Emission Traces Research Articles

ALMA RESULTS OF THE PSEUDODISK, ROTATING DISK, AND JET IN THE CONTINUUM AND HCO+IN THE PROTOSTELLAR SYSTEM HH 212

HH 212 is a nearby (400 pc) Class 0 protostellar system showing several components that can be compared with theoretical models of core collapse. We have mapped it in 350 GHz continuum and HCO+ J=4-3 emission with ALMA at up to ~ 0.4" resolution. A flattened envelope and a compact disk are seen in continuum around the central source, as seen before. The HCO+ kinematics shows that the flattened envelope is infalling with small rotation (i.e., spiraling) into the central source, and thus can be identified as a pseudodisk in the models of magnetized core collapse. Also, the HCO+ kinematics shows that the disk is rotating and can be rotationally supported. In addition, to account for the missing HCO+ emission at low-redshifted velocity, an extended infalling envelope is required, with its material flowing roughly parallel to the jet axis toward the pseudodisk. This is expected if it is magnetized with an hourglass B-field morphology. We have modeled the continuum and HCO+ emission of the flattened envelope and disk simultaneously. We find that a jump in density is required across the interface between the pseudodisk and the disk. A jet is seen in HCO+ extending out to ~ 500 AU away from the central source, with the peaks upstream of those seen before in SiO. The broad velocity range and high HCO+ abundance indicate that the HCO+ emission traces internal shocks in the jet.

A resolved analysis of cold dust and gas in the nearby edge-on spiral NGC 891

We investigate the connection between dust and gas in the nearby edge-on spiral galaxy NGC 891. High resolution Herschel PACS and SPIRE 70, 100, 160, 250, 350, and 500 $\mu$m images are combined with JCMT SCUBA 850 $\mu$m observations to trace the far-infrared/submillimetre spectral energy distribution (SED). Maps of the HI 21 cm line and CO(J=3-2) emission trace the atomic and molecular hydrogen gas, respectively. We fit one-component modified blackbody models to the integrated SED, finding a global dust mass of 8.5$\times$10$^{7}$ M$_{\odot}$ and an average temperature of 23$\pm$2 K. We also fit the pixel-by-pixel SEDs to produce maps of the dust mass and temperature. The dust mass distribution correlates with the total stellar population as traced by the 3.6 $\mu$m emission. The derived dust temperature, which ranges from approximately 17 to 24 K, is found to correlate with the 24 $\mu$m emission. Allowing the dust emissivity index to vary, we find an average value of $\beta$ = 1.9$\pm$0.3. We confirm an inverse relation between the dust emissivity spectral index and dust temperature, but do not observe any variation of this relationship with vertical height from the mid-plane of the disk. A comparison of the dust properties with the gaseous components of the ISM reveals strong spatial correlations between the surface mass densities of dust and the molecular hydrogen and total gas surface densities. Observed asymmetries in the dust temperature, and the H$_{2}$-to-dust and total gas-to-dust ratios hint that an enhancement in the star formation rate may be the result of larger quantities of molecular gas available to fuel star formation in the NE compared to the SW. Whilst the asymmetry likely arises from dust obscuration due to the geometry of the line-of-sight projection of the spiral arms, we cannot exclude an enhancement in the star formation rate in the NE side of the disk.

An experimental investigation of the scratch behaviour of polymers – 2: Influence of hard or soft fillers

Variation in the scratch behaviour of polymers with incorporation of different types and amounts of fillers was investigated both in terms of scratch visibility and scratch hardness. Scratch tests were carried out by a microscratch tester. The effect of fillers on the scratch deformation mode and hence on scratch visibility was evaluated by examining recorded penetration depth and acoustic emission traces together with optical microscope images of the groove left on the surface. Scratch hardness was determined by using a recently proposed scratch model. Adequacy of the model to interpret the local phenomenon induced by addition of fillers was questioned.It was demonstrated that incorporation of hard fillers can enhance the scratch hardness of polymers as well as their basic mechanical properties but leads to an increase in scratch visibility due to a change in scratch deformation mode from ductile ploughing to a brittle failure with crack formation. On the contrary, addition of soft fillers causes a reduction in scratch hardness but it also reduces scratch visibility since it improves the recovery characteristics of the polymer.

