zimmermann have raised questions about the evidence for increased UV-B flux across the end-Permian mass extinction (EPME) that was presented in our recent study, specifically regarding the measurement of UV-B-absorbing compound (UAC) levels in fossil pollen. We respond to these points, arguing that the comparison of FTIR spectra of >250 million-year-old Permian fossil pollen with ~700-year-old subfossil pollen is not valid and that negligible nonrandom interference derived from water vapor fluctuations during data generation cannot coincidentally produce a substantial UAC peak during the EPME. Furthermore, we refute the suggestion that the measured aromatic peak at 1600 cm-1 could have been influenced by diagenetic products from other organic constituents of pollen. The most productive route forward will be to generate sporomorph geochemical data from additional Permian-Triassic boundary sections to test the results put forward in our study.

Stepwise deforestation during the Permian-Triassic boundary crisis linked to rising temperatures

Although the trajectory of the marine mass extinction at the ∼252-Ma Permian-Triassic (P-Tr) boundary has been well studied, details of the coeval collapse of terrestrial ecosystems remain murky. Here, we use hydrocarbon biomarker compositions and other geological records (i.e., organic carbon isotopes (δ13Corg), charcoal abundance, and Hg content) from a tropical peatland succession in southwestern China to reconstruct in detail the history of terrestrial ecosystem collapse during the P-Tr crisis. Our high-resolution hydrocarbon biomarker records reveal that this collapse proceeded in a stepwise manner with increasing intensity as the crisis unfolded. We recognize three discrete crisis stages: Stage I within the uppermost Xuanwei Formation and Stages II and III within the lowermost Kayitou Formation. Stage I, the early crisis stage, is marked by a significant decline in terrestrial biomass (continuing into the later stages), as recorded by reduced C29 steranes relative to total steranes and a concomitant reduction in the ratio of pristane to phytane (Pr/Ph). Stage II, the main crisis stage, records intensified soil erosion and sediment flux as revealed by rising dibenzofuran (DBF) content and high hopane/sterane ratios, the disappearance of coal seams, a sharp negative shift in δ13Corg, and peak concentrations of charcoal reflecting increased wildfire incidence. Stage III, the late crisis stage characterized by enhanced soil erosion, corresponds to peak values of Hg and Hg/TOC but no charcoal peak, suggesting intensified volcanism and a return to a humid climate. These stages closely follow temperature records, which show a stepwise rise during the crisis interval, implying that the deforestation process was strongly influenced by punctuated rises in temperature and/or its attendant effects (e.g., climate aridification). This P-Tr transition scenario suggests that global warming can trigger deforestation and reduce terrestrial carbon storage, thus serving as a positive climate feedback, with important implications for present-day climate change.

The Early–Middle Triassic Supervolcano in the Yangtze Block, South China and associated obstacles to biotic recovery

The end–Permian mass extinction was one of the major global crises spanning the entire Early Triassic or longer. Eruptions of volcanos were one of the factors that delayed the biotic recovery after this event. Supervolcano eruptions can cause catastrophic effects on global environment, climate, and life. Here we investigate the tuff layers from Early–Middle Triassic boundary in the Yangtze Block and identify a supervolcano eruption event. The zircon U–Pb ages of the section–Langdai, section–Daijiagou and section–Longmendong tuff samples are 247.1 ± 1.9 Ma, 247.6 ± 2.0 Ma and 247.7 ± 1.7 Ma, respectively. These ages mark the Olenekian–Anisian boundary. The zircon grains from the tuff layers have negative εHf(t) (−15.3 to −0.8), two–stage Hf model (TDM2) ages (1.7 to 2.2 Ga) and display high–δ18O values (mostly > 10‰). Clay minerals and quartz dominate the rock composition. The whole rock compositions show that the tuff layers were derived from magma of intermediate to felsic composition, which formed by the remelting of Paleoproterozoic materials of continental crust. The volcanic eruption site is located in the Jinshajiang–Ailaoshan–Song Ma suture zone in the southwestern margin of the Yangtze Block. A combination of the closure of the Paleo–Tethys Ocean Basin and the collision of the Indochina Block and South China contributed to the eruption, which was a supervolcano eruption under the active continental margin arc settings. We speculate that this supervolcano eruption might have contributed to the delayed biotic recovery after the end–Permian mass extinction.