Manipulating fluorescence characteristics of conjugated fluorescent molecules incorporated into three-dimensional poly(methyl methacrylate) opal photonic crystals

We compare the fluorescence characteristics of conjugated molecules (coumarin 6, C-6) in solution, aggregation state, and poly(methyl methacrylate) PMMA opal photonic crystals (PCs), and investigate the manipulation mechanism of PCs on C-6. We find that the PCs effectively inhibit the aggregate-induced fluorescence quenching of C-6 by breaking the intermolecular interaction and manipulate the fluorescence characteristics of C-6 by changing the photonic stop band (PSB). The emission traces of C-6 have been analyzed using the continuous rate distribution model. The control of fluorescence characteristics of C-6 in PCs depends on the mesh microporous structure and the PSB of PCs.

THE CURIOUS MORPHOLOGY AND ORIENTATION OF ORION PROPLYD HST-10

HST-10 is one of the largest proplyds in the Orion Nebula and is located approximately 1' SE of the Trapezium. Unlike other proplyds in Orion, however, the long-axis of HST-10 does not align with theta 1 C Ori, but is instead aligned with the rotational axis of the HST-10 disk. This cannot be easily explained using current photo-evaporation models. In this letter, we present high spatial resolution near-infrared images of the Orion proplyd HST-10 using Keck/NIRC2 with the Laser Guide Star Adaptive Optics system, along with multi-epoch analysis of HH objects near HST-10 using Hubble Space Telescope WFPC2 and ACS cameras. Our narrow-band near-IR images resolve the proplyd ionization front (IF) and circumstellar disk down to 23 AU at the distance to Orion in Br gamma, He I, H_2, and PAH emission. Br gamma and He I emission primarily trace the IF (with the disk showing prominently in silhouette), while the H_2 and PAH emission trace the surface of the disk itself. PAH emission also traces small dust grains within the proplyd envelope which is asymmetric and does not coincide with the IF. The curious morphology of the PAH emission may be due to UV-heating by both theta 1C Ori and theta 2A Ori. Multi-epoch HST images of the HST-10 field show proper motion of 3 knots associated with HH 517, clearly indicating that HST-10 has a jet. We postulate that the orientation of HST-10 is determined by the combined ram-pressure of this jet and the FUV-powered photo-ablation flow from the disk surface.

Distant activity of Comet C/2002 VQ94 (LINEAR): Optical spectrophotometric monitoring between 8.4 and 16.8 au from the Sun

Spectrophotometric monitoring of distant Comet C/2002 VQ94 (LINEAR) was performed with the 6-m telescope of SAO RAS (Special Astrophysical Observatory of Russian Academy of Sciences) and with the 2.5-m Nordic Optical Telescope (Observatory del Roque de los Muchachos, Canarias, Spain) between 2008 and 2013. During this period the comet was on the outbound segment of its orbit, between heliocentric distances of 8.36au and 16.84au. Analysis of the spectra revealed the presence of the CO+ and N2+ emissions in the cometary coma at a distance of 8.36au from the Sun. This distance is larger than ionic emissions have been detected in any previous objects. Only continuum, with no traces of emissions, was detected in the spectrum obtained in 2009 when the comet was at a distance of 9.86au. From the spectra obtained in 2008, average column densities of 2.04×109molcm−2 for N2+ and 3.26×1010molcm−2 for CO+ were measured in the cometary coma. The derived values correspond to N2+/CO+=0.06 within the projected slit. Images obtained through a red continuum filter in 2008 showed a bright, dust coma, indicating a high level of physical activity. A considerably lower level of activity was observed in 2009 and 2011 at distances of 9.86au and 13.40au respectively. No noticeable activity was detected in 2013 at a heliocentric distance of 16.84au. The Afρ parameter, which is used as an indicator of cometary activity, was measured as 2000cm in 2008, and 800cm in 2009 and 2011. The Afρ values correspond to dust production rates between 10–20kgs−1, 4–6kgs−1 and 3–5kgs−1 at 8.36, 9.86, and 13.40au respectively. There is an obvious correlation between the decrease of the dust production rate of the nucleus and the disappearance of the emissions in the spectrum of C/2002 VQ94 (LINEAR) at heliocentric distances greater than 9au. The colors and size of the nucleus of C/2002 VQ94 (LINEAR) were estimated from the images obtained during the late stage at a heliocentric distance of 16.84au, when the activity had probable ceased. The B–V and V–R colors were estimated to be 1.07±0.05 and 0.54±0.03 respectively. The effective nucleus radius of 48±2km is in agreement with the previously published results, obtained from the observations of the comet during its early inactive stage (Jewitt, D. [2005]. Astron. J. 129, 530–538; Weiler, M., Rauer, H., Sterken, C. [2011]. Icarus 212, 351–366).

Evidence of environmental dependencies of Type Ia supernovae from the Nearby Supernova Factory indicated by local Hα

(Abridged) We study the host galaxy regions in close proximity to Type Ia supernovae (SNe Ia) to analyze relations between the properties of SN Ia events and environments most similar to where their progenitors formed. We focus on local H\alpha\ emission as an indicator of young environments. The Nearby Supernova Factory has obtained flux-calibrated spectral timeseries for SNe Ia using integral field spectroscopy, allowing the simultaneous measurement of the SN and its immediate vicinity. For 89 SNe Ia we measure H\alpha\ emission tracing ongoing star formation within a 1 kpc radius around each SN. This constitutes the first direct study of the local environment for a large sample of SNe Ia also having accurate luminosity, color and stretch measurements. We find that SNe Ia with local H\alpha\ emission are redder by 0.036+/-0.017 mag, and that the previously-noted correlation between stretch and host mass is entirely driven by the SNe Ia coming from passive regions. Most importantly, the mean standardized brightness for SNe Ia with local H\alpha\ emission is 0.094+/-0.031 mag fainter than for those without. This offset arises from a bimodal structure in the Hubble residuals, that also explains the previously-known host-mass bias. We combine this bimodality with the cosmic star-formation rate to predict changes with redshift in the mean SN Ia brightness and the host-mass bias. This change is confirmed using high-redshift SNe Ia from the literature. These environmental dependences point to remaining systematic errors in SNe Ia standardization. The observed brightness offset is predicted to cause a significant bias in measurements of the dark energy equation of state. Recognition of these effects offers new opportunities to improve SNe Ia as cosmological probes - e.g. SNe Ia having local H\alpha\ emission are more homogeneous, having a brightness dispersion of 0.105+/-0.012 mag.

Stellar clusters in the inner Galaxy and their correlation with cold dust emission

Stars are born within dense clumps of giant molecular clouds, constituting young stellar agglomerates known as embedded clusters, which only evolve into bound open clusters under special conditions. We statistically study all embedded clusters (ECs) and open clusters (OCs) known so far in the inner Galaxy, investigating particularly their interaction with the surrounding molecular environment and the differences in their evolution. We first compiled a merged list of 3904 clusters from optical and infrared clusters catalogs in the literature, including 75 new (mostly embedded) clusters discovered by us in the GLIMPSE survey. From this list, 695 clusters are within the Galactic range |l| < 60 deg and |b| < 1.5 deg covered by the ATLASGAL survey, which was used to search for correlations with submm dust continuum emission tracing dense molecular gas. We defined an evolutionary sequence of five morphological types: deeply embedded cluster (EC1), partially embedded cluster (EC2), emerging open cluster (OC0), OC still associated with a submm clump in the vicinity (OC1), and OC without correlation with ATLASGAL emission (OC2). Together with this process, we performed a thorough literature survey of these 695 clusters, compiling a considerable number of physical and observational properties in a catalog that is publicly available. We found that an OC defined observationally as OC0, OC1, or OC2 and confirmed as a real cluster is equivalent to the physical concept of OC (a bound exposed cluster) for ages in excess of ~16 Myr. Some observed OCs younger than this limit can actually be unbound associations. We found that our OC and EC samples are roughly complete up to ~1 kpc and ~1.8 kpc from the Sun, respectively, beyond which the completeness decays exponentially. Using available age estimates for a few ECs, we derived an upper limit of 3 Myr for the duration of the embedded phase... (Abridged)

PHYSICAL PROPERTIES OF LUMINOUS DUST-POOR QUASARS

We identify and characterize a population of luminous dust poor quasars at 0<z<5, similar in photometric properties to the objects found at z>6 previously. This class of active galactic nuclei has been known to show little IR emission from a dusty structure, but is yet poorly understood in terms of number evolution or of dependence on physical quantities. In order to better understand the luminous dust poor quasar properties, we compiled a rest-frame UV to IR library of 41,000 optically selected type-1 quasars with $L_{bol}>10^{45.7} erg s^{-1}$. After fitting the broad-band spectral energy distributions (SEDs) with accretion disk and dust components, we find 0.6% of our sample to be hot dust poor with a rest-frame 2.3 micron to 0.51 micron flux density ratio of -0.5 dex or less. The dust poor SEDs are blue in the UV-optical and weak in the MIR, such that their accretion disks are less obscured, and that hot dust emission traces that of warm dust down to the dust poor regime. At a given bolometric luminosity, dust poor quasars are lower in black hole mass and higher in Eddington ratio than general luminous quasars, suggesting that they are in a rapidly growing evolutionary state in which the dust poor phase appears as a short or rare phenomenon. The dust poor fraction increases with redshift, and possible implications for the evolution of the dust poor fraction are discussed.