Prolonged and gradual recovery of metazoan-algal reefs following the end-Permian mass extinction

The tempo of biotic recovery following extinction reflects the time scales of evolutionary processes and the long-term consequences of degraded ecosystems, but recovery patterns are poorly resolved. In this study, we investigated the tempo of biotic recovery by evaluating metazoan-algal reef assembly following the end-Permian mass extinction. We combined satellite imagery analysis, field mapping, biostratigraphy, and quantitative petrography to assess recovery in the oldest-known and most stratigraphically extensive Lower to Middle Triassic platform-margin reef. The reef occurs in upper Spathian (upper Lower Triassic) to upper Anisian (lower Middle Triassic) strata of the Great Bank of Guizhou (GBG) isolated carbonate platform in south China. Previous work suggests that metazoan-algal reefs were absent for 8−10 m.y. following extinction but were biologically diverse from their Pelsonian (middle Anisian) initiation. This pattern implies that reefs can reassemble rapidly (<< 1 m.y.) when environmental conditions are favorable. In contrast, our analyses indicate that calcareous sponges, calcareous algae, and early scleractinian corals occurred progressively in the GBG reef and that biotic recovery metrics increased gradually. Unlike nonreef ecosystems, biodiverse metazoan-algal reefs were delayed until the late Pelsonian or early Illyrian, postdating broader marine ecosystem recovery and isotopic evidence for carbon-cycle stabilization by 2−4 m.y. Our findings suggest that reef and nonreef ecosystems differ in their recovery pattern and tempo. Reef recovery from severe environmental perturbation can require several million years, even after hospitable conditions return, highlighting the importance of modern reef conservation.

An armoured marine reptile from the Early Triassic of South China and its phylogenetic and evolutionary implications.

Sauropterygia was a taxonomically and ecomorphologically diverse clade of Mesozoic marine reptiles spanning the Early Triassic to the Late Cretaceous. Sauropterygians are traditionally divided into two groups representing two markedly different body plans - the short-necked, durophagous Placodontia and the long-necked Eosauropterygia - whereas Saurosphargidae, a small clade of armoured marine reptiles, is generally considered as the sauropterygian sister-group. However, the early evolutionary history of sauropterygians and their phylogenetic relationships with other groups within Diapsida are still incompletely understood. Here, we report a new saurosphargid from the Early Triassic (Olenekian) of South China - Prosaurosphargis yingzishanensis gen. et sp. nov. - representing the earliest known occurrence of the clade. An updated phylogenetic analysis focussing on the interrelationships among diapsid reptiles recovers saurosphargids as nested within sauropterygians, forming a clade with eosauropterygians to the exclusion of placodonts. Furthermore, a clade comprising Eusaurosphargis and Palatodonta is recovered as the sauropterygian sister-group within Sauropterygomorpha tax. nov. The phylogenetic position of several Early and Middle Triassic sauropterygians of previously uncertain phylogenetic affinity, such as Atopodentatus, Hanosaurus, Majiashanosaurus, and Corosaurus, is also clarified, elucidating the early evolutionary assembly of the sauropterygian body plan. Finally, our phylogenetic analysis supports the placement of Testudines and Archosauromorpha within Archelosauria, a result strongly corroborated by molecular data, but only recently recovered in a phylogenetic analysis using a morphology-only dataset. Our study provides evidence for the rapid diversification of sauropterygians in the aftermath of the Permo-Triassic mass extinction event and emphasises the importance of broad taxonomic sampling in reconstructing phylogenetic relationships among extinct taxa.