NEAR-INFRARED H 2 AND CONTINUUM SURVEY OF EXTENDED GREEN OBJECTS. II. COMPLETE CENSUS FOR THE NORTHERN GALACTIC PLANE

We discuss 94 Extended Green Objects (EGOs) in the northern Galactic plane cataloged by Cyganowski et al, based on near-infrared narrowband H2 (2.122 {\mu}m and continuum observations from the United Kingdom Infrared Telescope. This data set is three times larger than our previous study, and is unbiased by preselection. As discussed in the previous paper, the morphologies of the 4.5 {\mu}m emission generally resemble those of the near-infrared continuum, but are different from those of the H2 emission. Of our sample, only 28% of EGOs with H2 emission show similar morphologies between 4.5 {\mu}m and H2 emission. These results suggest that the 4.5 {\mu}m emission mainly comes from scattered continuum from the embedded young stellar object (YSO), and partially from H2 emission. About half of EGOs are associated with H2 outflows, if the H2 outflow incompleteness is considered. The H2 outflow detection rate for EGOs with K-band detections (61%) is significantly higher than for those without K-band detections (36%). This difference may be due to the fact that both H2 and K-band emissions are associated with outflows, i.e., H2 emission and K-band continuum are associated with shocks and outflow cavities, respectively. We also compared the correlation between the H2 outflows and Class I 44 GHz methanol masers from literature. The methanol masers can be located upstream or downstream of the H2 outflows and some bright H2 spots or outflows are not associated with methanol masers, suggesting that methanol masers and H2 emission trace different excitation conditions.

Use of In-Situ Optical Emission Spectroscopy for Leak Fault Detection and Classification in Plasma Etching

In-situ optical emission spectroscopy (OES) is employed for leak detection in plasma etching system. A misprocessing is reported for significantly reduced silicon etch rate with chlorine gas, and OES is used as a supplementary sensor to analyze the gas phase species that reside in the process chamber. Potential cause of misprocessing reaches to chamber O-ring wear out, MFC leaks, and/or leak at gas delivery line, and experiments are performed to funnel down the potential of the cause. While monitoring the plasma chemistry of the process chamber using OES, the emission trace for nitrogen species is observed at the chlorine gas supply. No trace of nitrogen species is found in other than chlorine gas supply, and we found that the amount of chlorine gas is slightly fluctuating. We successfully found the root cause of the reported misprocessing which may jeopardize the quality of thin film processing. Based on a quantitative analysis of the amount of nitrogen observed in the chamber, we conclude that the source of the leak is the fitting of the chlorine mass flow controller with the amount of around 2-5 sccm.

Herschel–PACS observations of shocked gas associated with the jets of L1448 and L1157

In the framework of the WISH key program, several H2O (E_u>190 K), high-J CO, [OI], and OH transitions are mapped with PACS in two shock positions along the two prototypical low-luminosity outflows L1448 and L1157. Previous HIFI H2O observations (E_u=53-249 K) and complementary Spitzer mid-IR H2 data are also used, with the aim of deriving a complete picture of the excitation conditions. At all selected spots a close spatial association between H2O, mid-IR H2, and high-J CO emission is found, whereas the low-J CO emission traces either entrained ambient gas or a remnant of an older shock. The excitation analysis at L1448-B2 suggests that a two-component model is needed to reproduce the H2O, CO, and mid-IR H2 lines: an extended warm component (T~450 K) is traced by the H2O emission with E_u =53-137 K and by the CO lines up to J=22-21, and a compact hot component (T=1100 K) is traced by the H2O emission with E_u>190 K and by the higher-J CO lines. At L1448-B2 we obtain an H2O abundance (3-4)x10^{-6} for the warm component and (0.3-1.3)x10^{-5} for the hot component; we also detect OH and blue-shifted [OI] emission, spatially coincident with the other molecular lines and with [FeII] emission. This suggests a dissociative shock for these species, related to the embedded atomic jet. On the other hand, a non-dissociative shock at the point of impact of the jet on the cloud is responsible for the H2O and CO emission. The other examined shock positions show an H2O excitation similar to L1448-B2, but a slightly higher H2O abundance (a factor of 4). The two gas components may represent a gas stratification in the post-shock region. The extended and low-abundance warm component traces the post-shocked gas that has already cooled down to a few hundred Kelvin, whereas the compact and possibly higher-abundance hot component is associated with the gas that is currently undergoing a shock episode.

HST/WFC3 imaging of protostellar jets in Carina: [Fe II] emission tracing massive jets from intermediate-mass protostars

We present narrowband WFC3-UVIS and -IR images of four externally irradiated protostellar jets in the Carina nebula: HH666, HH901, HH902, and HH1066. These massive jets are unusual because they are bathed in UV radiation from dozens of nearby O stars, but despite the strong incident ionizing radiation, portions of the jet remain neutral. Near-IR [Fe II] images reveal dense, neutral gas that was not seen in previous studies of H-alpha emission. We show that near-IR [Fe II] emitting gas must be self-shielded from Lyman continuum photons, regardless of its excitation mechanism (shocks, FUV radiation, or both). High densities are required for the survival of Fe+ amid the strong Lyman continuum from Tr14, raising estimates of the mass-loss rates by an order of magnitude. Higher jet mass-loss rates require higher accretion rates onto their driving protostars, implying that these jets are driven by intermediate-mass (IM; ~2-8 Msun) stars. Indeed, the IR driving sources of two of these outflows have luminosities that require IM protostars. All four of these HH jets are highly collimated, with opening angles of only a few degrees, similar to those observed in low-mass protostars. We propose that these jets reflect essentially the same outflow phenomenon seen in wide-angle molecular outflows associated with IM and high-mass protostars, but that the collimated atomic jet core is irradiated and rendered observable in Carina's harsh radiative environment. In more quiescent environments, this atomic core remains invisible, and outflows traced by shock-excited molecules in the outflow cavity give the impression that these outflows have a wider opening angle. Thus, the externally irradiated jets in Carina constitute a new view of collimated jets from IM protostars, and offer strong additional evidence that stars up to at least ~8 Msun form by the same accretion mechanisms as low-mass stars.

Radiative efficiency, variability and Bondi accretion on to massive black holes: the transition from radio AGN to quasars in brightest cluster galaxies

We examine unresolved nuclear X-ray sources in 57 brightest cluster galaxies to study the relationship between nuclear X-ray emission and accretion onto supermassive black holes (SMBHs). The majority of the clusters in our sample have prominent X-ray cavities embedded in the surrounding hot atmospheres, which we use to estimate mean jet power and average accretion rate onto the SMBHs over the past several hundred Myr. We find that ~50% of the sample have detectable nuclear X-ray emission. The nuclear X-ray luminosity is correlated with average accretion rate determined using X-ray cavities, which is consistent with the hypothesis that nuclear X-ray emission traces ongoing accretion. The results imply that jets in systems that have experienced recent AGN outbursts, in the last ~10^7yr, are `on' at least half of the time. Nuclear X-ray sources become more luminous with respect to the mechanical jet power as the mean accretion rate rises. We show that nuclear radiation exceeds the jet power when the mean accretion rate rises above a few percent of the Eddington rate, where the AGN apparently transitions to a quasar. The nuclear X-ray emission from three objects (A2052, Hydra A, M84) varies by factors of 2-10 on timescales of 6 months to 10 years. If variability at this level is a common phenomenon, it can account for much of the scatter in the relationship between mean accretion rate and nuclear X-ray luminosity. We find no significant change in the spectral energy distribution as a function of luminosity in the variable objects. The relationship between accretion and nuclear X-ray luminosity is consistent with emission from either a jet, an ADAF, or a combination of the two, although other origins are possible. We also consider the longstanding problem of whether jets are powered by the accretion of cold circumnuclear gas or nearly spherical inflows of hot keV gas.[abridged]