Zirconium and neodymium isotopes record intensive felsic volcanism in South China region during the Permian-Triassic boundary crisis

The Permian-Triassic mass extinction (PTME), the largest biocrisis in Earth's history, is regarded as having been triggered by volcanism, although the source and nature of this volcanic activity in the South China region remains in debate. In this regard, determining the geochemical composition of the volcanic and terrestrial source fluxes to marine depositional systems is crucial for differentiating material derived from the Siberian Traps Large Igneous Province versus regional volcanic arcs. Here, we report zirconium (Zr) isotopic compositions (δ94/90Zr) of Permian-Triassic boundary strata from a deep carbonate-ramp setting at Xiakou, South China, providing new insights regarding the provenance of volcanic ash layers and their host silicic mudstones. The δ94/90Zr composition of magmatically sourced materials is generally controlled by degree of melt crystallization and has the potential to discriminate between primitive and evolved igneous sources. At Xiakou, the pre-PTME Lower Unit contains volcanic ash layers with δ94/90Zr (+0.05 ± 0.03‰, 2SD) similar to that of upper continental crustal (UCC), recording dominantly detrital zircon sources. About 10 kyr before the mass extinction, a single ash layer (Bed 249) records a transient excursion to mantle-like values (∼0‰), followed by a protracted shift across the Permian-Triassic boundary (PTB) toward signatures characteristic of more evolved felsic sources (+0.19 ± 0.12‰) accompanied by a positive shift in Nd isotopes (εNd(t)). The high δ94/90Zr of volcanic ash layers from the Middle Unit (corresponding approximately to the interval between the PTME and PTB) indicates dominance of regional felsic volcanic sources. In this interval, volcanic ash δ94/90Zr values at Xiakou are distinctly higher than those at Meishan, suggesting that primary volcanic signatures are better preserved in deep-water facies (Xiakou) than in shallow-water facies (Meishan). In the Middle (excluding the Bed 249) and Upper (post-PTME) units, positive covariation of δ94/90Zr with Al2O3/TiO2, Zr/TiO2 and Zr/Sc ratios was the product of mixing of detrital and volcanic materials, with the latter having a dominantly felsic source. This study provides new insight into the sources of zircons in PTB sections of South China, and it demonstrates the general utility of sedimentary Zr isotopic compositions in determining magmatic provenance.

Subduction–Accretion History of the Paleo-Pacific Plate Beneath the Eurasian Continent: Evidence from the Tongjiang Accretionary Complex, NE China

Detrital zircons in the matrix of an accretionary complex play an important role in providing evidence to reconstruct oceanic plate subduction and accretion processes. The Nadanhada accretionary complex (NAC) dominated by the Yuejinshan, Raohe and Tongjiang accretionary complexes provides significant geological evidence to better understand the Paleo-Pacific subduction–accretion process. Most previous studies have focused on the Yuejinshan and Raohe accretionary complexes, while those of the Tongjiang accretionary complex on the north side have focused on blocks. In this study, we present zircon U–Pb dating and Hf isotopic data for the matrix of metasedimentary rock in the Tongjiang accretionary complex. The analysis results show that the zircons in the fine silty mudstone, phyllonite and fine argillaceous siltstone define the youngest weighted mean ages (youngest detrital zircon ages) of 261.4 ± 2.9 Ma (247 Ma), 175.2 ± 4.9 Ma (169 Ma) and 168.6 ± 2.1 Ma (162 Ma), respectively, and yield a younging trend of the accretion materials from west to east. Provenance analysis indicates that the matrix was mainly sourced from the neighboring Jiamusi and Xingkai blocks. Based on previous results of the Permian and Late Triassic blocks in the Yuejinshan region, the Permian and Early Jurassic blocks in the Tongjiang region, and the Late Triassic and Early–Middle Jurassic blocks in the Raohe region, as well as the lower limit of the depositional age of the Late Triassic matrix in the Yuejinshan region and the Middle Jurassic and Early Cretaceous matrices in the Raohe region, we propose that the NAC may record the Late Permian–Triassic, Jurassic and Early Cretaceous oceanic accretion events, representing the westward subduction and accretion process of the Paleo–Pacific Ocean Plate.