Approach to identifying pollutant source and matching flow field

Accidental pollution events often threaten people's health and lives, and it is necessary to identify a pollutant source rapidly so that prompt actions can be taken to prevent the spread of pollution. But this identification process is one of the difficulties in the inverse problem areas. This paper carries out some studies on this issue. An approach using single sensor information with noise was developed to identify a sudden continuous emission trace pollutant source in a steady velocity field. This approach first compares the characteristic distance of the measured concentration sequence to the multiple hypothetical measured concentration sequences at the sensor position, which are obtained based on a source-three-parameter multiple hypotheses. Then we realize the source identification by globally searching the optimal values with the objective function of the maximum location probability. Considering the large amount of computation load resulting from this global searching, a local fine-mesh source search method based on priori coarse-mesh location probabilities is further used to improve the efficiency of identification. Studies have shown that the flow field has a very important influence on the source identification. Therefore, we also discuss the impact of non-matching flow fields with estimation deviation on identification. Based on this analysis, a method for matching accurate flow field is presented to improve the accuracy of identification. In order to verify the practical application of the above method, an experimental system simulating a sudden pollution process in a steady flow field was set up and some experiments were conducted when the diffusion coefficient was known. The studies showed that the three parameters (position, emission strength and initial emission time) of the pollutant source in the experiment can be estimated by using the method for matching flow field and source identification.

Evaluation of spatially explicit emission scenario of land-use change and biomass burning using a process-based biogeochemical model

Using a socioeconomic scenario of representative concentration scenarios, terrestrial emissions from biomass burning and anthropogenic land-use change for the twenty-first century are evaluated in a spatially explicit manner using a biogeochemical model. The model is validated with the historical net land-use change CO2 emission and biomass-burning trace gas emission: net land-use change CO2 emission for 1990s to be from 1.03 to 1.53 Pg C year−1 and black carbon emission from biomass burning during 1997–2000 to be 3.1 Tg BC year−1. For future emissions, uncertainty due to CO2 concentration and land-use change scenario is examined using sensitivity experiments and reveals significant effect of CO2 on the biomass-burning emissions in terms of direct effect of vegetation mass and the indirect feedback through the fire ignition probability. It also reveals the importance of CO2 fertilization on net land-use change CO2 emission through the regrowing absorption in abandoned agricultural land.

Crystal growth, structure, optical and scintillation properties of Ce3+-doped Tb2.2Lu0.8Al5O12 single crystals

Single crystals of undoped and 0.5 at.% Ce3+-doped Tb2.2Lu0.8Al5O12 (LuTbAG) with dimensions of up to ∅25 × 30 mm3 have been successfully grown by the Czochralski pulling method. After the single-phase was confirmed using X-ray diffraction analysis, the absorption coefficient of the undoped LuTbAG was investigated. By using the results of Rietveld refinement and electron probe micro-analysis, the site occupations in undoped and Ce-doped LuTbAG crystals were indirectly revealed. The optical and scintillation characteristics of Ce3+-doped LuTbAG crystals were investigated in detail. In the transmittance spectra, Ce3+-doped crystals showed not only absorption bands at around 340 and 459 nm which are ascribed to the transition from the 4f ground state to the 5d excited state of Ce3+, but also the typical 4f–4f absorption of Tb3+. Under X-ray and UV excitation, strong emission peaks at 530 nm and 565 nm because of the Ce3+ 5d–4f transition and the line emission traces of 4f–4f transitions featuring Tb3+ were both observed for the Ce3+ doped crystal. The scintillation efficiency of the LuTbAG:Ce crystal under X-ray excitation was about two times larger than that of a BGO commercial crystal measured under the same conditions. Pulsed X-ray luminescence measurements showed two exponential decay components of 1.8 μs and 161 μs. These initial results make the LuTbAG:Ce crystal an attractive and promising scintillator for X-ray detection. In addition, the point defects in the undoped and Ce-doped LuTbAG crystals were investigated by a wavelength-resolved thermoluminescence technique.

Mercury stable isotope fractionation in six utility boilers of two large coal-fired power plants

Coal-fired utility boiler (CFUB) emissions of mercury (Hg) represent the largest anthropogenic Hg source to the atmosphere. Hg stable isotope signatures in coal have been shown to vary among coal deposits and coal basins. There is therefore a substantial interest in tracing CFUB Hg emissions at local, regional and global scales. However, CFUB operating conditions, Hg capture technologies and post-emission Hg transformations may potentially alter the original feed coal Hg isotope signatures. Here we investigate Hg isotopic fractionation between feed coal and coal combustion products in six utility boilers of two large power plants in Huainan City, Anhui Province, China. We observe identical trends in all six boilers: relative to feed coal with δ202Hg ranging from −0.67 to −0.18‰, oxidized Hg species in bottom ash and fly ash are enriched in the lighter isotopes with δ202Hg from −1.96 to −0.82‰. Flue gas desulphurization by-product gypsum shows δ202Hg from −0.99 to −0.47‰. No mass independent fractionation was observed during the transport and transformation of Hg inside the boilers. An isotope mass balance suggests that gaseous stack Hg emissions are enriched by up to 0.3‰ in the heavier Hg isotopes relative to feed coal and that the enrichment depends on the Hg capture technology. The observation that oxidized Hg species are enriched in the lighter isotopes suggests that oxidized and reduced forms of Hg in stack emission carry different isotope signatures. This has implications for near-field and far-field Hg emission tracing.