Calcium isotopes reveal shelf acidification on southern Neotethyan margin during the Smithian-Spathian boundary cooling event

The Smithian-Spathian transition of the late Early Triassic was a critical period of environmental and biological upheavals, following the end-Permian mass extinction. Changes in carbonate deposition during this period have been attributed to intensified upwelling along shelf margins, but relevant studies are scarce. Here, we present calcium isotopes of bulk marine carbonate (δ44/40Cacarb) from a Smithian–Spathian boundary (SSB) succession (Guryul Ravine section, Kashmir) on the southern margin of the Neo-Tethys. Our smoothed δ44/40Cacarb curve reveals a ∼ 0.2‰ negative shift (from ∼ − 1.1‰ to ∼ − 1.3‰) across the SSB, concurrent with a ∼ +10‰ shift in δ13Ccarb. While increased Ca isotopic fractionation could play a role, we specifically examine potential impacts due to changes in marine Ca fluxes. Using a Ca-cycle mass balance model, we explore scenarios of decreased carbonate burial flux (Fcarb), decreased riverine flux (Friv), and a combination of these processes. The modeling suggest that a pulse decrease in Fcarb by 40% over ∼0.06 Myr match the negative shift in δ44/40Cacarb at Guryul Ravine. We infer that this decrease was likely related to intensified upwelling of acidic deep seawater due to invigorated global-oceanic circulation during the SSB cooling event. We suggest that the regionally diverse excursions in δ44/40Cacarb in the Tethyan region could be attributed to spatially varied upwellings in the shelf margin. The upwelling of acidic and anoxic deep seawater may have driven the second-order extinction of ammonoids and conodonts at the beginning of the SSB cooling event.

Middle Triassic (Muschelkalk) transgression in the West Tethys: biostratigraphic evidence from Sardinia (Italy)

Stratigraphic and palaeontological analyses of the Middle Triassic (latest Anisian–Ladinian) in Muschelkalk facies are performed here to further unravel the palaeogeographic evolution of Sardinia in this time-frame. These shallow marine successions reveal a significant palaeontological record comprising facies and marker fossils (ammonoids, bivalves, conodonts, foraminifera etc.) reflecting a regional transgressive episode recorded throughout the West Mediterranean, after the Permian–Triassic biotic crisis. Particularly rich in the Nurra and Sarcidano-Gerrei areas, the facies/fossil record indicates the progressive westward settling of carbonate platforms, and consequently the development of new migration and irradiation routes for Sephardic faunas from the southeast (Palaeotethys) and Alpine faunas (Neotethys) from the northeast. Based on new findings and the revision of palaeontological associations previously reported, comparisons were made with associations of adjacent domains (Balearic Islands, Levantine area), thus refining their palaeoecological distribution and better framing Sardinia as a key area in the palaeogeographic evolution of the West Tethys during the Ladinian.

The tetrapod fauna of the upper Permian Naobaogou Formation of China: 10. Jimusaria monanensis sp. nov. (Dicynodontia) shows a unique epipterygoid.

Jimusaria is the first reported Chinese dicynodont, previously only known from Xinjiang. Here we refer two specimens from the Naobaogou Formation, Nei Mongol, China to Jimusaria based on the following features: squamosal separated from supraoccipital by tabular, tabular contacting opisthotic, sharp and thin lateral dentary shelf expanding anteriorly into a thick swelling, nasals fused as single element, rod-like medial bar formed by footplate of epipterygoid connecting to the parabasisphenoid and periotic medially. A new species, J. monanensis, is named based on the diagnostic characters on these two specimens such as distinct caniniform buttress lacking posteroventral furrow, naso-frontal suture forming an anterior directed sharp angle, and converging ventral ridges on posterior portion of anterior pterygoid rami. In Jimusaria, the epipterygoid posteromedially contacts the parabasisphenoid and the periotic as a rod-like bar, a unique morphology unknown in any other dicynodonts. This structure probably increases the stability of the palatal complex. A similar structure might also appear in other dicynodonts as a cartilage connection. The new occurrence of Jimusaria increases the diversity of the tetrapod assemblage from the Naobaogou Formation, and further strengthens the connection between the tetrapod faunas from Nei Mongol and Xinjiang. Based on the current record, Jimusaria is one of the few tetrapod genera which survived in the end-Permian mass extinction.