VLT-SINFONI integral field spectroscopy of low-zluminous and ultraluminous infrared galaxies

We present an atlas of a sample of local (U)LIRGs covering the luminosity range log(L_IR/L_sun)=11.1-12.4. The atlas is based on near-infrared H and K-band VLT-SINFONI IFS, and presents the ionised, partially ionised, and warm molecular gas 2D flux distributions and kinematics over a FoV of 3x3 kpc (LIRGs) and 12x12kpc (ULIRGs) and with average linear resolutions of 0.2kpc and 0.9kpc, respectively. The different phases of the gas show a wide morphological variety with the nucleus as the brightest Br_g source for 33% of the LIRGs and 71% of the ULIRGs, whereas all the (U)LIRGs have their maximum H_2 emission in their nuclear regions. In LIRGs, the ionised gas distribution is dominated by the emission from the star-forming rings or giant HII regions in the spiral arms. The Br_g and [FeII] line at 1.644 micron trace the same structures, although the emission peaks at different locations in some of the objects, and the [FeII] seems to be more extended and diffuse. The ULIRG subsample contains mainly pre-coalescence interacting systems. Although the peaks of the molecular gas emission and the continuum coincide in 71% of the ULIRGs, regions with intense Pa_a (Br_g) emission tracing luminous star-forming regions located at distances of 2-4kpc away from the nucleus are also detected, usually associated with secondary nuclei or tidal tails. The gas kinematics in LIRGs are primarily due to rotational motions around the centre of the galaxy, although local deviations associated with radial flows and/or regions of higher velocity dispersions are present. The ionised and molecular gas share the same kinematics to first order, showing slight differences in the velocity amplitudes in some cases, whereas the average velocity dispersions are compatible within uncertainties. As expected, the kinematics of the ULIRG subsample is more complex, owing to the interacting nature of the objects of the sample.

THECHANDRAX-RAY SURVEY OF PLANETARY NEBULAE (CHANPLANS): PROBING BINARITY, MAGNETIC FIELDS, AND WIND COLLISIONS

We present an overview of the initial results from the Chandra Planetary Nebula Survey (ChanPlaNS), the first systematic (volume-limited) Chandra X-ray Observatory survey of planetary nebulae (PNe) in the solar neighborhood. The first phase of ChanPlaNS targeted 21 mostly high-excitation PNe within ~1.5 kpc of Earth, yielding 4 detections of diffuse X-ray emission and 9 detections of X-ray-luminous point sources at the central stars (CSPNe) of these objects. Combining these results with those obtained from Chandra archival data for all (14) other PNe within ~1.5 kpc that have been observed to date, we find an overall X-ray detection rate of ~70%. Roughly 50% of the PNe observed by Chandra harbor X-ray-luminous CSPNe, while soft, diffuse X-ray emission tracing shocks formed by energetic wind collisions is detected in ~30%; five objects display both diffuse and point-like emission components. The presence of X-ray sources appears correlated with PN density structure, in that molecule-poor, elliptical nebulae are more likely to display X-ray emission (either point-like or diffuse) than molecule-rich, bipolar or Ring-like nebulae. All but one of the X-ray point sources detected at CSPNe display X-ray spectra that are harder than expected from hot (~100 kK) central star photospheres, possibly indicating a high frequency of binary companions to CSPNe. Other potential explanations include self-shocking winds or PN mass fallback. Most PNe detected as diffuse X-ray sources are elliptical nebulae that display a nested shell/halo structure and bright ansae; the diffuse X-ray emission regions are confined within inner, sharp-rimmed shells. All sample PNe that display diffuse X-ray emission have inner shell dynamical ages <~5x10^3 yr, placing firm constraints on the timescale for strong shocks due to wind interactions in PNe.